Sumamne Yaa Paper Reference Pos Pann) 6243/02 mes Edexcel GCE aa Chemistry Advanced Subsidiary Unit Test 3B , Tuesday 18 January 2005 — Morning Time: 1 hour ‘Materials required for examination _Items inclutled with question papers Ni Nir Instructions to Candidates in the boxes above, write your centre number, candidate number, your sumame, initials) and signature. ‘Answer ALL the questions in the spaces provided in this question paper. ‘You may use a calculator. Shaw all the steps in any calculations and state the units. Information for Candidates ‘The total mark for this paper is 50. ‘The marks for the individual questions and paris of questions are shown in round brackets: e.g. (2). There are 16 pages in this question paper. Pages 4 and 10 are blank pages. A Periodic Table is printed on the back cover of this booklet. Advice to Candidates You are reminded of the importance of clear English end careful presentation in your answers. You will be assessed on your Quality of Written Communication in this paper. “person nay ee peat src wh Ulake Cals Lender ht pl. Turn over edexcel SRS RRRAnswer ALL the questions in the spaces provided. 1. (@) A white solid, A, gives a yellow colour in a flame test. When dilute hydrochloric acid followed by aqueous barium chloride is added to an aqueous solution of A, a white precipitate, B, is formed. Identify A and B by giving their names or formulae. ®@ (b) When a white solid, C, is warmed with aqueous sodium hydroxi evolved which turns damp red litmus paper blue. , & gas, D, is ‘When dilute nitric acid followed by aqueous silver nitrate is added to an aqueous solution of C, a precipitate, E, is formed. E does not dissolve in dilute aqueous ammonia, but does dissolve in concentrated aqueous ammonia, (i Identify C and D by giving their names or formulae. o NHB D ... i) State the colour of the precipitate E. CreamHl (© An organic compound, F, has two carbon atoms and one functional group in its molecule. When phosphorus pentachloride is added to F, a gas, G, is evolved, which forms steamy fumes in moist air. When F is warmed with aqueous potassium dichromate(V1) and dilute sulphuric acid, a colour change occurs as F is oxidised. (i). Identify F and G by giving their names or formulae. @ (ii) Describe the colour change that is seen when F is warmed with aqueous potassium dichromate(VI) and dilute sulphuric acid. Orange to green “ @ (@) Abhydrocarbon, H, has three carbon atoms and one functional group in its molecule. When H is shaken with aqueous bromine, a reaction, accompanied by a colour change, occurs. (i) Identify H by giving its name or formula. Propene a (ii) State the colour change that is seen when H reacts with aqueous bromine. From m La (Total 10 marks) CO SESS SS SSS eee 3 Tura ever