Estudio Teórico de un ácido débil + base fuerte

Dado que se tiene

HA + OH- ↔ A- + H2O
Con dos ácidos con un pKa de 4.7 y 9.2 respectivamente

H+ HA HA´ 14
pH

0 OH-
4.7 9.2

Tabla de variación de especies para los dos ácidos

HA OH- <--> A- H2O

Inicio Co --- --- ---
Agregado --- XCo --- ---
Reacciona XCo XCo --- ---
Produce --- --- XCo ---
A.P.E Co(1-X) ≈0 XCo ---
P.E ≈0 ≈0 Co ---
D.P.E ≈0 (X-1) Co Co ---

Se cuentan con las siguientes ecuaciones:

Para X= 0  pH = 1/2 pKa – 1/2 log Co
𝑋𝐶𝑜
Para 0 < x < 1  pH = pKa + log 𝐶𝑜(1−𝑋)

Para X=1  pH = 7 + ½ pKa + ½ log Co

Para X > 1  pH = 14 + log [(X-1) Co]

 Para el primer ácido con un pKa= 4.7 la Keq es:

Keq= 109.3 y una Co= 1x10-2

X pH
0 3.199485
0.1 3.7457
0.2 4.0979
0.3 4.332
 0.4 4.5239
0.5 4.7
pH Vs X
0.6 4.876 14

0.7 5.0679 12
0.8 5.302 10
0.9 5.6542
8
1 8.35

pH
1.1 11 6
1.2 11.301 4
1.3 11.4771
2
1.4 11.602
1.5 11.6989 0
0 0.5 1 1.5 2 2.5
1.6 11.7781
X
1.7 11.845
1.8 11.903
1.9 11.9542
2 12

Y también se puede detallar mejor como:

0 3.199485
0.01 2.70436481
0.02 3.00980392
0.03 3.19034952 pH vs X
0.04 3.31978876 14
0.05 3.4212464
12
0.06 3.5050234
0.07 3.57661509 10

0.08 3.63930216 8
pH

0.09 3.69520112 6
0.1 3.74575749
4
0.11 3.79200268
0.12 3.83469857 2
0.13 3.8744241 0
0.14 3.91162958 0 0.5 1 1.5 2 2.5
0.15 3.94667233 X
0.16 3.9798407
0.17 4.01137083
0.18 4.04145865
0.19 4.07026858
0.2 4.09794001
0.21 4.1245922
0.22 4.15032808
0.23 4.17523711
0.24 4.19939765
0.25 4.22287875
0.26 4.24574163
0.27 4.2680409
0.28 4.28982553
0.29 4.31113965
0.3 4.33202321
0.31 4.3525126
0.32 4.37264107
0.33 4.39243914
0.34 4.41193498
0.35 4.43115469
0.36 4.45012253
0.37 4.46886117
0.38 4.48739191
0.39 4.50573477
0.4 4.52390874
0.41 4.54193185
0.42 4.5598213
0.43 4.5775936
0.44 4.59526465
0.45 4.61284982
0.46 4.63036407
0.47 4.64782199
0.48 4.66523789
0.49 4.6826259
0.5 4.7
0.51 4.7173741
0.52 4.73476211
0.53 4.75217801
0.54 4.76963593
0.55 4.78715018
0.56 4.80473535
0.57 4.8224064
0.58 4.8401787
0.59 4.85806815
0.6 4.87609126
0.61 4.89426523
0.62 4.91260809
0.63 4.93113883
0.64 4.94987747
0.65 4.96884531
0.66 4.98806502
0.67 5.00756086
0.68 5.02735893
0.69 5.0474874
0.7 5.06797679
0.71 5.08886035
0.72 5.11017447
0.73 5.1319591
0.74 5.15425837
0.75 5.17712125
0.76 5.20060235
0.77 5.22476289
0.78 5.24967192
0.79 5.2754078
0.8 5.30205999
0.81 5.32973142
0.82 5.35854135
0.83 5.38862917
0.84 5.4201593
0.85 5.45332767
0.86 5.48837042
0.87 5.5255759
0.88 5.56530143
0.89 5.60799732
0.9 5.65424251
0.91 5.70479888
0.92 5.76069784
0.93 5.82338491
0.94 5.8949766
0.95 5.9787536
0.96 6.08021124
0.97 6.20965048
0.98 6.39019608
0.99 6.69563519
1 8.35
1.01 10.30103
1.02 10.60206
1.03 10.7781513
1.04 10.90309
1.05 11
1.06 11.0791812
1.07 11.146128
1.08 11.20412
1.09 11.2552725
1.1 11.30103
1.11 11.3424227
1.12 11.3802112
1.13 11.4149733
1.14 11.447158
1.15 11.4771213
1.16 11.50515
1.17 11.5314789
1.18 11.5563025
1.19 11.5797836
1.2 11.60206
1.21 11.6232493
1.22 11.6434527
1.23 11.6627578
1.24 11.6812412
1.25 11.69897
1.26 11.7160033
1.27 11.7323938
1.28 11.748188
1.29 11.763428
1.3 11.7781513
1.31 11.7923917
1.32 11.80618
1.33 11.8195439
1.34 11.8325089
1.35 11.845098
1.36 11.8573325
1.37 11.8692317
1.38 11.8808136
1.39 11.8920946
1.4 11.90309
1.41 11.9138139
1.42 11.9242793
1.43 11.9344985
1.44 11.9444827
1.45 11.9542425
1.46 11.9637878
1.47 11.9731279
1.48 11.9822712
1.49 11.9912261
1.5 12
1.51 12.0086002
1.52 12.0170333
1.53 12.0253059
1.54 12.0334238
1.55 12.0413927
1.56 12.049218
1.57 12.0569049
1.58 12.064458
1.59 12.071882
1.6 12.0791812
1.61 12.0863598
1.62 12.0934217
1.63 12.1003705
1.64 12.10721
1.65 12.1139434
1.66 12.1205739
1.67 12.1271048
1.68 12.1335389
1.69 12.1398791
1.7 12.146128
1.71 12.1522883
1.72 12.1583625
1.73 12.1643529
1.74 12.1702617
1.75 12.1760913
1.76 12.1818436
1.77 12.1875207
1.78 12.1931246
1.79 12.1986571
1.8 12.20412
 1.81 12.209515
1.82 12.2148438
1.83 12.2201081
1.84 12.2253093
1.85 12.2304489
1.86 12.2355284
1.87 12.2405492
1.88 12.2455127
1.89 12.25042
1.9 12.2552725
1.91 12.2600714
1.92 12.2648178
1.93 12.2695129
1.94 12.2741578
1.95 12.2787536
1.96 12.2833012
1.97 12.2878017
1.98 12.2922561
1.99 12.2966652
2 12.30103

 Para el segundo ácido con un pKa= 9.2 la Keq es:

Keq= 104.8 y una Co= 1x10-2
X pH
0 5.6
0.1 8.2457
pH Vs X
0.2 8.5979
14
0.3 8.832
0.4 9.0239 12
0.5 9.2 10
0.6 9.376
8
0.7 9.5679
pH

0.8 9.502 6

0.9 10.1542 4
1 10.6 2
1.1 11
0
1.2 11.301 0 0.5 1 1.5 2 2.5
1.3 11.4771 X
1.4 11.602
1.5 11.6989
 1.6 11.7781
1.7 11.845
1.8 11.903
1.9 11.9542
2 12

Y también se puede detallar mejor como:

X pH
0 5.6
0.01 7.20436481
0.02 7.50980392
0.03 7.69034952
0.04 7.81978876
0.05 7.9212464
0.06 8.0050234
0.07 8.07661509
0.08 8.13930216
0.09 8.19520112
0.1 8.24575749
0.11 8.29200268
0.12 8.33469857
0.13 8.3744241
0.14 8.41162958
0.15 8.44667233 pH
0.16 8.4798407 14
0.17 8.51137083 12
0.18 8.54145865 10
0.19 8.57026858
8
0.2 8.59794001
pH

6
0.21 8.6245922
4
0.22 8.65032808
0.23 8.67523711 2

0.24 8.69939765 0
0 0.5 1 1.5 2 2.5
0.25 8.72287875
X
0.26 8.74574163
0.27 8.7680409
0.28 8.78982553
0.29 8.81113965
0.3 8.83202321
0.31 8.8525126
0.32 8.87264107
0.33 8.89243914
0.34 8.91193498
0.35 8.93115469
0.36 8.95012253
0.37 8.96886117
0.38 8.98739191
0.39 9.00573477
0.4 9.02390874
0.41 9.04193185
0.42 9.0598213
0.43 9.0775936
0.44 9.09526465
0.45 9.11284982
0.46 9.13036407
0.47 9.14782199
0.48 9.16523789
0.49 9.1826259
0.5 9.2
0.51 9.2173741
0.52 9.23476211
0.53 9.25217801
0.54 9.26963593
0.55 9.28715018
0.56 9.30473535
0.57 9.3224064
0.58 9.3401787
0.59 9.35806815
0.6 9.37609126
0.61 9.39426523
0.62 9.41260809
0.63 9.43113883
0.64 9.44987747
0.65 9.46884531
0.66 9.48806502
0.67 9.50756086
0.68 9.52735893
0.69 9.5474874
0.7 9.56797679
0.71 9.58886035
0.72 9.61017447
0.73 9.6319591
0.74 9.65425837
0.75 9.67712125
0.76 9.70060235
0.77 9.72476289
0.78 9.74967192
0.79 9.7754078
0.8 9.80205999
0.81 9.82973142
0.82 9.85854135
0.83 9.88862917
0.84 9.9201593
0.85 9.95332767
0.86 9.98837042
0.87 10.0255759
0.88 10.0653014
0.89 10.1079973
0.9 10.1542425
0.91 10.2047989
0.92 10.2606978
0.93 10.3233849
0.94 10.3949766
0.95 10.4787536
0.96 10.5802112
0.97 10.7096505
0.98 10.8901961
0.99 11.1956352
1 10.6
1.01 10.30103
1.02 10.60206
1.03 10.7781513
1.04 10.90309
1.05 11
1.06 11.0791812
1.07 11.146128
1.08 11.20412
1.09 11.2552725
1.1 11.30103
1.11 11.3424227
1.12 11.3802112
1.13 11.4149733
1.14 11.447158
1.15 11.4771213
1.16 11.50515
1.17 11.5314789
1.18 11.5563025
1.19 11.5797836
1.2 11.60206
1.21 11.6232493
1.22 11.6434527
1.23 11.6627578
1.24 11.6812412
1.25 11.69897
1.26 11.7160033
1.27 11.7323938
1.28 11.748188
1.29 11.763428
1.3 11.7781513
1.31 11.7923917
1.32 11.80618
1.33 11.8195439
1.34 11.8325089
1.35 11.845098
1.36 11.8573325
1.37 11.8692317
1.38 11.8808136
1.39 11.8920946
1.4 11.90309
1.41 11.9138139
1.42 11.9242793
1.43 11.9344985
1.44 11.9444827
1.45 11.9542425
1.46 11.9637878
1.47 11.9731279
1.48 11.9822712
1.49 11.9912261
1.5 12
1.51 12.0086002
1.52 12.0170333
1.53 12.0253059
1.54 12.0334238
1.55 12.0413927
1.56 12.049218
1.57 12.0569049
1.58 12.064458
1.59 12.071882
1.6 12.0791812
1.61 12.0863598
1.62 12.0934217
1.63 12.1003705
1.64 12.10721
1.65 12.1139434
1.66 12.1205739
1.67 12.1271048
1.68 12.1335389
1.69 12.1398791
1.7 12.146128
1.71 12.1522883
1.72 12.1583625
1.73 12.1643529
1.74 12.1702617
1.75 12.1760913
1.76 12.1818436
1.77 12.1875207
1.78 12.1931246
1.79 12.1986571
1.8 12.20412
1.81 12.209515
1.82 12.2148438
1.83 12.2201081
1.84 12.2253093
1.85 12.2304489
1.86 12.2355284
1.87 12.2405492
1.88 12.2455127
1.89 12.25042
1.9 12.2552725
1.91 12.2600714
1.92 12.2648178
1.93 12.2695129
1.94 12.2741578
1.95 12.2787536
1.96 12.2833012
1.97 12.2878017
1.98 12.2922561
1.99 12.2966652
2 12.30103