WO2014053401A2

(43) International Publication Date (12) INTERNATIONAL APPLICATION PUBL (19) World Intellectual Property Orgai International Bureau Z = 10 April 2014 (10.04.2014) SHED UNDER TH p PATE! ‘T COOPERATION TREATY (PCT) ANOKA TA (10) International Publication Number WO 2014/053401 A2 WIPO|PCT 61) en @ es, 26) G0) am International Patent Classification ADIN 43/56 (2006.01) International Application Number: Per 0131070154 al Filing Date: 27 September 2013 ( 09.2013) Filing Language: English Publication Language: Pnelish Priority Data: 61/708,059 1 October 2012(01.10.2012) us 617708061 1 October 2012 (01.10.2012) us 61/708,066 1 October 2012(01.10 2012) us 61/708,067 1 October 2012 (01.10.2012) us 6U708071 1 October 2012(01.10.2012) us GU/729.387 22 November 2012 (22.11.2012) us 61/763,965 13 February 2013 (13.02.2013) us 61/763,966 pruary 2013 (13.02.2013) us 61/763,970 rary 2013 (13.02.2013) us 61/763,974 pruary 2013 (13.02.2013) us 61/763,978 13 February 2013 (13.02.2013) us 61/764,083 ruary 2013 (13.02.2013) Us. 6767831 pruary 2013 (22.02.2013) us Applicant IDEDE| 67056 Ludwigshafen (By ms sn) (72) Inventors: KORBER, Karsten; Hintere Lisgewann 26, 69214 Eppelheim (DE). WACH, Jean-Yves; Kirchen- strale 5, 68159 Manaheim (DE). KAISER, Flor Spelzenstr. 9, 68167 Mannheim (DE). POHLMAN, Mat- thias; Am Langenstein 13, 67251 Freinsbeim (DE), DESHMUKH, Prashant; Meerfeldst. 62, 68163 Man sheim (DE), CULBERTSON, Deborah L.: 6400 Vintage Ridge Lane, Fuquay Varina, NC 27526 (US). ROGI \W. David; 2804 Ashland Drive, Durham, NC 27705 (US), GUNIIMA, Koshi; Heighths Tskara-3 205, 97Shirskawe: cho, Toyohashi-ity, Aichi Prefecture 441-8021. OP). DAVID, Michael; 5913 Greenevers Drive, Raleigh, NC 027613 (US). BRAUN, Franz Josef; 3602 Long Ridge Road, Durham, NC 27703 (US), Common Representative: BASF SE; shafen (DE), Designated States (unless otherwise Indicated, for every lind of national protection available): AB, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA; CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, FE, EG, BS, Fl, GB, GD, GP, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KN, KP, KR 57086 Ludwig. KZ, LA, LG, LK, LR, LS, LT, LU, LY, MA, MD, ME MG, MK, MN, MW, MX, TY, MZ, NA, NG, NI, NO, NZ, "QA, RO, RS, RU, RW, SA, SY, TH, TJ, TM, {Continued on newt page) a =< Ss = oe & s + Ss a g (87) Abstract: The present invention relates to methods of improving plant health, and to meth ds for reducing nitrous oxide emission from soils, using authranilamide compounds of for nul (I, wherein R!, B®, RF, RS, RP, RY, RY and ae as defined in the description; and their mixtures and compositions.WO 2014/053401 A2 MINIM HKD 0 ACTA ‘TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, aw SM, TR), OAPI (BE, BI, CR, CG, Cl, CM, GA, GN, GO, (84) Designated States (unless orherise indicated, for every ON» KM ML MR, NF, SN, TD. TG). ind of regional protection available): ARIPO (BW, GH, Published: , LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, | ZM, ZW), Furasian (AM, AZ, BY, KG, KZ, RU, TI, suropean (AL, AT, BE, BG, CH, CY, CZ, DE, DK, BE, BS, Fl, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, without international search report and to be republished ‘upon rece'pt of that report (Rule 48.2(a))10 15 20 25 30 2013/070154 Wo 2014/053401 1 PCr Method of improving plant health Description The present invention relates to a composition comprising an anthranilamide compound of formula (|), the use of this composition for improving plant health and a method for improving plant health by treating a plant, its propagules or the locus where the plant is growing or is to grow with the above composition. The invention relates to to the use of the compounds of formula (|) itself and their stereoisomers, salts, tautomers or N-oxides, especially their salts, and their mixtures, for increasing the health of plants, for increasing the yield, the resistance against fungi or animal pests or external factors like heat, cold or drought, and for increasing the quality of the crops and other parameters. This also includes the use or method of reducing nitrous oxide emission from soils. In crop protection, there is a continuous need for compositions that improve the health of plants, Healthier plants are desirable since they result in better crop yields andlor a better quality of the plants or crops. Healthier plants also better resist to biotic and/or abiotic stress. A high resistance against biotic stresses in tum allows the person skilled in the art to reduce the quantity of pesticides applied and consequently to slow down the development of resistances against the respective pesticides. twas therefore an object of the present invention to provide a pesticidal composition which solves the problems outlined above. In particular, the composition should improve plant health. The present invention is based on the surprising finding that a compound selected from the chemical class of N-thio-anthranilamides can be successfully used to improve plant health. Thus in the first aspect of the invention there is provided a method of improving plant health, which method comprises applying at least one pesticidally active anthranilamide compound of formula (I): @ Sse a” SO), wherein R'is selected from the group consisting of halogen, methyl and halomethyl;,10 15 20 25 30 35 40 WO 2014/053401 2 PCT/EP2013/070154 R? R! R®is selected from the group consisting of hydrogen, halogen, halomethyl and cyano; is selected from hydrogen, Ci-Ce alkyl, C1-Ce haloalkyl, Cz-Ce-alkenyl, CoCo- haloalkenyl, Cx-Cs-alkinyl, Cz-Ce-haloalkinyl, Cs-Cs-cycloalkyl, Cx-Cs-halocycloalky!, C1-Ce-alkoxy-Ci-Cyalkyl, Cr-Cs-haloalkoxy-C-Cx-alkyl, C(=O)R®, C(=O)OR? and C(=O)NR°R is hydrogen or halogen; R®, R® are selected independently of one another from the group consisting of hydrogen, R? Re Ci-Cro-alkyl, Cs-Co-cycloalkyl, CzCro-alkenyl, Cz-Crc-alkynyl, wherein the aforementioned aliphatic and cycloaliphatic radicals may be substituted with 1 to 10 substituents R®, and phenyl, which is unsubstituted or carries 1 to 5 substituents R’; or Rand R® together represent a C2-Cr-alkylene, Cz-Cr-alkenylene or Co-Ce-alkynylene chain forming together with the sulfur atom to which they are attached a 3-, 4-, 5-, 6-,7-, 8, 9- or 10-membered saturated, partially unsaturated or fully unsaturated ring, wherein 1 to 4 of the CH. groups in the Cz-Cr-alkylene chain or 1 to 4 of any of the CHz or CH groups in the CCr-alkenylene chain or 1 to 4 of any of the CHe groups in the Cs-Ce-alkynylene chain may be replaced by 1 to 4 groups independently selected from the group consisting of C=O, C=S, O, S, N, NO, SO, $O2 and NH, and wherein the carbon and/or nitrogen atoms in the Co- Cralkylene, C-Cr-alkenylene or Cs-Ceralkynylene chain may be substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, Ci-Cevalkyl, C1-Ce-haloalkyl, Ci-Ce-alkoxy, Cr-Ce-haloalkoxy, C1-Ce-alkylthio, Cr-Ce-haloalkylthio, Cs-Cs-cycloalkyl, Ca-Cs-halocycloalkyl, CzCe-alkenyl, C-Ce- haloalkenyl, Co-Ce-alkynyl and C2-Ce-haloalkynyl; said substituents being identical or different from one another if more than one substituent is present; is selected from the group consisting of bromo, chloro, difluoromethyl, trifluoromethyl, nitro, cyano, OCHs, OCHF2, OCH2F, OCH.CFs, S(=O).CHs, and S(=O).CFs; is selected from the group consisting of C1-Ce-alkyl, CxCe-alkenyl, Cz-Ce-alkinyl, Cor Ce-cycloalkyl, Ci-Ce-alkoxy, Cr-Ce-alkyithio, Ci-Ce-alkylsulfinyl, Ci-Cs-alkylsulfonyl, wherein one or more CH2 groups of the aforementioned radicals may be replaced by a C=O group, andlor the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 substituents selected from C1-Cx alkoxy; phenyl, benzyl, pyridyl and phenoxy, wherein the last four radicals may be unsubstituted, partially or fully halogenated and/or carry 1, 2 or 3 substituents selected from C1-Ce-alkyl, Cr-Ce-haloalkyl, C1-Cs-alkoxy, C1-Ce-haloalkoxy, (C1-Ce-alkoxy)carbonyl, C1-Ce-alkylamino and di(C1-Ce-alkyl)amino,10 15 20 25 30 35 40 Wo 20147053401 3 Pcl Re Re 2013/070154 is selected from the group consisting of C1-Ce-alkyl, C-Ceralkenyl, Co-Ce-alkinyl, Cx- Ce-cycloalkyl, C1-Ce-alkoxy, C1-Ce-alkylthio, C1-Cs-alkyisulfinyl, C1-Ce-alkylsulfonyl, wherein one or more CHe groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 substituents selected from C:-Ce-alkoxy; phenyl, benzyl, pyridyl and phenoxy, wherein the last four radicals may be unsubstituted, partially or fully halogenated and/or carry 1, 2 or 3 substituents selected from Cr-Ce-alkyl, Cr-Cs-haloalkyl, C1-Ce-alkoxy, C1-Ce-haloalkoxy and (C1-Ce- alkoxy)carbonyl; Ré are, independently from one another and independently of each occurrence, selected from the group consisting of hydrogen, cyano, Ci-Ce-alkyl, Co-Cs-alkenyl, Co- Ce-alkinyl, Cs-Cs-cycloalkyl, wherein one or more CHe groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 radicals selected from C1-C-alkoxy; Ci-Ce-alkoxy, Ci-Ce-haloalkoxy, Ci-Ce-alkylthio, C:-Ce-alkylsutfinyl, Ci-Co- alkylsulfonyl, C1-Ce-haloalkylthio, phenyl, benzyl, pyridyl and phenoxy, wherein the four last mentioned radicals may be unsubstituted, partially or fully halogenated and/or carry 1, 2 or 3 substituents selected from Ci-Ce-alkyl, C1-Ce-haloalkyl, C1-Ce- alkoxy, C1-Cs haloalkoxy and (C1-Cs-alkoxy}oarbonyl; or Re and Ré, together with the nitrogen atom to which they are bound, may form a 3-, 4-, 5-, 6- or 7-membered saturated, partially unsaturated or fully unsaturated hetero- cyclic ring which may additionally contain 1 or 2 further heteroatoms or heteroatom groups selected from N, O, S, NO, SO and SOz, as ring members, where the heter- ocyclic ring may optionally be substituted with halogen, C:-C.rhaloalkyl, C1-Ca- alkoxy or C1-Ci-haloalkoxy; is independently selected from the group consisting of halogen, cyano, nitro, -OH, - SH, -SCN, Ci-Ce-alkyl, Co-Ce-alkenyl, CrCe-alkinyl, Cs-Ca-cycloalkyl, wherein one or more CHe groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 radicals selected from C1-Cs alkoxy; Ci-Ce-alkoxy, Ci-Ce-haloalkoxy, C-Ce-alkylthio, C:-Ce-alkylsutfinyl, Ci-Co- alkylsulfonyl, C1-Ce-haloalkylthio, -OR®, -NR°R®, -S(O)sR*, -S(O)sNR°RY, -C(=O)R®, -C(=O)NR&R®, -C(=O)OR?, -C(=S)R*, -C(=S)NR°R*, -C(=S)OR?, -C(=S)SR°, -C(=NR®)R°, -C(=NR®)NR°R¥, phenyl, benzyl, pyridyl and phenoxy, wherein the last four radicals may be unsubstituted, partially or fully halogenated and/or carry 1, 2 or 3 substituents selected from C1-Ce-alkyl, Cr-Ce-haloalkyl, Cr-Cs- alkoxy and C1-Cs-haloalkoxy; or two vicinal radicals R® together form a group =O, =CH(C1-Cr-alky!) alkyl)C1-Ce-alkyl, =N(C1-Cevalkyl) or =NO(C1-Ce-alkyl); =C(Cr-Cx-10 15 20 25 30 35 40 WoO 2014/053401 4 PCI 2013/070154 R'__ is independently selected from the group consisting of halogen, cyano, nitro, -OH, - SH, -SCN, C1-Ce-alkyl, Cx-Ce-alkenyl, CxCe-alkinyl, Cs-Ca-cycloalkyl, wherein one or more CHe groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 radicals selected from C1-Cs alkoxy; C1-Ce-alkoxy, C1-Cs-haloalkoxy, C1-Ce-alkylthio, C:-Ce-alkylsulfinyl, C1-Ce- alkylsulfonyl, C1-Cs-haloalkylthio, -OR2, -NRR, -S(O)sR®, -S(O),NR°R4, -C(=O)R®, -C(=O)NR®R®, -C(=O)OR®, -C(=S)R*, -C(=S)NR°R’, -C(=S)OR?, -C(=S)SR®, -C(=NR°)R°, and -C(=NR°)NRRs, k — isOort; nis 0, 10r2; or a stereoisomer, salt, tautomer or N-oxide, or a polymorphic crystalline form, a co-crystal or a solvate of a compound or a stereoisomer, salt, tautomer or N-oxide thereof. Accordingly, the present invention relates to the use of a compound of formula (|) as defined herein, or a stereoisomer, salt, tautomer or N-oxide thereof, or a composition comprising it, for improving the plant health of at least one plant variety. ‘Compounds of formula I WO 2007/006670, describes N-thio-anthranilamide compounds with a sulfilimine or sulfoximine group and their use as pesticides. PCT/EP2012/065650, PCT/EP2012/065651, and the un- published applications US 61/578267, US 61/593897 and US 61/651050 describe certain N- Thio-anthranilamide compounds and their use as pesticides. PCTIEP2012/065648, PCT/EP2012/065649 and EP11189973.8 describe processes for the synthesis of N-Thio-anthranilamide compounds. However, although the anthranilamide compounds of formula (|) themselves and their combined application with other insecticides are known to have shown activity against certain crop damag- ing insect pests, the compounds of formula | and some of their selected mixtures with pesticidally active compounds (I!) have not yet been described for solving discussed problems as mentioned above. The compounds of formula | as well as the terms "compounds for methods according to the (present) invention”, "compounds according to the (present) invention" or "compounds of formu- ta (1)" or “compound(s) II", which all compound(s) are applied in methods and uses according to the present invention comprise the compound(s) as defined herein as well as a known stereoi- ‘somer, salt, tautomer or N-oxide thereof.10 15 20 25 30 35 40 Wo 2014/053401 5 rer 2013/070154 The term "composition(s) according to the invention" or "composition(s) of the present invention’ ‘encompasses composition(s) comprising at least one compound of formula | or mixtures of the ‘compounds of formula | with other pesticidally active compound(s) II for being used and/or applied in methods according to the invention as defined above. Depending on the substitution pattern, the compounds of the formula (I) may have one or more centers of chirality, in which case they are present as mixtures of enantiomers or diastereomers. The invention provides both the pure enantiomers or pure diastereomers of the compounds of formula (I), and their mixtures and the use according to the invention of the pure enantiomers or pure diastereomers of the compound of formula (I) or its mixtures. Suitable compounds of the formula (|) also include all possible geometrical stereoisomers (cis/trans isomers) and mixtures thereof. Cis/trans isomers may be present with respect to an alkene, carbon-nitrogen double- bond, nitrogen-sulfur double bond or amide group. The term "stereoisomer(s)" encompasses both optical isomers, such as enantiomers or diastereomers, the latter existing due to more than ‘one center of chirality in the molecule, as well as geometrical isomers (cis/trans isomers). Salts of the compounds of the present invention are preferably agriculturally and veterinarily acceptable salts. They can be formed ina customary method, e.g. by reacting the compound with an acid if the compound of the present invention has a basic functionality or by reacting the ‘compound with a suitable base if the compound of the present invention has an acidic functionality. In general, suitable “agriculturally useful salts” or “agriculturally acceptable salts" are especially the salts of those cations or the acid addition salts of those acids whose cations and anions, respectively, do not have any adverse effect on the action of the compounds according to the present invention. Suitable cations are in particular the ions of the alkali metals, preferably lithi- um, sodium and potassium, of the alkaline earth metals, preferably calcium, magnesium and barium, and of the transition metals, preferably manganese, copper, zinc and iron, and also ammonium (NHs*) and substituted ammonium in which one to four of the hydrogen atoms are replaced by Cr-Ce-alkyl, C1-C-hydroxyalkyl, C1-Ci-alkoxy, Cr-Cr-alkoxy-Cr-Ce-alkyl, hydroxy-Ci- Ce-alkoxy-C1-Cralkyl, phenyl or benzyl. Examples of substituted ammonium ions comprise me- thylammonium, isopropylammonium, dimethylammonium, diisopropylammonium, trime- thylammonium, tetramethylammonium, tetraethylammonium, tetrabutylammonium, 2- hydroxyethylammonium, 2-(2-hydroxyethoxy)ethykammonium, bis(2-hydroxyethyl)ammonium, benzyltrimethylammonium and benzyltriethylammonium, furthermore phosphonium ions, sul fonium ions, preferably tri(C1-C.-alkyl)sulfonium, and sulfoxonium ions, preferably tri(Ci-Ce- alky!)sulfoxonium, ‘Anions of useful acid addition salts are primarily chloride, bromide, fluoride, hydrogen sulfate, sulfate, dihydrogen phosphate, hydrogen phosphate, phosphate, nitrate, hydrogen carbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and the anions of C1-Cr-alkanoic acids, preferably formate, acetate, propionate and butyrate. They can be formed by reacting the ‘compounds of the formulae | with an acid of the corresponding anion, preferably of hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid. The compounds of the formula (I) may be present in the form of their N-oxides. The term “N-10 15 20 25 30 35 40 Wo 2014/053401 6 rer 20131070154 oxide” includes any compound of the present invention which has at least one tertiary nitrogen atom that is oxidized to an N-oxide moiety. N-oxides of compounds (|) can in particular be prepared by oxidizing the ring nitrogen atom(s) of the pyridine ring and/or the pyrazole ring with a suitable oxidizing agent, such as peroxo carboxylic acids or other peroxides. The person skilled in the art knows if and in which positions compounds of the formula (|) of the present invention may form N-oxides. ‘The compounds of the present invention may be amorphous or may exist in one ore more different crystalline states (polymorphs) which may have different macroscopic properties such as stability or show different biological properties such as activities. The present invention includes both amorphous and crystalline compounds of formula (|), their enantiomers or diastereomers, mixtures of different crystalline states of the respective compound of formula (I), its enantiomers or diastereomers, as well as amorphous or crystalline salts thereof. The term "co-crystal" denotes a complex of the compounds according to the invention or a stereoisomer, salt, tautomer or N-oxide thereof, with one or more other molecules (preferably one molecule type), wherein usually the ratio of the compound according to the invention and the other molecule is a stoichiomettic ratio. The term "solvate" denotes a co-complex of the compounds according to the invention, or a stereoisomer, salt, tautomer or N-oxide thereof, with solvent molecules. The solvent is usually liquid. Examples of solvents are methanol, ethanol, toluol, xylol. A preferred solvent which forms solvates is water, which solvates are referred to as “hydrates”. A solvate or hydrate is usually characterized by the presence of a fixed number of n molecules solvent per m molecules compound according to the invention The organic moieties mentioned in the above definitions of the variables are - like the term hal- ‘gen - collective terms for individual listings of the individual group members. The prefix Ci-Cm indicates in each case the possible number of carbon atoms in the group. The term halogen denotes in each case fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine. The term “partially or fully halogenated” will be taken to mean that 1 or more, €.. 1, 2, 3, 4 or 5 or all of the hydrogen atoms of a given radical have been replaced by a halogen atom, in particular by fluorine or chlorine. A partially or fully halogenated radical is termed below also "halo- radical’. For example, partially or fully halogenated alkyl is also termed haloalkyl. The term "alkyl" as used herein (and in the alkyl moieties of other groups comprising an alkyl group, e.g. alkoxy, alkylcarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl and alkoxyalkyl) denotes in each case a straight-chain or branched alkyl group having usually from 1 to 12 or 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms and in particular from 1 to 3 carbon atoms. Examples of C1-Cr-alkyl are methyl, ethyl, n-propyl, isopropyl, n-butyl, 2-butyl (sec-butyl), isobutyl and tert-butyl. Examples for C1-Cs-alkyl are, apart those mentioned for C1-Cx-alkyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, ‘Lethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2- dimethylbutyl, 2,3-dimethylbuty|, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-10 15 20 25 30 35 40 WoO 2014/053401 7 PCI 20131070154 trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl. Exam- ples for C1-Cic-alkyl are, apart those mentioned for C1-Cs-alkyl, n-heptyl, 1-methylhexyl, 2- methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl, 1-ethylpentyl, 2-ethylpentyl, 3- ethylpentyl, n-octyl, 1-methyloctyl, 2-methylheptyl, 1-ethylhexyl, 2-ethylhexyl, 1,2-dimethylhexyl, ‘-propylpentyl, 2-propylpentyl, nonyl, decyl, 2-propylhepty! and 3-propylhepty/ The term "alkylene" (or alkanediyl) as used herein in each case denotes an alkyl radical as defined above, wherein one hydrogen atom at any position of the carbon backbone is replaced by ‘one further binding site, thus forming a bivalent moiety. The term “haloalkyl” as used herein (and in the haloalkyl moieties of other groups comprising a haloalkyl group, e.g. haloalkoxy, haloalkylthio, haloalkyicarbonyl, haloalkyisulfonyl and haloal- kylsulfinyl) denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms ("C1-Cio-haloalkyl"), frequently from 1 to 6 carbon atoms ("C1-Ce-haloalky!"), more frequently 1 to 4 carbon atoms ("Ci-Cio-haloalkyl"), wherein the hydrogen atoms of this group are partially or totally replaced with halogen atoms. Preferred haloalkyl moieties are selected from C1-Ci-haloalkyl, more preferably from C:-Co-haloalkyl, more preferably from halomethyl, in particular from C1-Czfluoroalkyl. Halomethyl is methyl in which 1, 2 or 3 of the hydrogen atoms are replaced by halogen atoms. Examples are bromomethyl, chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl and the like. Examples for C1-Crfluoroalkyl are fluoromethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, and the like. Examples for C:-C2-haloalkyl are, apart those mentioned for C1- C-fluoroalkyl, chloromethyl, dichloromethyl, trichloromethyl, bromomethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifiuoromethyl, 1-chloroethyl, 2-chloroethyl, 2,2,-dichloroethyl, 2,2,2- trichloroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 1- bromoethyl, and the like. Examples for C1-C.-haloalkyl are, apart those mentioned for Ci-C= haloalkyl, 1-fluoropropyl, 2-fluoropropyl, 3-fluoropropyl, 3,3-difluoropropyl, 3,3,3-trifluoropropyl, heptafluoropropyl, 1,1,1-triluoroprop-2-y1, 3-chloropropyl, 4-chlorobutyl and the like. The term "cycloalkyl" as used herein (and in the cycloalkyl moieties of other groups comprising a cycloalkyl group, e.g. cycloalkoxy and cycloalkylalkyl) denotes in each case a mono- or bicyclic cycloaliphatic radical having usually from 3 to 10 carbon atoms ("Cx-Cic-oycloalkyl"), preferably 3 to 8 carbon atoms ("Ca-Cs-cycloalky!") or in particular 3 to 6 carbon atoms ("Cs-Ce~ cycloalkyl"). Examples of monocyclic radicals having 3 to 6 carbon atoms comprise cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. Examples of monocyclic radicals having 3 to 8 carbon atoms comprise cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl. Ex- amples of bicyclic radicals having 7 or 8 carbon atoms comprise bicyclof2.1.1]hexyl, bicy- clof2.2. tJheptyl, bicyclo[3.1.1}heptyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2}octyl and bicy- olo[3.2. 1Joctyl. The term "cycloalkylene” (or cycloalkanediyl) as used herein in each case denotes an cycloalkyl radical as defined above, wherein one hydrogen atom at any position of the carbon backbone is replaced by one further binding site, thus forming a bivalent moiety. The term "halocycloalkyl" as used herein (and in the halocycloalkyl moieties of other groups ‘comprising an halocycloalkyl group, e.g. halocycloalkyimethyl) denotes in each case a mono- or bicyclic cycloaliphatic radical having usually from 3 to 10 carbon atoms, preferably 3 to 8 carbon atoms or in particular 3 to 6 carbon atoms, wherein at least one, ¢.g. 1, 2, 3, 4 oF 5 of the hydro-10 15 20 25 30 35 40 Wo 20147053401 8 Pcl 2013/070154 gen atoms are replaced by halogen, in particular by fluorine or chlorine. Examples are 1- and 2- fluorocyclopropyl, 1,2-, 2,2- and 2,3-difluorocyclopropyl, 1,2,2-trifluorocyclopropyl, 2,2,3,3- tetrafiuorocyclpropyl, 1- and 2-chlorocyclopropyl, 1,2-, 2,2- and 2,3-dichlorocyclopropyl, 1,2,2- trichlorocyclopropyl, 2,2,3,3+tetrachlorocyclpropyl, 1-,2- and 3-fluorocyclopentyl, 1,2-, 2,2-, 2, 3,3-, 3,4+, 2,5-difluorocyclopentyl, 1-,2- and 3-chlorocyclopentyl, 1,2-, 2,2-, 2,3+, 3,3-, 3.4, 2,5- dichlorocyclopentyl and the like. The term "cycloalky!-alky!" used herein denotes a cycloalkyl group, as defined above, which is bound to the remainder of the molecule via an alkylene group. The term "Cs-Ca-cycloalkylCi- Crealkyl" refers to a Ca-Ce-cycloalkyl group as defined above which is bound to the remainder of the molecule via a C1-C-alkyl group, as defined above. Examples are cyclopropyimethyl, cyclopropylethyl, cyclopropylpropyl, cyclobutylmethyl, cyclobutylethyl, cyclobutylpropyl, cyclopentylmethyl, cyclopentylethyl, cyclopentylpropyl, cyclohexylmethyl, cyclohexylethyl, cyclohexylpro- pyl, and the like. The term "alkenyl" as used herein denotes in each case a monounsaturated straight-chain or branched hydrocarbon radical having usually 2 to 10 ("C2-Cro-alkeny!"), preferably 2 to 6 carbon atoms ("Cz-Ce-alkeny!"), in particular 2 to 4 carbon atoms ("Cz-C.-alkeny!"), and a double bond in any position, for example C2-C.-alkenyl, such as ethenyl, 1-propenyl, 2-propenyl, 1- methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-t-propenyl, 1- methyl-2-propenyl or 2-methyl-2-propenyl; C-Cevalkenyl, such as ethenyl, 1-propenyl, 2- propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-t-propenyl, 2-methyl-1- propenyl, 1-methyl2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4- pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyi-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3- butenyl, 4,1-dimethyl-2-propenyl, 1,2-dimethyl-t-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1- propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl 1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl, 4-methyl-1-pentenyl, 1-methyl-2- pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-penteny/l, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl- 4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3- butenyl, 1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethy! butenyl, 4,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2- butenyl, 4-ethyl-1-butenyl, 4-ethyl-2-butenyl, 4-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethy!-3-butenyl, 1,1,2-trimethyl2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1- ethyl-2-methyl-1-propenyl, 1-ethyl2-methyl-2-propenyl and the like, or Cz-Cro-alkenyl, such as. the radicals mentioned for C-Ce-alkenyl and additionally 1-heptenyl, 2-heptenyl, 3-heptenyl, 1- coctenyl, 2-octenyl, 3-octenyl, 4-octenyl, 1-nonenyl, 2-nonenyl, 3-nonenyl, 4-nonenyl, 1-decenyl 2-decenyl, 3-decenyl, 4-decenyl, 5-decenyl and the positional isomers thereof. The term “alkenylene" (or alkenediyl) as used herein in each case denotes an alkenyl radical as defined above, wherein one hydrogen atom at any position of the carbon backbone is replaced by one further binding site, thus forming a bivalent moiety. The term "haloalkenyl" as used herein, which may also be expressed as "alkenyl which may be substituted by halogen", and the haloalkeny! moieties in haloalkenyloxy, haloalkenylcarbonyl and the like refers to unsaturated straight-chain or branched hydrocarbon radicals having 2 to10 15 20 25 30 35 40 WO 2014/033401 9 PCT/EP2013/070154 10 ("Cz-Cio-haloalkeny!") or 2 to 6 ("Cz-Ce-haloalkenyl") or 2 to 4 ("Cz-C.-haloalkenyl") carbon atoms and a double bond in any position, where some or all of the hydrogen atoms in these groups are replaced by halogen atoms as mentioned above, in particular fluorine, chlorine and bromine, for example chlorovinyl, chloroallyl and the like. The term "alkynyl" as used herein denotes unsaturated straight-chain or branched hydrocarbon radicals having usually 2 to 10 ("Co-Cro-alkynyl"), frequently 2 to 6 ("Cz-Ce-alkyny!"), preferably 2 to 4 carbon atoms ("C2-C.-alkynyl") and one or two triple bonds in any position, for example C2- Crealkynyl, such as ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2- propynyl and the like, Co-Ce-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2- butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1- methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyi-3-butynyl, 3-methyl1-butynyl, 1,1-dimethyl-2- propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, S-hexynyl, 1-methyl-2- pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3- methyl-1-pentynyl, 3-methyl-4-pentynyl, 4-methyl-1-pentynyl, 4-methy-2-pentynyl, 1,1-dimethyl- 2-butynyl, 4,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1- butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and the like. The term “alkynylene" (or alkynediyl) as used herein in each case denotes an alkynyl radical as defined above, wherein one hydrogen atom at any position of the carbon backbone is replaced by one further binding site, thus forming a bivalent moiety. The term "haloalkynyl" as used herein, which is also expressed as “alkynyl which may be substituted by halogen’, refers to unsaturated straight-chain or branched hydrocarbon radicals having iusually 3 to 10 carbon atoms ("C2-Cio-haloalkynyl"), frequently 2 to 6 ("C2-Cs-haloalkyny!"), preferabyl 2 to 4 carbon atoms ("C2-C-haloalkynyl"), and one or two triple bonds in any position (as mentioned above), where some or all of the hydrogen atoms in these groups are replaced by halogen atoms as mentioned above, in particular fluorine, chlorine and bromine. The term "alkoxy" as used herein denotes in each case a straight-chain or branched alkyl group usually having from 1 to 10 carbon atoms ("C1-Cro-alkoxy"), frequently from 1 to 6 carbon atoms ("C1-Ce-alkoxy"), preferably 1 to 4 carbon atoms ("C1-C.-alkoxy"), which is bound to the remainder of the molecule via an oxygen atom. C1-Cz-Alkoxy is methoxy or ethoxy. C1-Cs-Alkoxy is additionally, for example, n-propoxy, 1-methylethoxy (isopropoxy), butoxy, 1-methylpropoxy (sec-butoxy), 2-methylpropoxy (isobutoxy) or 1,1-dimethylethoxy (tert-butoxy). C1-Ce-Alkoxy is. additionally, for example, pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 1,1- dimethylpropoxy, 1,2-dimethylpropoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1- methylpentoxy, 2-methylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1,1-dimethylbutoxy, 1,2- dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1-ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy, 1,2,2- trimethylpropoxy, 1-ethyl-1-methylpropoxy or 1-ethyl-2-methylpropoxy. C1-Cs-Alkoxy is additionally, for example, heptyloxy, octyloxy, 2-ethylhexyloxy and positional isomers thereof. Ci-Cio- Alkoxy is additionally, for example, nonyloxy, decyloxy and positional isomers thereof. The term "haloalkoxy" as used herein denotes in each case a straight-chain or branched alkoxy group, as defined above, having from 1 to 10 carbon atoms ("C1-Cio-haloalkoxy"), frequently from 1 to 6 carbon atoms ("Ci-Cs-haloalkoxy"), preferably 1 to 4 carbon atoms ("C1-Ce- haloalkoxy"), more preferably 1 to 3 carbon atoms ("Ci-C:-haloalkoxy"), wherein the hydrogen10 15 20 25 30 35 40 Wo 2014053401 10 PCT 2013/070154 atoms of this group are partially or totally replaced with halogen atoms, in particular fluorine atoms. C1-Cx-Haloalkoxy is, for example, OCH2F, OCHF2, OCFs, OCH-CI, OCHCl,, OCCls, chlorofluoromethoxy, dichlorofiuoromethoxy, chlorodifiuoromethoxy, 2-fluoroethoxy, 2- chloroethoxy, 2-bromoethoxy, 2-iodoethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2- fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy or OC-Fs, C1-Cs-Haloalkoxy is additionally, for example, 2-fluoropropoxy, 3-fluoropropoxy, 2.2- difluoropropoxy, 2,3-difluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, 2,3-dichloropropoxy, 2- bromopropoxy, 3-bromopropoxy, 3,3,3-trifluoropropoxy, 3,3,3-trichloropropoxy, OCH2-CaFs, OCF 2-CoFs, 1-(CH2F)-2-fluoroethoxy, 1-(CH:Cl)-2-chloroethoxy, 1-(CH2Br)-2-bromoethoxy, 4-fluorobutoxy, 4-chlorobutoxy, 4-bromobutoxy or nonafluorobutoxy. C1-Cs-Haloalkoxy is additionally, for example, 5-fluoropentoxy, 5-chloropentoxy, 5-brompentoxy, 5-iodopentoxy, unde- cafluoropentoxy, 6-fluorohexoxy, 6-chlorohexoxy, 6-bromohexoxy, 6-iodohexoxy or dodecafluo- rohexoxy. The term "alkoxyalkyl" as used herein denotes in each case alkyl usually comprising 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, wherein 1 carbon atom carries an alkoxy radical usually comprising 1 to 10, frequently 1 to 6, in particular 1 to 4, carbon atoms as defined above. °C1-Ce-Alkoxy-C1-Ce-alkyl’ is a C1-Ce-alkyl group, as defined above, in which one hydrogen atom is replaced by a C-Cs-alkoxy group, as defined above. Examples are CH,OCHs, CH OC2Hs, n-propoxymethyl, CH-OCH(CHs)2, n-butoxymethyl, (1-methylpropoxy}-methyl, (2- methylpropoxy)methyl, CH2-OC(CHs)s, 2-(methoxy)ethyl, 2-(ethoxy)ethyl, 2-(n-propoxy)-ethyl, 2- (1-methylethoxy)-ethyl, 2-(n-butoxy)ethyl, 2-(1-methylpropoxy)-ethyl, 2-(2-methylpropoxy-ethyl, 2-(1,1-dimethylethoxy)-ethyl, 2-(methoxy)-propyl, 2-(ethoxy)-propyl, 2-(n-propoxy)-propyl, 2-(1- methylethoxy)-propyl, 2-(n-butoxy)-propyl, 2-(1-methylpropoxy)-propyl, 2-(2-methylpropoxy)- propyl, 2-(1,1-dimethylethoxy)-propyl, 3-(methoxy)-propyl, 3-(ethoxy)-propyl, 3-(n-propoxy)- propyl, 3-(1-methylethoxy)-propyl, 3-(n-butoxy)-propyl, 3-(1-methylpropoxy)-propyl, 3-(2- methylpropoxy)-propyl, 3-(1,1-dimethylethoxy)-propyl, 2-(methoxy)-butyl, 2-(ethoxy)-butyl, 2-(n- propoxy)-butyl, 2-(1-methylethoxy)-butyl, 2-(n-butoxy)-butyl, 2-(1-methylpropoxy)-butyl, 2-(2- methyl-propoxy)-butyl, 2-(1,1-dimethylethoxy)-butyl, 3-(methoxy)-butyl, 3-(ethoxy)-butyl, 3-(n- propoxy)-butyl, 3-(1-methylethoxy)-butyl, 3-(n-butoxy)-butyl, 3-(1-methylpropoxy)-butyl, 3-(2- methylpropoxy)-butyl, 3-(1,1-dimethylethoxy)-butyl, 4-(methoxy)-butyl, 4-(ethoxy)-butyl, 4-(n- propoxy)-butyl, 4-(1-methylethoxy)-butyl, 4-(n-butoxy)-butyl, 4-(1-methylpropoxy)-butyl, 4-(2- methylpropoxy)-butyl, 4-(1,1-dimethylethoxy)-butyl and the like. The term "haloalkoxy-alkyl" as used herein denotes in each case alkyl as defined above, usually comprising 4 to 6 carbon atoms, preferably 1 to 4 carbon atoms, wherein 1 carbon atom carries. an haloalkoxy radical as defined above, usually comprising 1 to 10, frequently 1 to 6, in partiou- lar 1 to 4, carbon atoms as defined above. Examples are fluoromethoxymethyl, difluoromethox- ymethyl, trifluoromethoxymethyl, 4-fluoroethoxymethyl, 2-fluoroethoxymethyl, 1,1- difluoroethoxymethyl, 1,2-difluoroethoxymethyl, 2,2-difluoroethoxymethyl, 1,1,2- trifluoroethoxymethyl, 1,2,2-trifluoroethoxymethyl, 2,2,2-trifluoroethoxymethyl, pentafluoroethox- ymethyl, 1-fluoroethoxy-1-ethyl, 2-fluoroethoxy-1-ethyl, 1,1-difluoroethoxy-1-ethyl, 1,2- difluoroethoxy-1-ethyl, 2,2-difluoroethoxy-1-ethyl, 1,1,2-trifluoroethoxy-1-ethyl, 1,2,2- trifluoroethoxy-1-ethyl, 2,2,2-trifluoroethoxy-1-ethyl, pentafluoroethoxy-1-ethyl, 1-fluoroethoxy-2- ethyl, 2-fluoroethoxy-2-ethyl, 1,1-difluoroethoxy-2-ethyl, 1,2-difluoroethoxy-2-ethyl, 2,2-10 15 20 25 30 35 40 WO 20147053401 " a 2013/070154 difluoroethoxy-2-ethyl, 1,1,2-trifluoroethoxy-2-ethyl, 1,2,2-trifluoroethoxy-2-ethyl, 2,2,2- trifluoroethoxy-2-ethyl, pentafluoroethoxy-2-ethyl, and the like. The term “alkylthio"(also alkyisulfanyl or alkyl-S-)" as used herein denotes in each case a i-chain or branched saturated alkyl group as defined above, usually comprising 1 to 10 carbon atoms ("Ci-Cro-alkylthio"), frequently comprising 1 to 6 carbon atoms ("Ci-Ce-alkylthio’ preferably 1 to 4 carbon atoms ("C1-Cs-alkylthio"), which is attached via a sulfur atom at any position in the alkyl group. Ci-C2-Alkylthio is methylthio or ethylthio. C1-Ca-Alkylthio is additionally, for example, n-propylthio, 1-methylethylthio (isopropylthio), butylthio, 1-methylpropyithio (sec- butylthio), 2-methylpropylthio (isobutylthio) or 1,1-dimethylethyithio (tert-butylthio). Cr-Ce- Alkyithio is additionally, for example, pentylthio, 1-methylbutyithio, 2-methylbutyithio, 3- methylbutyithio, 1,1-dimethylpropyithio, 1,2-dimethylpropylthio, 2,2-dimethylpropylthio, 1- ethylpropyithio, hexylthio, 1-methylpentyithio, 2-methylpentylthio, 3-methylpentylthio, 4- methylpentyithio, 1,1-dimethylbutylthio, 1,2-dimethylbutylthio, 1,3-dimethylbutylthio, 2,2- dimethylbutylthio, 2,3-dimethylbutylthio, 3,3-dimethylbutylthio, 1-ethylbutylthio, 2-ethylbutylthio, 1,1,2-trimethylpropylthio, 4,2,2-trimethylpropylthio, 1-ethyl1-methylpropylthio or 1-ethyl-2- methylpropylthio, Ci-Ce-Alkylthio is additionally, for example, heptylthio, octyithio, 2- ethylhexyithio and positional isomers thereof. C1-C1o-Alkylthio is additionally, for example, nonyl- thio, decyithio and positional isomers thereof. The term "haloalkylthio" as used herein refers to an alkylthio group as defined above wherein the hydrogen atoms are partially or fully substituted by fluorine, chlorine, bromine and/or iodine. C1-Co-Haloalkylthio is, for example, SCHaF, SCHF2, SCF, SCHsCl, SCHClz, SCChs, chlorofluo- romethylthio, dichlorofluoromethylthio, chlorodifiuoromethylthio, 2-fluoroethylthio, 2- chloroethyithio, 2-bromoethylthio, 2-iodoethylthio, 2,2-difluoroethyithio, 2,2,2-trifluoroethylthio, 2- chloro-2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2-dichloro-2-fluoroethylthio, 2,2,2trichloroethylthio or SC2Fs. C:-Cs-Haloalkylthio is additionally, for example, 2-fluoropropylthio, 3-fluoropropylthio, 2,2-difluoropropylthio, 2,3-difluoropropylthio, 2-chloropropylthio, 3-chloropropylthio, 2,3-dichloropropylthio, 2-bromopropylthio, 3-bromopropyithio, 3,3,3-trifluoropropyithio, 3,3,3-trichloropropyithio, SCH2-C2Fs, SCF-CaFs, 1- (CH,F)-2-fluoroethylthio, 1-(CH2CI)-2-chloroethylthio, 1-(CH2Br)-2-bromoethylthio, 4-fluorobutylthio, 4-chlorobutyithio, 4-bromobutylthio or nonafluorobutyithio. C:-Cs-Haloalkylthio is additionally, for example, 5-fluoropentylthio, 5-chloropentylthio, 5-brompentylthio, 5-iodopentylthio, undecafluoropentylthio, 6-fluorohexylthio, 6-chlorohexylthio, 6-bromohexylthio, 6-iodohexylthio or dodecafluorohexylthio. The terms “alkylsulfinyl" and "S(O),-alkyl" (wherein n is 1) are equivalent and, as used herein, denote an alkyl group, as defined above, attached via a sulfinyl [S(O)] group. For example, the term "C;-Cralkylsulfiny!" refers to a Ci-Cr-alkyl group, as defined above, attached via a sulfinyl [S(O)] group. The term "C1-Cy-alkylsulfinyl" refers to a Ci-Cialkyl group, as defined above, attached via a sulfinyl [S(O)] group. The term "Ci-Ce-alkylsulfinyl" refers to a C+-Ce-alkyl group, as defined above, attached via a sutfinyl [S(O)] group. C1-Cz-alkylsulfiny| is methylsulfinyl or ethyl- sulfinyl. C;-C.-alkylsulfinyl is additionally, for example, n-propylsulfinyl, 1-methylethyisulfiny! (isopropylsuifinyl), butylsulfinyl, 1-methylpropylsulfiny! (sec-butylsulfinyl), 2-methylpropylsulfinyl (isobutylsulfiny!) or 1,1-dimethylethylsulfinyl (tert-butylsulfinyl). C1-Cs-alkylsulfinyl is additionally, for example, pentyisulfinyl, 1-methylbutylsulfinyl, 2-methylbutylsulfinyl, 3-methylbutyisulfinyl, 1,1-dimethylpropyisulfinyl, 1,2-dimethylpropylsutfinyl, 2,2-dimethylpropylsulfinyl,10 15 20 25 30 35 40 WO 20147053401 12 a 2013/070154 1-ethylpropylsulfinyl, hexylsulfinyl, 1-methylpentylsulfinyl, 2-methylpentylsulfiny!, 3-methylpentyisulfinyl, 4-methylpentyisulfinyl, 1,1-dimethylbutyisulfinyl, 1,2-dimethylbutylsulfinyl, 1,3-dimethylbutylsutfinyl, 2,2-dimethylbutylsutfinyl, 2,3-dimethylbutylsutfinyl, 3,3- dimethylbutylsulfinyl, 1-ethylbutylsutfinyl, 2-ethylbutylsulfinyl, 1,1,2-trimethylpropylsulfinyl, 1,2,2- trimethylpropylsutfinyl, 1-ethyl-1-methylpropylsulfinyl or 1-ethyl-2-methylpropylsulfiny| The terms “alkylsulfonyl" and "S(O),-alkyl" (wherein n is 2) are equivalent and, as used herein, denote an alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. The term "C1-Co- alkylsulfonyl" refers to a C1-Cz-alkyl group, as defined above, attached via a sulfonyl [S(O)2} group. The term "C1-Ce-alkyisulfonyl" refers to a C1-C.-alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. The term "C1-Ce-alkylsulfonyl" refers to a C1-Ce-alkyl group, as defined above, attached via a sulfonyl [S(O)z] group. C1-C-alkylsulfonyl is methylsulfonyl or ethyl- sulfonyl. C;-C.-alkylsulfonyl is additionally, for example, n-propylsulfonyl, 1-methylethylsulfonyl (isopropyisulfonyl), butylsulfonyl, 1-methylpropylsulfonyl (sec-butylsulfonyl), 2- methylpropylsulfonyl (isobutylsutfonyl) or 1,1-dimethylethylsulfonyl (tert-butylsulfonyl). C1-Ce- alkylsulfonyl is additionally, for example, pentylsulfonyl, 1-methylbutyisutfonyl, 2- methylbutyisulfonyl, 3-methylbutylsutfonyl, 1,1-dimethylpropylsulfonyl, 1,2- dimethylpropylsulfonyl, 2,2-dimethylpropylsulfonyl, 1-ethylpropylsulfonyl, hexylsulfonyl, 1- methylpentylsulfonyl, 2-methylpentyisulfonyl, 3-methylpentylsulfonyl, 4-methylpentylsulfonyl, 1,1-dimethylbutylsulfonyl, 1,2-dimethylbutylsulfonyl, 1,3-dimethylbutylsulfonyl, 2,2-dimethylbutyisulfonyl, 2,3-dimethylbutyisulfonyl, 3,3-dimethylbutyisulfonyl, ‘-ethylbutylsulfonyl, 2-ethylbutyisulfonyl, 1,1,2-trimethylpropylsulfonyl, 1,2,2-trimethylpropylsulfonyl, 1-ethyl-1-methylpropylsulfonyl or 1-ethyl-2-methylpropylsutfonyl. The term "alkylamino” as used herein denotes in each case a group -NHR, wherein R is a straight-chain or branched alkyl group usually having from 1 to 6 carbon atoms (°C1-Cs- alkylamino’), preferably 1 to 4 carbon atoms("C:-C-alkylamino’). Examples of C1-Cs-alkylamino are methylamino, ethylamino, n-propylamino, isopropylamino, n-butylamino, 2-butylamino, iso- butylamino, tert-butylamino, and the like. The term “dialkylamino" as used herein denotes in each case a group-NRR’, wherein R and R’, independently of each other, are a straight-chain or branched alkyl group each usually having from 1 to 6 carbon atoms ("di-(C1-Ce-alkyl)-amino"), preferably 1 to 4 carbon atoms (‘di-(Ci-Ce- alkyl)-amino"). Examples of a di-(C1-Ce-alkyl)-amino group are dimethylamino, diethylamino, dipropylamino, dibutylamino, methyl-ethyl-amino, methylpropy-amino, methyl-isopropylamino, methyl-buty-amino, methyl-isobutyl-amino, ethyl-propyl-amino, ethybisopropylamino, ethyl- buty-amino, ethyl-isobutykamino, and the like. The term "oycloalkylamino” as used herein denotes in each case a group -NHR, wherein Ris a cycloalkyl group usually having from 3 to 8 carbon atoms ("C:-Ce-cycloalkylamino’), preferably 3 to 6 carbon atoms("Cs-Cs-cycloalkylamino”). Examples of Cs-Cs-cycloalkylamino are cycloprop- ylamino, cyclobutylamino, cyclopentylamino, cyclohexylamino, and the like. The term “alkylaminosulfonyl" as used herein denotes in each case a straight-chain or branched alkylamino group as defined above, which is bound to the remainder of the molecule via a sul fonyl [S(O)z] group. Examples of an alkylaminosulfonyl group are methylaminosulfonyl, ethyla- minosulfonyl, n-propylaminosulfonyl, isopropylaminosulfonyl, n-butylaminosutfonyl, 2- butylaminosulfonyl, iso-butylaminosulfonyl, tert-butylaminosulfonyl, and the like. The term "dialkylaminosulfony!" as used herein denotes in each case a straight-chain or10 15 20 25 30 35 40 Wo 2014/053401 13 PCr 2013/070154 branched alkylamino group as defined above, which is bound to the remainder of the molecule via a sulfonyl [S(O)2] group. Examples of an dialkylaminosulfonyl group are dimethylaminosul- fonyl, diethylaminosulfonyl, dipropylaminosulfonyl, dibutylaminosulfonyl, methyl-ethyl- aminosulfonyl, methypropyl-aminosulfonyl, methy/-isopropylaminosulfonyl, methyl-butylaminosulfonyl, methy-isobutyl-aminosulfonyl, ethyl-propyl-aminosulfonyl, ethyl isopropytaminosulfonyl, ethy!-buty-aminosulfonyl, ethyl-isobutyl-aminosulfonyl, and the like. The suffix ,-carbonyl" in a group denotes in each case that the group is bound to the remainder of the molecule via a carbonyl C=O group. This is the case e.g. in alkylcarbonyl, haloalkylcar- bonyl, aminocarbonyl, alkylaminocarbony|, dialkylaminocarbonyl, alkoxycarbonyl, haloal- koxycarbonyl. The term "aryl" as used herein refers to a mono-, bi- or tricyolic aromatic hydrocarbon radical such as phenyl or naphthyl, in particular phenyl The term "het(ero)aryl” as used herein refers to a mono-, bi- or tricyclic heteroaromatic hydrocarbon radical, preferably to a monocyclic heteroaromatic radical, such as pyridyl, pyrimidyl and the like. A saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur, is a ring system wherein two ‘oxygen atoms must not be in adjacent positions and wherein at least 1 carbon atom must be in the ring system e.g. thiophene, furan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1,3,4-oxadlazole, 1,3,4-thiadiazole, 1,3,4-triazole, 1,2,4-oxadiazole, 1,2,4- thiadiazole, 1,2,4-triazole, 1,2,3-triazole, 1,2,3,4-tetrazole, benzo[blthiophene, benzo[b]furan, indole, benzofo}thiophene, benzo[c}furan, isoindole, benzoxazole, benzthiazole, benzimidazole, benzisoxazole, benzisothiazole, benzopyrazole, benzothiadiazole, benztriazole, dibenzofuran, dibenzothiophene, carbazole, pyridine, pyrazine, pyrimidine, pyridazine, 1,3,5-triazine, 1,2,4- triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, cinnoline, 1,8- naphthyridine, 1,5-naphthyridine, 1,6-naphthyridine, 1,7-naphthyridine, phthalazine, pyri- dopyrimidine, purine, pteridine, 4H-quinolizine, piperidine, pyrrolidine, oxazoline, tetrahydrofuran, tetrahydropyran, isoxazolidine or thiazolidine, oxirane or oxetane. A saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur also is e.g a saturated, partially unsaturated or unsaturated 5-or 6-membered heterocycle which contains 1 to 4 heteroatoms selected from oxygen, nitrogen and sulfur, such as pyridine, pyrimidine, (1,2,4)-oxadiazole, (1,3,4)-oxadiazole, pyrrole, furan, thiophene, oxazole, thiazole, imidazole, pyrazole, isoxazole, 1,2,4-triazole, tetrazole, pyrazine, pyridazine, oxazoline, thiazoline, tetrahydrofuran, tetrahydropyran, morpholine, piperidine, piperazine, pyrroline, pyrrolidine, oxazolidine, thiazolidine; or a saturated, partially unsaturated or unsaturated 5-or 6-membered heterocycle which contains 1 nitrogen atom and 0 to 2 further heteroatoms selected from oxygen, nitrogen and sulfur, preferably from oxygen and nitrogen, such as piperidine, piperazin and morpholine. Preferably, this ring system is a saturated, partially unsaturated or unsaturated 3- to 6- membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sul fur, wherein two oxygen atoms must not be in adjacent positions and wherein at least 1 carbon atom must be in the ring system.10 15 20 25 30 WO 20147053401 14 rc 20131070154 Most preferably, this ring system is a radical of pyridine, pyrimidine, (1,2,4)-oxadiazole, 1,3,4-oxadiazole, pyrrole, furan, thiophene, oxazole, thiazole, imidazole, pyrazole, isoxazole, 1,2,4-triazole, tetrazole, pyrazine, pyridazine, oxazoline, thiazoline, tetrahydrofuran, tetrahydropyran, morpholine, piperidine, piperazine, pyrroline, pyrrolidine, oxazolidine, thiazolidine, oxirane or oxetane. Preparation of the compounds of formula | can be accomplished according to standard methods of organic chemistry, e.g. by the methods or working examples described in WO 2007/006670, PCTIEP2012/065650 and PCT/EP2012/065651, without being limited to the routes given therein, The preparation of the compounds of formula | above may lead to them being obtained as iso- mer mixtures. If desired, these can be resolved by the methods customary for this purpose, such as crystallization or chromatography, also on optically active adsorbate, to give the pure isomers. Agronomically acceptable salts of the compounds | can be formed in a customary manner, €.g. by reaction with an acid of the anion in question. Preferences The remarks made below as to preferred embodiments of the variables (substituents) of the ‘compounds of formulae (|) are valid on their own as well as preferably in combination with each other, as well as in combination with the stereoisomers, tautomers, N-oxides or salts thereof, and, where applicable, as well as concerning the uses and methods according to the invention and the compositions according to the invention. Preferred compounds according to the invention are compounds of formulae (I) or a stereoisomer, N-oxide or salt thereof, wherein the salt is an agriculturally or veterinarily acceptable salt. The compounds | of formula (|) and their examples include their tautomers, racemic mixtures, individual pure enantiomers and diastereomers and their optically active mixtures. Preferred are methods and uses of compounds of formula (I), wherein the compound of formula lis a compound of formula IA: (A)Wo 2014053401 15 PCT 2013/070154 wherein R'is halogen, and wherein the variables R', R?, R’, R®, R® and k are as defined herein. Preferred are methods and uses of compounds of formula (I), in which the compound of formula | is a compound of formula IB: Ny uJ ((B) 5 Nog BS RO), 10 wherein R?__ is selected from the group consisting of bromo, chloro, cyano; R’_ is selected from the group consisting of bromo, chloro, trifluoromethyl. OCHF2, and wherein the variables R?, R’, R°, R° and k are as defined herein. 15 Preferred are methods and uses of compounds of formula (|), in which the compound of formula lis a compound of formula IC: (Ic) Ss, _ Renee wherein R?__ is selected from the group consisting of halogen and halomethyl; 20 R?__ is selected from the group consisting of bromo, chloro and cyano, and wherein the variables R®, R® and k are as defined herein.10 15 20 25 30 Wo 2014053401 16 PCT 2013/070154 Preferred are methods and uses of compounds of formula (I), in which the compound of formula lis a compound of formula ID: (ID) 5 Nog ‘Ss R° SO), wherein R'is selected from the group consisting of halogen, methyl and halomethyl; R? is selected from the group consisting of bromo, chloro and cyano, and wherein the variables R®, R® and k are as defined herein. Preferred are methods and uses of compounds of formula (I), in which R®, R® are selected independently of one another from the group consisting of hydrogen, C1-Cio-alkyl, Ce-Ce-cycloalkyl, wherein the aforementioned aliphatic and cycloaliphatic radicals may be substituted with 1 to 10 substituents Re; or R® and R° together represent a C-Cr-alkylene chain forming together with the sulfur atom to which they are attached a 3-, 4-, 5-, 6-, 7- or 8- membered saturated, partially unsaturated or fully unsaturated ring, wherein 1 to 4 of the CHe groups in the Co-Cr-alkylene chain may be replaced by 1 to 4 groups independently selected from the group consisting of C=O, C=S, O, §, N, NO, SO, SOz and NH, and wherein the carbon and/or nitrogen atoms in the Cz-C7-alkylene chain may be substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, C1-Cs-alkyl, C1-Ce-haloalkyl, C1-Ce-alkoxy, C1-Cs-haloalkoxy, Ci-Ce- alkylthio, Ci-Cs-haloalkylthio, Cs-Cs-cycloalkyl, Cs-Cs-halocycloalkyl, Co-Ce-alkenyl, C-Co~ haloalkenyl, Cz-Cs-alkynyl and Cz-Cs-haloalkynyl; said substituents being identical or different from one another if more than one substituent is present. Preferred are methods and uses of compounds of formula (I), in which R®, R® are selected independently of one another from the group consisting of hydrogen, C1-Cio-alkyl, Cs-Cs-cycloalkyl, wherein the aforementioned aliphatic and cycloaliphatic radicals may be substituted with 1 to 10 substituents R°. Preferred are methods and uses of compounds of formula (I), in which R’ is selected from the group consisting of bromo, difluoromethyl, trifluoromethyl, cyano, OCHF2, OCHF and OCH,CFs,10 15 20 25 30 WO 20147053401 7 a 2013/070154 Preferred are methods and uses of compounds of formula (I), in which R’ is selected from the group consisting of bromo, difluoromethyl, trifluoromethyl and OCHF2 Preferred are methods and uses of compounds of formula (I), in which R® is independently selected from the group consisting of halogen, cyano, -OH, -SH, -SCN, C1-Ce-alkyl, C-Ceralkenyl, CzCe-alkinyl, Cs-Ce-cycloalkyl, wherein one or more CHe groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated and/or may carry 1 or 2 radicals selected from C;-Ce-alkoxy, C1-Cs-haloalkoxy, C1-Ce-alkylthio, C1-Ce-alkylsutfinyl, Cs- Ce-alkylsutfonyl, C1-Ce-haloalkylthio, -OR®, -NR°R¥, -S(O),R®, -S(O),NRER®, -C(=O)R®, -C(=O)NRFR®, -C(=O)OR’, -C(=S)R®, -C(=S)NRFR®, -C(=S)OR®, -C(=S)SR°, -C(=NR®)R°, -C(=NR®)NR'R¥, phenyl, benzyl, pyridyl and phenoxy, wherein the last four radicals may be unsubstituted, partially or fully halogenated and/or carry 1, 2 or 3 substituents selected from C:-Ce-alkyl, C1-Cs-haloalkyl, C:-Ce-alkoxy and C:-Ce-haloalkoxy. Preferred are methods and uses of compounds of formula (!), in which R® is independently selected from the group consisting of halogen, cyano, -OH, -SH, -SCN, Cr-Ce-alkyl, C-Ce-alkenyl, CzCe-alkinyl, Cs-Ce-cycloalkyl, wherein one or more CHz groups of the aforementioned radicals may be replaced by a C=O group, and/or the aliphatic and cycloaliphatic moieties of the aforementioned radicals may be unsubstituted, partially or fully halogenated, Preferred are methods and uses of compounds of formula (I) as described herein, in which in the compound of formula | R® and R® are selected from methyl, ethyl, isopropyl, n-propyl, n-butyl, isobutyl, tert-butyl, cyclopropyl, cyclopropylmethyl. Preferred are methods and uses of compounds of formula (I) as described herein, in which in the compound of formula | R® and R® are identical In a particularly preferred embodiment, the methods and uses according to the invention comprise at least one compound of formula (IA) (A) s Sy cae k10 15 20 25 30 WoO 2014/053401 18 2013/070154 wherein Ri isl, R'is selected from the group consisting of Cl, Br, and methyl; R® is selected from the group consisting of bromo and chloro; R®, R® are selected independently of one another from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl R? is selected from the group consisting of difluoromethyl, trifluoromethyl. Examples of especially preferred anthranilamide compounds | of the present invention are of formula (IA-1) (At) wherein R', R’, R’, R°, R® are as defined herein. Examples of preferred compounds of formula | in the methods and uses according to the invention are compiled in tables 1 to 60 below. Moreover, the meanings mentioned below for the individual variables in the tables are per se, independently of the combination in which they are mentioned, a particularly preferred embodiment of the substituents in question. Table 1 Compounds of the formula (IA~1) in which Rt is F, R? is Cl, R” is CFs and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 2 Compounds of the formula (IA-1) in which Rt is Br, R? is Cl, R’ is CFs and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 3. Compounds of the formula (IA~1) in which Rt is Cl, R? is Cl, R’ is CFs and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 4 Compounds of the formula (IA-1) in which Rt is methyl, R? is Cl, R” is CFs and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 5 Compounds of the formula (IA-1) in which Rt is F, R? is Br, R’ is CFs and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 6 Compounds of the formula (IA~1) in which Rt is Br, R? is Br, R’ is CFs and the combination of RS and R® for a compound corresponds in each case to one row of Table A; Table 7 Compounds of the formula (IA~1) in which Rt is Cl, R? is Br, R” is CFs and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A;10 15 20 25 30 35 40 Wo 2014053401 19 PCT Table 8 Compounds of the formula (IA~1) in which R" is methyl, R?is Br, R’ is CFs and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 9 Compounds of the formula (IA-1) in which R' is F, R? is cyano, R’ is CFs and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 10 Compounds of the formula (IA~1) in which Rt is Br, R? is cyano, R is CFs and the combination of RS and R® for a compound corresponds in each case to one row of Table A; Table 11 Compounds of the formula (IA-1) in which Rt is Cl, R? is cyano, R’ is CFs and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 12 Compounds of the formula (IA-1) in which R' is methyl, R? is cyano, R” is CFs and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 13. Compounds of the formula (IA~1) in which Rt is F, R? is Cl, R” is CHF? and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 14 Compounds of the formula (IA~1) in which R* is Br, R? is Cl, R’ is CHF, and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 15 Compounds of the formula (/A-1) in which R' is Cl, Ris Cl, R” is CHF2 and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 16 Compounds of the formula (IA~1) in which Rt is methyl, R? is Cl, R” is CHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 17 Compounds of the formula (IA~1) in which Rt is F, R? is Br, R’ is CHF2 and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 18 Compounds of the formula (IA-1) in which R' is Br, R?is Br, R’ is CHF2 and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 19 Compounds of the formula (IA~1) in which Rt is Cl, R? is Br, R” is CHF, and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 20 Compounds of the formula (IA-1) in which R' is methyl, R? is Br, R’ is CHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 21 Compounds of the formula (IA~1) in which Rt is F, R? is cyano, R’ is CHF2 and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 22. Compounds of the formula (IA~1) in which Rt is Br, R? is cyano, R’ is CHF2 and the ‘combination of RS and R® for a compound corresponds in each case to one row of Table A; Table 23 Compounds of the formula (IA~1) in which R'is Cl, R? is cyano, R’ is CHF: and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 24 Compounds of the formula (IA-1) in which R is methyl, R? is cyano, R” is CHF2 and the combination of R® and R® for a compound corresponds in each case to one row of Table A 2013/070154 Table 25 Compounds of the formula (IA~1) in which R'is F, R? is Cl, R’ is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 26 Compounds of the formula (IA~1) in which R' is Br, R? is Cl, R” is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 27 Compounds of the formula (IA~1) in which Rt is Cl, R?is Cl, R’ is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 28 Compounds of the formula (IA~1) in which R' is methyl, R?is Cl, R’ is Br and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A;10 15 20 25 30 35 40 Wo 2014053401 20 PCT 2013/070154 Table 29. Compounds of the formula (IA-1) in which Rt is F, R? is Br, R” is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 30 Compounds of the formula (IA-1) in which R' is Br, R?is Br, R’ is Br and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 31 Compounds of the formula (IA~1) in which Rt is Cl, R? is Br, R” is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 32 Compounds of the formula (IA-1) in which R* is methyl, R? is Br, R’ is Br and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 33. Compounds of the formula (IA~1) in which Rt is F, R? is cyano, R’ is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 34 Compounds of the formula (IA~1) in which Rt is Br, R? is cyano, R’ is Br and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 35 Compounds of the formula (IA~1) in which Rt is Cl, R? is cyano, R’ is Br and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 36 Compounds of the formula ((A-1) in which R' is methyl, R?is cyano, R” is Br and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 37 Compounds of the formula (IA~1) in which Rt is F, R? is Cl, R’ is Cl and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 38 Compounds of the formula (IA~1) in which Rt is Br, R? is Cl, R’ is Cl and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 39. Compounds of the formula (IA-1) in which Rt is Cl, R? is Cl, R’ is Cl and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 40 Compounds of the formulla (IA~1) in which Rt is methyl, R? is Cl, R” is Cl and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 41 Compounds of the formula (IA-1) in which R' is F, R? is Br, R” is Cl and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 42 Compounds of the formula (IA-1) in which R' is Br, Ris Br, R’ is Cl and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 43. Compounds of the formula (IA~1) in which Rt is Cl, R? is Br, R’ is Cl and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 44 Compounds of the formula (IA-1) in which R' is methyl, R? is Br, R’ is Cl and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 45 Compounds of the formula (IA~1) in which Rt is F, R? is cyano, R’ is Cl and the combination of RS and R® for a compound corresponds in each case to one row of Table A; Table 46 Compounds of the formula (IA-1) in which Rt is Br, R? is cyano, R’ is Cl and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 47 Compounds of the formula (IA~1) in which Rt is Cl, R? is cyano, R” is Cl and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 48 Compounds of the formula (IA~1) in which Rt is methyl, R? is cyano, R” is Cl and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 49. Compounds of the formula (IA-1) in which Rt is F, R? is Cl, R” is OCHF? and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 50 Compounds of the formula (IA~1) in which Rt is Br, R? is Cl, R’ is OCHF? and the ‘combination of R® and R® for a compound corresponds in each case to one row of Table A;10 15 20 WO 2014/053401 2 PCT/EP2013/070154 Table 51 Compounds of the formula (IA-1) in which Rt is Cl, R@is Cl, R’ is OCH? and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 52 Compounds of the formula (IA-1) in which Rt is methyl, R? is Cl, R’ is OCHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A Table 53 Compounds of the formula (IA-1) in which R' is F, R? is Br, R” is OCHF? and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 54 Compounds of the formula (IA-1) in which R' is Br, R? is Br, R? is OCHF2 and the combination of R® and R° for a compound corresponds in each case to one row of Table A; Table 55 Compounds of the formula (IA-1) in which Rt is Cl, R? is Br, R” is OCHF? and the combination of R® and R® for a compound corresponds in each case to one row of Table A; Table 56 Compounds of the formula (IA-1) in which R' is methyl, R? is Br, R? is OCHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 57 Compounds of the formula (IA-1) in which Rt is F, R2 is cyano, R’ is OCHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A; Table 58 Compounds of the formula (IA-1) in which R' is Br, R? is cyano, R” is OCHF2 and the combination of R° and Ré for a compound corresponds in each case to one row of Table A; Table 59 Compounds of the formula (IA-1) in which R' is Cl, R? is cyano, R’ is OCHF2 and the combination of R° and R® for a compound corresponds in each case to one row of Table A; ‘Table 60 Compounds of the formula (IA-1) in which R' is methyl, R? is cyano, R’ is OCHF2 and the combination of R® and R® for a compound corresponds in each case to one row of Table A Table A Re Re Re Re At | CHs CHa A-20_| o-CeH CHa A2 | CHs CH A21_| CHzo-C:Hs CH A:3__| CH=CHe CHa A-22_| CH(CHs)-c-CsHs | CHa Ad | CHeCH,CHs CHa A23 | CHro-CsHo CHa AS | CH(CHs)2 CHa A-24 | CHeo-CHis CHa AG | CHeCH;CH2CHs | CHa A25 | CcHs CHa AT | C(CHa)a CHa A-26 | CHa Cos AB | CHeCH(CHs)2 CHa AQT CoH ‘AQ | CH(CHs)CH2CHs_| CHa A-28 Cos A-10_| CHSCH=CHe CHa A:29 | CHeCH;CHs CoH A-l1_| CH2C=CH CHa A-30_| CH(CHs)2 Cos A12_| CH(CHs)CH=CH? | CH At [CHeCH;CH2CHs _| CoHs A-13_| CHF? CHa A-32_| C(CHs)s Cos A-14_| CHCl CHa A33__ | CHeCH(CHs)2 Cols A-15 | CH2CH2CN CHa A-34_ | CH(CHs)CH2CHs | Cos A-16_| CHCH,CI CH A-35 | CHeCH=CHe Cols AAT | -CsHs CHa A-36_| CHsC=CH Cos A18 | o-CiHr CHa A:37_| CH(CHs)CH=CH2_| CoHs AA9 | o-CsHe CH A-38_| CHF, CoHsWO 2014053401 22 PCT/EP2013/070154 Re Re Re Re A-39_| CHCl CoHs A-81_ | CHsCH2CH2CHs _| CH2CH2CHs A-40_| CHoCH2CN CoHs A-82_| C(CHs)s CH2CH2CHs A-41_| CHCH-CI CaHs A-83_ | CH2CH(CHs)2 CH2CH2CHs A-42_| c-CoHs CoHs A-84__| CH(CHs)CH2CHs | CH2CH2CHs A-43 | o-CiHr CoHs A-85_ | CHsCH=CH2 CH2CH2CHa A-44 | c-CsHe CoHs A-86_ | CH2C=CH CH2CH2CHs AAS | o-CoHi Cas A-87_ | CH(CHs)CH=CH2 | CH2CH2CHs A-46 | CHo-c-CaHs CoHs A-88_| CHF. CH2CH2CHs A-47 | CH(CHs)--CaHs | CoHs A-89_| CHCl CH2CH2CHa A-48 | CHe-c-CsHo CoHs A-90_| CHsCH2CN CH2CH2CHs A-49 | CHo-0-CoHis Cals A-91 | CHzCH2CI CH2CH2CHa A50 | CoHs CoHs A92_| -CaHs CH2CH2CHs AS1_ | CHs CH=CH A-93 | c-CaHr CH2CH2CHa A52 | CHs CH=CH, A94 | c-CsHo CH:CH2CHs A-53_ | CH=CH2 CH=CHe A-95 | c-CoHss CH2CH2CHa A54 | CHoCH2CHs CH=CH2 A96_ | CHr-c-CsHs CH2CH2CHs A-55_| CH(CHs)2 CH=CHe A-97__| CH(CHs)-c-CaHs | CH2CH2CHs A56_ | CHeCH2CH2CHs_| CH=CHe A-98_| CHx-c-CsHo CH2CH2CHs A57_| C(CHa)a CH=CHe A-99 | CHo-o-Cettss CH2CH2CHa A-58 | CH2CH(CHa)2 CH=CH2 A-100 | Css CH2CH2CHs A59_| CH(CHs)CH2CHs_| CH=CHe A101 | CHs CH(CHs)2 ‘A60_| CHoCH=CH2 CH=CH2 A-102 | CoHs CH(CHa)2 A61_ | CHeC=CH CH=CH? ‘A-103 | CH=CH CH(CHs)2 ‘A62_| CH(CHs)CH=CH2 | CH=CHe ‘A104 | CHsCH2CHs CH(CHa) A63_| CHF? CH=CH? A105 | CH(CHs)2 CH(CHs)2 A-64 | CHCl CH=CHe A106 | CHsCH2CH2CHs | CH(CHs)2 A65 | CHoCH-CN CH=CH? A-107 | C(CHs)s CH(CHs)2 A-66 | CH2CH,CI CH=CH ‘A-108 | CHzCH(CHs)2 CH(CHa)2 ACT | o-CaHs CH=CH A109 | CH(CHs)CH2CHs | CH(CHs)2 AB | c-CiHr CH=CH A110 | CHsCH=CH2 CH(CHa)2 A69 | C-CsHo CH=CH, A111 | CH.C=CH CH(CHa)2 A-70 | o-CoHi CH=CH Ac112 | CH(CHa)CH=CH2_| CH(CHs)2 ATI | CHe-c-CoHs CH=CH, A113 | CHF2 CH(CHa)2 A:72_| CH(CHs)-c-CaHs | CH=CHe A114 | CHCl CH(CHo)2 ALT3_| CHe-c-CsHo CH=CH, A115 | CH2CH2CN CH(CHa)2 AsT4 | CHo-c-CoHi CH=CHe A116 | CHzCH2CI CH(CHo)2 AL75 | CoHs CH=CH2 A117 | 6-CaHs CH(CHa)2 A-76_| CHs CH2CH2CHa A118 | c-CaHr CH(CHo)2 ATT | CoHs CH2CH2CHs A119 | ¢-CsHo CH(CHs)2 A78_| CH=CH2 CH2CH2CHa A120 | o-CoHis CH(CHa)2 A-T9_| CHaCH2CHs CH2CH2CHs A-t21 | CH2-o-CoHs CH(CHa)2 ‘A:80__| CH(CHs)2 CH2CH2CHa ‘A122 | CH(CHa)-c-CsHs | CH(CHs)2WO 2014/053401 23 PCT/EP2013/070154 R® Re R® Re A123 | CHo-c-CsHo CH(CHa)2 A-165 | CH>CH.CN C(CHs)s A-124 | CH2-c-CeHis CH(CHs)2 A-166 | CH2CH-CI C(CHs)s A-125 | CoHs CH(CHa)2 A167 | o-CHs C(CHs)s, A-126 | CHs CH2CH2CH2CH3, A-168 | c-CaH7 C(CHs)s A-127 | CoHs CH-CH.CH.CHs _|| A-169 | o-C:Ho C(CHs)s A-128 | CH=CH2 CH2CH2CH2CH3, A-170 | c-CoHia C(CHs)s ‘A129 | CH.CH.CHs CH-CHCH.CHs _|| A-171 | CHo-c-CsHs C(CHs)s A-130 | CH(CHs)2 CH2CH2CH2CH3 A-172 | CH(CHs)-c-CsHs | C(CHs)s A-131 | CHoCHoCH.CHs | CH¢CH.CH.CHs _| | A-173 | CHo-c-CsHo [C(CHs)s A-132 | C(CHs)s CH2CH2CH2CH3 A-174 | CHe-c-CeHis C(CHs)s. A-133 | CH2CH(CHs)2___| CH¢CHCHACHs _|| A-175 | CsHo [C(CHa)s A-134 | CH(CHs)CH2CHs | CH2CH2CH2CH3. A-176 | CHs (CHZCH(CHs)2 A135 | CHoCH=CH2 | CH-CH.CH.CHs _|| A177 | CoHo [.CH.CH(CHs)2 A-136 | CH2C=CH CH2CH2CH2CHs A-178 | CH=CHe (CHZCH(CHs)2 A-137 | CH(CHs)CH=CHz | CH¢CH.CH.CHs || A-179 | CHoCH.CHs __| CH-c-CsHs [CH.CH(CHs)2 A-155 | CH(CHs)2 C(CHs)s A-197 | CH(CHs)-c-CsHs | CH2CH(CHs)2 A156 | CHCH.CH.CHs | C(CHs)s A198 | CH2-o-CsHo [CH.CH(CHs)2 A-157 | C(CHs)s C(CHs)s A-199 | CH2-c-CeHis (CH2CH(CHs)2 A158 | CHCH(CHs)2__| C(CHs)s ‘A-200 | CoHs [CH.CH(CHs)2 A-159 | CH(CHs)CH2CHs | C(CHs)s A-201 | CHs (CH(CHs)CH2CHs A160 |CH:CH=CH. | C(CHs)s ‘A202 | CzHs | CH(CHs)CH:CHs A-161 | CH2C=CH C(CHs)s A-203 | CH=CH2 (CH(CHs)CH2CHs A-162 | CH(CHs)CH=CH2 TC(CHa)s A-204 | CH2CH2CH3 | CH(CHs)CH2CHs A-163 | CHF2 C(CHs)s A-205 | CH(CHs)2 (CH(CHs)CH2CHs A164 | CHzCl C(CHa)s ‘A206 | CH2CH:CH:CHs | CH(CH:)CH2CHs24 Wo 2014053401 PCT/EP2013/070154 R® Re Re Re A207 | C(CHs)s CH(CHs)CH2CHs || A-249 | CHo-c-CoHis | CHoCH=CH? A-208 | CH2CH(CHs)2 (CH(CH3)CH2CHs A-250 | CeHs | CH2CH=CH2 A209 | CH(CHs)CH2CHs_| CH(CHs)CH2CHs || A-251 | CHs CH-C=CH A-210 | CH2CH=CH2 (CH(CHa)CH2CHs A-252 | CoHs (CH2C=CH A211 | CH;C=CH CH(CHs)CH:CHs _| | A-253 | CH=CH, | CH.C=CH A-212 | CH(CHs)CH=CH2 | CH(CHs)CH2CHs A-254 | CH2CH2CHs (CH2C=CH A213 | CHF? CH(CHs)CH:CHs _| | A-255 | CH(CHs)2 | CH.C=CH A-214 | CHCl (CH(CHa)CH2CHs A-256 | CH2CH2CH2CHs (CH2C=CH A216 | CH>CH2CN CH(CHs)CH:CHs _| | A-257 | C(CHs)s CH.C=CH A216 | CH.CH.CI CH(CHs)CH:CHs || A-258 | CH:CH(CHs)2___| CHC=CH A217 | C-CsHs CH(CHs)CH:CHs _| | A-259 | CH(CHs)CH:CHs_| CH,C=CH A218 | -CsHr CH(CHs)CH.CHs _| | A-260 | CH:CH=CHz CH.C=CH ‘A-219 | c-CsHo (CH(CHs)CH2CHs A-261 | CH2C=CH ‘CH2C=CH A220 | o-GsHi1 CH(CHs)CH:CHs _| | A-262 | CH(CHs)CH=CH2 | CH2C=CH ‘A-221 | CHz-c-C3Hs. (CH(CHs)CH2CHs A-263 | CHF2 (CH2C=CH A222 | CH(CHs)-c-CsHs_| CH(CHs)CHCHs _| | A-264 | CHCl CH.C=CH ‘A-223 | CHz-c-CsHo (CH(CHs)CH2CHs A-265 | CH2CH2CN ‘CH2C=CH A224 | CHo-c-CoHir CH(CHs)CH:CHs _| | A-266 | CH,CH,CI [[CH.CeCH ‘A-225 | CoHs (CH(CHs)CH2CHs A-267 | c-C3Hs (CH2C=CH A226 | CHs CH;CH=CH2 A268 | c-CsHr [[CH.C=CH A-227 | CoHs (CH2CH=CH2 A-269 | c-CsHo (CH2C=CH A:228 | CH=CH? ‘CH:CH=CH2 A270 | Gs | CHeC=CH A-229 | CH2CH2CH3 (CH2CH=CH2 A-271 | CH2-c-CaHs (CH2C=CH A230 | CH(CHs)2 CH:CH=CH2 A272 | CH(CHs)-c-CsHs | CHC=CH A-231 | CH2CH2CH2CHs (CH2CH=CH2 A-273 | CH2-c-CsHo (CH2C=CH A-232 | C(CH:)s CH:CH=CH2 A274 | CHrc- CoH: CH.C=CH A-233 | CH2CH(CHs)2 (CH2CH=CH2 A-275 | CeHs (CH2C=CH A234 | CH(CHs)CH.CHs_| CHoCH=CHz A276 | CHs CH(CHs)CH=CHz A235 | CH.CH=CHe ‘CH.CH=CH2 A277 | CoHs CH(CHs)CH=CH, ‘A-236 | CH2C=CH (CH2CH=CH2 A-278 | CH=CH2 (CH(CHs)CH=CH2 A237 | CH(CHs)CH=CH2 | CH:CH=CHz ‘279 | CH.CH.CHs CH(CHs)CH=CH, ‘A-238 | CHF2 (CH2CH=CH2 A-280 | CH(CHs)2 (CH(CHs)CH=CHz A239 | CHCI CH.CH=CH2 ‘A281 | CH.CHoCH:CHs | CH(CHs)CH=CH. ‘A-240 | CH2CH2CN (CH2CH=CH2 A-282 | C(CHs)s (CH(CHs)CH=CHz A241 | CH.CH.CI CH.CH=CH2 ‘A283 | CHCH(CHs)2__| CH(CHs)CH=CH. ‘A-242 | c-CsHs (CH2CH=CH2 A-284 | CH(CHs)CH2CHs | CH(CHs)CH=CH2 A243 | o-CsHr CH.CH=CH2 A285 | CH.CH=CH. CH(CHs)CH=CH, ‘A-244 | c-CsHo (CH2CH=CH2 A-286 | CH2,C=CH (CH(CHs)CH=CH2 A245 | o-CeHi1 CH.CH=CH2 ‘A287 | CH(CHs)CH=CH, | CH(CHs)CH=CH. ‘A-246 | CHe-c-C3Hs. (CH2CH=CH2 A-288 | CHF (CH(CHs)CH=CH2 A247 | CH(CHs)-c-CsHs_| CHsCH=CHz A289 | CH.CI [/CH(CHs)CH=CH. ‘A-248 | CHe-c-CsH9 (CH2CH=CH2 A-290 | CH2CH2CN (CH(CHs)CH=CH2WO 2014053401 25 PCT/EP2013/070154 Re Re Re Re A-291 | CH2CHZCI CH(CHs)CH=CHe _ || A-333 | CH-CH(CHs)2 CH.Cl A-292 | o-CaHs CH(CHs)CH=CHe || A-334 | CH(CHa)CH2CHs | CHCl A-293 | c-CuHr CH(CHs)CH=CHe _ || A-336 | CH:CH=CH2 CH.Cl A-294 | c-CsHo CH(CHs)CH=CH2 || A-336 | CH2C=CH CHCl A-295 | c-CoHi CH(CHs)CH=CH2 || A-337 | CH(CHa)CH=CH2 | CH2CI A-296 | CH-o-CsHs CH(CHs)CH=CHe _ || A-338 | CHF CHCl ‘A-297 | CH(CHa)-0-CaHs | CH(CHs)CH=CH2 _| | A-339 | CHCl CH.Cl A-298 | CH-o-CsHo CH(CHs)CH=CHe _ || A-340 | CH2CH2CN CH.CI ‘A-299 | CHe-c-CsHo CH(CHs)CH=CH2 _ || A-344 | CH2CHZCI CH.CI A-300 | CcHs CH(CHs)CH=CHe _ || A-342 | o-CaHs CH.Cl A-301 | CHa CHF. A343 | c-CuHr CHCl A-302 | CoHs CHF. A344 | c-CsHe CHCl A-303 | CH=CH2 CHF2 A345 | c-CoHi CH.CI ‘A-304 | CH2CH:CHs CHF, A:346 | CHz-o-C3Hs CHCl ‘A-305 | CH(CHs)2 CHF2 A:347 | CH(CHa)-c-CaHs | CHCl A-306 | CH2CH2CH2CHa | CHF A-348 | CHz-o-CsHo CHCl A-307 | C(CHa)s CHF2 A-349 | CHeo-CoHi CH.CI A-308 | CHsCH(CHs)2 CHFe A-350 | CoHs CHCl A-309 | CH(CH)CH2CHs | CHF A-351 | CHa CH2CH2CN A-310 | CH2CH=CH2 CHF2 A352 | CoHs ‘CH2CH2CN A-311 | CH2C=CH CHFe ‘A-353 | CH=CHe CH:CH2CN A-312 | CH(CHa)CH=CH2_| CHF2 ‘A-354 | CH2CH:CHs ‘CH2CH2CN A-313 | CHF2 CHFe A-355 | CH(CHa)2 (CH:CH2CN A-314 | CHCl CHF2 ‘A:356 | CH2CH2CH2CHa _| CH2CH2CN A-315 | CH2CH2CN CHFe A-357 | C(CHa)s ‘CH2CH2CN A-316 | CH-CH.CI CHF2 A:358 | CH2CH(CHs)2 ‘CH2CH2CN A317 | o-CsHs CHF, ‘A-359 | CH(CHa)CH2CHs | CH2CH2CN A-318 | c-CuHr CHF2 A-360 | CH-CH=CH2 ‘CH2CH2CN A-319 | c-CsHe CHF. A-361 | CH;C=CH ‘CH:CH2CN A-320 | c-CoH CHF2 ‘A:362_ | CH(CHa)CH=CH2_| CH2CHoCN A-321 | CHo-CsHs CHF. A-363 | CHF: ‘CH:CH2CN A-322 | CH(CHa)-c-CaHs | CHF2 A-364 | CH-CI ‘CH2CH2CN A-323 | CHo-CsHo CHFe A-365 | CH;CH.CN ‘CH:CH2CN A-324 | CHo-CoHi CHF2 A-366 | CH-CH2CI ‘CH2CH2CN A-325 | CoHs CHFe A367 | 6-CaHs ‘CH:CH2CN A-326 | CHa CHCl A:368 | o-CiHr ‘CH2CH2CN A-327 | CoHs CHCl A369 | 6-CsHe ‘CH:CH2CN A-328 | CH=CHe CHCl A370 | CoH ‘CH2CH2CN A-329 | CH2CH:CHs CHCl A371 | CHz--CsHs ‘CH:CH2CN ‘A-330 | CH(CHs)2 CHCl A:372 | CH(CHa)-c-CaHs | CH2CHoCN A-331 | CHsCH2zCH2CHa _| CH2CI A:373 | CHz--CsHo CH2CH2CN ‘A-332 | C(CHo)s CHCl A:374 | CHz-c-CsHo CH2CH2CNWO 2014053401 26 PCT/EP2013/070154 Re Re Re Re A375 | CeHts CH.CH.CN AIT | -CHs OCH A-376 | CHs CH2CHZCI A418 | 6-CaHr 6-CoHs A377 | Cats CHACH.CI A419 | -CsHe OCH A-378 | CH=CHo CH2CHZCI A-420 | 6-CoHis o-CoHs A-379 | CH:CH.CHs ‘CHCH.CI A421 | CHro-CoHs o-CiHs A-380 | CH(CHs)2 CH2CHZCI A-422 | CH(CHs)-c-CaHs | o-CaHs A-381 | CHsCH2CH2CHs _| CH2CH.CI ‘A-423 | CHr-o-CsHo o-CaHs A-382 | C(CHs)s CH2CHZCI A424 | CHo-c-CoHi1 6-CoHs A-383 | CHsCH(CHa)e ‘CHACH.CI A-425 | Cots o-CaHs A-384 | CH(CHs)CH2CHs_| CH2CH,CI ‘A426 | CHs o-CsHr A-385 | CHsCH=CH2 CHACH.CI A427 | Colts Cir A-386 | CH2C=CH ‘CH2CHZCl ‘A-428 | CH=CH2 o-CsHr ‘A-387 | CH(CH:)CH=CHe | CH2CH.CI A-429 | CHsCH2CHs Cir A388 | CHFe CH.CH,CI A-430 | CH(CHs)2 o-CsHr A-389 | CHCl ‘CH2CH.CI A-431 | CH2CH2CH2CHa _| 6-CiHr ‘A-390 | CH:CH2CN CH2CH,Cl A-432 | C(CHa)s o-CiHy A-391 | CHsCH-Cl CH2CH.CI A-433 | CHCH(CHa)o Cir A392 | o-CsHs ‘CH-CH,Cl A-434 | CH(CH:)CH2CHs_| 6-CsHy A-393 | c-CsHr CH2CH;CI ‘A-435 | CH2CH=CHe CH A-394 | 6-CsHe CHACH.CI ‘A-436 | CH2C=CH Cir A-395 | 6-CoHis CHeCH-CI ‘A-437 | CH(CHs)CH=CHo | 6-CaHy ‘A-396 | CHs-0-CsHs CH.CH.CI A-438 | CHF Cir A-397 | CH(CHs)-c-CsHs_| CH-CH-CI A-439 | CHCl o-CaHr ‘A-398 | CHs-0-CsHo ‘CHACH.CI ‘A-440 | CHsCH2CN Cir A-399 [ CHr-o-CoHs CHeCH.CI ‘A-441 | CH.CH-CI o-CsHr A400 | Gets ‘CHACH.CI A-442 | o-CaHs Cir ‘A-401 | CHs 6-CaHs ‘A443 | CAH o-CsHr A-402 | Colts o-CaHs A444 | o-CsHo Cir ‘A-403 | CH=CH. o-CoHs A-445 | 6-CoHi1 o-CsHr A-404 | CHsCH2CHs o-CaHs A-446 | CHs-o-CaHs Cir ‘A-405 | CH(CHs)2 o-CaHs A-447 | CH(CHs)-o-CoHs | 6-CsHy A-406 | CHsCH2CH2CHa_| o-CaHs ‘A-448 | CHs-o-CsHo Cir A-407 | C(CHs)s o-CaHs A-449 | CHr-o-CoHis o-CsHr A-408 | CHsCH(CHa)e o-CaHs A-450 | CsHs Cir A-409 | CH(CHs)CHzCH> | o-CaHs A-451 | CHa 6-CsHo A-410 | CHsCH=CH2 o-CaHs A482 | Cots o-CsHe ‘A411 | CH.C=CH o-CsHs A-453 | CH=CH2 o-CsHo A-412 | CH(CH:)CH=CHp | 6-CaHs A-454 | CH:CH2CHs o-CsHe A413 | CHF, o-CsHs A-455 | CH(CHs)2 6-CsHo A-414 | CHCl o-CaHs A-456 | CHxCH:CH2CHa _| 6-C:Ho ‘A-415 | CH:CHACN o-CsHs A-457 | C(CHa)s o-CsHo A-416 | CHsCH-Cl o-CaHs ‘A-458 | CH2CH(CHs)2 o-CoHeWO 2014053401 a7 PCT/EP2013/070154 Re Re Re Re ‘A-459 | CH(CH:)CHACHs | 6-C:He A-501 | CH CHe-c-C3Hs ‘A-460 | CH2CH=CH2 6-CsHs ‘A-602 | CoHs (CHo-c-CaH ‘A-461 | CH.C=CH o-CoHe ‘A-503 | CH=CHe CHe-c-C3Hs ‘A-462 | CH(CHs)CH=CHe | o-CsHo A-604 | CHzCH2CHs (CHo-c-CaH A-463 | CHF o-CsHe ‘A-505 | CH(CHa)2 CHo-c-CaHs A-464 | CHCl o-CsHe ‘A-606 | CHzCH2CH2CHa | CH-0-CaHs A-465 | CHsCH2CN o-CeHe A-807 | C(CHs)s CHo-c-CaHs A-466 | CH.CH.CI 6-CsHs A-608 | CHzCH(CHs)2__| CHr-c-CsHs A467 | 6-CsHs o-CsHe ‘A-509 | CH(CHa)CH2CHs | CH2-0-CaHs A-468 | ¢-CsHr 6-CsHs ‘A610 | CHsCH=CH2 CHo-c-CsHs | A-469 | 6-CsHo o-CeHe A811 | CHsC=CH CHo-c-CaHs A470 | 6-H 6-CsHs ‘A612 | CH(CHs)CH=CHe_| CHz-0-C3Hs A471 | CHs-0-CoHs o-CsHe A513 | CHF2 (CHo-c-CaHs A-472 | CH(CHs)-c-CsHs_| o-CsHlo A814 | CHCl CHo-c-CsHs | ‘A473 | CHi-0-CsHo -CsHe A-515 | CHsCH2CN (CHo-c-CaHs A474 | CHe-o-CcH1 6-CsHs A816 | CH.CH.CI CHe-c-CsHs A-AT5 | CoHs o-CsHe A517 | &-C3Hs (CHo-c-CaHs A476 | CHa o-CcH A818 | o-CiHr CHe-c-CsHs A477 | CoHs o-CeHit A519 | c-CsHo (CHo-c-CaH ‘A478 | CH=CHe oC A820 | -CsHit (CHe-o-CaHs A479 | CH:CH2CHs o-CoHns ‘A-621 | CHr-o-CaHs (CHo-c-CaH ‘A-480 | CH(CHs)2 oC ‘A-822 | CH(CHs}-0-CsHs_ | CH2-0-CaHs A-481 | CHsCH2CH2CHs _| 6-CoHss ‘A-623 | CHr-o-CsHo (CHo-c-CaH A-482 | C(CHs)s o-CeHn A824 | CHo-CeHi (CHo-c-CaHs A-483 | CHsCH(CHa)2___| 6-CoHss A-625 | CoHs (CHo-c-CaH ‘A-484 | CH(CHa)CH2CHs | o-CeHis A-526 | CH CH(CHs)-c-CsHs ‘A-485 | CH:CH=CH> o-CoHn A827 | CoHs CH(CH:)--CaHs ‘A-486 | CH2C=CH Cen ‘A-28 | CH=CHo CH(CHs)-c-CaHs ‘A-487 | CH(CHs)CH=CH? | o-CeHi A629 | CHsCHsCHs CH(CH:)-c-CaHs A-488 | CHF Cen ‘A-830 | CH(CHa)e A-489 | CHCl o-CoHi1 A-631 | CHxCH2CHsCHs ‘A-490 | CHsCH2CN Cen A-832 | C(CHa)s ‘A-491 | CH.CH-CI o-CcHis A633 | CH2CH(CHs)2___| CH(CHs)-c-CsHs A-492 | 6-CaHs Cen ‘A-834 | CH(CHa)CH2CHs_ | CH(CHs)-o-CHs A-493 | 6-CsH 6-OcHns ‘A-635 | CHsCH=CH2 CH(CH;)-c-CsHs A-494 | c-CsHo oC ‘A-836 | CH2C=CH CH(CHs)-c-CsHs, A495 | o-CsH 6-CsHn ‘A537 | CH(CHs)CH=CH2_| CH(CHa)-c-CaHs ‘A-496 | CHs-0-CaHs CH A-638 | CHF CH(CHs)-c-CaHs A-497 | CH(CHs)-c-C:Hs | ¢-CeH1 A539 | CHCl CH(CH;)-c-CsHs ‘A-498 | CHs-0-CsHo CH A-640 | CHsCH2CN CH(CHs)-c-CaHs, A-499 | CHr-c-CoHi o-OcHns A641 | CH.CH.Cl CH(CH:)-c-CaHs A-600 | CcHs CoH A-642 | c-CaHs CH(CHs)-c-CaHs,WO 2014053401 28 PCT/EP2013/070154 Re Re Re Re A543 | o-CiHr CH(CH,)-c-CaHs | | A-585 | CH,CH=CH, CHao-CsHit A544 | o-CsHo CH(CHs)-c-CaHts _| | A-586 | CHzC=CH (CHe-c-CoHti1 A545 | O-CeHi CH(CH,)-c-CaHs | | A-587 | CH(CHs)CH=CH. | CHz-o-CsHin A646 | CHo-o-CaHs CH(CHs)-c-CaHls_| | A-588 | CHF CHe-o-CoHi1 ‘A-547 | CH(CHs)-c-CaHs | CH(CH3)-0-C:Hs || A-589 | CHLCI CHae-CsHit A648 | CHo-o-CsHo CH(CHs)-c-CsHls_| | A-690 | CH>CH2CN (CHe-c-CoHi1 ‘A549 | CHo-o-CeHit CH(CHa)-c-CaHs | | A591 | CHsCH.CI CHao-CsHit A-860 | CoH CH(CHs)-c-CaHs || A-592 | c-CaHs CHe-o-CoHi1 A551 | CHe CHao-CsHo A-593 | 6-CiHr CHao-CsHit A852 | CHs CHz-o-CsHs ‘A-504 | 6-CsHe CHeo-CoHi1 ‘A-553 | CH=CHe (CHac-CsHo A595 | 6-CaHit CHeo-CsHi1 ‘A-654 | CH2CH2CHs CHz-o-CsHs ‘A-696 | CHr-0-CaHs CHe-o-CoHi1 ‘A555 | CH(CHs)2 (CHo-o-CsHo ‘A-597 | CH(CHs)-c-CaHs | CHo-o-CsHit ‘A656 | CH2CH2CH:CHa_| CHr-0-CsHo ‘A-698 | CH2-0-CsHo CHeo-CoHi1 A587 | (CHa) (CHa-o-CsHo A-899 | CHs-o-CoHis CHao-CsHit A-668 | CH:CH(CHs)2__| CHz-o-CsHo A-600 | CoHs CHzo-CoHi1 ‘A-559 | CH(CHs)CHzCH | CH-o-CsHo ‘A-601 | CH CeHs ‘A-660 | CH:CH=CH2 CHz-o-CsHs A602 | CoHs CoH ‘A561 | CH2C=CH CHo-c-CsHo ‘A-603 | CH=CHe CoH ‘A-562 | CH(CHs)CH=CH2 | CHro-CsHe ‘A-604 | CH.CH.CHs CoH ‘A-863 | CHF2 CHo-c-CsHs A-605 | CH(CHs)2 CoHs ‘A564 | CH.CI CHa-CsHe ‘A-606 | CH2CH:CH.CHs | CeHs ‘A-665 | CH:CH2CN CHo-c-CsHs A-607 | C(CHs)a CoHs ‘A-566 | CH2CH.CI (CHo-CsHo ‘A-608 | CHaCH(CHa)o | CeHs A567 | o-CsHs CHo-c-CsHs A-609 | CH(CHs)CH2CHs _| Colts A568 | o-CiHr CHao-CsHo ‘A-610 | CH2CH=CH2 CoH ‘A569 | o-CsHo CHz-o-CsHs A611 | CH=CH CoHs A570 | o-CeHis CHao-CsHo ‘A-612 | CH(CHs)CH=CHe | CeHs A871 | CHz-o-CaHs CHz-o-CsHs A613 | CHF CoH A572 | CH(CHs)-c-CaHs | CHro-CsHo A614 | CHC! CoH A873 | CHz-o-CsHo CHz-o-CsHs A615 | CH.CH.CN CoH A574 | CHo-o-CeHit (CHo-6-CsHo A-616 | CH2CH.Cl CeHs A875 | CoHs CHzo-CsHs A617 | c-CHs CoHs A576 | CHe CHao-CoHit A618 | CH CeHs A877 | CHs (CHe-6-Colti1 A619 | -C:Ho CoH ‘A578 | CH=CHe CHao-CoHit A620 | o-CeHit CoHs ‘A-679 | CH2CH2CHs (CHe-6-Colti1 A-621 | CH2-c-CaHs CoH ‘A580 | CH(CHs)2 CHa-6-CoHit ‘A-622 | CH(CHs)-c-CaHs | CeHs ‘A681 | CH:CH2CH:CH | CHr-c-CoHi1 ‘A-623 | CH2-c-CsHo CoH ‘A582 | C(CHs)s CHe-c-CoHi1 ‘A-624 | CH2-0-CsHo CoH ‘A-683 | CH:CH(CHs)2__| CHz-o-CoH11 A625 | CoHs CoH ‘A684 | CH(CHs)CH2CHa_| CH2-o-CoHi1 A-626 | CHs (CHo-c-CiHrWO 2014053401 29 PCT/EP2013/070154 Re Re Re Re A-627 | CoHs (CHo-c-CaHr A-669 | c-CsHlo CHeCHo-c-CaHs ‘A-628 | CH=CHe CHeo-CaHr A670 | o-CsHi1 CHCHo-c-C3H5, A-629 | CH2CH2CHs (CHo-c-CaHr ‘A-671 | CHz-o-CoHs CHeCHo-c-CaHs A-630 | CH(CH3)2 CHeo-CaHr A672 | CH(CHa)}-0-CsHs_| CHsCH2-6-CsHs A-631 | CH2CH2CH2CHa_ | CHz-0-CaHr ‘A-673 | CHr-o-CsHo CHeCHo-c-CaHs A-632 | C(CHs)s, CHo-CaHr A674 | CHro-CeHi CHCH2-c-C3H5 ‘A-633 | CH¢CH(CHs)2__| CHr-o-CaHty A675 | CoHs CHeCHo-c-CaHs ‘A-634 | CH(CHs)CH2CHs | CHz-0-CiHr A-676 | CHs CHa(CH2)sCHs: ‘A-635 | CH2CH=CH2 CHo-c-CaHr A677 | CoHs CHe(CH2)sCHs ‘A-636 | CH2C=CH CHo-e-CaHy A-678 | CH=CHe CHa(CH2)sCHs. ‘A-637 | CH(CHs)CH=CHo_| CHz--CsH7 A-679 | CHsCH2CHs CHe(CH2)sCHs A-638 | CHF CHoo-CaH ‘A-680 | CH(CHa)2 CHa(CH2)sCHs. A639 | CHCl CHeo-CaHr ‘A681 | CH2CH2CH2CHs | CH2(CHz)sCHa A-640 | CHsCH.CN CHo-o-CaH A-682 | C(CHa)s CHa(CH2)sCHs. ‘A-641 | CHCH.CI CHeo-CaHr A-683 | CHzCH(CHs)2__| CHo(CH2)sCHs A-642 | o-CaHs (CHo-o-CaH ‘A-684 | CH(CHa)CH2CHs | CHa(CH2)sCHe A643 | o-CaH CHr-c-CaHy ‘A-685 | CH:CH=CH2 CHz(CH2)sCHa A-644 | c-CsHo (CHo-c-CaH ‘A-686 | CH2C=CH CHa(CHa)sCHs A645 | c-CoHi1 CH-c-CaHty ‘A687 | CH(CHs)CH=CH2 | CH.(CHz)sCHs ‘A-646 | CHr-o-CoHs CHe-c-CaHr ‘A-688 | CHF CHe(CH2)sCHa A-647 | CH(CHs)}-0-CsHs_ | CHs-0-CuHr A-689 | CH.CI CHa(CH2)sCHs. ‘A-648 [| CHr-o-CsHo CHo-c-CaHr ‘A-690 | CH2CH-CN CHe(CHa)sCHa A-649 | CHeo-CeHi CHo-CaHr A-691 | CH.CH.CI CHA(CH2)sCHs. A-650 | CoHs (CHo-c-CaHr ‘A-692 | c-Catts CHe(CH2)sCH A-651 | CHs CH2CH2-c-C3Hs5 A-693 | c-CaH CHA(CH2)sCHs. A-652 | CoHs CHeCH2-c-CaHs A-694 | c-CsHls CHe(CH2)sCHs ‘A-653 | CH=CH CHeCHa-0-C3H5 A-695 | o-CsHi1 CHA(CH2)sCHs. A-654 | CH:CH2CHs CHeCH2-c-CaHs ‘A-696 | CHr-o-CoHs CHe(CH2)sCHs A-655 | CH(CHa)2 CHeCH-0-CaH5, ‘A-697 | CH(CHa)}-0-CsHs_ | CHa(CHz)sCHs A-656 | CH>CH-CH:CHs _| CHzCHz-c-CaHs A698 | CHr-o-CsHo CHz(CH2)sCH A-657 | C(CHa)s CHeCHa-0-CaH5 A-699 | CHro-CeHi CHa(CH2)sCHs. A-658 | CH>CH(CHs)2__| CHsCHz-c-CsHs A-700 | CoHs CHa(CHa)sCHa ‘A-659 | CH(CHa)CH2CHs | CHsCHo-0-CsHs A-701 | CHs CH(CHs)CH(CHa)2 ‘A-660 | CH:CH=CH2 CHsCH-c-CsHs A-702 | CHs CH(CHs)CH(CHs)2 ‘A-661 | CHzC=CH CH2CHa-c-CaHs ‘A-703 | CH=CHe CH(CHs)CH(CHa)2 ‘A-662 | CH(CHs)CH=CH2 | CH2CHz-0-CsHs A-704 | CH/CH-CHs CH(CHs)CH(CHs)2 A-663 | CHF CHCHe-c-CaHs A-705 | CH(CH2)2 CH(CHs)CH(CHa)2 A-664 | CH.CI CH2CHr-c-CsHs ‘A-706 | CH2CH2CH2CHs _ | CH(CHs)CH(CHs)2 ‘A-665 | CH:CH2CN CHeCHa-c-CaHs A-707 | C(CHa)s, CH(CHs)CH(CHa)2 A-666 | CH:CH,CI (CHsCH-c-CsHs A-708 | CH2CH(CHs)2__| CH(CHs)CH(CHs)2 A-667 | c-CaHs CHeCHo-c-CaHs A-709 | CH(CHs)CH2CHs_ | CH(CHa)CH(CHs)2 A-668 | o-CiHy CH2CH-c-CsHs ‘A-740 | CH:CH=CH2 CH(CHs)CH(CHa)210 15 WO 2014/053401 30 PCT/EP2013/070154 Re Re Re Re A-T11 | CH>C=CH (CH(CHs)CH(CHs)2_| | A-729 | CHa{CHz)-c-C3Hs ‘A724 | CHo-CoHit (CH(CHs)CH(CHa)2_| | A-742 | CH(CHs)CH(CHs)2_ | CH(CHa)CH(CHa)2 4-725 | CoHs (CH(CHs)CH(CHs)2_| | A-743 | CHACHz)sCHs | CHa{CH2)sCHs ‘A-726 | CHa (CH.(CH2)sCHs A744 | (CHo)s A727 | Gs (CH-(CH2)sCHs ‘A-745 | CH-CHSCH2 ‘A-728 | C(CHs)s (CH:(CHz)CHs c-CsHs: cyclopropyl; c-C4Hr: cyclobutyl; c-CsHe: cyclopentyl; c-CsH;1: cyclohexyl; CHz-¢-CsHs: cyclopropylmethyl; CH(CHs)-c-C2Hs: 1-cyclopropylethy|; CHz-c-CsHe: cyclopentylmethyl; CHo-c-CsHe: cyclopentylmethyl; CéHs: phenyl CHCHe-c-CsHs: 2-cyclopropylethyl; CHz-c-C:H7: 2-cyclobutylmethy|; 2-EtHex: CHsCH(C2Hs)(CHa)sCH A group of especially preferred compounds of formula | are compounds I+1 to I-40 of formula IA-1 which are listed in the table C in the example section. In one embodiment, a compound selected from the compounds I-1 to I-40 as defined in Table C in the Example Section at the end of the description, are preferred in the methods and uses according to the invention, In one embodiment, a compound selected from compounds I-11, I-16, I-21, 1-26, |-31 is the compound | in the methods and uses according to the invention, which are defined in accordance with Table C of the example section:10 15 20 25 WO 2014/053401 31 2013/0 70154 (At) Table C” RU [Re [R? [Re Re 1-11 | Me cl CFs C2Hs CoHs ie [or [er | CFs | Cas CoHs 1-21 | Me cl CFs CH(CHs)2_ | CH(CHa)2 126 [or [cl | CFs | CH(CHs)2_| CH(CHs)2 1-31 | Br Br CFs CoHs Cas In one embodiment, I-11 is the compound | in the methods and uses according to the invention. In one embodiment, I-16 is the compound | in the methods and uses according to the invention. In one embodiment, |-21 is the compound | in the methods and uses according to the invention. In one embodiment, |-26 is the compound | in the methods and uses according to the invention. In one embodiment, I-31 is the compound | in the methods and uses according to the invention. Methods of improving plant health The compounds of formula (|) as defined herein, or a stereoisomer, salt, tautomer or N-oxide thereof, or the compositions comprising them, are used for improving the health of plants when applied to plants, parts of plants, propagules of the plants or to their actual or intended locus of growth, Thus, the invention also relates to a method for improving the health of plants, which comprises treating the plant, a part of the plant, the locus where the plant is growing or is expected to grow, and/or the propagules from which the plant grows with the compound or composition used according to the invention. ‘As a matter of course, the compound of formula (I) is used in an effective and non-phytotoxic amount. This means that they are used in a quantity which allows to obtain the desired effect but which does not give rise to any phytotoxic symptom on the treated plant or on the plant grown from the treated propagule or treated soil10 15 20 25 30 35 40 WO 20147053401 32 rc 20131070154 The plants to be treated are generally plants of economic importance and/or men-grown plants. Thus, they are preferably selected from agricultural, silvicultural and ornamental plants. The term “plant health" (health of a plant) is defined as a condition of the plant and/or its products which is determined by several aspects alone or in combination with each other such as yield (for example increased biomass and/or increased content of valuable ingredients), plant vigor (for example improved plant growth and/or greener leaves (“greening effect"), quality (for ‘example improved content or composition of certain ingredients) and tolerance to abiotic and/or biotic stress. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. Each listed plant health indicator listed below, and which is selected from the groups consisting of yield, plant vigor, quality and tolerance to abiotic and/or biotic stress, is to be understood as a preferred embodiment of the present invention either each on its own or preferably in combination with each other. ‘One indicator for the condition of the plant is the crop yield. “Crop yield” is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting. Thus, the invention relates to a method for increasing the yield of a plant or its product. According to the present invention, “increased yield” of a plant, in particular of an agricultural, silvicultural and/or ornamental plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the compound or composition of the invention. Increased crop yield can be characterized, among others, by following improved properties of the plant: * increased plant weight, * increased plant height, * increased biomass such as higher overall fresh weight * higher grain yield + more tillers * larger leaves * increased shoot growth * increased protein content * increased oil content * increased starch content * increased pigment content10 15 20 25 30 35 40 WoO 2014/053401 33 PCT 20131070154 According to one embodiment of the present invention, the yield is increased by at least 1%. According to one embodiment of the present invention, the yield is increased by at least 2%. According to one embodiment of the present invention, the yield is increased by at least 4%. According to one embodiment of the present invention, the yield is increased by at least 5 %. According to another embodiment of the present invention, the yield is increased by least 10%. According to another embodiment of the present invention, the yield is increased by least 15%. According to another embodiment of the present invention, the yield is increased by least 30%. Another indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. Thus, the invention relates to a method for increasing the vigor of a plant or its product. Improved plant vigor can be characterized, among others, by following improved properties of the plant: * improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), * improved emergence, * enhanced root growth and/or more developed root system, * enhanced nodulation, in particular rhizobial nodulation, * bigger leaf blade, * bigger size, * increased plant weight, * increased plant height, * increased tiller number, * increased shoot growth, * increased root growth (extensive root system), * increased yield when grown on poor soils or unfavorable climate, * enhanced photosynthetic activity * enhanced pigment content (e.g. Chlorophyll content) * earlier flowering, * earlier fruiting, * earlier and improved germination, + earlier grain maturity, * improved self-defence mechanisms * improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, insects, heat stress, cold stress, drought stress, UV stress and/or salt stress + less non-productive tillers, + less dead basal leaves, * less input needed (such as fertilizers or water) + greener leaves10 15 20 25 30 35 40 WO 2014/033401 34 PCT/EP2013/070154 + complete maturation under shortened vegetation periods + less fertilizers needed, + less seeds needed, * easier harvesting * faster and more uniform ripening + longer shelf-life * longer panicles, * delay of senescence, * stronger and/or more productive tillers, * better extractability of ingredients + improved quality of seeds (for being seeded in the following seasons for seed production) * reduced production of ethylene and/or the inhibition of its reception by the plant The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the composition or active ingredients. Another indicator for the condition of the plant is the “quality” of a plant and/or the products of the respective plant. According to the present invention, enhanced quality means that certain crop characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the composition of the present invention. The quality of a product of the respective plant becomes manifest in several aspects. Thus, the invention relates to a method for increasing the quality of a plant or its product. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content increased protein content increased content of fatty acids increased metabolite content increased carotenoid content increased sugar content increased amount of essential amino acids improved nutrient composition improved protein composition improved composition of fatty acids improved metabolite composition improved carotenoid composition improved sugar composition improved amino acids composition * improved or optimal fruit color10 15 20 25 30 35 40 WoO 2014/053401 35 PCT 20131070154 + improved leaf color * higher storage capacity + higher processability of the harvested products Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic andlor abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. ‘Thus, the invention relates to a method for increasing the tolerance and/or resistance of a plant or its product against biotic and/or abiotic stress. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, "enhanced tolerance or resistance to biotic and/or abiotic stress factors" means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to wns, but without being treated with the compound or composition of the invention and (2.) that the negative effects are not diminished by a direct action of the composition on the stress factors, e.g. by its fungicidal or insecticidal action which directly destroys the microorganisms or pests, but rather by a stimulation of the plants’ own defensive reactions against said stress factors. plants exposed to the same condi Increased tolerance or resistance can be characterized, among others, by following improved properties of the plant or its product: when grown under the impact of biotic and/or abiotic stress factors. Negative factors caused by biotic stress such as pathogens and pests are widely known and range from dotted leaves to total destruction of the plant. Biotic stress can be caused by living organisms, such as: * pests (for example insects, arachnides, nematodes), * competing plants (for example weeds), * microorganisms such as phythopathogenic fungi bacteria, + viruses Negative factors caused by abiotic stress are also well-known and can often be observed as reduced plant vigor (see above), for example dotted leaves, "burned leaves", reduced growth, less flowers, less biomass, less crop yields, reduced nutritional value of the crops, later crop maturity, to give just a few examples. Abiotic stress can be caused for example by: extremes in temperature such as heat or cold (heat stress / cold stress), * strong variations in temperature, * temperatures unusual for the specific season, * drought (drought stress), + extreme wetness, + high salinity (salt stress), * radiation (for example by increased UV radiation due to the decreasing ozone layer),10 15 20 25 30 35 40 WO 2014/033401 36 PCT/EP2013/070154 + increased ozone levels (ozone stress) * organic pollution (for example by phythotoxic amounts of pesticides) + inorganic pollution (for example by heavy metal contaminants), Thus, in one embodiment, the invention relates to a method for increasing the resistance to heat, cold or strong variations in temperature. As a result of biotic and/or abiotic stress factors, the quantity and the quality of the stressed plants, their crops and fruits decrease. As far as quality is concerned, reproductive development is usually severely affected with consequences on the crops which are important for fruits or seeds. Synthesis, accumulation and storage of proteins are mostly affected by temperature; growth is slowed by almost all types of stress; polysaccharide synthesis, both structural and storage is reduced or modified: these effects bring to a decrease in biomass (yield) and to changes in the nutritional value of the product. Advantageous properties, obtained especially from treated seeds, are e.g. improved germination and field establishment, better vigor, more homogen field establishment. The above identified indicators for the health condition of a plant may be interdependent and may result from each other. For example, an increased resistance to biotic and/or abiotic stress may lead to a better plant vigor, e.g. to better and bigger crops, and thus to an increased yield. Inversely, a more developed root system may result in an increased resistance to biotic and/or abiotic stress. However, these interdependencies and interactions are neither all known nor fully understood and therefore the different indicators will be described separately. In one embodiment, the invention relates to a methods and uses according to the invention wherein the plant is an agricultural, silvicultural and/or ornamental plant. In one embodiment of the invention, the present invention provides the use of the compound of the invention for increasing the yield of a plant or its product, preferably of an agricultural, sil cultural and/or ornamental plant. In one embodiment of the invention, the present invention provides the use of the compound of the invention for increasing the vigor of a plant or its product, preferably of an agricultural, silvicultural and/or ornamental plant. In one embodiment of the invention, the present invention provides the use of the compound of the invention for increasing the quality of a plant or its product, preferably of an agricultural, silvicultural and/or omamental plant. In one embodiment of the invention, the present invention provides the use of the compound of the invention for increasing the tolerance andlor resistance of a plant or its product against biotic and/or abiotic stress, preferably of an agricultural, silvicultural and/or ornamental plant.10 15 20 25 30 35 40 WO 20147053401 37 rc 20131070154 In one embodiment of the invention, the present invention provides the use of the compound of the invention for increasing the yield and/or improving the vigor of a plant, e.g. of an agricultural, silvicultural and/or ornamental plant. In one embodiment of the invention, the tolerance of and/or resistance against biotic stress factors is enhanced. Thus, according to a preferred embodiment of the present invention, the inventive compounds or compositions are used for stimulating the natural defensive reactions of a plant against a pathogen and/or a pest. Thereby, the plant can be protected against unwanted microorganisms such as phytopathogenic fungi and/or bacteria or even viruses and/or against pests such as insects, arachnids and nematodes, and it has been found that the inventive compositions result in plant strengthening effects. Therefore, they are useful for mobilizing the plant's defense mechanisms against the attack of unwanted microorganisms and/or pests. Con- ‘sequently, the plant becomes tolerant or even resistant towards these microorganisms and/or pests. In one embodiment of the invention, the tolerance of and/or resistance against abiotic stress factors is enhanced. Thus, according to a further embodiment of the present invention, the inventive compounds or compositions are used for stimulating a plant's own defensive reactions against abiotic stress such as extremes in temperature, e.g. heat or cold or strong variations in temperature or temperatures unusual for the specific season, drought, extreme wetness, high salinity, radiation (e.g. increased UV radiation due to the decreasing ozone protective layer), increased ozone levels, organic pollution (e.g. by phythotoxic amounts of pesticides) and/or inorganic pollution (e.g. by heavy metal contaminants) In one embodiment of the invention, the inventive compositions are used for stimulating a plant’s own defensive reactions against abiotic stress, where the abiotic stress factors are preferably selected from extremes in temperature, drought, salt and extreme wetness. Therefore, the invention relates to the use of a compound of formula (|) as defined here! ‘composition comprising said compound, for * improving the health of a plant, and/or * for increasing the yield of a plant or its product, , and/or * for increasing the vigor of a plant or its product., and/or * for increasing the quality of a plant or its product, and/or * for increasing the tolerance and/or resistance of a plant or its product against biotic andjor abiotic stress, and/or * for increasing the resistance to heat, cold or strong variations in temperature. In one embodiment, the invention relates to a method for improving the health of a plant, which method comprises applying a compound of formula I, which is selected from the compounds I+1 to |-40 as defined in Table C. More specifically, the compound | is selected from compounds I- 11, 1-16, I-21, |-26, |-31 which are defined in accordance with Table C of the example section,10 15 20 25 30 35 40 WoO 2014/053401 38 PCT 2013/070154 more specifically compound I-11, more specifically compound I-16, more specifically compound 1-21, more specifically compound I-26, more specifically compound I-31 In one embodiment, the invention relates to a method for increasing the yield of a plant or its product, which method comprises applying a compound of formula |, which is selected from the ‘compounds I-1 to |-40 as defined in Table C. More specifically, the compound lis selected from ‘compounds I-11, I-16, I-21, I-26, |-31 which are defined in accordance with Table C of the example section, more specifically compound I-11, more specifically compound I-16, more specifically compound |-21, more specifically compound I-26, more specifically compound I-31. In one embodiment, the invention relates to a method for increasing the vigor of a plant or its product, which method comprises applying a compound of formula |, which is selected from the ‘compounds I-1 to |-40 as defined in Table C. More specifically, the compound lis selected from ‘compounds I-11, |-16, 1-21, I-26, |-31 which are defined in accordance with Table C of the example section, more specifically compound I-11, more specifically compound I-16, more specif cally compound |-21, more specifically compound I-26, more specifically compound I-31. In one embodiment, the invention relates to a method for increasing the quality of a plant or its product, which method comprises applying a compound of formula |, which is selected from the ‘compounds I-1 to |-40 as defined in Table C. More specifically, the compound lis selected from ‘compounds I-11, |-16, I-21, I-26, |-31 which are defined in accordance with Table C of the example section, more specifically compound I-11, more specifically compound I-16, more specifically compound |-21, more specifically compound I-26, more specifically compound I-31. In one embodiment, the invention relates to a method for increasing the tolerance and/or resistance of a plant or its product against biotic and/or abiotic stress, which method comprises. applying a compound of formula |, which is selected from the compounds I-1 to I-40 as defined in Table C. More specifically, the compound | is selected from compounds I-11, I-16, 1-21, 1-26, 1-31 which are defined in accordance with Table C of the example section, more specifically ‘compound I-11, more specifically compound I-16, more specifically compound I-21, more specifically compound I-26, more specifically compound I-31 In one embodiment, the invention relates to a method for increasing the resistance to heat, cold or strong variations in temperature, which method comprises applying a compound of formula |, which is selected from the compounds I-1 to I-40 as defined in Table C. More specifically, the ‘compound | is selected from compounds I-11, I-16, -21, I-26, 1-31 which are defined in accordance with Table C of the example section, more specifically compound I-11, more specifically ‘compound I-16, more specifically compound I-21, more specifically compound |-26, more specifically compound I-31 In one embodiment of the invention, the plant of which the health is to be improved by the treatment with the compound or composition of the invention is an agricultural plant. Agricultural plants are plants of which a part or all is harvested or cultivated on a commercial scale or which serve as an important source of feed, food, fibers (e.g. cotton, linen), combustibles (e.g. wood, bioethanol, biodiesel, biomass) or other chemical compounds. Agricultural plants also horticul tural plants, i.e. plants grown in gardens (and not on fields), such as certain fruits and vegetables.10 15 20 25 30 35 40 WoO 2014/053401 39 PCT 20131070154 It has to be emphasized that the above mentioned effects of the compound or composition according to the invention, i.e. enhanced health of the plant, are also present when the plant is not under biotic stress and in particular when the plant is not under fungal- or pest pressure. Itis evident that a plant suffering from fungal or insecticidal attack produces a smaller biomass and a smaller crop yield as compared to a plant which has been subjected to curative or preventive treatment against the pathogenic fungus or pest and which can grow without the damage caused by the biotic stress factor. However, the method according to the invention leads to an enhanced plant health even in the absence of any biotic stress and in particular of any phytopathogenic fungi or pest. This means that the positive effects of the compound or composition of the invention cannot be explained just by the fungicidal or insecticidal activities of the compounds of components (A) and (B), but are based on further activity profiles. But of course, plants under biotic stress can be treated, too, according to the methods of the present invention Method and uses for reducing nitrous oxide emission ‘As mentioned above, the uses and methods according to the invention also include methods for reducing nitrous oxide emission from soils. These methods may also be considered as methods improving plant health, due to the beneficial effect on the plant itself. Thus, the present invention relates to a method for reducing nitrous oxide emission from soils ‘comprising treating a plant growing on the respective soil and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows with at least one ‘compound of formula | according to the invention, more preferably a compound of formula IA, also preferably a compound of formula IB, also preferably a compound of formula IC, also preferably a compound of formula ID; more preferably a compound selected from the compounds I- 1 to I-40 as defined in Table C; more preferably a compound selected from compounds I-11, I- 16, 1-21, I-26, |-31 according to Table C/C’. The present invention relates to a method for reducing nitrous oxide emission from soils comprising treating a plant growing on the respective soil and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows with A) atleast one compound of formula | according to the invention, more preferably a compound of formula IA, also preferably a compound of formula IB, also preferably a compound of formula IC, also preferably a compound of formula ID; more preferably a compound selected from the compounds I-1 to I-40 as defined in Table C; more preferably a compound selected from compounds I-11, I-16, I-21, 1-26, I-31 according to Table C/C’, B) and at least one ammonium- or urea-containing fertilizer (compound B) selected from the group consisting of: (B1) inorganic fertilizer: NPK fertilizer, ammonium nitrate, calcium ammonium nitrate, ammonium sulfate; nitrate, ammonium sulfate and ammonium phosphate; (82) organic fertilizer: liquid manure, semi-liquid manure, stable manure and straw manure, worm castings, compost, seaweed and guano;10 15 20 25 30 35 40 Wo 2014/053401 40 PCr 2013/070154 The invention relates to such a method as described above, wherein the application of at least ‘one compound | (A) and at least one compound (B) is carried out with a time lag of at least 1 day. In addition, the present invention relates to a method for reducing nitrous oxide emission from soils as described above, wherein the ammonium- or urea-containing fertilizer (compound B) is applied together with at least one nitrification inhibitor (compound C) selected from the group consisting of 2-(3,4-dimethyl-pyrazol-1-yl)-succinic acid, 3,4-dimethylpyrazolephosphate (DMPP), dicyandiamide (DCD), 1H-1,2,4-triazole, 3-methylpyrazole (3-MP), 2-chloro-6- ((richloromethyl)-pyridine, 5-ethoxy-3-trichloromethyl-1,2,4-thiadiazol, 2-amino-4-chloro-6- methyl-pyrimidine, 2-mercapto-benzothiazole, 2-sulfanilamidothiazole, thiourea, sodium azide, potassium azide, 1-hydroxypyrazole, 2-methylpyrazole-1-carboxamide, 4-amino-1,2,4-triazole, 3-mercapto-1,2,4-triazole, 2,4-diamino-6-trichloromethyl-6-triazine, carbon bisulfide, ammonium thiosulfate, sodium trithiocarbonate, 2,3-dihydro-2,2-dimethyl-7-benzofuranol methyl carbamate and N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-alanine methyl ester. Nitrogen is an essential element for plant growth and reproduction. About 25% of the plant- available nitrogen in soils (ammonium and nitrate) originate from decomposition processes (mineralization) of organic nitrogen compounds such as humus, plant and animal residues and organic fertilizers. Approximately 5% derive from rainfall. On a global basis, the biggest part (70%), however, are supplied to the plant by inorganic nitrogen fertilizers. Without the use of nitrogenous fertilizers, the earth would not be able to support its current population. Soil microorganisms convert organic nitrogen to ammonium (NHs*) which is subsequently oxidized to nitrate (NOs) in a process known as nitrification. Nitrate is very important in agriculture, because it is one form of nitrogen which is preferably taken up by the plants due to its high plant-availability. However, nitrate is also highly mobile in the soil. As a consequence, it may be readily lost from soils leaching to groundwater. In addition, nitrogen is lost by denitrification which is the microbiological conversion of nitrate and nitrite (NO) to gaseous forms of nitrogen such as nitrous oxide (NO) and molecular nitrogen (Nz). As a result of the various losses, approximately 50% of the applied nitrogen is lost during the year following fertilizer addition (cf. Nelson and Huber; Nitrification inhibitors for corn production (2001). National Corn Handbook, lowa State University). Consequently, there is great concern that the intensive use of fertilizer and the application of livestock wastes may lead to increased nitrogen levels in the groundwater and surface waters which in turn could lead to increased eutrophication of lakes and streams. In addition, nitrogen fertilization and livestock wastes may increase the production of nitrous oxide, significantly contributing to the stratospheric ozone destruction and global warming. Be- sides nitrous oxide, carbon dioxide (CO2) and methane (CHs) are important gases produced by native and agricultural soils. Depending on various parameters such as weather and soil type, increased fertilization and tillage can additionally increase nitrous oxide emissions.10 15 20 25 30 35 40 WO 20147053401 a rc 2013/070154 As a consequence, one of the biggest challenge to the world community in the coming years will be the reduction of gases responsible for the greenhouse effect in the atmosphere or at least the stabilization of greenhouse gas concentrations in the atmosphere at a level that would pre- vent dangerous anthropogenic interference with the climate system. This concem is expressed in the Kyoto Protocol in which the ratifying countries commit to reduce their emissions of greenhouse gases or engage in emissions trading if they maintain or increase emissions of these gases. ‘One of the best known greenhouse gases is carbon dioxide. However, nitrous oxide is another cause of great concem. Throughout the 20th century and continuing into the 21st century, nitrous oxide has increased by 50 parts per billion in the atmosphere and is rising further by 0.25% each year. Although nitrous oxide only accounts for around 9% of the total greenhouse gas emissions, one has to keep in mind that it has a 300-fold greater global warming potential than carbon dioxide over the next 100 years and an atmospheric lifetime of approximately 150 years. The above listed trends may result in increased levels of nitrogen in natural waters, crop residue, and municipal and agricultural wastes, creating national and international concems about the environment and the public health. Dharnaraj P.S. in Lal and Lal (Editors) (Effects of pesticides on nitrification and denitrification (1988). Pesticides and Nitrogen Cycle) describes the effect of various pesticides on nitrification and denitrification. The studies described therein show that most fungicides do not have any effect on nitrification and denitrification. In addition, the method steps according to the invention as well as the surprising effect are not disclosed. Mosier et al. (Nitrous oxide emission from agricultural fields; Assessment, measurement and mitigation (1996). Plant and Soil 131: 95.108) summarized the effects of nitrification inhibitors ‘on NO emissions from fertilized soils. A number of studies indicated that nitrification inhibitors did limit NzO emission from soils fertilized with ammonium-based fertilizers. Furthermore, Kinney et al. (Effects of fungicides on trace gas fluxes (2004). Journal of Geo- physical Research 109: 1- 15) have hypothesized that the variations in gases flux from agricultural soils may also be affected by the quantity and type of agricultural chemicals (pesticides) used. They carried out field experiments and determined the effect to two commonly used multi- site fungicides, mancozeb and chlorothalonil, on trace gas exchange. Kinney et al. (Laboratory investigations into the effects of the pesticides mancozeb, chlorothalonil , and prosulfuron on nitrous oxide and nitric oxide production in fertilized soil (2008). Soil Biology & Biochemistry 37: 837-850) additionally investigated the effects of mancozeb, chlor- thalonil and the herbicide prosulfuron on N2O production by nitrifying and denitrifying bacteria in fertilized soil ‘Somda et al. (1991). Influence of biocides on tomato nitrogen uptake and soil nitrification and denitirification. Journal of Plant Nutrition 14 (11): 1187-99) investigated the impact of benlate, captan, and lime-sulfur fungicides compared to nitrification inhibitors on nitrification.10 15 20 25 30 35 40 WO 20147053401 42 rc 20131070154 WO 98/05607 is directed to the use of inorganic or organic polyacids for the treatment of inorganic fertilizers, in particular the use of the polyacids as a mixture with at least one nitrification inhibitor for the treatment of inorganic fertilizers, WO 08/059083 relates to a method for increasing the carbon dioxide sequestration from the atmosphere by treating a plant, a part of the plant, the locus where the plant is growing or is intended to grow and/or the plant propagules with certain active ingredients. The invention also relates to the use of the compounds for increasing the dry biomass of a plant. Nitrification and denitrification are the two main processes by which nitrous oxide is produced in soil environments. It is expected that the yearly application of nitrogen fertilizers and pesticides will more than double over the next 50 years. In addition, the agricultural cropland is expected to increase by 5,5 x 10® ha hectares by the year 2050 (of. Tilman et al. (2001): Forecasting agricul turally driven global environmental change. Science. Vol. 292: 281-284). As a consequence, agricultural soils will ikely have an ever-increasing influence on the global atmospheric budgets of carbon dioxide, nitrous oxide and methane. With respect to agricultural production systems, it could be shown that fertilization and tillage more than double N-O emissions from soils. There is also concer that the intensive use of fertilizer and the application of livestock wastes could lead to increased nitrogen levels in groundwater and surface waters, and that this in turn could lead to increased eutrophication of lakes and streams, Besides the potential impact on global warming, the production of NzO reduces the amount of nitrogen available to the plants. It was therefore an object of the present invention to provide a reliable method which solves the problems outlined above, and which should, in particular, reduce nitrous oxide emission from soils. In particular, from soils which are fertilized. ‘Surprisingly, we have found that this object is achieved when treating a plant and/or the locus such as the soil where the plant is growing or is intended to grow and/or the seeds from which the plant grows with at least one compound of formula | according to the invention (compound ‘A) and at least one ammonium- or urea-containing fertilizer (compound B) wherein the application of compound (A) and compound (B) is carried out with a time lag of at least 1 day. The object of the present invention can also be achieved when treating a plant and/or the locus such as the soil where the plant is growing or is intended to grow and/or the seeds from which the plant grows with an agrochemical mixture, comprising at least one compound of formula | according to the invention, in combination with at least one compound II as defined herein (compound group A), and at least one ammonium- or urea-containing fertilizer (compound B) wherein the application of the mixture comprising at least two compounds (A) and compound (8) must be carried out with a time lag of at least 1 day. The time gap between the application of a compound of formula | according to the invention (or a respective mixture thereof) (compound A) from the application of a fertilizer (compound B) is10 15 20 25 30 35 40 Wo 2014/053401 43 PCr 20131070154 the crucial method step because it could be shown that the joint application may have no impact or even results in an increased NO emission while only a timely separated application of a fungicide and a fertilizer according to the method of the present invention, results in a strong decrease of NzO emission. Consequently, the time gap between the application of a fungicide (compound A) and a fertilizer (compound 8) is a special technical feature which results in a surprising effect being a new and inventive technical teaching to any person skilled in the art. The application of active ingredients according to the method of the invention provides signifi- cant ecological and economical advantages. From an ecological stand point, the cutback of N2O emissions significantly reduces the impact of modem agriculture on the environment and its atmosphere as well as on global warming. In addition, losses of nitrogen to the groundwater, risk of eutrophication of lakes and streams are also minimized due to an optimized use of soil nitrogen. The compounds of formula | may be combined with further pesticides in the methods and uses. In one embodiment of the method according to the invention, the nitrous oxide emission from soils is reduced by applying a compound of formula | together with a compound Il selected from the group consisting of azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fenoxystrobin (flufenoxystrobin), fluoxastrobin, kresoxim-methyl, mandestrobin, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyribencarb, triclopyricarb (chlorodincarb), trifloxystrobin, 2-(2-(2,5-dimethyl- phenoxymethyl)-phenyl]-3-methoxy-acrylic acid methyl ester and 2-(2-(3-(2,6-di-chlorophenyl)- ‘1-methyballylidene-aminooxy-methyl)-phenyl)-2-methoxyimino-N-methyl-acetamide. In a preferred embodiment of the method according to the invention, compound 1! is a strobilurin selected from the group consisting of azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim- methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin and trfloxystrobin. In a preferred embodiment of the method according to the invention, compound II is a strobilurin selected from the group consisting of pyraclostrobin, orysastrobin, azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metominostrobin, picoxystrobin, pyribencarb and trifloxystrobin. In a preferred embodiment of the method according to the invention, compound 1! is a strobilurin selected from the group consisting of azoxystrobin, pyraclostrobin and trifloxystrobin. In an especially preferred embodiment of the method according to the invention, compound Il is pyraclostrobin. In one embodiment of the method according to the invention, compound (B) is an ammonium- or urea-containing fertilizer (compound B) selected from the group of inorganic fertilizer (B1) consisting of NPK fertilizer, ammonium nitrate, calcium ammonium nitrate, ammonium sulfate nitrate, ammonium sulfate and ammonium phosphate. In a preferred embodiment of the method according to the invention, compound (B) is selected from the group consisting of ammonium sulfate nitrate and ammonium sulfate. In another embodiment of the method according to the invention, compound (B) is an ammoni10 15 20 25 30 35 40 WoO 2014/053401 44 PCI 20131070154 um- or urea-containing fertilizer (compound B) selected from the group of organic fertilizer (B2) consisting of liquid manure, semi-liquid manure, stable manure and straw manure, worm castings, compost, seaweed and guano. Ina preferred embodiment of the method according to the inver manure. §n, compound (B) is In one embodiment of the method according to the invention, the application of at least one ‘compound (A) and at least one compound (B) is carried out with a time lag of at least 1 day. In a preferred embodiment of the method according to the invention, the application of at least ‘one compound (A) and at least one compound (8) is carried out with a time lag of at least 4 days. In another preferred embodiment of the method according to the invention, the application of at least one compound (A) and at least one compound (B) is carried out with a time lag of at least 8 days. In another preferred embodiment of the method according to the invention, the application of at least one compound (A) and at least one compound (B) is carried out with a time lag of at least 10 days. In yet another preferred embodiment of the method according to the invention, the application of at least one compound (A) and at least one compound (B) is carried out with a time lag of at least 16 days. In one embodiment of the method according to the invention, the nitrous oxide emission from soils is reduced by applying the compound of formula | according to the invention (compound A) and the ammonium. or urea-containing fertilizer (compound B) together with at least one nitrification inhibitor (compound C) selected from the group consisting of 2-(3,4-dimethyl-pyrazol-1- yl)-succinic acid, 3,4-dimethylpyrazolephosphate (DMPP), dicyandiamide (DCD), 1H-1,2,4- triazole, 3-methyloyrazole (3-MP), 2-chloro-6-(trichloromethyl)-pyridine, 5-ethoxy-3- trichloromethyl-1,2,4-thiadiazol, 2-amino-4-chloro-6-methyl-pyrimidine, 2-mercapto- benzothiazole, 2-sulfanilamidothiazole, thiourea, sodium azide, potassium azide, 1- hydroxypyrazole, 2-methylpyrazole-1-carboxamide, 4-amino-1,2,4-triazole, 3-mercapto-1,2,4- triazole, 2,4-diamino-6-trichloromethy!-S-triazine, carbon bisulfide, ammonium thiosulfate, sodium trithiocarbonate, 2,3-dihydro-2,2-dimethyl-7-benzofuranol methyl carbamate and N-(2,6- dimethylphenyl)-N-(methoxyacety!)-alanine methyl ester. In a preferred embodiment of the method according to the invention, the nitrous oxide emission from soils is reduced by applying the compound of formula | according to the invention (compound A) and the ammonium or urea-containing fertilizer (compound B) together with at least ‘one nitrification inhibitor (compound C) selected from the group consisting of 2-(3,4-dimethyl pyrazol-1-yl)-succinic acid, 3,4-dimethylpyrazole-phosphate (DMPP), dicyandiamide (DCD), 1H- 1,2,4-triazole, 3-methylpyrazole (3-MP), 2-chloro-6-(trichloromethyl)-pyridine and 5-ethoxy-3- trichloromethy!-1,2,4-thiadiazol.10 15 20 25 30 Wo 2014/053401 45 PCr 2013/070154 In another embodiment of the method according to the invention, the nitrous oxide emission from soils is reduced by applying an agrochemical mixture comprising at lease one the compound of formula | according to the invention (compound A) and at least one compound (B) and at least one nitrification inhibitor (compound C). In another embodiment of the method according to the invention, the nitrous oxide emission from soils is reduced by applying an agrochemical mixture comprising one compound of formula | according to the invention (compound A) and one compound (B) and one nitrification inhibitor (compound C). The secondary mixtures listed in table BC, comprising one compound (B) and one compound (C) are a preferred embodiment of the method of the current invention. Table BC: Mixture ‘Compound (B) ‘Compound (C) BC-1 ‘ammonium sulfate nitrate | 3,4-dimethylpyrazolephosphate BC-2 ‘ammonium sulfate 3,4-dimethylpyrazolephosphate BC-3 ‘ammonium sulfate nitrate | dicyandiamide BC-4 ammonium sulfate dicyandiamide BCS ammonium sulfate nitrate | __2-chloro-6-(trichloromethy!)-pyridine BC-6 ‘ammonium sulfate 2-chloro-6-(trichloromethyl)-pyridine BC-7 ammonium sulfate nitrate | _ 2-(3,4-dimethy!-pyrazol-1-yi)-succinic acid BC-8 ‘ammonium sulfate 2:3,4-dimethy-pyrazol-1-yi)-succinic acid In the terms of the present invention "agrochemical mixture” is not restricted to a physical mixture comprising at least two compounds, but refers to any preparation form of at least one compound | according to the invention and at least one further compound, the use of which is time- and locus-related. In one embodiment of the invention "agrochemical mixture” refers to a physical mixture comprising compounds A and B. In one embodiment of the invention "agrochemical mixture” refers to a physical mixture of at lease one compound A and at least one compound (B) and at least one compound (C). The agrochemical mixtures may be formulated separately but applied in a temporal relationship, i.e. simultaneously or subsequently, the subsequent application having a time interval which allows a combined action of the compounds. Furthermore, the individual compounds of the agrochemical mixtures according to the invention such as parts of a kit or parts of the binary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate (tank mix). This applies also in case ternary mixtures are used according to the invention. In one embodiment of the invention, the method according to the invention comprises the steps ) application of at least one compound (A) as defined in any of the embodiments above; and b)10 15 20 25 30 35 40 Wo 2014/053401 46 PCr 2013/070154 application of at least one compound (B) as defined in any of the embodiments above; to a plant and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows, wherein the application of at least one compound (A) in step a) and at least one ‘compound (B) in step b) is carried out with a time lag of at least 1 day. In another embodiment of the invention, the method according to the invention comprises the steps a) application of at least one compound (A) as defined in any of the embodiments above; and b) application of at least one compound (B) as defined in any of the embodiments above together with at least one compound (C) as defined in any of the embodiments above; to a plant and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows wherein the application of at least one compound (A) in step a) and at least one ‘compound (B) together with at least one compound (C) in step b) is carried out with a time lag ofat least 1 day. In yet another embodiment of the invention, the method according to the invention comprises the steps a) application of at least one compound (B) as defined in any of the embodiments above; and b) application of at least one compound (A) as defined in any of the embodiments above; to a plant and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows, wherein the application of at least one compound (B) in step a) and at least one compound (a) in step b) is carried out with a time lag of at least 1 day. In yet another embodiment of the invention, the method according to the invention comprises the steps a) application of at least one compound (B) as defined in any of the embodiments above together with at least one compound (C) as defined in any of the embodiments above; and b) application of at least one compound (A) as defined in any of the embodiments above to a plant and/or the locus where the plant is growing or is intended to grow and/or the seeds from which the plant grows; wherein the application of at least one compound (B) together with at least one compound (C) in step a) and the application of at least one compound (A) in step b) is cartied out with a time lag of at least 1 day. The plants to be treated according to the invention are selected from the group consisting of agricultural, silvicultural, ornamental and horticultural plants, each in its natural or genetically modified form, more preferably from agricultural plants. More preferred agricultural plants are field crops, such as potatoes, sugar beets, wheat, barley, rye, oat, sorghum, rice, corn, cotton, rape, oilseed rape, canola, soybeans, peas, field beans, sunflowers, sugar cane; cucumbers, tomatoes, onions, leeks, lettuce, squashes; even more preferably the plant is selected from the group consisting of wheat, barley, oat, rye, soybean, corn, oilseed rape, cotton, sugar cane, rice and sorghum. In an especially preferred embodiment of the current invention, the plants to be treated are selected from the group consisting of wheat, barley, oat, rye, soybean, com, oilseed rape, canola, sunflower, cotton, sugar cane, sugar beet, rice and sorghum. In one embodiment, the aforementioned method for reducing nitrous oxide emission from soils, comprises treating the plant propagules, preferably the seeds of an agricultural, horticultural, ‘oramental or silivcultural plant selected from the group consisting of transgenic or non- transgenic plants.10 15 20 25 30 35 40 WO 20147053401 47 rc 2013/070154 The term “plants” is to be understood as plants of economic importance and/or men-grown plants. They are preferably selected from agricultural, silvicultural and horticultural (including ornamental) plants. The term “plant” as used herein includes all parts of a plant such as germi- nating seeds, emerging seedlings, herbaceous vegetation as well as established woody plants including all belowground portions (such as the roots) and aboveground portions. The term “nitrification inhibitors" is to be understood as any chemical substance which slows down or stops the nitrification process. Nitrification inhibitors retard the natural transformation of ammonium into nitrate, by inhibiting the activity of bacteria such as Nitrosomonas spp.. The term “nitrification” is to be understood as the biological oxidation of ammonia (NHs) or ammonium (NHs*) with oxygen into nitrite (NOz) followed by the oxidation of these nitrites into nitrates (NOs) by microorganisms. Besides nitrate (NOs’) nitrous oxide is also produced though nitrification. Nitrification is an important step in the nitrogen cycle in soil. The term “denitrification” is to be understood as the microbiological conversion of nitrate (NOs) and nitrite (NOz) to gaseous forms of nitrogen, generally Nz or NO. This respiratory process reduces oxidized forms of nitrogen in response to the oxidation of an electron donor such as organic matter. The preferred nitrogen electron acceptors in order of most to least thermodynamically favorable include: nitrate (NO), nitrite (NO), nitric oxide (NO), and nitrous oxide (N20). Within the general nitrogen cycle, denitrification completes the cycle by returning No to the atmosphere. The process is performed primarily by heterotrophic bacteria (such as Para- coccus denitrificans and various pseudomonads), although autotrophic denitrifiers have also been identified (e.g. Thiobacillus denitrificans). Denitrifiers are represented in all main phyloge- netic groups. When faced with a shortage of oxygen many bacterial species, are able switch from using oxygen to using nitrates to support respiration in a process known as denitrification, during which the water-soluble nitrates are converted to gaseous products, including nitrous oxide, that are emitted into the atmosphere. “Nitrous oxide", commonly known as happy gas or laughing gas, is a chemical compound with the chemical formula NO. At room temperature, it is a colorless non-flammable gas. Nitrous oxide is produced naturally in soils through the microbial processes of nitrification and denitrification. These natural emissions of nitrous oxide can be increased by a variety of agricultural practices and activities including for example a) direct addition of nitrogen to soils by using mineral and organic fertilizers b) growing of nitrogen-fixing crops ) cultivation of high organic content soils d) application of livestock manure to croplands and pasture. The term “fertilizers” is to be understood as chemical compounds applied to promote plant and fruit growth. Fertilizers are typically applied either through the soil (for uptake by plant roots) or by foliar feeding (for uptake through leaves). The term “fertilizers” can be subdivided into two major categories: a) organic fertilizers (composed of decayed plant/animal matter) and b) inorganic fertiizers (composed of chemicals and minerals). Organic fertilizers include manure, slur ry, worm castings, peat, seaweed, sewage, and guano. Green manure crops are also regularly10 15 20 25 30 35 40 Wo 2014/053401 48 PCr 2013/070154 grown to add nutrients (especially nitrogen) to the soil. Manufactured organic fertilizers include compost, blood meal, bone meal and seaweed extracts. Further examples are enzyme digested proteins, fish meal, and feather meal. The decomposing crop residue from prior years is another source of fertility. In addition, naturally occurring minerals such as mine rock phosphate, sulfate of potash and limestone are also considered inorganic fertilizers. Inorganic fertilizers are usually manufactured through chemical processes (such as the Haber process), also using naturally ‘occurring deposits, while chemically altering them (e.g. concentrated triple superphosphate) Naturally occurring inorganic fertilizers include Chilean sodium nitrate, mine rock phosphate, and limestone. “NPK fertilizer" are inorganic fertilizers formulated in appropriate concentrations and combina- tions comprising the three main nutrients nitrogen (N), phosphorus (P) and potassium (K). In one embodiment, the plant to be treated according to the method of the invention is an agricultural plant. “Agricultural plants” are plants of which a part (e.g. seeds) or all is harvested or cultivated on a commercial scale or which serve as an important source of feed, food, fibres (e.g. cotton, linen), combustibles (e.g. wood, bioethanol, biodiesel, biomass) or other chemical compounds. Preferred agricultural plants are for example cereals, e.g. wheat, rye, barley, trtica- le, oats, sorghum or rice, beet, ¢.g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e.g. apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or gooseberries; leguminous plants, such as lentils, peas, alfalfa or soybeans; oil plants, such as rape, oilseed rape, canola, linseed, mustard, olives, sunflowers, coconut, cocoa beans, castor oil plants, oil palms, ground nuts or soybeans; cucurbits, such as squashes, cu- ‘cumber or melons; fiber plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruits or mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, cartots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceous plants, such as avocados, cinnamon or camphor; energy and raw material plants, such as corn, soybean, rape, canola, sugar cane or oil palm; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grape juice grape vines); hop; turf; natural rubber plants. In one embodiment, the plant to be treated according to the method of the invention is a horticultural plant. The term “horticultural plants” are to be understood as plants which are commonly used in horticulture - e.g. the cultivation of omamentals, vegetables and/or fruits. Examples for ornamentals are turf, geranium, pelargonia, petunia, begonia and fuchsia. Examples for vegetables are potatoes, tomatoes, peppers, cucurbits, cucumbers, melons, watermelons, garlic, onions, carrots, cabbage, beans, peas and lettuce and more preferably from tomatoes, onions, peas and lettuce. Examples for fruits are apples, pears, cherries, strawberry, citrus, peaches, apricots and blueberries. In one embodiment, the plant to be treated according to the method of the invention is an ornamental plants. “Omamental plants” are plants which are commonly used in gardening, e.g. in parks, gardens and on balconies. Examples are turf, geranium, pelargonia, petunia, begonia and fuchsia.10 15 20 25 30 35 40 Wo 2014/053401 49 PCr 2013/070154 In one embodiment, the plant to be treated according to the method of the invention is a silvicultural plants. The term ‘silvicultural plant’ is to be understood as trees, more specifically trees used in reforestation or industrial plantations. Industrial plantations generally serve for the ‘commercial production of forest products, such as wood, pulp, paper, rubber tree, Christmas trees, or young trees for gardening purposes. Examples for silvicultural plants are conifers, ike pines, in particular Pinus spec.., fir and spruce, eucalyptus, tropical trees like teak, rubber tree, oil palm, willow (Salix), in particular Salix spec., poplar (cottonwood), in particular Populus spec., beech, in particular Fagus spec., birch, oil palm, and oak. The term “locus” is to be understood as any type of environment, soil, area or material where the plant is growing or intended to grow. Especially preferred according to the invention is soil The term “at least one” is to be understood as 1, 2, 3 or more of the respective compound selected from the group consisting of compound of formula | (compound A), fertilizer (compound B) and nitrification inhibitors (compound C). The reduction of nitrous oxide emission is independent of the presence of pests. Accordingly, in a preferred embodiment of the method, the application of the active ingredients (compound A) and/or mixtures comprising at least one compound (A) is carried out in the absence of pest pressure. The term “BBCH principal growth stage” refers to the extended BBCH-scale which is a system for a uniform coding of phenologically similar growth stages of all mono- and dicotyledonous plant species in which the entire developmental cycle of the plants is subdivided into clearly recognizable and distinguishable longer-lasting developmental phases. The BBCH-scale uses a decimal code system, which is divided into principal and secondary growth stages. The abbre- viation BBCH derives from the Federal Biological Research Centre for Agriculture and Forestry (Germany), the Bundessortenamt (Germany) and the chemical industry. In one embodiment of the invention, at least one compound (A) is applied at a growth stage (GS) between GS 00 and GS 65 BBCH of the plant. In preferred embodiment of the invention, at least one compound (A) is applied at a growth stage between GS 14 and GS 55 BBCH of the plant. In a more preferred embodiment of the invention, at least one compound (A) is applied at the growth stage between GS 14 and GS 47 BBCH of the plant. In one embodiment of the invention, at least one fertilizer (compound B) is applied before and at sowing, before emergence, and until harvest (GS 00 to GS 89 BBCH). In another embodiment of the invention, at least one fertilizer (compound B) is applied together with at least one nitrification inhibitor (compound C) before and at sowing, before emergence, and until harvest (GS 00 to GS 89 BBCH). In another embodiment of the invention, at least one compound (A) is applied during leaf devel- ‘opment to flowering (GS 14 to GS 65 BBCH) of the treated plant, provided that the application10 15 20 25 30 35 40 WoO 2014/053401 50 PCT 2013/070154 of at least one compound (A) and at least one compound (B) is carried out with a time lag of at least 1 day. In a preferred embodiment of the invention, an agrochemical mixture comprising an ammonium- or urea-containing fertilizer (compound B) and at least one nitrification inhibitor (compound C) is. applied at least once during the growth stages GS 00 to GS 89 BBCH (before sowing until harvest) while at least one compound (A) is applied at least once during the growth stages GS 14 to GS 65 BBCH (leaf development to flowering) of the treated plant, provided that the application of at least one compound (A) and at least one compound (B) is carried out with a time lag of atleast 1 day. In another embodiment of the invention, the agrochemical mixture comprising an ammonium- or urea-containing fertilizer (compound B) and at least one nitrification inhibitor (compound C) is applied before and at sowing, before emergence, and until shooting/shoot development (GS 00 to GS 33 BBCH) of the plant while at least one compound (A) is applied during leaf development to inflorescence emergence (GS 14 to GS 65 BBCH) provided that the application of at least one compound (A) and at least one compound (B) is carried out with a time lag of at least 1 day. fan agricultural mixture comprising at least two compounds (A) according to the present invention(compound of formula | and a compound II) is used in this inventive method, the plant propagules are preferably treated simultaneously (together or separately) or subsequently. The subsequent application is carried out with a time interval which allows a combined action of the applied compounds. Preferably, the time interval for a subsequent application of a first compound (A) and a second compound (A) ranges from a few seconds up to 3 months, preferably, from a few seconds up to 1 month, more preferably from a few seconds up to 2 weeks, even more preferably from a few seconds up to 3 days and in particular from 1 second up to 24 hours. Ina preferred embodiment of the invention, the application according to the method of the current invention is repeatedly carried out. In one embodiment, the application is repeated two to ten times, preferably, two to five times; most preferably two times. In one embodiment, the application of at least one compound (A) is repeatedly carried out. In another embodiment, the application of at least one compound (B) is repeatedly carried out. In yet another embodiment, the application of one compound (B) together with one compound (C) is repeatedly applied. In each case, there must be a time lag of at least 1 day between the last application of at least one compound (A) and the last application of at least one compound (B) (optionally together with at least one compound C). ‘As a matter of course, compounds (A), (B) and (C) and in case mixtures are employed, compounds selected from the group consisting of compounds (A), (B) and (C) are used in an effective and non-phytotoxic amount. This means that they are used in a quantity which allows to obtain the desired effect but which does not give rise to any phytotoxic symptoms on the treated plant or on the plant raised from the treated propagule or treated soil.10 15 20 25 30 35 40 WO 2014/053401 51 PCT/EP2013/070154 Application rates for compounds of formula |, also in seed treatment, are as defined in this application. For the use according to the invention, the application rates of compounds (B) are between 10 kg and 300 kg of N per hectare, preferably between 50 kg and 250 kg of N per hectare. In all embodiments, the agrochemical mixtures are applied in nitrous oxide emission from soils, reducing amounts. In one embodiment, the agrochemical mixtures are applied in synergistically the nitrous oxide emission from soils reducing amounts. In an especially preferred embodiment of the method for reducing nitrous oxide emission, compound (A) is applied as seed treatment. In another especially preferred embodiment of the method for reducing nitrous oxide emission, compound (A) is applied as foliar and/or in-furrow application. Formulations In the methods and uses according to the invention, the compounds of formula (I) are used in the form of agrochemical compositions comprising an auxiliary and at least one compound of formula (|) according to the invention, ot a stereoisomer, salt, tautomer or N-oxide thereof. ‘An agrochemical composition comprises a pesticidally effective amount of a compound of formula (|). The term “effective amount" denotes an amount of the composition or of the compounds |, which is sufficient for controlling invertebrate pests on cultivated plants or in the protection of materials and which does not result in a substantial damage to the treated plants or material. Such an amount can vary in a broad range and is dependent on various factors, such as the invertebrate (e.g. insect) species to be controlled, the treated cultivated plant or material, the climatic conditions and the specific compound | used. The compounds |, and their stereoisomers, salts, tautomers and N-oxides, can be converted into customary types of agrochemical compositions, e. g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof. Examples for ‘composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g. WG, SG, GR, FG, GG, MG), insecticidal articles (e.g. LN), as well as gel formulations for the treatment of plant propagation materials such as seeds (e.g. GF). These and further compositions types are defined in the “Catalogue of pesticide formulation types and international coding system”, Tech- nical Monograph No. 2, 6" Ed. May 2008, CropLife International. The compositions are prepared in a known manner, such as described by Mollet and Grube- mann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. Examples for suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective col loids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.10 15 20 25 30 35 40 WO 20147053401 52 rc 2013/070154 Suitable solvents and liquid carriers are water and organic solvents, such as mineral oll frac- tions of medium to high bolling point, e.g. kerosene, diesel cil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, al- kylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g. lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof. Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharide powders, e.g. cellulose, starch; fertilizers, e.g. ammonium suifate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, €.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof, Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emusifier, dispersant, solubilizer, wetter, penetration enhancer, protective col loid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1: Emulsifiers & De- tergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.) Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of con- densed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkyinaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates. Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide. Exam- ples of N-subsititued fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar- based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or al- kylpolyglucosides. Examples of polymeric surfactants are home- or copolymers of vinylpyrroli- done, vinylalcohols, or vinylacetate, Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium ‘compounds with one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetains and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of10 15 20 25 30 35 40 WoO 2014/053401 53 PCT 20131070154 polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or po yethyleneamines. ‘Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the compound | on the target. Examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5. Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates. Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones. Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids. Suitable colorants (e.g. in red, blue, or green) are pigments of low water solubility and water- soluble dyes. Examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer- rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine colorants). Suitable tackifiers or binders are polyvinylpyrrolidons, polyvinylacetates, polyvinyl alcohols, pol- yacrylates, biological or synthetic waxes, and cellulose ethers. Examples for composition types and their preparation are: i) Water-soluble concentrates (SL, LS) 10-60 wt% of a compound | according to the invention and 5-15 wt% wetting agent (e.g. alcohol alkoxylates) are dissolved in water andlor in a water-soluble solvent (e.g. alcohols) up to 100 wt%. The active substance dissolves upon dilution with water. il) Dispersible concentrates (DC) 5-25 wt% of a compound | according to the invention and 1-10 wt% dispersant (e. g. polyvi- nylpyrrolidone) are dissolved in up to 100 wt% organic solvent (e.g. cyclohexanone). Dilution with water gives a dispersion. ili) Emulsifiable concentrates (EC) 15-70 wt% of a compound | according to the invention and 5-10 wt% emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in up to 100 wt% water- insoluble organic solvent (e.g. aromatic hydrocarbon). Dilution with water gives an emulsion. iv) _ Emulsions (EW, EO, ES) 5-40 wt% of a compound | according to the invention and 1-10 wt% emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor cil ethoxylate) are dissolved in 20-40 wt% water-insoluble organic solvent (e.g. aromatic hydrocarbon). This mixture is introduced into up to 100 wt% water by means of an emulsifying machine and made into a homogeneous emulsion. Dilution with water gives an emulsion. v) Suspensions (SC, OD, FS) In an agitated ball mill, 20-60 wt% of a compound | according to the invention are comminuted with addition of 2-10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0,1-2 wt% thickener (e.g. xanthan gum) and up to 100 wt% water to give a fine active substance suspension. Dilution with water gives a stable suspension of the active sub-10 15 20 25 30 35 40 Wo 20147053401 54 Pcl 2013/070154 stance. For FS type composition up to 40 wt% binder (e.g. polyvinylalcohol) is added. vi) Water-dispersible granules and water-soluble granules (WG, SG) 50-80 wt% of a compound | according to the invention are ground finely with addition of up to 100 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) and prepared as water-dispersible or water-soluble granules by means of technical appliances (e.g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance. vii) Water-dispersible powders and water-soluble powders (WP, SP, WS) 50-80 wt% of a compound | according to the invention are ground in a rotor-stator mill with addition of 1-5 wt% dispersants (e.g. sodium lignosulfonate), 1-3 wt% wetting agents (e.g. alcohol ethoxylate) and up to 100 wt% solid carrier, e.g. silica gel. Dilution with water gives a stable dispersion or solution of the active substance. vill) Gel (GW, GF) In an agitated ball mill, 5-25 wt% of a compound | according to the invention are comminuted with addition of 3-10 wt% dispersants (e.g. sodium lignosulfonate), 1-5 wt% thickener (e.g. car- boxymethyicellulose) and up to 100 wt% water to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance. ix) Microemulsion (ME) 5-20 wt% of a compound | according to the invention are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g alkohol ethoxylate and arylphenol ethoxylate), and water up to 100 %. This mixture is stirred for 1h to produce spontaneously a thermodynamically stable microemulsion. x) Microcapsules (CS) ‘An oil phase comprising 5-50 wt% of a compound | according to the invention, 0-40 wi% water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e.g. methylmethacrylate, methacrylic acid and a di- or triacrylate) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules. Alternatively, an oil phase comprising 5-50 wt% of a compound | according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g. diphenylme- thene-4,4-diisocyanatae) are dispersed into an aqueous solution of a protective colloid (2. polyvinyl alcohol). The addition of a polyamine (e.g. hexamethylenediamine) results in the formation of a polyurea microcapsules. The monomers amount to 1-10 wt%. The wt% relate to the total CS composition. xi) Dustable powders (DP, DS) 1-10 wt% of a compound | according to the invention are ground finely and mixed intimately with up to 100 wt% solid carrier, e.g. finely divided kaolin. xii) Granules (GR, FG) 0.5-30 wt% of a compound | according to the invention is ground finely and associated with up to 100 wt% solid carrier (e.g. silicate). Granulation is achieved by extrusion, spray-drying or the fluidized bed. xili) Ultra-low volume liquids (UL) 1-50 wt% of a compound | according to the invention are dissolved in up to 100 wt% organic10 15 20 25 30 35 40 WoO 2014/053401 55 2013/070154 solvent, e.g. aromatic hydrocarbon. The compositions types i) to xii) may optionally comprise further auxiliaries, such as 0,1-1 wt% bactericides, 5-15 wt% anti-freezing agents, 0,1-1 wt% anti-foaming agents, and 0,1-1 wt% colorants The agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and most preferably between 0.5 and 75%, by weight of active substance. The active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum) In one embodiment, a suspoconcentration (SC) is preferred for the application in crop protec tion. In one sub-embodiment thereof, the SC agrochemical composition comprises between 50 to 500 giL (grams per Litre), or between 100 and 250 g/L, or 100 g/L or 150g/L or 200g/L or 250 git. In a further embodiment, the granules according to formulation type xii are especially preferred for the application in rice. Water-soluble concentrates (LS), Suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds. The compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Appli- cation can be carried out before or during sowing. Methods for applying or treating compound | and compositions thereof, respectively, on to plant propagation material, especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material. Preferably, compound I or the compositions thereof, respectively, are applied on to the plant propagation material by a method such that germination is not induced, e.g. by seed dressing, pelleting, coating and dusting, When employed in plant protection, the amounts of active substances applied are, depending on the kind of effect desired, from 0.001 to 2 kg per ha, preferably from 0.001 to 1 kg per ha, more preferably from 0.005 to 0.9 kg per ha, in particular from 0.005 to 0.5 kg per ha In treatment of plant propagation materials such as seeds, e. g. by dusting, coating or drenching seed, amounts of active substance of from 0.1 to 1000 g, preferably from 0.1 to 300 g, more preferably from 0.1 to 100 g and most preferably from 0.25 to 100 g, per 100 kilogram of plant propagation material (preferably seed) are generally required. When used in the protection of materials or stored products, the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.008 g to 1 kg, of active substance per cubic meter of treated material.10 15 20 25 30 35 40 WoO 2014/053401 56 PCT 2013/070154 Various types of oils, wetters, adjuvants, fertilizer, or micronutrients, and other pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, safeners) may be added to the active substances or the compositions comprising them as premix or, if appropriate not until immediately prior to use (tank mix). These agents can be admixed with the compositions according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1 The user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system. Usually, the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained. Usually, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area According to one embodiment, individual components of the composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate. In a further embodiment, either individual components of the composition according to the invention or partially premixed components, e. g. components comprising compounds | and/or active substances , e.g. from the groups M or F, may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate. Ina further embodiment, either individual components of the composition according to the invention or partially premixed components, e. g. components comprising compounds | and/or active substances from the group M or F, can be applied jointly (e.g. after tank mix) or consecu- tively. Mixtures In the methods and uses according to the invention, the compounds of the present invention, including their stereoisomers, salts, tautomers and N-oxides, may be applied with other active ingredients, for example with other pesticides, insecticides, herbicides, fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators, safeners and nematicides. These additional ingredients may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix). For example, the plant(s) may be sprayed with a ‘composition of this invention either before or after being treated with other active ingredients, In a particular embodiment of the invention, in the methods and uses according to the invention, the compound of formula | is combined with one or more other pesticidally active compound(s) Il selected from insecticides or fungicides. Therefore, the present invention also relates to methods and uses, wherein a mixture or com- Position comprising at least one compound of formula (|), or a stereoisomer, tautomer , N-oxide or agriculturally or veterinarily acceptable salt thereof, and at least one further pesticide. The compounds of formula (|), and their stereoisomers, salts, tautomers and N-oxides, may be applied with other insecticides as compound II, which are listed in the following categorized list10 15 20 25 30 35 40 Wo 2014053401 57 PCT 2013/070154 M of pesticides, which are, whenever possible, classified according to the Insecticide Re- sistance Action Committee (IRAC). M.1 Acetylcholine esterase (AChE) inhibitors from the class of M.1A carbamates, for example aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodi- carb, thiofanox, trimethacarb, XMC, xylylearb and triazamate; or from the class of M.1B organophosphates, for example acephate, azamethiphos, azinphos-ethyl, azinphosme- thyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos/ DDVP, dicrotophos, dimetho- ate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O- (methoxyaminothio- phosphoryl) salicylate, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion, parathion- methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos- methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupi- rimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon and vamidothi- on; M.2. GABA-gated chloride channel antagonists such as: M.2A oyolodiene organochlorine compounds, as for example endosulfan or chlordane; or M.2B fiproles (phenylpyrazoles), as for example ethiprole, fipronil, lufiprole, pyrafluprole and pyriprole; M.3 Sodium channel modulators from the class of M.3A pyrethroids, for example acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifen- thrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta- cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha- cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, del- tamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, meperfluthrin,metofluthrin, momfluorothrin, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethylfluthrin, tetramethrin, tralomethrin and transfluthrin; or M.3B sodium channel modulators such as DDT or methoxychlor; M.4 Nicotinic acetylcholine receptor agonists (nAChR) from the class of M.4A neonicotinoids, for example acteamiprid, chlothianidin, dinotefuran, imidacloprid, niten- pyram, thiacloprid and thiamethoxam; or the compounds M4A.1: — 1-{(6-chloro-3-pyridinyl)methyl]-2,3,5,6,7,8-hexahydro-9-nitro-(5S,8R)-5.8-epoxy-1H- imidazof1,2-a]azepine; or M4A2: — 1-[(6-chloro-3-pyridyl)methyl}-2-nitro-1-[(E)-pentylideneamino]guanidine; or10 15 20 25 30 35 40 WO 2014/053401 58 Pct M4A3: — 1-[(6-chloro-3-pyridyl)methyl|-7-methyl-8-nitro-5-propoxy-3,5,6,7-tetrahydro-2H- imidazo[1,2-alpyridine; or M.4B nicotine. 2013/070154 M.5 Nicotinic acetylcholine receptor allosteric activators from the class of spinosyns, for example spinosad or spinetoram; M66 Chloride channel activators from the class of avermectins and milbemycins, for example abamectin, emamectin benzoate, ivermectin, lepimectin or milbemectin; M.7 Juvenile hormone mimics, such as M.7A juvenile hormone analogues as hydroprene, kinoprene and methoprene; or others as M.7B fenoxycarb, or M.7C pyriproxyfen; M.8 miscellaneous non-specific (multi-site) inhibitors, for example M.BA alkyl halides as methyl bromide and other alkyl halides, or M.8B chloropicrin, or M,C sulfuryl fluoride, or M.8D borax, or M.8E tartar emetic; M.9 Selective homopteran feeding blockers, for example M.9B pymetrozine, or M.9C flonicamid; M.10 Mite growth inhibitors, for example M.10A clofentezine, hexythiazox and diflovidazin, or M.10B etoxazole; M.11 Microbial disruptors of insect midgut membranes, for example bacillus thuringiensis or bazillus sphaericus and the insecticdal proteins they produce such as bacillus thuringiensis subsp. israelensis, bacillus sphaericus, bacillus thuringiensis subsp. aizawai, bacillus thuringiensis subsp. kurstaki and bacillus thuringiensis subsp. tenebrionis, or the Bt crop proteins: CrytAb, CrytAc, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb and Cry34/35Ab1; M.12 Inhibitors of mitochondrial ATP synthase, for example M.12A diafenthiuron, or M.12B organotin miticides such as azocyclotin, cyhexatin or fenbutatin oxide, or M.12C pro- pargite, or M.12D tetradifon; M.13 Uncouplers of oxidative phosphorylation via disruption of the proton gradient, for example chlorfenapyr, DNOC or sulfluramid;10 15 20 25 30 35 40 WoO 2014/053401 59 PCT 2013/070154 M.14 Nicotinic acetylcholine receptor (nAChR) channel blockers, for example nereistoxin analogues as bensultap, cartap hydrochloride, thiocyclam or thiosultap sodium; M.15 Inhibitors of the chitin biosynthesis type 0, such as benzoylureas as for example bistriflu- ron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novalu- ron, noviflumuron, teflubenzuron or triflumuron; M.16 Inhibitors of the chitin biosynthesis type 1, as for example buprofezin; M.17 Moutting disruptors, Dipteran, as for example cyromazine; M.18 Ecdyson receptor agonists such as diacylhydrazines, for example methoxyfenozide, tebufenozide, halofenozide, fufenozide or chromafenozide; M.19 Octopamin receptor agonists, as for example amitraz; M.20 Mitochondrial complex III electron transport inhibitors, for example M.20A hydramethyinon, or M.20B acequinocyl, or M.20€ fluacrypyrim; M.21 Mitochondrial complex | electron transport inhibitors, for example M.21A METI acaricides and insecticides such as fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad or tolfenpyrad, or M.21B rotenone; M.22 Voltage-dependent sodium channel blockers, for example M.22A indoxacarb, or M.22B metaflumizone; or M.22C — 1-{(E)-{2-(4-cyanophenyl)-1-[3-(trifluoromethyl) phenyllethylidenejamino}-3-[4- (difluoromethoxy)phenyljurea; M.23 Inhibitors of the of acetyl CoA carboxylase, such as Tetronic and Tetramic acid derivatives, for example spirodiclofen, spiromesifen or spirotetramat; M.24 Mitochondrial complex IV electron transport inhibitors, for example M.24A phosphine such as aluminium phosphide, calcium phosphide, phosphine or zinc phosphide, or M.24B cyanide. M.25 Mitochondrial complex II electron transport inhibitors, such as beta-ketonitrile derivatives, for example cyenopyrafen or cyflumetofen; M.26 Ryanodine receptor-modulators from the class of diamides, as10 15 20 25 30 35 40 WO 2014053401 60 PCT 2013/070154 for example flubendiamide, chlorantraniliprole (rynaxypyr®), cyantraniliprole (cyazypyr®), or the phthalamide compounds M.26.1: (R)-3-Chlor-N1-{2-methyl-4-(1,2,2,2 -tetrafluor-1-(trfluormethyl)ethyljphenyl+N2-(1- methyl-2-methylsulfonylethyl)phthalamid and M.26.2: (S)-3-Chlor-N1-{2-methy}-4-[1,2,2,2 ~tetrafiuor-1-(trifluormethyl)ethyl]phenyl}-N2-(1- methyl-2-methylsulfonylethy!)phthalamid, or the compound M.26.3: 3-bromo-N-{2-bromo-4-chloro-6-{(1-cyclopropylethy!)carbamoyl}pheny!}-1-(3- chlorpyridin-2-yl)-1H-pyrazole-5-carboxamide (proposed ISO name: cyclaniliprole), or the compound M.26.4: methyl-2-{3,5-dibromo-2-({[3-bromo-1-(3-chlorpyridin-2-yl)-1H-pyrazol-5- yllcarbony!}amino)benzoyll-1,2-dimethylhydrazinecarboxylate; or a compound selected from M.26.Sa) to M.26.5d): M.26.5a: _N-[2-(5-amino-t 3,4-thiadiazol-2-yl)-4-chloro-6-methyl-phenyl]-5-bromo-2-(3-chloro- 2-pyridy))pyrazole-3-carboxamide; M.26.5b: _5-chloro-2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(1-cyano-1-methyl- ethyl)carbamoyl]phenyllpyrazole-3-carboxamide; M.26.50: _ 5-bromo-N-[2,4-dichloro-6-(methylcarbamoyl)phenyl]-2-(3,5-dichloro-2- pyridy!)pyrazole-3-carboxamide; M.26.5d: _N-(2-(tert-butylcarbamoy!)-4-chloro-6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5- (fluoromethoxy)pyrazole-3-carboxamide; or M266: —N2-(1-cyano-1-methyl-ethyl)-N1-(2,4-dimethylpheny!)-3-iodo-phthalamide; or M267: — 3-chloro-N2-(1-cyano--methylethyl)-N1-(2,4-dimethylphenyl)phthalamide; M.X insecticidal active compounds of unknown or uncertain mode of action, as for example afidopyropen, azadirachtin, amidoflumet, benzoximate, bifenazate, bromopropylate, chinome- thionat, cryolite, dicofol, flufenerim, flometoquin, fluensulfone, flupyradifurone, piperonyl butox- ide, pyridalyl, pyrifluquinazon, sulfoxaflor, pyflubumide, or the compounds M.X.1: 4-[5-(3,5-Dichloro-phenyl)-5-trifluoromethyl-4,5-dihydro-isoxazol-3-yl]-2-methylN-{(2,2,2- trifluoro-ethylcarbamoyl)-methyl|-benzamide, or the compound M.X.2: cyclopropaneacetic acid, 1,1'-[(3S,4R,4aR,6S,6aS,12R,12aS, 12bS)-4-[[(2- cyclopropylacetyljoxyjmethyl}-1,3,4,4a,5,6,6a,12,12a, 12b-decahydro-12-hydroxy-4,6a, 12b- trimethyl 1-0xo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-elpyran-3,6-diyl] ester, or the compound M.X.3: 11-(4-chloro-2,6-dimethylphenyl)-12-hydroxy-1 4-dioxa-9-azadispiro[4.2.4.2|+tetradec-11- en-10-one, or the compound M.X.4: 3-(4'-fluoro-2,4-dimethylbiphenyl-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4.5]dec-3-en-2-one, or the compound M.X.5: 1-[2-fluoro-4-methyl-5-[(2,2,2-trifluoroethy!)sulfiny!}phenyl]-3-(trfluoromethyl)-1H-1,2,4- triazole-5-amine, or actives on basis of bacillus firmus (Votivo, |-1582), or M.X.6: a compound selected from the group of, M.X.€a: (E/Z)-N-[1-{(6-chloro-3-pyridyl)methyl]-2-pyridylidene}-2,2,2-trifluoro-acetamide; M.X.6b: (E/Z)-N-[1-{(6-chloro-5-fluoro-3-pyridyl)methyl]-2-pyridylidene}-2,2,2-trifluoro-acetamide; M.X.60: (E/Z)-2,2,2-trifluoro-N-{1-{(6-fluoro-3-pyridyl)methyl]-2-pyridylidenejacetamide;10 15 20 25 30 35 40 WO 2014/053401 61 Pct M.X.6d: (E/Z)-N-[1-{(6-bromo-3-pyridyl}methyl]-2-pyridylidene]-2,2,2-trifluoro-acetamide; M.X.6e: (E/Z)-N-[1-[1-(6-chloro-3-pyridyl)ethy!}-2-pyridylidene}-2,2,2-trifluoro-acetamide; M.X.6t: (E/2)-N-[1-(6-chloro-3-pyridyl)methyl]-2-pyridylidene}-2,2-difluoro-acetamide; M.X.6g; (E/Z)-2-chloro-N-{1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene}-2,2-difluoro-acetamide; M.X.6h: (E/Z)-N-[1-{(2-chloropyrimidin-5-yl) methyl}-2-pyridylidene}-2,2,2-trifluoro-acetamide and M.X.6i: (E/Z)-N-[1-[(6-chloro-3-pyridyl) methyl]-2-pyridylidene]-2,2,3,3,3-pentafluoro- propanamide); or MX7: triflumezopyrim; or MX8: — 44{5-[3-chloro-5-(trifluoromethy!)phenyl]-5-(trifluoromethyl)-4H-isoxazol-3-yl]-N-[2- ox0-2-(2,2,2-trifluoroethylamino)ethyl|naphthalene-1-carboxamide, or M.X.9: 3-[3-chloro-5-(trifluoromethy!} phenyl]-4-oxo-1-(pyrimidin-5-ylmethyl)pyrido[1,2- alpyrimidin-1-ium-2-olate; or M.X.10: _ 8-chloro-N-[2-chloro-5-methoxyphenyl)sulfonyl}-6-trifluoromethyl)-imidazof1,2- alpyridine-2-carboxamide; or MX.11: 45-(3,5-dichlorophenyl)-5-(trifluoromethy!)-4H-isoxazol-3-yl]-2-methyl-N-(1- oxothietan-3-yl)benzamide; or M.X.12: 5-[3-12,6-dichloro-4-(3,3-dichloroallyloxy)phenoxylpropoxy}-1H-pyrazole; or 2013/070154 MY Biopesticides, e.g. M.Y-1: Microbial pesticides with insecticidal, acaricidal, molluscidal and/or nematicidal activity: Bacillus firmus, B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana, Burkholderia sp., Chromobacterium sub-tsugae, Cydia pomonella granulo- sis virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (formerly Verticilium lecanii), Metarhizium an-isopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp., P. nishizawae, P. reneformis, P. us-agae, Pseudomonas fluorescens, Steinernema feltiae, Streptomces galbus; M.Y-2) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and/or nematicidal activity: L-carvone, citral, (E,Z)-7,9-dodecadien-1-yl ace-tate, ethyl formate, (E,Z)- 2,4-ethyl decadienoate (pear ester), (Z,Z,E)-7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulyl senecioate, 2-methyl 1-butanol, methyl eugenol, methyl jasmonate, (E,Z)- 2,13-octadecadien-1-ol, (E,Z)-2,13-octadecadien-1-ol acetate, (E,Z)-3,13-octadecadien-1-ol, R- 1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E,Z,2)-3,8,11- tetradecatrienyl acetate, (Z,E)-9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9- tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, Acacia negra extract, extract of grapefruit seeds and pulp, extract of Chenopodium ambrosiodae, Catnip oil, Neem oil, Quillay extract, Ta-getes oll. The commercially available compounds of the group M listed above may be found in The Pesti- cide Manual, 15th Edition, C. D. S. Tomlin, British Crop Protection Council (2011) among other publications. The quinoline derivative flometoquin is shown in WO2006/013896. The aminofuranone compounds flupyradifurone is known from WO 2007/115644. The sulfoximine compound sulfoxafior is known from WO2007/149134. The pyrethroid momfluorothrin is known from US6908945. The10 15 20 25 30 35 40 Wo 2014053401 62 PCT 2013/070154 pyrazole acaricide pyflubumide is known from W02007/020986. The isoxazoline compound M.X.1 has been described in WO2005/085216, M.X.8 in WO2009/002809 and in WO2011/149749 and the isoxazoline M.X.11 in WO2013/050317. The pytipyropene derivative M.X.2 has been described in WO 2006/129714. The spiroketal-substituted cyclic ketoenol derivative M.X.3 is known from WO2006/089633 and the biphenyl-substituted spirocyclic ke-toenol derivative M.X.4 from WO2008/06791 1. Triazoylphenylsulfide like M.X.5 have been described in WO2006/043635 and biological control agents on basis of bacillus firmus in WO2009/124707. The neonicotionids M4A.1 is known from WO20120/069266 and WO2011/06946, the M.4A.2, from W02013/003977, the M4A.3.from WO2010/069266. The metaflumizone analogue M.22C. is described in CN 10171877. Cyantraniliprole (Cyazypyr) is known from e.g. WO 2004/067528. The phthalamides M.26.1 and M.26.2 are both known from WO 2007/101540. The anthranilamide M.26.3 has been described in WO 2005/077934. The hydrazide compound M.26.4 has been described in WO 2007/043677. The anthranilamide M.26.5a) is described in WO201 1/085575, the M.26.5b) in WO2008/134969, the M.26.5c) in US2011/046186 and the M.26.5d in WO2012/034403. The diamide compounds M.26.6 and M.26.7 can be found in CN102613183, The compounds M.X.6a) to M.X.6i) listed in M.X.6 have been described in WO2012/029672 The mesoionic antagonist compound M.X.9 was described in WO2012/0921 15, the nemati-cide M.X.10 in WO2013/055584 and the Pyridalyl-type analogue M.X.12 in WO2010/060379. Biopesticides The biopesticides from group M.Y, and from group F.XIIl) as described below, their preparation and their biological activity e.g. against harmful fungi, pests is known (e-Pesticide Manual V 5.2 (ISBN 978 1 901396 85 0) (2008-2011); http:/www.epa.govlopp00001 /biopesticides/, see prod- Uct lists therein; http://www.omri.org/omri-lsts, see lists therein; Bio-Pesticides Database BPDB httpi//sitem.herts.ac.uklaeru/bpdb/, see A to Z link therein). Many of these biopesticides are reg- istered and/or are commercially available: aluminium silicate (SCREEN™ DUO from Certis LLC, USA), Ampelomyces quisqualis M-10 (e.g. AQ 10® from Intrachem Bio GmbH & Co. KG, Ger- many), Ascophyllum nodosum (Norwegian kelp, Brown kelp) extract (e.g. ORKA GOLD from Becker Underwood, South Africa), Aspergillus flavus NRRL 21882 (e.g. AFLA-GUARD® from ‘Syngenta, CH), Aureobasidium pullulans (e.g. BOTECTOR® from bio-ferm GmbH, Germany), Azospirillum brasilense XOH (e.g. AZOS from Xtreme Gardening, USA USA or RTI Reforesta- tion Technologies Intemational; USA), Bacillus amyloliquefaciens IT-45 (CNCM | 3800, NCBI 1091041) (e.g. RHIZOCELL C from ITHEC, France), B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595, deposited at United States Department of Agriculture) (e.g. INTE- GRAL®, CLARITY, SUBTILEX NG from Becker Underwood, USA), B. pumilus QST 2808 (NRRL Accession No. B 30087) (e.g. SONATA® and BALLAD® Plus from AgraQuest Inc. USA), B. subtilis GB03 (e.g. KODIAK from Gustafson, Inc., USA), B. subtilis GBO7 (EPIC from Gustafson, Inc., USA), B. subtilis QST-713 (NRRL-Nr. B 21661 in RHAPSODY®, SERENADE® MAX and SERENADE® ASO from Agra-Quest Inc., USA), B. subtilis var. amyloliquenfaciens FZB24 (e.g. TAEGRO® from Novozyme Biologicals, Inc., USA), B. subtilis var. amyloliquefaciens D747 (e.g. Double Nickel 55 from Certis LLC, USA), Bacillus thuringiensis ssp. kurstaki ‘SB4 (e.g. BETA PRO® from Becker Underwood, South Africa), Beauveria bassiana GHA (BOTANIGARD® 22WGP from Laverlam Int. Corp., USA), B. bassiana 12256 (e.g. BIOEX-10 15 20 25 30 35 40 WO 2014053401 63 PCT PERT® SC from Live Sytems Technology S.A., Colombia), B. bassiana PRP! 5339 (ARSEF number 5339 in the USDA ARS collection of entomopathogenic fungal cultures) (e.g BROAD7BAND@® from Becker Underwood, South Africa), Bradyrhizobium sp. (e.g. VAULT® from Becker Underwood, USA), B. japonicum (e.g. VAULT® from Becker Underwood, USA), Candida oleophila I-82 (e.g. ASPIRE® from Ecogen Inc., USA), Candida saitoana (e.g. BIO- CUREG (in mixture with lysozyme) and BIOCOAT® from Micro Flo Company, USA (BASF SE) and Arysta), Chitosan (e.g. ARMOUR-ZEN from BotriZen Ltd., NZ), Clonostachys rosea f. ca- tenulata, also named Gliocladium catenulatum (e.g. isolate J1446: PRESTOP® from Verdera, Finland), Coniothyrium minitans CON/M/91-08 (e.g. Contans® WG from Prophyta, Germany), Cryphonectria parasitica (e.g. Endothia parasitica from CNICM, France), Cryptococcus albidus (e.g. YIELD PLUS® from Anchor Bio-Technologies, South Africa), Ecklonia maxima (kelp) extract (e.g. KELPAK SL from Kelp Products Ltd, South Africa), Fusarium oxysporum (e.g. BIO- FOX® from S.LA.P.A., Italy, FUSACLEANG from Natural Plant Protection, France), Glomus intraradices (e.g. MYC 4000 from ITHEC, France), Glomus intraradices RTI-801 (e.g. MYKOS from Xtreme Gardening, USA or RT! Reforestation Technologies International; USA), grapefruit seeds and pulp extract (e.g. BC-1000 from Chemie S.A., Chile), Isaria fumosorosea Apopka-97 (ATCC 20874) (PFR-97™ from Certis LLC, USA), Lecanicillium muscarium (formerly Verticillium lecanii) (e.g. MYCOTAL from Koppert BV, Netherlands), Lecanicillium longisporum KV42 and KV71 (e.g. VERTALEC® from Koppert BV, Netherlands), Metarhizium anisopliae var. acridum IMI 330189 (deposited in European Culture Collections CAB!) (2.9. GREEN MUSCLE® from Becker Underwood, South Africa), M. anisopliae Fl-1045 (e.g. BIOCANE® from Becker Under- wood Ply Ltd, Australia), M. anisopliae var. acridum FI-985 (e.g. GREEN GUARD® SC from Becker Underwood Pty Ltd, Australia), M. anisopliae F52 (e.g. MET52® Novozymes Biologicals BioAg Group, Canada), M. anisopliae ICIPE 69 (e.g. METATHRI~POL from ICIPE, Kenya) Metschnikowia fructicola (e.g. SHEMER® from Agrogreen, Israel), Microdochium dimerum (e.g. ANTIBOT® from Agrauxine, France), Neem cil (e.g. TRILOGY®, TRIACT® 70 EC from Certis LLC, USA), Paecilomyces funosoroseus strain FE 9901 (e.g. NO FLY™ from Natural Indus- tries, Inc., USA), P. lilacinus DSM 15169 (e.g. NEMATA® SC from Live Systems Technology S.A., Colombia), P. lilacinus BCP2 (e.g. PL GOLD from Becker Underwood BioAg SA Ltd, South Africa), mixture of Paenibacillus alvei NAS6G6 and Bacillus pumilis (e.g. BAC-UP from Becker Underwood South Africa), Penicillium bilaiae (e.g. JUMP START® from Novozymes Biologicals BioAg Group, Canada) Phlebiopsis gigantea (e.g. ROTSTOP® from Verdera, Fin- land), potassium silicate (e.g. Si-MATRIX™ from Certis LLC, USA), Pseudozyma flocculosa (e.g. SPORODEX® from Plant Products Co. Ltd., Canada), Pythium oligandrum DV74 (e.g. POLYVERSUM@ from Remeslo SSRO, Biopreparaty, Czech Rep.), Reynoutria sachlinensis extract (¢.g. REGALIA® from Marrone BioInnovations, USA), Rhizobium leguminosarum bv. phaseolil (e.g. RHIZO-STICK from Becker Underwood, USA), R. |. trifolii (e.g. DORMAL from Becker Underwood, USA), R. |. by. viciae (e.g. NODULATOR from Becker Underwood, USA), ‘Sinorhizobium meliloti (e.g. DORMAL ALFALFA from Becker Underwood, USA; NITRAGIN@ Gold from Novozymes Biologicals BioAg Group, Canada), Steinernema feltiae (NE- MA7SHIELD® from BioWorks, Inc., USA), Streptomyces lydicus WYEC 108 (e.g. Actinovate® from Natural Industries, Inc., USA, US 5,403,584), S. violaceusniger YCED-9 (e.g. DT-98 from Natural Industries, Inc., USA, US 5,968,503), Talaromyces flavus V117b (e.g. PROTUS® from 2013/07015410 15 20 25 30 35 40 Wo 20147053401 64 Pcl 2013/070154 Prophyta, Germany), Trichoderma asperellum SKT-1 (e.g. ECO-HOPE® from Kumiai Chemical Industry Co., Ltd., Japan), T. atroviride LC52 (e.g. SENTINEL® from Agrimm Technologies Ltd, NZ), T. fertile JM41R (e.g. RICHPLUS™ from Becker Underwood Bio Ag SA Ltd, South Africa), T. harzianum T-22 (e.g. PLANTSHIELD® der Firma BioWorks Inc., USA), T. harzianum TH 35 (e.g. ROOT PRO® from Mycontrol Ltd., Israel), T. harzianum T-39 (e.g. TRICHODEX® and TRICHODERMA 2000 from Mycontrol Ltd., Israel and Makhteshim Ltd., Israel), T. harzianum and T. viride (e.g. TRICHOPEL from Agrimm Technologies Ltd, NZ), T. harzianum ICCO12 and T. viride ICC080 (e.g. REMEDIER® WP from Isagro Ricerca, Italy), T. polysporum and T. harzianum (e.g. BINAB® from BINAB Bio-Innovation AB, Sweden), T. stromaticum (e.g. TRICO- VAB® from C.E.P.LA.C., Brazil), T. virens GL-24 (also named Gliocladium virens) (e.g. SOIL- GARD® from Certis LLC, USA), T. viride (e.g. TRIECO® from Ecosense Labs. (India) Pvt. Ltd., Indien, BIO-CURE® F from T. Stanes & Co. Ltd., Indien), T. viride TV1 (e.g. T. viride TV1 from Agribiotec st, Italy), Ulocladium oudemansii HRU3 (e.g. BOTRY-ZEN@ from Botty-Zen Ltd, NZ), Bacillus amyloliquefaciens AP-136 (NRRL B-50614), B. amyloliquefaciens AP-188 (NRRL B-50615), B. amyloliquefaciens AP-218 (NRRL 8-50618), B. amyloliquefaciens AP-219 (NRRL B-50619), B. amyloliquefaciens AP-295 (NRRL B-50620), B. mojavensis AP-209 (No. NRRL B- 50616), B. solisalsi AP-217 (NRRL B-50617), B. pumilus strain INR-7 (otherwise referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185)), B. simplex ABU 288 (NRRL B-50340) and B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595) have been mentioned iva. in US patent appl. 20120149571, WO 2012/079073. Beauveria bassiana DSM 12256 is known from US200020031495. Bradyrhizobium japonicum USDA is known from US patent 7,262,151 ‘Sphaerodes mycoparasitica IDAC 301008-01 (IDAC = Intemational Depositary Authority of Canada Collection) is known from WO 2011/022809. Bacillus amyloliquefaciens subsp. plantarum MBI600 having the accession number NRRL B- ‘50595 is deposited with the United States Department of Agriculture on Nov. 10, 2011 under the strain designation Bacillus subtilis 1430. It has also been deposited at The National Collections of Industrial and Marine Bacteria Ltd. (CIB), Torry Research Station, P.O. Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland.under accession number 1237 on December 22, 1986. Bacillus amyloliquefaciens MBI600 is known as plant growth-promoting rice seed treatment from Int. J. Microbiol. Res. ISSN 0975-5276, 3(2) (2011), 120-130 and further desoribed e.g. in US 2012/0149571 A1. This strain MBI600 is commercially available as liquid formulation product Integral® (Becker-Underwood Inc., USA). Recently, the strain MBI 600 has been re- classified as Bacillus amyloliquefaciens subsp. plantarum based on polyphasic testing which combines classical microbiological methods relying on a mixture of traditional tools (such as culture-based methods) and molecular tools (such as genotyping and fatty acids analysis). Thus, Bacillus subtilis MBI600 (or MBI 600 or MBI-600) is identical to Bacillus amyloliquefaciens subsp. plantarum MBI600, formerly Bacillus subtilis MBI600. Metathizium anisopliae IMI33 is commercially available from Becker Underwood as product Green Guard. M. anisopliae var acridium strain IMI 330189 (NRRL-50758) is commercially available from Becker Underwood as product Green Muscle. Bacillus subtilis strain FB17 was originally isolated from red beet roots in North America (Sys- tem Appl. Microbiol 27 (2004) 372-379). This Bacillus subtilis strain promotes plant health (US 2010/0260735 A1; WO 201 1/109395 A2). B. sublilis F817 has also been deposited at American

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