Formulario de Q.A.

III

Celdas electroquímicas S = π r2 ε
Ecel = Ecátodo - Eánodo – IR + ηcátodo + ηánodo p = mS / (mM + mS ) = k / (k + 1)
Potenciometría q = 1 – p = 1 / (k + 1)
Ecelda = Eind – Eref + Ej v = L / tR = u q
Eind = L’ + (0.0592/Za) log(a1 + kA,Bb1Za/Zb) k = mS / mM = KD (VS / VM )
pHu = pHp – (Eu – Ep)/0.0592 k = (tR – tM ) / tM
Voltamperometría N = L/ H
Eapl = E½ - 0.0592/n log(i/il – i) H = A + B/ +C
(id)avg = 607nD½m⅔t⅙C opt = (B/C) ½
Polarografía diferencial de impulsos w = 4σ
ip = nFAD½C/(πtm)½ (1 – σ/1 + σ) N = 16 (tR / w) 2 = 5,5 (tR / w1/2 ) 2
σ = exp[(nF/RT)(ΔE/2)] R = (tR,B – tR,A ) / [(wB + wA) / 2 ]
Ep = E½ - ΔE/2 α = KD,B / KD,A = (tR,B – tM ) /(tR,A – tM )
W½= 3.52 RT/nF R = (N 1/2 / 4) [(α – 1) / α ] [k / (k + 1)]
Extracción líquido-líquido Detección
KP,A = [A]o / [A]a LOD = 3sbl / b
k = mA,o / mA,a = KP,A (Vo / Va ) = KP,A β LDR = log (UL / LOD)
p = R = mA,o / (mA,a + mA,o ) = k / (k + 1 ) GC
q = 1 - R = 1 / (k + 1) log k = ΔH / (2,3 R T) + A
KD,A = cA,o / cA,a = KP,A / ( χo / χa ) HPLC
qn = (1 - R)n = [ 1 / (k + 1) ]n N ~ K L / dp
pn = Rn = 1 - (1 - R)n = 1 - [ 1 / (k + 1) ]n ln k = A - Bφ
Teoria de la cromatografia (δM + δS - 2δ i ) (δM - δS ) ~ 0
KD = CS / CM δ M = Σ φj δ j
φMeOH = 1,29 φACN = 1,63 φTHF
u = L / tM = F / S 0,78 φMeOH = φACN = 1,26 φTHF
0,62 φMeOH = 0,79 φACN = φTHF
F = V / t = VM / tM = VR / tR Δt/ tG < 0,25