Estime la fugacidad del cloroformo liquido a la temperatura de 200°C y 40 bar

Formula
DATOS T 200 °C
problema P 40 bar
TABLA B-1 w 0.222
Tc 536.4 °K
* R 83.1447 cm3_bar/mol°K
Pc 54.72 bar
Zc 0.293
Vc 239 cm3/mol
A 3.96288
B 1106.904
C 218.552
log_10*pvap= 1.318276701
10^x 20.81022141
pres vap Psat 20.81022141 bar
psatr=psat/pc Psat r
B0 -0.432817807
B1 -0.15233
fsat 0.817760208
Fi= fsat*Psat 17.01777098 exp^ Vsat(P-Psat)
18.06768657 RT
Vsat 122.7298972
2/7= 0.285714286
*directo fi 18.06768657 bar
eratura de 200°C y 40 bar

473.15 °K

Tr=T/Tc Tr 0.882084265

0.380303754

2355.159552
39339.91481
 Presión (kPa) V (m3/kg) H (kJ/Kg) S (kJ/Kg*K) f (kPa) f
Estado de Ref 1 28.482 2977.8 9.3 1 1 vsc
P 2000 0.1115 2903.3 6.5475 285.354337 0.14267717 vsc
Psat 3976.2 0.05013 2800.9 6.0722 522.849271 0.13149471 liqcom
Pmax 4200 0.04747 2799.6 6.0198 582.549627 0.13870229 liqcom

T= 250 °C R= 8.314
523.15 K

Tabla A-4 Tabla A-6 VSC @250 °C

Psat @ 250°C= 3976.2 kPa P= 0.01 Mpa P= 0.05 Mpa P=
v= 24.136 v= 4.8206 v=
h= 2977.5 h= 2976.2 h=
s= 9.1015 s= 8.3568 s=

R= 8.31447 P= 3.5 Mpa P= 4 Mpa P=

kPa*m3/kmol*K v= 0.05706 v= 0.04978 v=
h= 2802.7 h= 2800.8 h=
s= 6.1244 s= 6.0696 s=
 Interpolación Lineal Extrapolación Lineal
4000 6.0696 0.050 8.3568
4200 6.04968 0.010 9.1015
4500 6.0198 0.001 9.2690575

2 Mpa
0.1115
2903.3
6.5475

4.5 Mpa
0.044006
2798
6.0198
Calcule la fugacidad del isobutano como gas a 85°C y 13bar T=
Tabla B1
w= 0.181 P=
Tc= 408.1 K
Pc= 36.48 bar
Pc= 3648 kPa
Zc= 0.282 Tr=T/Tc 0.8776
Vc= 262.7 cm3/mol Pr=P/Pc 0.3564
Tn= 261.4 K B0=0.083-(0.422/(Tr)^1.6) -0.4370
B1=0.139-(0.172/(Tr)^4.2) -0.1586

f= 0.8277
f*p=f 10.76 bar
 85 °C
358.15 K
13 bar
1300 kPa
 N-octano liquido a t de punto ebullicionn y 85 bar de
presion
Formula
DATOS T 125.6 °C 398.75
problema P 85 bar
TABLA B-1 w 0.4
Tc 568.7 °K Tr=T/Tc
cm3_bar/
* R 83.1447 mol°K
Pc 24.9 bar
Zc 0.256
Vc 486 cm3/mol
A 4.05075
B 1356.36
C 209.635
log_10*pvap
= 0.00475242
10^x 1.01100294
pres vap Psat 1.01100294 bar
psatr=psat/
pc Psat r 0.04060253
B0 -0.6617397
*como si da T la Tr es con B1 -0.625
esa fsat 0.94857281
*por partes Fi= fsat*Psat 0.95900989 exp^ Vsat(P-Psat) 15552.633
1.53303525 RT 33153.9491
Vsat 185.174649
2/7= 0.28571429
*directo fi 1.53303525 bar
°K

Tr 0.70116054