Problem: Find the molar volume of ammonia gast at 56 atm a

a=4.2527, b=0.02590, pc=111.3 atm, Tc=405.5 K; units o

Redlich-Kwong Equation of State

where:
P = pressure Tc = critical temperat
Vm = molar volume
Pc = critical pressure
R = gas constant
a = constant that corr
T = temperature
b = constant that corr

Derivation
V^3P-V^2RT+V(a-Pb62)-RTb)-ab=0
P (atm)
56

T (K) R (L atm/mol K)
450

0.08206

Pc (atm)

Tc (K)

111.3

405.5

a ( L/gmol) b (L/gmol)
4.2527

0.0259

a gast at 56 atm and 450 K using the Redlich-Kwong equation of state,

=405.5 K; units of a and b correspond to v in liter/gmol

Tc = critical temperature
Pc = critical pressure
a = constant that corrects for attractive potential of molecule
b = constant that corrects for volume

Vm

0.680374

2.650433
0

equation of state,

LABORATORY PROBLEM:

Find the molar volume of ammonia gas at conditions from 50 to 250 atm and 400 to 800 K using the Redlich
SOLUTION:

Redlich-Kwong Equation of State

Deriving the formula:

3

(P*T*Vm ) - (R*T*T*Vm2) - Vm(Pb2*T + RTb*T- a) - ab

C = Pb2*T + RTb*T
D = a* b

Let A = P*T
B = R*T*T

P (atm)

Temp (K)

50

400

4.2527 0.0259

20

0.08206 1000 656.48 13.4209

51

400

4.2527 0.0259

20

0.08206 1020 656.48 13.4344

52

400

4.2527 0.0259

20

0.08206 1040 656.48 13.4478

53

400

4.2527 0.0259

20

0.08206 1060 656.48 13.4612

54

400

4.2527 0.0259

20

0.08206 1080 656.48 13.4746

55

400

4.2527 0.0259

20

0.08206 1100 656.48 13.4880

56

400

4.2527 0.0259

20

0.08206 1120 656.48 13.5014

57

400

4.2527 0.0259

20

0.08206 1140 656.48 13.5149

58

400

4.2527 0.0259

20

0.08206 1160 656.48 13.5283

59

400

4.2527 0.0259

20

0.08206 1180 656.48 13.5417

60

400

4.2527 0.0259

20

0.08206 1200 656.48 13.5551

61

400

4.2527 0.0259

20

0.08206 1220 656.48 13.5685

62

400

4.2527 0.0259

20

0.08206 1240 656.48 13.5819

63

400

4.2527 0.0259

20

0.08206 1260 656.48 13.5954

64

400

4.2527 0.0259

20

0.08206 1280 656.48 13.6088

65

400

4.2527 0.0259

20

0.08206 1300 656.48 13.6222

66

400

4.2527 0.0259

20

0.08206 1320 656.48 13.6356

67

400

4.2527 0.0259

20

0.08206 1340 656.48 13.6490

68

400

4.2527 0.0259

20

0.08206 1360 656.48 13.6624

69

400

4.2527 0.0259

20

0.08206 1380 656.48 13.6758

70

400

4.2527 0.0259

20

0.08206 1400 656.48 13.6893

71

400

4.2527 0.0259

20

0.08206 1420 656.48 13.7027

72

400

4.2527 0.0259

20

0.08206 1440 656.48 13.7161

73

400

4.2527 0.0259

20

0.08206 1460 656.48 13.7295

74

400

4.2527 0.0259

20

0.08206 1480 656.48 13.7429

75

400

4.2527 0.0259

20

0.08206 1500 656.48 13.7563

76

400

4.2527 0.0259

20

0.08206 1520 656.48 13.7698

77

400

4.2527 0.0259

20

0.08206 1540 656.48 13.7832

78

400

4.2527 0.0259

20

0.08206 1560 656.48 13.7966

79

400

4.2527 0.0259

20

0.08206 1580 656.48 13.8100

80

400

4.2527 0.0259

20

0.08206 1600 656.48 13.8234

81

400

4.2527 0.0259

20

0.08206 1620 656.48 13.8368

82

400

4.2527 0.0259

20

0.08206 1640 656.48 13.8503

83

400

4.2527 0.0259

20

0.08206 1660 656.48 13.8637

84

400

4.2527 0.0259

20

0.08206 1680 656.48 13.8771

85

400

4.2527 0.0259

20

0.08206 1700 656.48 13.8905

86

400

4.2527 0.0259

20

0.08206 1720 656.48 13.9039

87

400

4.2527 0.0259

20

0.08206 1740 656.48 13.9173

88

400

4.2527 0.0259

20

0.08206 1760 656.48 13.9308

89

400

4.2527 0.0259

20

0.08206 1780 656.48 13.9442

90

400

4.2527 0.0259

20

0.08206 1800 656.48 13.9576

91

400

4.2527 0.0259

20

0.08206 1820 656.48 13.9710

92

400

4.2527 0.0259

20

0.08206 1840 656.48 13.9844

93

400

4.2527 0.0259

20

0.08206 1860 656.48 13.9978

94

400

4.2527 0.0259

20

0.08206 1880 656.48 14.0113

95

400

4.2527 0.0259

20

0.08206 1900 656.48 14.0247

96

400

4.2527 0.0259

20

0.08206 1920 656.48 14.0381

97

400

4.2527 0.0259

20

0.08206 1940 656.48 14.0515

98

400

4.2527 0.0259

20

0.08206 1960 656.48 14.0649

99

400

4.2527 0.0259

20

0.08206 1980 656.48 14.0783

100

400

4.2527 0.0259

20

0.08206 2000 656.48 14.0918

101

400

4.2527 0.0259

20

0.08206 2020 656.48 14.1052

102

400

4.2527 0.0259

20

0.08206 2040 656.48 14.1186

103

400

4.2527 0.0259

20

0.08206 2060 656.48 14.1320

104

400

4.2527 0.0259

20

0.08206 2080 656.48 14.1454

105

400

4.2527 0.0259

20

0.08206 2100 656.48 14.1588

106

400

4.2527 0.0259

20

0.08206 2120 656.48 14.1722

107

400

4.2527 0.0259

20

0.08206 2140 656.48 14.1857

108

400

4.2527 0.0259

20

0.08206 2160 656.48 14.1991

109

400

4.2527 0.0259

20

0.08206 2180 656.48 14.2125

110

400

4.2527 0.0259

20

0.08206 2200 656.48 14.2259

111

400

4.2527 0.0259

20

0.08206 2220 656.48 14.2393

112

400

4.2527 0.0259

20

0.08206 2240 656.48 14.2527

113

400

4.2527 0.0259

20

0.08206 2260 656.48 14.2662

114

400

4.2527 0.0259

20

0.08206 2280 656.48 14.2796

115

400

4.2527 0.0259

20

0.08206 2300 656.48 14.2930

116

400

4.2527 0.0259

20

0.08206 2320 656.48 14.3064

117

400

4.2527 0.0259

20

0.08206 2340 656.48 14.3198

118

400

4.2527 0.0259

20

0.08206 2360 656.48 14.3332

119

400

4.2527 0.0259

20

0.08206 2380 656.48 14.3467

120

400

4.2527 0.0259

20

0.08206 2400 656.48 14.3601

121

400

4.2527 0.0259

20

0.08206 2420 656.48 14.3735

122

400

4.2527 0.0259

20

0.08206 2440 656.48 14.3869

123

400

4.2527 0.0259

20

0.08206 2460 656.48 14.4003

124

400

4.2527 0.0259

20

0.08206 2480 656.48 14.4137

125

400

4.2527 0.0259

20

0.08206 2500 656.48 14.4272

126

400

4.2527 0.0259

20

0.08206 2520 656.48 14.4406

127

400

4.2527 0.0259

20

0.08206 2540 656.48 14.4540

128

400

4.2527 0.0259

20

0.08206 2560 656.48 14.4674

129

400

4.2527 0.0259

20

0.08206 2580 656.48 14.4808

130

400

4.2527 0.0259

20

0.08206 2600 656.48 14.4942

131

400

4.2527 0.0259

20

0.08206 2620 656.48 14.5077

132

400

4.2527 0.0259

20

0.08206 2640 656.48 14.5211

133

400

4.2527 0.0259

20

0.08206 2660 656.48 14.5345

134

400

4.2527 0.0259

20

0.08206 2680 656.48 14.5479

135

400

4.2527 0.0259

20

0.08206 2700 656.48 14.5613

136

400

4.2527 0.0259

20

0.08206 2720 656.48 14.5747

137

400

4.2527 0.0259

20

0.08206 2740 656.48 14.5882

138

400

4.2527 0.0259

20

0.08206 2760 656.48 14.6016

139

400

4.2527 0.0259

20

0.08206 2780 656.48 14.6150

140

400

4.2527 0.0259

20

0.08206 2800 656.48 14.6284

141

400

4.2527 0.0259

20

0.08206 2820 656.48 14.6418

142

400

4.2527 0.0259

20

0.08206 2840 656.48 14.6552

143

400

4.2527 0.0259

20

0.08206 2860 656.48 14.6686

144

400

4.2527 0.0259

20

0.08206 2880 656.48 14.6821

145

400

4.2527 0.0259

20

0.08206 2900 656.48 14.6955

146

400

4.2527 0.0259

20

0.08206 2920 656.48 14.7089

147

400

4.2527 0.0259

20

0.08206 2940 656.48 14.7223

148

400

4.2527 0.0259

20

0.08206 2960 656.48 14.7357

149

400

4.2527 0.0259

20

0.08206 2980 656.48 14.7491

150

400

4.2527 0.0259

20

0.08206 3000 656.48 14.7626

151

400

4.2527 0.0259

20

0.08206 3020 656.48 14.7760

152

400

4.2527 0.0259

20

0.08206 3040 656.48 14.7894

153

400

4.2527 0.0259

20

0.08206 3060 656.48 14.8028

154

400

4.2527 0.0259

20

0.08206 3080 656.48 14.8162

155

400

4.2527 0.0259

20

0.08206 3100 656.48 14.8296

156

400

4.2527 0.0259

20

0.08206 3120 656.48 14.8431

157

400

4.2527 0.0259

20

0.08206 3140 656.48 14.8565

158

400

4.2527 0.0259

20

0.08206 3160 656.48 14.8699

159

400

4.2527 0.0259

20

0.08206 3180 656.48 14.8833

160

400

4.2527 0.0259

20

0.08206 3200 656.48 14.8967

161

400

4.2527 0.0259

20

0.08206 3220 656.48 14.9101

162

400

4.2527 0.0259

20

0.08206 3240 656.48 14.9236

163

400

4.2527 0.0259

20

0.08206 3260 656.48 14.9370

164

400

4.2527 0.0259

20

0.08206 3280 656.48 14.9504

165

400

4.2527 0.0259

20

0.08206 3300 656.48 14.9638

166

400

4.2527 0.0259

20

0.08206 3320 656.48 14.9772

167

400

4.2527 0.0259

20

0.08206 3340 656.48 14.9906

168

400

4.2527 0.0259

20

0.08206 3360 656.48 15.0041

169

400

4.2527 0.0259

20

0.08206 3380 656.48 15.0175

170

400

4.2527 0.0259

20

0.08206 3400 656.48 15.0309

171

400

4.2527 0.0259

20

0.08206 3420 656.48 15.0443

172

400

4.2527 0.0259

20

0.08206 3440 656.48 15.0577

173

400

4.2527 0.0259

20

0.08206 3460 656.48 15.0711

174

400

4.2527 0.0259

20

0.08206 3480 656.48 15.0846

175

400

4.2527 0.0259

20

0.08206 3500 656.48 15.0980

176

400

4.2527 0.0259

20

0.08206 3520 656.48 15.1114

177

400

4.2527 0.0259

20

0.08206 3540 656.48 15.1248

178

400

4.2527 0.0259

20

0.08206 3560 656.48 15.1382

179

400

4.2527 0.0259

20

0.08206 3580 656.48 15.1516

180

400

4.2527 0.0259

20

0.08206 3600 656.48 15.1650

181

400

4.2527 0.0259

20

0.08206 3620 656.48 15.1785

182

400

4.2527 0.0259

20

0.08206 3640 656.48 15.1919

183

400

4.2527 0.0259

20

0.08206 3660 656.48 15.2053

184

400

4.2527 0.0259

20

0.08206 3680 656.48 15.2187

185

400

4.2527 0.0259

20

0.08206 3700 656.48 15.2321

186

400

4.2527 0.0259

20

0.08206 3720 656.48 15.2455

187

400

4.2527 0.0259

20

0.08206 3740 656.48 15.2590

188

400

4.2527 0.0259

20

0.08206 3760 656.48 15.2724

189

400

4.2527 0.0259

20

0.08206 3780 656.48 15.2858

190

400

4.2527 0.0259

20

0.08206 3800 656.48 15.2992

191

400

4.2527 0.0259

20

0.08206 3820 656.48 15.3126

192

400

4.2527 0.0259

20

0.08206 3840 656.48 15.3260

193

400

4.2527 0.0259

20

0.08206 3860 656.48 15.3395

194

400

4.2527 0.0259

20

0.08206 3880 656.48 15.3529

195

400

4.2527 0.0259

20

0.08206 3900 656.48 15.3663

196

400

4.2527 0.0259

20

0.08206 3920 656.48 15.3797

197

400

4.2527 0.0259

20

0.08206 3940 656.48 15.3931

198

400

4.2527 0.0259

20

0.08206 3960 656.48 15.4065

199

400

4.2527 0.0259

20

0.08206 3980 656.48 15.4200

200

400

4.2527 0.0259

20

0.08206 4000 656.48 15.4334

201

400

4.2527 0.0259

20

0.08206 4020 656.48 15.4468

202

400

4.2527 0.0259

20

0.08206 4040 656.48 15.4602

203

400

4.2527 0.0259

20

0.08206 4060 656.48 15.4736

204

400

4.2527 0.0259

20

0.08206 4080 656.48 15.4870

205

400

4.2527 0.0259

20

0.08206 4100 656.48 15.5005

206

400

4.2527 0.0259

20

0.08206 4120 656.48 15.5139

207

400

4.2527 0.0259

20

0.08206 4140 656.48 15.5273

208

400

4.2527 0.0259

20

0.08206 4160 656.48 15.5407

209

400

4.2527 0.0259

20

0.08206 4180 656.48 15.5541

210

400

4.2527 0.0259

20

0.08206 4200 656.48 15.5675

211

400

4.2527 0.0259

20

0.08206 4220 656.48 15.5810

212

400

4.2527 0.0259

20

0.08206 4240 656.48 15.5944

213

400

4.2527 0.0259

20

0.08206 4260 656.48 15.6078

214

400

4.2527 0.0259

20

0.08206 4280 656.48 15.6212

215

400

4.2527 0.0259

20

0.08206 4300 656.48 15.6346

216

400

4.2527 0.0259

20

0.08206 4320 656.48 15.6480

217

400

4.2527 0.0259

20

0.08206 4340 656.48 15.6614

218

400

4.2527 0.0259

20

0.08206 4360 656.48 15.6749

219

400

4.2527 0.0259

20

0.08206 4380 656.48 15.6883

220

400

4.2527 0.0259

20

0.08206 4400 656.48 15.7017

221

400

4.2527 0.0259

20

0.08206 4420 656.48 15.7151

222

400

4.2527 0.0259

20

0.08206 4440 656.48 15.7285

223

400

4.2527 0.0259

20

0.08206 4460 656.48 15.7419

224

400

4.2527 0.0259

20

0.08206 4480 656.48 15.7554

225

400

4.2527 0.0259

20

0.08206 4500 656.48 15.7688

226

400

4.2527 0.0259

20

0.08206 4520 656.48 15.7822

227

400

4.2527 0.0259

20

0.08206 4540 656.48 15.7956

228

400

4.2527 0.0259

20

0.08206 4560 656.48 15.8090

229

400

4.2527 0.0259

20

0.08206 4580 656.48 15.8224

230

400

4.2527 0.0259

20

0.08206 4600 656.48 15.8359

231

400

4.2527 0.0259

20

0.08206 4620 656.48 15.8493

232

400

4.2527 0.0259

20

0.08206 4640 656.48 15.8627

233

400

4.2527 0.0259

20

0.08206 4660 656.48 15.8761

234

400

4.2527 0.0259

20

0.08206 4680 656.48 15.8895

235

400

4.2527 0.0259

20

0.08206 4700 656.48 15.9029

236

400

4.2527 0.0259

20

0.08206 4720 656.48 15.9164

237

400

4.2527 0.0259

20

0.08206 4740 656.48 15.9298

238

400

4.2527 0.0259

20

0.08206 4760 656.48 15.9432

239

400

4.2527 0.0259

20

0.08206 4780 656.48 15.9566

240

400

4.2527 0.0259

20

0.08206 4800 656.48 15.9700

241

400

4.2527 0.0259

20

0.08206 4820 656.48 15.9834

242

400

4.2527 0.0259

20

0.08206 4840 656.48 15.9969

243

400

4.2527 0.0259

20

0.08206 4860 656.48 16.0103

244

400

4.2527 0.0259

20

0.08206 4880 656.48 16.0237

245

400

4.2527 0.0259

20

0.08206 4900 656.48 16.0371

246

400

4.2527 0.0259

20

0.08206 4920 656.48 16.0505

247

400

4.2527 0.0259

20

0.08206 4940 656.48 16.0639

248

400

4.2527 0.0259

20

0.08206 4960 656.48 16.0773

249

400

4.2527 0.0259

20

0.08206 4980 656.48 16.0908

250

400

4.2527 0.0259

20

0.08206 5000 656.48 16.1042

400 to 800 K using the Redlich-Kwong equation of state. Plot the molar volume in a 3D plot and a contour plot.

P vs Vm at 400K
300
200
100

C = Pb *T + RTb*T- a
D = a* b

D
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

Vm
0.67655773
0.663697772
0.651332864
0.639434982
0.627978173
0.616938384
0.606293272
0.59602206
0.586105407
0.576525283
0.567264862
0.558308418
0.549641241

derived formulaTemp(K)
-1.81661E-07
800
-7.55288E-07
800
-2.50926E-07
800
6.48728E-07
800
-9.14176E-07
800
-9.14956E-07
800
-2.87457E-07
800
-3.66799E-08
800
-1.62837E-07
800
-6.50573E-07
800
-2.28853E-07
800
-2.42241E-07
800
-8.70488E-08
800

145

136

Pb2*T + RTb*T- a) - ab = 0

1
10
19
28
37
46
55
64
73
82
91
100
109
118
127

e formula:

28.28427125

1414.213562 1856.805839

28.28427125

1442.497834 1856.805839

28.28427125

1470.782105 1856.805839

28.28427125

1499.066376 1856.805839

28.28427125

1527.350647 1856.805839

28.28427125

1555.634919 1856.805839

28.28427125

1583.91919 1856.805839

28.28427125

1612.203461 1856.805839

28.28427125

1640.487732 1856.805839

28.28427125

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28.28427125

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28.28427125

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28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

2743.574311 1856.805839

800 28.28427125

2771.858582 1856.805839

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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800 28.28427125

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0.153770943
0.153250741

-3.98932E-07
-7.99818E-07
-2.18683E-07
-4.12975E-07
-7.36463E-07
-2.24201E-07
-3.86158E-07
-6.38337E-07

800 28.28427125

6873.077913 1856.805839

800 28.28427125

6901.362184 1856.805839

800 28.28427125

6929.646456 1856.805839

800 28.28427125

6957.930727 1856.805839

800 28.28427125

6986.214998 1856.805839

800 28.28427125

7014.499269 1856.805839

800 28.28427125

7042.783541 1856.805839

800 28.28427125

7071.067812 1856.805839

P vs. Vm at 800 k

at 400K
1.5
1
0.5
0

199

190

181

172

163

154

145

25
0
24
9
24
8
24
7

C
44.78723983
44.8062132
44.82518657
44.84415994
44.86313331
44.88210669
44.90108006
44.92005343
44.9390268
44.95800017
44.97697355
44.99594692
45.01492029

Vm
derived formula
1.336695861
-5.51777E-08
1.310953966
3.9271E-07
1.286202233
1.27127E-07
1.262384614
9.76957E-07
1.239449215
-4.71639E-07
1.217347914
-1.13825E-07
1.196036026
-7.87254E-07
1.175472005
-4.21859E-07
1.155617167
-7.92543E-07
1.136435451
-4.18249E-07
1.117893201
-2.1339E-07
1.099958968
4.15644E-07
1.082603331
-2.27596E-07

45.03389366
45.05286703
45.07184041
45.09081378
45.10978715
45.12876052
45.14773389
45.16670727
45.18568064
45.20465401
45.22362738
45.24260075
45.26157413
45.2805475
45.29952087
45.31849424
45.33746761
45.35644099
45.37541436
45.39438773
45.4133611
45.43233447
45.45130785
45.47028122
45.48925459
45.50822796
45.52720133
45.54617471
45.56514808
45.58412145
45.60309482
45.62206819
45.64104157
45.66001494
45.67898831
45.69796168

1.065798739
1.04951936
1.033740955
1.01844075
1.003597335
0.989190556
0.975201429
0.961612055
0.948405542
0.935565938
0.923078164
0.910927957
0.899101814
0.887586942
0.876371215
0.865443126
0.854791752
0.844406716
0.834278155
0.824396684
0.814753372
0.805339714
0.796147604
0.787169313
0.778397469
0.769825033
0.761445283
0.753251797
0.745238434
0.737399319
0.729728833
0.722221594
0.714872444
0.707676446
0.700628862
0.693725147

-1.14073E-07
-5.32104E-07
-3.96446E-07
-4.11145E-07
-2.44102E-08
-2.24585E-07
-1.4761E-07
-2.42632E-07
-3.99784E-07
-6.53067E-08
-4.83707E-07
-6.35421E-07
-8.02497E-07
-5.04643E-07
-2.22447E-07
-3.26323E-07
-9.73391E-07
-5.72515E-07
-1.5026E-07
-2.17733E-07
-5.5008E-07
-5.74192E-07
-4.21628E-08
-6.66342E-08
-1.1066E-07
-3.56373E-07
-3.56747E-07
-5.83503E-07
-3.36478E-07
-3.94979E-07
-2.33126E-07
-2.05221E-07
-5.54802E-07
-1.11219E-07
-1.63658E-07
-9.75828E-07

45.71693505
45.73590843
45.7548818
45.77385517
45.79282854
45.81180191
45.83077529
45.84974866
45.86872203
45.8876954
45.90666877
45.92564215
45.94461552
45.96358889
45.98256226
46.00153563
46.02050901
46.03948238
46.05845575
46.07742912
46.09640249
46.11537587
46.13434924
46.15332261
46.17229598
46.19126935
46.21024273
46.2292161
46.24818947
46.26716284
46.28613621
46.30510959
46.32408296
46.34305633
46.3620297
46.38100307

0.686960944
0.680332066
0.673834493
0.667464364
0.661217966
0.65509173
0.649082224
0.643186142
0.637400305
0.631721651
0.626147229
0.620674197
0.615299814
0.610021438
0.60483652
0.5997426
0.594737304
0.58981834
0.584983496
0.580230631
0.575557679
0.570962643
0.56644359
0.56199865
0.557626019
0.553323945
0.549090736
0.54492475
0.540824401
0.53678815
0.532814506
0.528902025
0.525049306
0.521254989
0.517517759
0.513836336

-5.49553E-07
-6.32857E-07
-3.05619E-07
-1.0358E-07
-1.85373E-07
-8.08872E-07
-2.42156E-07
-4.26383E-07
-4.47948E-07
-3.5938E-07
-2.67985E-07
-1.34756E-07
-7.60073E-08
-9.60095E-07
-1.29032E-07
-4.53264E-08
-4.79338E-07
-8.32336E-07
-3.16173E-07
-5.8533E-07
-2.23186E-07
-4.13523E-07
-2.09127E-07
-8.04573E-07
-8.47271E-07
-4.55703E-07
-2.23431E-07
-9.47659E-07
-4.33473E-07
-8.43828E-07
-6.96825E-07
-4.58493E-07
-2.79314E-07
-1.65539E-07
-5.34712E-07
-1.76732E-07

46.39997645
46.41894982
46.43792319
46.45689656
46.47586993
46.49484331
46.51381668
46.53279005
46.55176342
46.57073679
46.58971017
46.60868354
46.62765691
46.64663028
46.66560365
46.68457703
46.7035504
46.72252377
46.74149714
46.76047051
46.77944389
46.79841726
46.81739063
46.836364
46.85533737
46.87431075
46.89328412
46.91225749
46.93123086
46.95020423
46.96917761
46.98815098
47.00712435
47.02609772
47.04507109
47.06404447

0.510209481
0.506635989
0.503114694
0.499644458
0.496224181
0.492852791
0.489529249
0.486252544
0.483021692
0.479835739
0.476693756
0.473594839
0.470538108
0.467522711
0.464547811
0.461612603
0.458716295
0.45585812
0.45303733
0.450253198
0.447505013
0.444792084
0.442113738
0.439469318
0.436858182
0.434279709
0.431733288
0.429218326
0.426734245
0.424280479
0.421856476
0.419461699
0.417095624
0.414757736
0.412447537
0.410164537

-1.27056E-07
-6.27993E-07
-1.98001E-07
-1.88589E-07
-2.67268E-08
-5.95074E-07
-1.27354E-07
-1.75343E-07
-1.46084E-07
-8.61477E-07
-4.72447E-07
-2.61264E-07
-7.77144E-07
-6.51957E-08
-9.40073E-07
-4.45827E-07
-1.8863E-07
-4.95959E-07
-6.94237E-07
-2.71931E-07
-4.85921E-07
-5.79925E-07
-3.89118E-07
-2.23996E-07
-9.74884E-07
-4.55668E-07
-2.20314E-07
-5.7708E-07
-2.10688E-07
-1.07499E-07
-4.50339E-07
-1.38329E-07
-2.19944E-07
-6.20834E-07
-1.76335E-08
-1.59605E-07

47.08301784
47.10199121
47.12096458
47.13993795
47.15891133
47.1778847
47.19685807
47.21583144
47.23480481
47.25377819
47.27275156
47.29172493
47.3106983
47.32967167
47.34864505
47.36761842
47.38659179
47.40556516
47.42453853
47.44351191
47.46248528
47.48145865
47.50043202
47.51940539
47.53837877
47.55735214
47.57632551
47.59529888
47.61427225
47.63324563
47.652219
47.67119237
47.69016574
47.70913911
47.72811249
47.74708586

0.407908258
0.405678236
0.403474013
0.401295147
0.399141202
0.397011753
0.394906385
0.392824691
0.390766276
0.388730751
0.386717737
0.384726861
0.382757763
0.380810086
0.378883483
0.376977615
0.375092147
0.373226756
0.371381122
0.369554933
0.367747884
0.365959675
0.364190014
0.362438613
0.360705194
0.358989477
0.357291197
0.355610087
0.353945888
0.352298348
0.350667217
0.349052252
0.347453214
0.345869868
0.344301986
0.34274934

-1.93976E-07
-1.53978E-07
-8.8277E-07
-4.83138E-07
-2.69351E-07
-8.1728E-07
-2.08691E-08
-5.14303E-07
-4.78345E-07
-2.84641E-07
-1.48617E-07
-5.54891E-07
-2.27462E-07
-5.12114E-07
-8.21825E-07
-3.34272E-08
-8.17905E-07
-7.81819E-07
-4.86279E-07
-2.71054E-07
-1.4787E-07
-5.44854E-07
-2.68916E-07
-7.28892E-07
-6.94612E-08
-3.67366E-07
-2.5881E-07
-1.30015E-07
-5.68874E-07
-2.04061E-07
-4.9408E-07
-8.44444E-07
-8.00655E-07
-9.21631E-07
-3.63324E-07
-8.97284E-07

47.76605923
47.7850326
47.80400597
47.82297935
47.84195272
47.86092609
47.87989946
47.89887283
47.91784621
47.93681958
47.95579295
47.97476632
47.99373969
48.01271307
48.03168644
48.05065981
48.06963318
48.08860655
48.10757993
48.1265533
48.14552667
48.16450004
48.18347341
48.20244679
48.22142016
48.24039353
48.2593669
48.27834027
48.29731365
48.31628702
48.33526039
48.35423376
48.37320713
48.39218051
48.41115388
48.43012725

0.341211712
0.339688885
0.338180644
0.336686782
0.335207096
0.333741384
0.332289448
0.330851097
0.32942614
0.328014391
0.32661567
0.325229794
0.323856589
0.322495881
0.321147502
0.319811284
0.318487063
0.31717468
0.315873975
0.314584795
0.313306987
0.3120404
0.310784889
0.309540309
0.308306517
0.307083374
0.305870742
0.304668489
0.30347648
0.302294584
0.301122676
0.299960627
0.298808316
0.297665619
0.296532418
0.295408592

-8.96691E-07
-6.81285E-08
-6.80055E-08
-5.65681E-07
-2.73349E-07
-1.33896E-07
-4.7101E-07
-2.17797E-07
-5.87528E-07
-9.30823E-07
-2.44148E-07
-6.50371E-07
-3.01658E-07
-5.22265E-07
-2.90182E-07
-1.31022E-07
-5.73906E-07
-2.08552E-07
-5.80607E-07
-2.03666E-07
-4.30603E-07
-7.66188E-07
-2.99428E-07
-8.11622E-08
-1.19902E-07
-1.04291E-07
-6.56056E-07
-3.74465E-07
-2.17129E-07
-7.00838E-07
-2.82391E-07
-4.32466E-07
-3.59456E-07
-2.16227E-07
-3.86309E-08
-7.75639E-07

48.44910062
48.46807399
48.48704737
48.50602074
48.52499411
48.54396748
48.56294085
48.58191423

0.29429403
0.293188615
0.292092235
0.291004782
0.289926145
0.288856218
0.287794898
0.286742078

-4.4299E-07
-2.35004E-07
-9.10883E-07
-4.1737E-07
-1.9938E-07
-4.96507E-07
-8.72666E-08
-6.56559E-07

t 800 k

A.
Assume 100g of mixture:
Molecular weight:

MW NH3
17.04

MW N2
28.02

MW H2
2.02

P (atm)
270

NH3
25
17.04
T (K)
550

N2
18.75
28.02

H2
56.25
2.02

R
SV NH3
0.08206 0.00981

SV N2
SV H2
0.005966 0.082752

The formula used are

Pressure*MW
Density = _______________
Gas Constant*Temperature

Specific Volume is the inverse of density

Specific Volume =

B. Redlich-Kwong equation of state

where:
R=0.08206 Latm/molK)
P=pressure(atm)
T=temperature(K)
Vm=molar volume (V/n)

P (atm)
270

T (K)
550

R
0.08206

pc
111.3

Tc
a
b
405.5 85.64088 0.025903

Consider a mixture of 25% ammonia, the rest nitrogen and hydrogen in a 1:3 ra
the specific volume using:
a. ideal gas law
b. Redlich-Kwong equation of state
c. soave-redlich-kwong equation of state
Total SV
0.098528

Where did you get the data you needed? How do the three answers compare? Is th

ume is the inverse of density

Gas Constant*Temperature
_____________________
Pressure * MW

a=constant that corrects for attractive potential of molecules

b=a constant that corrects for volume
Tc= critical temperature
Pc=critical pressure

ogen and hydrogen in a 1:3 ratio. The gas is at 270 atm and 550K. Compute

e three answers compare? Is the gas ideal or not?