[Samame Poper Reference Taal) | 6|2[4|4|/[o]1" Pipe Rete 6244/01 Edexcel GCE Chemistry Advanced Unit Test 4 Tuesday 25 January 2005 — Afternoon Time: 1 hour 30 minutes Materials required for examination _Items included with question papers Examiners use only ‘Team Leader's we only foveioa] wane ber| Bik wl aloele Nir Nil Instructions to Candidates In the boxes above, write your centre number, candidate number, your surname, initial(s) and signature. Answer ALL the questions in the spaces provided in this question paper. You may use a calculator. Show all the steps in any calculations and state the units, Information for Candidates The total mark for this paper is 75. The marks for individual questions and parts of questions are shown in round brackets: e.g. (2). There are 16 pages in this question paper. All blank pages are indicated. A Periodic Table is printed on the back cover of this question paper. Advice to Candidates You are reminded of the importance of clear English and careful presentation in your answers, Tecan as sep wi Soe MUON Total Turn over edexcel :ee Answer ALL the questions in the spaces provided. (a) Define the term lattice energy. (b) A Born—Haber cycle for the formation of lithium chloride is shown below. Li(g) +e°+ Cl(g) Li(g) + Cre) Lit(g) +e"+ 2Ch(g) Li(g) + 3Cl(g) AFan Li(s) + $Cl(g) y Licks) Enthalpy change ‘kJ molt Enthalpy of formation of lithium chloride(s) ~409 Enthalpy of atomisation of lithium +161 Enthalpy of atomisation of chlorine +122 Ist ionisation energy of lithium +519 Electron affinity of chlorine 349 202214 : 2(i) Calculate the lattice energy, AHisn, of lithium chloride. Q) (ii) The enthalpy change AH, is the enthalpy of atomisation of lithium metal. Suggest, and explain, whether you would expect the value of AH, for potassium to be more or less endothermic than that for lithium. @ (©) @ State TWO properties of ions that affect the value for the lattice energy of ionic compounds. @) The calculated value for the lattice energy of potassium chloride is almost exactly the same value as that found experimentally. Why is the theoretical value for the lattice energy of silver chloride, -833kJmol"', so different from the experimentally determined value of 905 kJ mol!? @ eee eee