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# Problem: Find the molar volume of ammonia gast at 56 atm a

## a=4.2527, b=0.02590, pc=111.3 atm, Tc=405.5 K; units o

Redlich-Kwong Equation of State

where:
P = pressure Tc = critical temperat
Vm = molar volume
Pc = critical pressure
R = gas constant
a = constant that corr
T = temperature
b = constant that corr

Derivation
V^3P-V^2RT+V(a-Pb62)-RTb)-ab=0
P (atm)
56

T (K) R (L atm/mol K)
450

0.08206

Pc (atm)

Tc (K)

111.3

405.5

a ( L/gmol) b (L/gmol)
4.2527

0.0259

## a gast at 56 atm and 450 K using the Redlich-Kwong equation of state,

=405.5 K; units of a and b correspond to v in liter/gmol

Tc = critical temperature
Pc = critical pressure
a = constant that corrects for attractive potential of molecule
b = constant that corrects for volume

Vm

0.680374

2.650433
0

equation of state,

LABORATORY PROBLEM:

Find the molar volume of ammonia gas at conditions from 50 to 250 atm and 400 to 800 K using the Redlich
SOLUTION:

3

## (P*T*Vm ) - (R*T*T*Vm2) - Vm(Pb2*T + RTb*T- a) - ab

C = Pb2*T + RTb*T
D = a* b

Let A = P*T
B = R*T*T

P (atm)

Temp (K)

50

400

4.2527 0.0259

20

51

400

4.2527 0.0259

20

52

400

4.2527 0.0259

20

53

400

4.2527 0.0259

20

54

400

4.2527 0.0259

20

55

400

4.2527 0.0259

20

56

400

4.2527 0.0259

20

57

400

4.2527 0.0259

20

58

400

4.2527 0.0259

20

59

400

4.2527 0.0259

20

60

400

4.2527 0.0259

20

61

400

4.2527 0.0259

20

62

400

4.2527 0.0259

20

63

400

4.2527 0.0259

20

64

400

4.2527 0.0259

20

65

400

4.2527 0.0259

20

66

400

4.2527 0.0259

20

67

400

4.2527 0.0259

20

68

400

4.2527 0.0259

20

69

400

4.2527 0.0259

20

70

400

4.2527 0.0259

20

71

400

4.2527 0.0259

20

72

400

4.2527 0.0259

20

73

400

4.2527 0.0259

20

74

400

4.2527 0.0259

20

75

400

4.2527 0.0259

20

76

400

4.2527 0.0259

20

77

400

4.2527 0.0259

20

78

400

4.2527 0.0259

20

79

400

4.2527 0.0259

20

80

400

4.2527 0.0259

20

81

400

4.2527 0.0259

20

82

400

4.2527 0.0259

20

83

400

4.2527 0.0259

20

84

400

4.2527 0.0259

20

85

400

4.2527 0.0259

20

86

400

4.2527 0.0259

20

87

400

4.2527 0.0259

20

88

400

4.2527 0.0259

20

89

400

4.2527 0.0259

20

90

400

4.2527 0.0259

20

91

400

4.2527 0.0259

20

92

400

4.2527 0.0259

20

93

400

4.2527 0.0259

20

94

400

4.2527 0.0259

20

95

400

4.2527 0.0259

20

96

400

4.2527 0.0259

20

97

400

4.2527 0.0259

20

98

400

4.2527 0.0259

20

99

400

4.2527 0.0259

20

100

400

4.2527 0.0259

20

101

400

4.2527 0.0259

20

102

400

4.2527 0.0259

20

103

400

4.2527 0.0259

20

104

400

4.2527 0.0259

20

105

400

4.2527 0.0259

20

106

400

4.2527 0.0259

20

107

400

4.2527 0.0259

20

108

400

4.2527 0.0259

20

109

400

4.2527 0.0259

20

110

400

4.2527 0.0259

20

111

400

4.2527 0.0259

20

112

400

4.2527 0.0259

20

113

400

4.2527 0.0259

20

114

400

4.2527 0.0259

20

115

400

4.2527 0.0259

20

116

400

4.2527 0.0259

20

117

400

4.2527 0.0259

20

118

400

4.2527 0.0259

20

119

400

4.2527 0.0259

20

120

400

4.2527 0.0259

20

121

400

4.2527 0.0259

20

122

400

4.2527 0.0259

20

123

400

4.2527 0.0259

20

124

400

4.2527 0.0259

20

125

400

4.2527 0.0259

20

126

400

4.2527 0.0259

20

127

400

4.2527 0.0259

20

128

400

4.2527 0.0259

20

129

400

4.2527 0.0259

20

130

400

4.2527 0.0259

20

131

400

4.2527 0.0259

20

132

400

4.2527 0.0259

20

133

400

4.2527 0.0259

20

134

400

4.2527 0.0259

20

135

400

4.2527 0.0259

20

136

400

4.2527 0.0259

20

137

400

4.2527 0.0259

20

138

400

4.2527 0.0259

20

139

400

4.2527 0.0259

20

140

400

4.2527 0.0259

20

141

400

4.2527 0.0259

20

142

400

4.2527 0.0259

20

143

400

4.2527 0.0259

20

144

400

4.2527 0.0259

20

145

400

4.2527 0.0259

20

146

400

4.2527 0.0259

20

147

400

4.2527 0.0259

20

148

400

4.2527 0.0259

20

149

400

4.2527 0.0259

20

150

400

4.2527 0.0259

20

151

400

4.2527 0.0259

20

152

400

4.2527 0.0259

20

153

400

4.2527 0.0259

20

154

400

4.2527 0.0259

20

155

400

4.2527 0.0259

20

156

400

4.2527 0.0259

20

157

400

4.2527 0.0259

20

158

400

4.2527 0.0259

20

159

400

4.2527 0.0259

20

160

400

4.2527 0.0259

20

161

400

4.2527 0.0259

20

162

400

4.2527 0.0259

20

163

400

4.2527 0.0259

20

164

400

4.2527 0.0259

20

165

400

4.2527 0.0259

20

166

400

4.2527 0.0259

20

167

400

4.2527 0.0259

20

168

400

4.2527 0.0259

20

169

400

4.2527 0.0259

20

170

400

4.2527 0.0259

20

171

400

4.2527 0.0259

20

172

400

4.2527 0.0259

20

173

400

4.2527 0.0259

20

174

400

4.2527 0.0259

20

175

400

4.2527 0.0259

20

176

400

4.2527 0.0259

20

177

400

4.2527 0.0259

20

178

400

4.2527 0.0259

20

179

400

4.2527 0.0259

20

180

400

4.2527 0.0259

20

181

400

4.2527 0.0259

20

182

400

4.2527 0.0259

20

183

400

4.2527 0.0259

20

184

400

4.2527 0.0259

20

185

400

4.2527 0.0259

20

186

400

4.2527 0.0259

20

187

400

4.2527 0.0259

20

188

400

4.2527 0.0259

20

189

400

4.2527 0.0259

20

190

400

4.2527 0.0259

20

191

400

4.2527 0.0259

20

192

400

4.2527 0.0259

20

193

400

4.2527 0.0259

20

194

400

4.2527 0.0259

20

195

400

4.2527 0.0259

20

196

400

4.2527 0.0259

20

197

400

4.2527 0.0259

20

198

400

4.2527 0.0259

20

199

400

4.2527 0.0259

20

200

400

4.2527 0.0259

20

201

400

4.2527 0.0259

20

202

400

4.2527 0.0259

20

203

400

4.2527 0.0259

20

204

400

4.2527 0.0259

20

205

400

4.2527 0.0259

20

206

400

4.2527 0.0259

20

207

400

4.2527 0.0259

20

208

400

4.2527 0.0259

20

209

400

4.2527 0.0259

20

210

400

4.2527 0.0259

20

211

400

4.2527 0.0259

20

212

400

4.2527 0.0259

20

213

400

4.2527 0.0259

20

214

400

4.2527 0.0259

20

215

400

4.2527 0.0259

20

216

400

4.2527 0.0259

20

217

400

4.2527 0.0259

20

218

400

4.2527 0.0259

20

219

400

4.2527 0.0259

20

220

400

4.2527 0.0259

20

221

400

4.2527 0.0259

20

222

400

4.2527 0.0259

20

223

400

4.2527 0.0259

20

224

400

4.2527 0.0259

20

225

400

4.2527 0.0259

20

226

400

4.2527 0.0259

20

227

400

4.2527 0.0259

20

228

400

4.2527 0.0259

20

229

400

4.2527 0.0259

20

230

400

4.2527 0.0259

20

231

400

4.2527 0.0259

20

232

400

4.2527 0.0259

20

233

400

4.2527 0.0259

20

234

400

4.2527 0.0259

20

235

400

4.2527 0.0259

20

236

400

4.2527 0.0259

20

237

400

4.2527 0.0259

20

238

400

4.2527 0.0259

20

239

400

4.2527 0.0259

20

240

400

4.2527 0.0259

20

241

400

4.2527 0.0259

20

242

400

4.2527 0.0259

20

243

400

4.2527 0.0259

20

244

400

4.2527 0.0259

20

245

400

4.2527 0.0259

20

246

400

4.2527 0.0259

20

247

400

4.2527 0.0259

20

248

400

4.2527 0.0259

20

249

400

4.2527 0.0259

20

250

400

4.2527 0.0259

20

## 0.08206 5000 656.48 16.1042

400 to 800 K using the Redlich-Kwong equation of state. Plot the molar volume in a 3D plot and a contour plot.

P vs Vm at 400K
300
200
100

C = Pb *T + RTb*T- a
D = a* b

D
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

Vm
0.67655773
0.663697772
0.651332864
0.639434982
0.627978173
0.616938384
0.606293272
0.59602206
0.586105407
0.576525283
0.567264862
0.558308418
0.549641241

derived formulaTemp(K)
-1.81661E-07
800
-7.55288E-07
800
-2.50926E-07
800
6.48728E-07
800
-9.14176E-07
800
-9.14956E-07
800
-2.87457E-07
800
-3.66799E-08
800
-1.62837E-07
800
-6.50573E-07
800
-2.28853E-07
800
-2.42241E-07
800
-8.70488E-08
800

145

136

Pb2*T + RTb*T- a) - ab = 0

1
10
19
28
37
46
55
64
73
82
91
100
109
118
127

e formula:

28.28427125

1414.213562 1856.805839

28.28427125

1442.497834 1856.805839

28.28427125

1470.782105 1856.805839

28.28427125

1499.066376 1856.805839

28.28427125

1527.350647 1856.805839

28.28427125

1555.634919 1856.805839

28.28427125

1583.91919 1856.805839

28.28427125

1612.203461 1856.805839

28.28427125

1640.487732 1856.805839

28.28427125

1668.772004 1856.805839

28.28427125

1697.056275 1856.805839

28.28427125

1725.340546 1856.805839

28.28427125

1753.624817 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.541249554
0.533120442
0.525241787
0.517602201
0.51019098
0.502998047
0.496013908
0.489229614
0.482636721
0.476227253
0.46999367
0.463928837
0.458026011
0.452278788
0.446681105
0.441227215
0.435911651
0.430729228
0.425675011
0.42074431
0.415932658
0.411235807
0.406649697
0.402170472
0.397794439
0.393518081
0.389338037
0.385251094
0.381254189
0.377344378
0.373518852
0.369774919
0.366110004
0.362521637
0.35900745
0.35556517

-4.06076E-07
-6.69582E-07
-6.43159E-07
-7.66824E-07
-5.004E-07
-1.65934E-07
-2.80403E-07
-7.12395E-07
-7.18126E-07
-6.01345E-07
-2.02988E-07
-8.00048E-07
-1.72124E-07
-8.15303E-08
-7.28172E-07
-2.14046E-07
-3.45365E-07
-1.60628E-07
-4.43601E-07
-3.94937E-07
-7.499E-07
-2.61835E-07
-9.13119E-07
-1.97221E-07
-2.57944E-07
-1.59371E-07
-2.63741E-07
-9.51291E-07
-2.74813E-07
-1.01647E-07
-6.23044E-08
-3.54074E-07
-6.03626E-07
-7.04664E-07
-1.94295E-07
-1.15402E-07

800 28.28427125

1781.909089 1856.805839

800 28.28427125

1810.19336 1856.805839

800 28.28427125

1838.477631 1856.805839

800 28.28427125

1866.761902 1856.805839

800 28.28427125

1895.046174 1856.805839

800 28.28427125

1923.330445 1856.805839

800 28.28427125

1951.614716 1856.805839

800 28.28427125

1979.898987 1856.805839

800 28.28427125

2008.183259 1856.805839

800 28.28427125

2036.46753 1856.805839

800 28.28427125

2064.751801 1856.805839

800 28.28427125

2093.036072 1856.805839

800 28.28427125

2121.320344 1856.805839

800 28.28427125

2149.604615 1856.805839

800 28.28427125

2177.888886 1856.805839

800 28.28427125

2206.173157 1856.805839

800 28.28427125

2234.457429 1856.805839

800 28.28427125

2262.7417 1856.805839

800 28.28427125

2291.025971 1856.805839

800 28.28427125

2319.310242 1856.805839

800 28.28427125

2347.594514 1856.805839

800 28.28427125

2375.878785 1856.805839

800 28.28427125

2404.163056 1856.805839

800 28.28427125

2432.447327 1856.805839

800 28.28427125

2460.731599 1856.805839

800 28.28427125

2489.01587 1856.805839

800 28.28427125

2517.300141 1856.805839

800 28.28427125

2545.584412 1856.805839

800 28.28427125

2573.868684 1856.805839

800 28.28427125

2602.152955 1856.805839

800 28.28427125

2630.437226 1856.805839

800 28.28427125

2658.721497 1856.805839

800 28.28427125

2687.005769 1856.805839

800 28.28427125

2715.29004 1856.805839

800 28.28427125

2743.574311 1856.805839

800 28.28427125

2771.858582 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.352192615
0.348887695
0.345648402
0.342472802
0.339359038
0.336305329
0.333309959
0.330371276
0.327487684
0.324657658
0.32187972
0.31915245
0.316474479
0.313844481
0.311261191
0.30872337
0.306229833
0.303779438
0.301371078
0.299003678
0.29667621
0.294387672
0.2921371
0.289923559
0.287746145
0.285603987
0.283496235
0.281422066
0.279380692
0.277371342
0.27539327
0.273445751
0.271528091
0.269639609
0.267779643
0.265947554

-2.98948E-07
-4.69564E-07
-2.96062E-07
-4.09684E-07
-9.06803E-07
-9.90247E-07
-7.40117E-07
-1.89177E-07
-5.07519E-07
-1.54625E-07
-2.91651E-07
-3.86724E-07
-1.2588E-07
-7.53935E-07
-1.36117E-07
-1.66154E-07
-6.64827E-07
-5.77305E-07
-2.37394E-08
-1.76837E-07
-1.0233E-07
-2.486E-07
-3.49628E-07
-3.92801E-07
-8.52615E-07
-3.54888E-07
-2.52263E-07
-6.94837E-07
-7.27509E-07
-5.63117E-07
-3.66062E-07
-8.54592E-07
-8.29313E-07
-2.61397E-07
-1.69424E-07
-3.42097E-07

800 28.28427125

2800.142853 1856.805839

800 28.28427125

2828.427125 1856.805839

800 28.28427125

2856.711396 1856.805839

800 28.28427125

2884.995667 1856.805839

800 28.28427125

2913.279938 1856.805839

800 28.28427125

2941.56421 1856.805839

800 28.28427125

2969.848481 1856.805839

800 28.28427125

2998.132752 1856.805839

800 28.28427125

3026.417023 1856.805839

800 28.28427125

3054.701295 1856.805839

800 28.28427125

3082.985566 1856.805839

800 28.28427125

3111.269837 1856.805839

800 28.28427125

3139.554108 1856.805839

800 28.28427125

3167.83838 1856.805839

800 28.28427125

3196.122651 1856.805839

800 28.28427125

3224.406922 1856.805839

800 28.28427125

3252.691193 1856.805839

800 28.28427125

3280.975465 1856.805839

800 28.28427125

3309.259736 1856.805839

800 28.28427125

3337.544007 1856.805839

800 28.28427125

3365.828278 1856.805839

800 28.28427125

3394.11255 1856.805839

800 28.28427125

3422.396821 1856.805839

800 28.28427125

3450.681092 1856.805839

800 28.28427125

3478.965363 1856.805839

800 28.28427125

3507.249635 1856.805839

800 28.28427125

3535.533906 1856.805839

800 28.28427125

3563.818177 1856.805839

800 28.28427125

3592.102448 1856.805839

800 28.28427125

3620.38672 1856.805839

800 28.28427125

3648.670991 1856.805839

800 28.28427125

3676.955262 1856.805839

800 28.28427125

3705.239533 1856.805839

800 28.28427125

3733.523805 1856.805839

800 28.28427125

3761.808076 1856.805839

800 28.28427125

3790.092347 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.264142725
0.262364553
0.260612455
0.258885861
0.257184222
0.255507
0.253853683
0.252223755
0.25061673
0.249032133
0.247469496
0.245928366
0.244408308
0.24290889
0.241429698
0.239970327
0.238530385
0.237109482
0.235707254
0.234323328
0.232957351
0.231608978
0.230277874
0.228963712
0.227666168
0.226384932
0.225119702
0.223870173
0.222636064
0.221417091
0.220212977
0.219023454
0.217848258
0.216687132
0.215539833
0.214406107

-3.89707E-07
-3.62471E-07
-3.08327E-07
-3.78228E-07
-4.33199E-07
-9.22377E-07
-3.0702E-07
-6.00656E-07
-8.38953E-07
-4.85205E-07
-3.85348E-07
-4.64471E-07
-1.98511E-07
-4.19408E-07
-5.51019E-07
-5.83024E-07
-3.50679E-07
-7.84818E-07
-2.59634E-07
-1.66403E-07
-4.23844E-07
-6.27456E-07
-7.42999E-07
-5.23101E-07
-5.5849E-07
-5.1899E-07
-1.82705E-07
-6.58691E-07
-7.80444E-07
-6.63151E-07
-4.70601E-07
-2.7619E-07
-3.82179E-07
-6.24289E-07
-2.084E-08
-1.75423E-07

800 28.28427125

3818.376618 1856.805839

800 28.28427125

3846.66089 1856.805839

800 28.28427125

3874.945161 1856.805839

800 28.28427125

3903.229432 1856.805839

800 28.28427125

3931.513703 1856.805839

800 28.28427125

3959.797975 1856.805839

800 28.28427125

3988.082246 1856.805839

800 28.28427125

4016.366517 1856.805839

800 28.28427125

4044.650788 1856.805839

800 28.28427125

4072.93506 1856.805839

800 28.28427125

4101.219331 1856.805839

800 28.28427125

4129.503602 1856.805839

800 28.28427125

4157.787873 1856.805839

800 28.28427125

4186.072145 1856.805839

800 28.28427125

4214.356416 1856.805839

800 28.28427125

4242.640687 1856.805839

800 28.28427125

4270.924958 1856.805839

800 28.28427125

4299.20923 1856.805839

800 28.28427125

4327.493501 1856.805839

800 28.28427125

4355.777772 1856.805839

800 28.28427125

4384.062043 1856.805839

800 28.28427125

4412.346315 1856.805839

800 28.28427125

4440.630586 1856.805839

800 28.28427125

4468.914857 1856.805839

800 28.28427125

4497.199128 1856.805839

800 28.28427125

4525.4834 1856.805839

800 28.28427125

4553.767671 1856.805839

800 28.28427125

4582.051942 1856.805839

800 28.28427125

4610.336213 1856.805839

800 28.28427125

4638.620485 1856.805839

800 28.28427125

4666.904756 1856.805839

800 28.28427125

4695.189027 1856.805839

800 28.28427125

4723.473298 1856.805839

800 28.28427125

4751.75757 1856.805839

800 28.28427125

4780.041841 1856.805839

800 28.28427125

4808.326112 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.213285718
0.212178436
0.211084033
0.210002287
0.20893298
0.2078759
0.206830835
0.205797589
0.20477596
0.203765753
0.202766779
0.201778855
0.200801798
0.199835432
0.198879575
0.19793407
0.196998745
0.196073433
0.195157981
0.194252231
0.193356033
0.192469231
0.191591682
0.190723241
0.189863775
0.189013134
0.188171197
0.18733782
0.186512878
0.185696251
0.184887804
0.18408742
0.18329498
0.182510366
0.181733466
0.180964162

-5.3158E-07
-7.43999E-07
-8.03001E-07
-7.7554E-07
-5.51285E-07
-1.98323E-07
-4.58858E-07
-2.72035E-07
-2.73721E-08
-2.11528E-07
-3.04712E-07
-2.92877E-07
-2.40061E-07
-1.5116E-08
-7.19272E-07
-5.34261E-07
-2.9303E-07
-6.68503E-07
-7.94208E-07
-6.81545E-07
-1.89591E-07
-3.31262E-07
-3.81405E-07
-6.67542E-07
-2.7666E-07
-8.41514E-07
-3.38875E-07
-6.08205E-07
-9.67185E-07
-3.28557E-07
-4.57993E-07
-5.8386E-07
-6.69819E-07
-6.58476E-07
-4.66025E-07
-6.57218E-07

800 28.28427125

4836.610383 1856.805839

800 28.28427125

4864.894655 1856.805839

800 28.28427125

4893.178926 1856.805839

800 28.28427125

4921.463197 1856.805839

800 28.28427125

4949.747468 1856.805839

800 28.28427125

4978.03174 1856.805839

800 28.28427125

5006.316011 1856.805839

800 28.28427125

5034.600282 1856.805839

800 28.28427125

5062.884553 1856.805839

800 28.28427125

5091.168825 1856.805839

800 28.28427125

5119.453096 1856.805839

800 28.28427125

5147.737367 1856.805839

800 28.28427125

5176.021638 1856.805839

800 28.28427125

5204.30591 1856.805839

800 28.28427125

5232.590181 1856.805839

800 28.28427125

5260.874452 1856.805839

800 28.28427125

5289.158723 1856.805839

800 28.28427125

5317.442995 1856.805839

800 28.28427125

5345.727266 1856.805839

800 28.28427125

5374.011537 1856.805839

800 28.28427125

5402.295808 1856.805839

800 28.28427125

5430.58008 1856.805839

800 28.28427125

5458.864351 1856.805839

800 28.28427125

5487.148622 1856.805839

800 28.28427125

5515.432893 1856.805839

800 28.28427125

5543.717165 1856.805839

800 28.28427125

5572.001436 1856.805839

800 28.28427125

5600.285707 1856.805839

800 28.28427125

5628.569978 1856.805839

800 28.28427125

5656.854249 1856.805839

800 28.28427125

5685.138521 1856.805839

800 28.28427125

5713.422792 1856.805839

800 28.28427125

5741.707063 1856.805839

800 28.28427125

5769.991334 1856.805839

800 28.28427125

5798.275606 1856.805839

800 28.28427125

5826.559877 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.180202347
0.179447916
0.178700758
0.177960766
0.177227846
0.176501891
0.175782802
0.175070494
0.174364859
0.173665812
0.172973256
0.172287103
0.171607271
0.170933665
0.170266204
0.169604804
0.168949391
0.168299872
0.167656174
0.167018225
0.166385938
0.165759244
0.165138069
0.164522341
0.16391199
0.163306947
0.162707137
0.162112508
0.161522976
0.16093848
0.160358965
0.159784357
0.159214605
0.158649639
0.158089401
0.157533841

-6.67086E-07
-2.49008E-07
-7.79764E-08
-3.90194E-07
-9.99666E-08
-3.18334E-07
-8.34732E-07
-2.18689E-07
-4.95801E-07
-1.43195E-07
-2.9563E-07
-5.67168E-07
-1.80355E-07
-3.28732E-07
-5.69972E-07
-9.46241E-07
-3.33984E-07
-4.99037E-07
-7.22001E-07
-1.63818E-07
-2.9111E-07
-4.47853E-07
-6.09806E-07
-7.30532E-07
-7.34791E-07
-5.11782E-07
-9.27206E-07
-2.04576E-08
-3.6101E-08
-4.403E-07
-1.07522E-07
-4.4803E-07
-1.02689E-07
-3.00902E-07
-7.45254E-07
-1.82053E-07

800 28.28427125

5854.844148 1856.805839

800 28.28427125

5883.128419 1856.805839

800 28.28427125

5911.412691 1856.805839

800 28.28427125

5939.696962 1856.805839

800 28.28427125

5967.981233 1856.805839

800 28.28427125

5996.265504 1856.805839

800 28.28427125

6024.549776 1856.805839

800 28.28427125

6052.834047 1856.805839

800 28.28427125

6081.118318 1856.805839

800 28.28427125

6109.402589 1856.805839

800 28.28427125

6137.686861 1856.805839

800 28.28427125

6165.971132 1856.805839

800 28.28427125

6194.255403 1856.805839

800 28.28427125

6222.539674 1856.805839

800 28.28427125

6250.823946 1856.805839

800 28.28427125

6279.108217 1856.805839

800 28.28427125

6307.392488 1856.805839

800 28.28427125

6335.676759 1856.805839

800 28.28427125

6363.961031 1856.805839

800 28.28427125

6392.245302 1856.805839

800 28.28427125

6420.529573 1856.805839

800 28.28427125

6448.813844 1856.805839

800 28.28427125

6477.098116 1856.805839

800 28.28427125

6505.382387 1856.805839

800 28.28427125

6533.666658 1856.805839

800 28.28427125

6561.950929 1856.805839

800 28.28427125

6590.235201 1856.805839

800 28.28427125

6618.519472 1856.805839

800 28.28427125

6646.803743 1856.805839

800 28.28427125

6675.088014 1856.805839

800 28.28427125

6703.372286 1856.805839

800 28.28427125

6731.656557 1856.805839

800 28.28427125

6759.940828 1856.805839

800 28.28427125

6788.225099 1856.805839

800 28.28427125

6816.509371 1856.805839

800 28.28427125

6844.793642 1856.805839

0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101
0.1101

0.156982889
0.156436492
0.155894603
0.155357153
0.154824093
0.154295378
0.153770943
0.153250741

-3.98932E-07
-7.99818E-07
-2.18683E-07
-4.12975E-07
-7.36463E-07
-2.24201E-07
-3.86158E-07
-6.38337E-07

800 28.28427125

6873.077913 1856.805839

800 28.28427125

6901.362184 1856.805839

800 28.28427125

6929.646456 1856.805839

800 28.28427125

6957.930727 1856.805839

800 28.28427125

6986.214998 1856.805839

800 28.28427125

7014.499269 1856.805839

800 28.28427125

7042.783541 1856.805839

800 28.28427125

7071.067812 1856.805839

P vs. Vm at 800 k

at 400K
1.5
1
0.5
0

199

190

181

172

163

154

145

25
0
24
9
24
8
24
7

C
44.78723983
44.8062132
44.82518657
44.84415994
44.86313331
44.88210669
44.90108006
44.92005343
44.9390268
44.95800017
44.97697355
44.99594692
45.01492029

Vm
derived formula
1.336695861
-5.51777E-08
1.310953966
3.9271E-07
1.286202233
1.27127E-07
1.262384614
9.76957E-07
1.239449215
-4.71639E-07
1.217347914
-1.13825E-07
1.196036026
-7.87254E-07
1.175472005
-4.21859E-07
1.155617167
-7.92543E-07
1.136435451
-4.18249E-07
1.117893201
-2.1339E-07
1.099958968
4.15644E-07
1.082603331
-2.27596E-07

45.03389366
45.05286703
45.07184041
45.09081378
45.10978715
45.12876052
45.14773389
45.16670727
45.18568064
45.20465401
45.22362738
45.24260075
45.26157413
45.2805475
45.29952087
45.31849424
45.33746761
45.35644099
45.37541436
45.39438773
45.4133611
45.43233447
45.45130785
45.47028122
45.48925459
45.50822796
45.52720133
45.54617471
45.56514808
45.58412145
45.60309482
45.62206819
45.64104157
45.66001494
45.67898831
45.69796168

1.065798739
1.04951936
1.033740955
1.01844075
1.003597335
0.989190556
0.975201429
0.961612055
0.948405542
0.935565938
0.923078164
0.910927957
0.899101814
0.887586942
0.876371215
0.865443126
0.854791752
0.844406716
0.834278155
0.824396684
0.814753372
0.805339714
0.796147604
0.787169313
0.778397469
0.769825033
0.761445283
0.753251797
0.745238434
0.737399319
0.729728833
0.722221594
0.714872444
0.707676446
0.700628862
0.693725147

-1.14073E-07
-5.32104E-07
-3.96446E-07
-4.11145E-07
-2.44102E-08
-2.24585E-07
-1.4761E-07
-2.42632E-07
-3.99784E-07
-6.53067E-08
-4.83707E-07
-6.35421E-07
-8.02497E-07
-5.04643E-07
-2.22447E-07
-3.26323E-07
-9.73391E-07
-5.72515E-07
-1.5026E-07
-2.17733E-07
-5.5008E-07
-5.74192E-07
-4.21628E-08
-6.66342E-08
-1.1066E-07
-3.56373E-07
-3.56747E-07
-5.83503E-07
-3.36478E-07
-3.94979E-07
-2.33126E-07
-2.05221E-07
-5.54802E-07
-1.11219E-07
-1.63658E-07
-9.75828E-07

45.71693505
45.73590843
45.7548818
45.77385517
45.79282854
45.81180191
45.83077529
45.84974866
45.86872203
45.8876954
45.90666877
45.92564215
45.94461552
45.96358889
45.98256226
46.00153563
46.02050901
46.03948238
46.05845575
46.07742912
46.09640249
46.11537587
46.13434924
46.15332261
46.17229598
46.19126935
46.21024273
46.2292161
46.24818947
46.26716284
46.28613621
46.30510959
46.32408296
46.34305633
46.3620297
46.38100307

0.686960944
0.680332066
0.673834493
0.667464364
0.661217966
0.65509173
0.649082224
0.643186142
0.637400305
0.631721651
0.626147229
0.620674197
0.615299814
0.610021438
0.60483652
0.5997426
0.594737304
0.58981834
0.584983496
0.580230631
0.575557679
0.570962643
0.56644359
0.56199865
0.557626019
0.553323945
0.549090736
0.54492475
0.540824401
0.53678815
0.532814506
0.528902025
0.525049306
0.521254989
0.517517759
0.513836336

-5.49553E-07
-6.32857E-07
-3.05619E-07
-1.0358E-07
-1.85373E-07
-8.08872E-07
-2.42156E-07
-4.26383E-07
-4.47948E-07
-3.5938E-07
-2.67985E-07
-1.34756E-07
-7.60073E-08
-9.60095E-07
-1.29032E-07
-4.53264E-08
-4.79338E-07
-8.32336E-07
-3.16173E-07
-5.8533E-07
-2.23186E-07
-4.13523E-07
-2.09127E-07
-8.04573E-07
-8.47271E-07
-4.55703E-07
-2.23431E-07
-9.47659E-07
-4.33473E-07
-8.43828E-07
-6.96825E-07
-4.58493E-07
-2.79314E-07
-1.65539E-07
-5.34712E-07
-1.76732E-07

46.39997645
46.41894982
46.43792319
46.45689656
46.47586993
46.49484331
46.51381668
46.53279005
46.55176342
46.57073679
46.58971017
46.60868354
46.62765691
46.64663028
46.66560365
46.68457703
46.7035504
46.72252377
46.74149714
46.76047051
46.77944389
46.79841726
46.81739063
46.836364
46.85533737
46.87431075
46.89328412
46.91225749
46.93123086
46.95020423
46.96917761
46.98815098
47.00712435
47.02609772
47.04507109
47.06404447

0.510209481
0.506635989
0.503114694
0.499644458
0.496224181
0.492852791
0.489529249
0.486252544
0.483021692
0.479835739
0.476693756
0.473594839
0.470538108
0.467522711
0.464547811
0.461612603
0.458716295
0.45585812
0.45303733
0.450253198
0.447505013
0.444792084
0.442113738
0.439469318
0.436858182
0.434279709
0.431733288
0.429218326
0.426734245
0.424280479
0.421856476
0.419461699
0.417095624
0.414757736
0.412447537
0.410164537

-1.27056E-07
-6.27993E-07
-1.98001E-07
-1.88589E-07
-2.67268E-08
-5.95074E-07
-1.27354E-07
-1.75343E-07
-1.46084E-07
-8.61477E-07
-4.72447E-07
-2.61264E-07
-7.77144E-07
-6.51957E-08
-9.40073E-07
-4.45827E-07
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t 800 k

A.
Assume 100g of mixture:
Molecular weight:

MW NH3
17.04

MW N2
28.02

MW H2
2.02

P (atm)
270

NH3
25
17.04
T (K)
550

N2
18.75
28.02

H2
56.25
2.02

R
SV NH3
0.08206 0.00981

SV N2
SV H2
0.005966 0.082752

## The formula used are

Pressure*MW
Density = _______________
Gas Constant*Temperature

## Specific Volume is the inverse of density

Specific Volume =

## B. Redlich-Kwong equation of state

where:
R=0.08206 Latm/molK)
P=pressure(atm)
T=temperature(K)
Vm=molar volume (V/n)

P (atm)
270

T (K)
550

R
0.08206

pc
111.3

Tc
a
b
405.5 85.64088 0.025903

Consider a mixture of 25% ammonia, the rest nitrogen and hydrogen in a 1:3 ra
the specific volume using:
a. ideal gas law
b. Redlich-Kwong equation of state
c. soave-redlich-kwong equation of state
Total SV
0.098528

Where did you get the data you needed? How do the three answers compare? Is th

## ume is the inverse of density

Gas Constant*Temperature
_____________________
Pressure * MW

## a=constant that corrects for attractive potential of molecules

b=a constant that corrects for volume
Tc= critical temperature
Pc=critical pressure

ogen and hydrogen in a 1:3 ratio. The gas is at 270 atm and 550K. Compute