Instituto Politcnico Nacional

Escuela superior de ingeniera qumica e industrias extrctivas

DIQI

Laboratorio de Termodinmica del equilibrio Qumico

Practica: EQUILIBRIO QUMICO INICO

Alumno: Segura Ceuleneer Diego

Gpo: 2IM41

EQUILIBRIO QUMICO INICO

TABLA DE RESULTADOS
#M

max

[Fe 3+]i

[SCN-1]i

SCN i

A
X=

CALCULOS DE LA CONCENTRACIN DEL FIERRO

1
2
3
4
5
6
7
8
9
10

459

0.131 0.0076
0.00096 136.448
2
9
2
(0
.
2
M
)(ml
de
Fe
(
NO
3 ) 3)
459
0.138 0.0148
0.00092 149.083
[Fe 3+]=
ml de
0
1 soluci n 6
459
0.152 0.0214
0.00089 170.352
1 (0.2 M )(0.1 ml de Fe3( NO 3 ) 3)
459
0.0275
0.00086 =0.00769
194.01
[Fe
3+]1= 0.167
( 2.5+0.1 ) ml de soluci n
2
8
2
459
0.186 0.0333
0.00083 224.172
(0.2 M )(0.5
8 ml de Fe3( NO 3 ) 3) 3
=0.0333 262.037
) ml de soluci
n
459( 2.5+ 0.50.211
0.0387
0.00080
3
1
6
459
0.235 0.0437
0.00078 301.466
(0.2 M )(0.2 ml de Fe ( NO 3 ) 3)
5
5
1
[Fe 3+]2=
=0.01481
(
2.5+0.2
)
ml
de
soluci
n
459
0.269 0.0484
0.00075
355.74
5
8
8
(0.2 M )(0.6
ml de Fe0.0529
( NO 3 ) 3) 0.00073 426.754
459
0.313
=0.03871
( 2.5+ 0.67) ml de soluci
4 n
5
459
0.369 0.0571
0.00071 517.88
9
4
4

(0.2 M )(0.3 ml de Fe ( NO 3 ) 3)
[Fe 3+]3=
=0.0214
( 2.5+ 0.3 ) ml de soluci n

Fe 3+ i
SCN i

A
Y=

[FeSCN2
+]i

17738.2

0.1225

10063.1

0.1292

7999.76

0.1358

7032.86

0.1419
[Fe 3+]5=

6725.16

0.1476

6769.28

0.1529

6890.64

0.1579

7337.14

[Fe 3+]6=
0.1626

8060.92

0.1671

9063.09

0.1712
[Fe 3+]7=

(0.2 M )(0.7 ml de Fe ( NO 3 ) 3)
=0.04375
( 2.5+0.7 ) ml de soluci n

[Fe 3+]4=

(0.2 M )(0.4 ml de Fe ( NO 3 ) 3)
=0.02758
( 2.5+ 0.4 ) ml de soluci n

[Fe 3+]8=

(0.2 M )(0.8 ml de Fe ( NO 3 ) 3)
=0.04848
( 2.5+0.8 ) ml de soluci n
[Fe 3+]9=

(0.2 M )(0.9 ml de Fe ( NO 3 ) 3)
=0.05241
( 2.5+0.9 ) ml de soluci n
[Fe 3+]10=

(0.2 M )(1 ml de Fe ( NO 3 ) 3)
=0.0571
( 2.5+1 ) ml de soluci n

CALCULOS DE LA CONCENTRACIN DE
TIOSIANATO
[SCN3+]I=

[SCN3+]1=

(0 . 001 M )(ml de KSCN )

=
ml de soluci n
(0.001 M )(2.5 ml de KSCN )
(2.5+0.1) ml de soluci n =0.00

(0.001 M )(2.5 ml de KSCN )

[SCN3+]5= (2.5+0.1) ml de soluci n
=0.00
0833
[SCN3+]6=
0806

0962
[SCN3+]2=

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.00

[SCN3+]7=

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.00

0893

(0.001 M )(2.5 ml de KSCN )

[SCN3+]4= (2.5+0.1) ml de soluci n
=0.00

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.00

0781

0926
[SCN3+]3=

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.00

[SCN3+]8=

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.00

0758

(0.001 M )(2.5 ml de KSCN )

[SCN3+]9= (2.5+0.1) ml de soluci n
=0.00
0735

0862
[SCN3+]10=

(0.001 M )(2.5 ml de KSCN )

(2.5+0.1) ml de soluci n =0.0

0071

CLCULOS DE LOS VALORES DE X

SCN i

A
X=

X 5=

459
=224.172
[0.000833]i

X 1=

459
=136.448
[0.000962] i

X 6=

459
=262.037
[0.000806]i

X 2=

459
=149.083
[0.000926]i

X 7=

459
=301.466
[0.000781]i

X 3=

459
=170.353
[0.000893] i

X 8=

459
=355.74
[0.000758]i

X 4=

459
=194.01
[0.000862]i

X 9=

459
=426.754
[0.000735]i

X 10=

459
=517.88
[0.000714 ]i

CLCULOS DE LOS VALORES DE Y

Fe 3+ i
SCN i

A
Y=

Y 5=

459
=6725.16
[0.033]i [0.00083]i

459
Y 1=
=17738.2
[0.000962]i [0.00769]i

Y 6=

459
=6769.28
[0.03871]i[0.000806]i

459
Y 2=
=10063.1
[0.000926]i[0.01481]i

Y 7=

459
=6890.64
[0.04375]i [0.000781]i

Y 8=

459
=7337.14
[0.04848]i[0.000758]i

Y 9=

459
=8060.92
[0.052941]i [0.000735]i

Y 3=

Y 4=

459
=7999.76
[0.0214 ]i [0.000893]i

459
=7032.86
[0.02758]i [0.000862] i

Y 10=

459
=9063.09
[0.0571]i[0.000714 ] i

POR MEDIO DE UNA REGRESIN LINEAL SE DETRMINA EL VALOR DE K

K=- 23.1279 donde k=-m
Y= b+ mx

Determinacion del valor de

k=

(nFe )(nSCN ) ,

[FeSCN2+]i

=0.1225

=0.1529

=0.1292

=0.1579

=0.1358

=0.1626

=0.1419

=0.1671

=0.1476

=0.1712

Determinacion del grado de conversin

n FeSCN
conversi n=
100=
n FeSCN
1.- 0.1225

6.- 0.1529

2.- 0.1292

7.- 0.1579

3.- 0.1358

8.- 0.1626

4.- 0.1419

9.- 0.1671

5.- 0.1476

10.- 0.1712