Centre] ae [Sumame initials) Simaae candidate No 6|2/4)2///0/1 ey Exanine' ee ony 6242/01 Edexcel GCE vane Chemistry Advanced Level/Advanced Subsidiary ‘ uci] Lane Unit Test 2 Ser Ban Friday 16 January 2004 — Morning 1 Time: | hour 2 3 Materials required for examination Items included with question papers Nil Nil 4 5 6 Instructions to Candidates In the boxes above, write your centre number, candidate number, your sumame, initials and your signature Answer ALL the questions in the spaces provided in this question paper. Show all the steps in any calculations and state the units. ‘You may use a calculator. Information for Candidates ‘The total mark for this paper is 60. The marks for individual questions and parts of questions are shown in round brackets: e.g. (2). A Periodic Table is printed on the back cover of this question paper. Advice to Candidates You are reminded of the importance of clear English and careful presentation in your answers, Total} N16450A Turn over Edexcel Success through qualifications1. (a) State the meaning of the following terms: (i) electrophile; a) (ii) free radical; Qa) (ii) nucleophile. ay (b) Classify the following reactions (i) chloroethane with aqueous sodium hydroxide; 2) (ii) ethane with chlorine; Q) (iii) ethene with hydrogen bromide. @) (Total 9 marks) Ni6850a, 2The first stage in the production of nitric acid, HNO, from ammonia, NH. involves oxidation by air using a platinuny/rhodium catalyst. (a) Balance the equation for this reaction. 4NH; + o> + H,0 a (b) Outline the steps by which nitric acid is then produced. (4) (©) If the reactions in the industrial process proceed to completion, 4 mol of ammonia should produce 4 mol of nitric acid. Calculate the mass of nitric acid that could be made from 50 tonnes of ammonia. (1 tonne = 1 x 10°g) Q) (d) Give ONE large-scale use for the product of the reaction between ammonia and nitric acid. a) (Total 8 marks) Leave blank Q SOA, 3 ‘Turn over