3358 56 1167 76

3268 51 1103 61
3067 73 1062 52
3039 71 1000 71
2924 4 889 90
2854 11 861 91
1459 32 811 86
1377 52 744 41
1342 63 578 84
1182 71 528 86

C, 71.98; H, 6.71

39.0 7.9 79.0 20.6 104.0 100.0 131.0 36.2

51.0 13.9 89.0 5.8 105.0 14.7 132.0 58.6
63.0 7.8 91.0 31.5 107.0 62.4 133.0 7.3
65.0 11.1 93.0 6.4 115.0 5.1 150.0 30.6
77.0 35.1 102.0 5.7 119.0 13.8
78.0 19.2 103.0 38.2 120.0 6.3

• Scambia con D2O DEPT/BBD

13C, 40 MHz

CH3, CH↓, CH2↑ 76.28

• 77.08
77.88

500 MHz •

140 125.70
130 120 110 100 90 80 70 60 50 40 30
126.50 75.10
127.49 72.17 33.24

136.80
137.63

150 140 130 120 110 100 90 80 70 60 50 40 30 20

Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

M+.
M+. 220

C, 70.89; H, 7.32;

O DEPT/BBD 76.28
13C, 40 MHz 77.08
O 77.88
OH
CH3, CH↓, CH2↑

Scambia
con D2O
500 MHz
134.23 129.04
134.70 118.27 116.67 68.40 31.62 25.35 14.10

167.41 162.37 111.69

1 1 1 1 1 1 1 2 2 2 3 150 100 50 0
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita
C, 77.87; H, 11.76

M+. 154

DEPT/BBD
13C, 40 MHz

OH CH3, CH↓, CH2↑ 76.28

77.08
77.88

500 MHz

27.35
121.30 61.90 32.95 18.40

133.85

130 120 110 100 90 80 70 60 50 40 30 20

Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

Br OH
S
M+ 268

Chemical Formula: C11H9BrOS

Exact Mass: 267,96
Molecular Weight: 269,16
m/z: 269,95 (100,0%), 267,96 (98,2%), 268,96 (12,6%), 270,96 (11,5%), 271,95 (4,3%), 270,95 (1,3%)
Elemental Analysis: C, 49.09; H, 3.37; Br, 29.69; O, 5.94; S, 11.91

C, 49.09; H, 3.37; S, 11.91 …..

40 MHz CDCl3
CH3, CH↓, CH2↑

400 MHz CDCl3

Scambia
125.95
con D2O 132.41 71.26

149.26 145.22 122.91

Corso Metodi Fisici in Chimica 160 155 150 145 140 135 130 125 120 115 110 105 100 95 90 85 80 75 70 65

Organica – Prof. Renzo LUISI –

Uniba. ® vietata la vendita
 C, 63.78; H, 4.51; …….
2926 8 1396 65 1086 63 855 73

2854 21 1373 48 1068 53 840 68

Nujol 1717 45 1308 46 1029 63 804 75

1692 36 1262 69 1011 72 753 63

m/z: 357,08 (M+., 100,0%),
359,07 (32,0%)
1588 74 1234 44 926 65 658 85

1479 48 905 75 483 85

1189 64

1456 35 1148 72

KBr

DEPT/BBD
13C, 40 MHz
500 MHz 76.28
77.08

CDCl3 + D2O CH3, CH↓, CH2↑ 77.88

128.82
130.65

116.97 115.82 103.82 55.91 28.97 13.47

138.80
174.66 168.24 153.04

2 2 1 1 1 3 2 3
150 100 50 0
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

C, 61,66; H, 8,47;

COOEt

COOEt

C11H18O4
Mol. Wt.: 214,2582
C, 61,66; H, 8,47; O, 29,87

M+

76.28
77.08
77.88

600 MHz 40 MHz

CH3, CH↓, CH2↑ 61.18

61.18 22.26
159.24 29.81 14.23

22.26

159.24 29.81 14.23

163.89
165.34 123.12

Corso Metodi Fisici in Chimica 150 100 50 0

Organica – Prof. Renzo LUISI –

Uniba. ® vietata la vendita
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

Ione molecolare
Normalizzato a 100
M+. =236,01 (100,0%), 237,02
(9,9%), 238,01 (4,6%)

C, 45.76; H, 2.99; F, 24.13...???

DEPT/BBD
CH3, CH↑, CH2↓
400 MHz CDCl3
129.66 127.90

140 130 120 110 100 90 80 70

40 MHz CDCl3
132.44
139.93 133.34

141.00

126.22 119.15
112.07

145 140 135 130 125 120 115 110 105 100 95 90 85 80 75
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

C, 66.27; H, 8.34; …..

EI 70 eV
M+ 181

76.28
77.08
77.88

Film

128.14

- 3.180

73.59
77.88 76.28
NH2 127.95 62.52 52.26

400 MHz, CDCl3 O OH

137.09

140 130 120 110 100 90 80 70 60 50

73.59
72.17 62.52

127.95
40 MHz CDCl3 52.26

CH3, CH↓, CH2↑

128.24
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

EI 70 eV

C, 75.45; H, 5.70…..
Film

40 MHz CDCl3
CH3, CH↓, CH2↑
76.28
77.08
77.88
N O

182.80 126.80 117.40 110.30 31.50

123.30 120.80

123.30 120.80
182.80 126.80 117.40 31.50

400 MHz, CDCl3

131.94
135.80

150 100 50
Corso Metodi Fisici in Chimica Organica – Prof. Renzo LUISI – Uniba. ® vietata la vendita

C, 83.13; H, 6.98; N, 4.62

GC-MS, 70eV

M+= 303
FT-IR
HO
KBr, cm-1 HN

1H 400 MHz, CDCl3

13CBBD
125 MHz, CDCl3

SCAMBIA SCAMBIA
CON D2O CON D2O