Instituto Politcnico Nacional

Escuela superior de ingeniera qumica e industrias extrctivas

DIQI

Laboratorio de Termodinmica del equilibrio Qumico

Practica: EQUILIBRIO QUMICO SIMULTNEO

Alumno: Segura Ceuleneer Diego

Gpo: 2IM41

Tabla de datos experimentales

Muestra
NaOH en ml
fase acuosa en
ml

1
10.5
2

2
8.5
1.9

3
6.5
1.5

4
3
1.2

Determinacin de las concentraciones

del cido benzoico

C cido=

VgastadocNaOH
V (alicuota)

C cido1=
C cido2=
C cido3=
C cido 4=
C cido5=

2 ml0.015 N
=0.007125 N
4 ml
1.9 ml0.015 N
=0.00633 N
4.5 ml
1.5 ml0.015 N
=0.00450 N
5 ml
1.2 ml0.015 N
=0.005142 N
3.5 ml
0.9 ml0.015 N
=0.003850 N
3.5 ml

Determinamos el grado de avance

K=

2
=6.3 x 105
Cacuoso

2
K 1=
=0.00063922
0.007125
K 2=

2
=0.00060078
0.00633
2

K 3=
=0.00050188
0.0045
2

K 4=

=0.00053853
0.005142

2
K 5=
=0.000462
0.00385

5
2.7
0.9

Determinacin de las concentraciones

de la fase orgnica

Corg nico=

VgastadocNaOH
V (alicuota)

Corg nica 1=

10.5 ml0.015 N
=0.035 N
4.5 ml

Corg nica 2=

8.5 ml0.015 N
=0.03187 N
4 ml

Corg nica 3=

6.5 ml0.015 N
=0.01625 N
6 ml

Corg nica 4=

3 ml0.015 N
=0.01 N
4.5 ml

Corg nica 5=

2.7 ml0.015 N
=0.068 N
6 ml

Determinamos los valores de (Y ,X)

Y=

Corg nica
C cido(1 )

X =C cido(1 )

Y 1=

0.035 N
=4.6697
0.007125 N ( 10.00063922 )

X 1=0.007125 ( 10.00063922) =0.0075

Y 2=

0.03187 N
=5.0359
0.00633 N ( 10.00060078 )

X 2=0.00633 ( 10.00060078 )=0.0063

Y 3=

0.01625 N
=3.6129
0.0045 N ( 10.00050188 )

X 3=0.0045 ( 10.00050188 )=0.0045

Y 4=

0.01 N
=1.9455
0.005142 N ( 10.0053853 )

X 4=0.00541 ( 10.00053853 ) =0.0051

Y 5=

0.068 N
=1.7508
0.00385 N ( 10.00462 )

X 1=0.00385 ( 10.000462) =0.0039

Concentraciones
f(x) = 820.92x - 1.08
R = 0.61

De la grfica determinamos:
Y= -1.0793+820.92x
Km=b
M=2KdKm2
Kd=m/2km2

Tabla de resultados

Km=-1.0793

1.043 2

Kd=
820.92

Sistema

Concentraci
on acuosa
(N)
0.00712

Concentraci
on orgnica
(N)
0.0350

0.00633

0.0318

0.00450

0.0162

0.00514

0.0100

0.00385

0.0068

Avance

0.0006392
2
0.0006007
8
0.0005018
8
0.0005385
3
0.000462

4.6697

0.0075

5.0359

0.0063

3.6129

0.0045

1.9455

0.0051

1.7508

0.0039