be BBs) 2/4/2]/[olap tre Peper Reference: = I. Tad 6242/01 Examiner we o'y Edexcel GCE caine Chemistry Advanced Subsidiary Unit Test 2 Tuesday 18 January 2005 — Morning Time: 1 hour Materials required for examination Items included with question papers fowesion] Leave Ree] ime Nil Ni Instructions to Candidates Tn the boxes above, write your centre number, candidate number, your sumame, initial(s) and your signature. ‘Answer ALL the questions in the spaces provided in this question paper. ‘You may use a calculator. Show all the steps in any calculations and state the units, formation for Candidates al ulate) ‘The total mark for this paper is 60. The marks for the individual questions and parts of questions are shown in round brackets: e.g. (2). There are 12 pages in this question paper. Page 7 is a blank page. A Periodic Table is printed on the back cover of this booklet. Advice to Candidates ‘You are reminded of the importance of clear English and careful presentation in your answers, ‘You will be assessed on your Quality of Written Communication in this paper. ‘pnts yy ee rc it Dosim utente tS edexcel 233 Total Turn overAnswer ALL the questions in the spaces provided. (a) Aluminium and chlorine are both manufactured by electrolytic processes. (Identify the electrolyte used in the manufacture of . aluminium ....... chlorine @ (ii) Explain why, in the manufacture of aluminium, the anode has to be replaced regularly. @ () (i) What TWO properties of aluminium make it especially useful as a material for aeroplane manufacture? (ii) State ONE large-scale use of chlorine. @ (©) (i) Chlorine reacts with alkenes. Give the structural formula of the product obtained when chlorine reacts with ethene. @ Gil) Classify the type of reaction occurring when the product in (c)(i) reacts with potassium cyanide, @ (Total 10 marks) BLeave blank 2. (@) (i) Write the structural formula of 2-iodobutane. @ (ii) Identify a reagent and the condition necessary for the conversion of 2-iodobutane to butan-2-ol. Reagent: . Condition: @ (iii) The same reagent can be used to convert 2-iodobutane to an alkene. In what way are the conditions different for this reaction? (iv) Draw the structures of the three isomers obtained in the reaction in (iii). e (b) The reaction in (a)(ii) takes place at a different rate when 2-bromobutane is used instead of 2-iodobutane. Suggest and explain in what way the rate would be different. ®@ (Total 10 marks)