Instituto Politcnico Nacional

Escuela superior de ingeniera qumica e industrias extrctivas

DIQI

Laboratorio de Termodinmica del equilibrio Qumico

Practica: EQUILIBRIO QUMICO HOMOGNEO EN FASE GAS

Alumno: Segura Ceuleneer Diego

Gpo: 2IM41

Tabla de datos
Temperatura

Presin aire

30
40
50
60

0.5
0.7
0.8
0.83

Presin del cido

actico
0.7
1.1
2.2
3.5

Determinacion de la presin absoluta de los sistemas

Pabs=PatmPaire

Pabs=PatmP cido

Pabs1=585 mmHg5 mmHg=580

Pabs1=585 mmHg7 mmHg=578

Pabs 2=585 mmHg7 mmHg=578

Pabs 2=585 mmHg11 mmHg=574

Pabs 3=585 mmHg8 mmHg=577

Pabs 3=585 mmHg22 mmHg=563

Pabs 4=585 mmHg8.33 mmHg=576.7

Pabs 4=585 mmHg35 mmHg=550

Determinacion de P

P=P cido Paire

Determinacion de la masa del

cido actico

m=v

P1=580 mmHg578 mmHg=2 mmHg

P2=578 mmHg574 mmHg=4 mmHg

=1.05

g
3
cm

m=1.05

g
10 c m3=10.5 g
3
cm

v =10 ml=c m 3

P3=577 mmHg563 mmHg=14 mmHg

P 4=576.7 mmHg556 mmHg=20.7 mmHg

Considerando

R=

0.082 atm
molk

Determinacion de

Pi=

RTwA
V

0.01<
0.082 atm
v =10 ml=0.01<
303.15 K0.175 mol =435.02 atm*
molk
P1=
m
10.5 g

n=
=
=0.175 mol
pm
g
60
760mmHg =330615 mmHg
mol
0.01<
0.082 atm
de cido actico
313.15 K0.175 mol =341521mmHg
molk
P2=

0.01<
0.082 atm
323.15 K0.175 mol =352427mmHg
molk
P3=

0.01<
0.082 atm
333.15 K0.175 mol =363333mmHg
molk
P 4=

Determinacion de K

Ka=4 (2 PiP)

K 1=4 (23306152) =2644912

mmHg

Determinacion
de y=InK

InK 1=14.7881

Determinacion de
x=

InK 2=14.8206

K 2=4 ( 23415214 ) =2732152

mmHg

K 3=4(235242714 ) =2819360

1
T

x 1=

InK 3=14.8520

InK 4=14.8825

003299

x 2=

mmHg

K 4=4 (236333320.7) =29065

1
303.15 K =0.
1
313.15 K =0.

003193

1
x 3=
323.15 K =0.

80mmHg

In K =b= 15.836

003095

x 4=

Y=
-317.96x+15.836

1
333.15 K =0.

InK=

003002

H=Rm=317.968.314=2643.52 J mol/k
G=( InKRT ) =

Hdisociaci n=

8.314 J

G 1= -(15.836*
molk

Hdis 1=

303.15K)=-39913 J

8.314 J

G 2= -(15.836*
molk

323.15K)=-42546.3 J

2643.52 J
=1321.76 J
2

mol/k

S=

H
T

S=

1321.76
=44.033 Jmol
30

S=

1321.76
=33.025 Jmol
40

313.15K)=-41229.6 J

8.314 J

G 3= -(15.836*
molk

H
2

H
RT

8.314 J

G 4= -(15.836*
molk
333.15K)= -43862.9 J

S=

1321.76
=26.42 Jmol
50

S=

1321.76
=22.01 Jmol
60