FEED

B1

R1-P
B2
B1
LIQUID

LIQUID
Substream: MIXED
Mass Flow kg/hr
TBP
STINI
STY
EB
DDM
POLYSTY
Mass Frac
TBP
STINI
STY
EB
DDM
POLYSTY
Total Flow kg/hr
Vapor Frac
Liquid Frac
Solid Frac
Temperature C
Pressure bar
Enthalpy Btu/lb
Entropy
Btu/lb-R
Average MW
POLYSTY SFRAC
STYRE-02
POLYSTY SFLOW kmol/hr
STYRE-02
POLYSTY DPN
DPN
POLYSTY DPW
DPW
POLYSTY PDI
PDI
POLYSTY MWN
MWN
POLYSTY MWW
MWW
POLYSTY ZMOM kmol/hr
ZMOM

R2-P
B3
B2
LIQUID

R3-P
B3
LIQUID

2.1
0
6860
133
4.9
0

1.249554
0
4982.585
132.995
4.899817
1878.27

0.0647485
0
2366.98
132.9804
4.899279
4495.075

0
0
1184.156
132.9713
4.898942
5677.974

3.00E-04
0
0.98
0.019
7.00E-04
0
7000
0
1
0
25
1.01325
415.3024
-0.7637317
104.2335

1.79E-04
0
0.7117979
0.0189992
7.00E-04
0.2683243
7000
0
1
0
120
1.01325
438.371
-0.6850451
104.2299

9.25E-06
0
0.33814
0.0189972
7.00E-04
0.6421536
7000
0
1
0
160
1.01325
397.471
-0.7001273
104.2248

0
0
0.1691652
0.0189959
7.00E-04
0.8111391
7000
0
1
0
200
1.01325
397.8198
-0.6867033
104.2245

18.0258

43.13926

54.49602

1672.849

1254.105

1176.714

2881.853

2304.896

2194.095

1.722722

1.837881

1.864595

1.74E+05

1.31E+05

1.23E+05

3.00E+05

2.40E+05

2.29E+05

0.0107755

0.0343984

0.046312

POLYSTY FMOM kmol/hr

FMOM
POLYSTY SMOM kmol/hr
SMOM
POLYSTY LDPN
LDPN
POLYSTY LZMOM kmol/hr
LZMOM
POLYSTY LFMOM kmol/hr
LFMOM
POLYSTY LSFLOW kmol/hr
STYRE-02
POLYSTY LSFRAC
STYRE-02
POLYSTY LEFLOW kmol/hr
STYRE-02
POLYSTY LEFRAC
STYRE-02
POLYSTY LPFRAC
LPFRAC

18.0258

43.13926

54.49602

51947.71

99431.52

1.20E+05

1050.647

710.1001

571.9927

2.86E-07

3.40E-07

2.86E-07

3.01E-04

2.41E-04

1.64E-04

3.01E-04

2.41E-04

1.64E-04

2.86E-07

3.40E-07

2.86E-07

2.66E-05

9.88E-06

6.18E-06

8000
7000
6000
5000
Styrene

4000
3000

Row 10

2000
1000
0
0.5

1.5

2.5

3.5

4.5

Axis Title

6000
5000
4000
Polystyrene

3000
Row 13

2000
1000
0
0.5

1.5

2.5

3.5

4.5

Axis Title

3500
3000
2500
2000
Polystyrene DPN

1500
1000
500
0
0.5

1.5

2.5

Axis Title

3.5

4.5

Polystyrene DPN

1500
1000
500
0
0.5

1.5

2.5

Axis Title

3.5

4.5

Row 10

4.5

Row 13

tle

4.5

1.9
1.85
1.8
DPN
DPW

Indice di polidispersit

1.75
1.7

3.5

4.5

1.65
0.5

1.

tle

DPN
DPW

Indice di polidispersit

1.75
1.7

3.5

4.5

1.65
0.5

1.

polidispersit

1.9
1.85
1.8
1.75

Row 39

1.7
1.65
0.5

1.5

2.5

3.5

4.5

polidispersit

1.75

Row 39

1.7
1.65
0.5

1.5

2.5

Axis Title

3.5

4.5

Degree of polym. (DPn)

Polymer CLD (wt. frac.) R1-P

1
2.33E-07
2
9.31E-07
3
2.09E-06
4
3.73E-06
5
5.82E-06
6
8.39E-06
7
1.14E-05
8
1.49E-05
9
1.89E-05
10
2.33E-05
11
2.83E-05
12
3.36E-05
13
3.95E-05
14
4.58E-05
15
5.26E-05
16
5.99E-05
17
6.77E-05
18
7.59E-05
19
8.46E-05
20
9.38E-05
21
0.0001034
22
0.00011353
23
0.00012413
24
0.00013521
25
0.00014677
26
0.00015881
27
0.00017133
28
0.00018432
29
0.0001978
31
0.00022619
35
0.00028876
39
0.00035906
44
0.00045784
50
0.00059245
56
0.00074467
63
0.00094463
70
0.00116877
79
0.00149268
89
0.00189994
100
0.00240577
112
0.003027
125
0.00378207
141
0.00482889
158
0.00608351

177
199
223
251
281
316
354
398
446
501
562
630
707
794
891
1000
1122
1258
1412
1584
1778
1995
2238
2511
2818
3162
3548
3981
4466
5011
5623
6309
7079
7943
8912
10000
11220
12589
14125
15848
17782
19952
22387
25118
28183

0.00765939
0.00971275
0.01223147
0.01553467
0.01950438
0.02468865
0.03097494
0.03908034
0.04888933
0.06129626
0.07640427
0.09475218
0.11720065
0.14434076
0.17631573
0.21370862
0.25647475
0.3041175
0.35657298
0.41160147
0.46733822
0.52000558
0.56557766
0.59953605
0.61712083
0.61425467
0.58860527
0.54028899
0.47252779
0.3911283
0.30425232
0.22078251
0.14809018
0.09092496
0.05055593
0.02512606
0.01101868
0.00419594
0.00136372
0.00037109
8.26E-05
1.47E-05
2.03E-06
2.12E-07
1.61E-08

31622
35481
39810
44668
50118
56234
63095
70794
79432
89125
100000

8.58E-10
3.06E-11
6.98E-13
9.61E-15
7.54E-17
3.13E-19
6.41E-22
5.90E-25
2.22E-28
3.06E-32
1.37E-36

Polymer CLD (wt. frac.) R2-P

Polymer CLD (wt. frac.) R3-P
4.86E-07
5.93E-07
1.94E-06
2.37E-06
Curva
4.37E-06
5.34E-06
7.00E-01
7.78E-06
9.49E-06
1.22E-05
1.48E-05
6.00E-01
1.75E-05
2.13E-05
2.38E-05
2.90E-05
5.00E-01
3.11E-05
3.79E-05
4.00E-01
3.94E-05
4.80E-05
4.86E-05
5.92E-05 Frazione massica
3.00E-01
5.88E-05
7.17E-05
7.00E-05
8.53E-05
2.00E-01
8.22E-05
0.00010003
9.53E-05
0.000116
1.00E-01
0.00010944
0.00013314
0.00E+00
0.00012452
0.00015145
0
0.00014058
0.00017094
0.00015761
0.00019161
0.00017562
0.00021346
0.0001946
0.00023647
0.00021456
0.00026066
0.00023549
0.00028602
0.00025739
0.00031256
0.00028027
0.00034026
0.00030412
0.00036914
0.00032894
0.00039918
0.00035474
0.00043039
0.00038151
0.00046277
0.00040926
0.00049632
0.00046767
0.00056691
0.00059618
0.00072206
0.00074026
0.00089578
0.00094223
0.00113895
0.00121665
0.00146878
0.00152597
0.00183989
0.00193089
0.00232471
0.0023831
0.00286503
0.00303379
0.00364066
0.00384776
0.00460826
0.00485311
0.00579981
0.00608027
0.00724962
0.00756187
0.00899414
0.00960009
0.01138489
0.01202149
0.0142131

di distrib

2000

0.0150338
0.018916
0.02361977
0.02970311
0.03690097
0.04613772
0.05711905
0.07096585
0.08730675
0.10739669
0.13108269
0.15882002
0.1913735
0.22888341
0.2706912
0.31653159
0.3651243
0.41455716
0.46319416
0.50729619
0.54372297
0.56842
0.57811205
0.57033791
0.54397679
0.50001995
0.44142398
0.37296974
0.30059298
0.22998501
0.16627001
0.11301245
0.07167451
0.04204686
0.02257373
0.01093779
0.00471482
0.00177602
0.00057356
0.00015554
3.46E-05
6.15E-06
8.50E-07
8.87E-08
6.74E-09

0.0177158
0.02220777
0.02762135
0.03458195
0.04276642
0.05319858
0.06551113
0.08091492
0.09893977
0.12089823
0.1465309
0.17622715
0.21067074
0.24983912
0.29285465
0.33922978
0.3874242
0.43528389
0.48092397
0.52050977
0.55087672
0.56824114
0.5697841
0.55369934
0.51970198
0.4696867
0.4073357
0.33785878
0.26718486
0.20056046
0.14231147
0.09503326
0.05931143
0.03431339
0.01821233
0.00874627
0.00374557
0.00140452
0.00045225
0.00012242
2.72E-05
4.83E-06
6.68E-07
6.97E-08
5.29E-09

3.59E-10
1.28E-11
2.92E-13
4.02E-15
3.15E-17
1.31E-19
2.68E-22
2.46E-25
9.27E-29
1.28E-32
5.71E-37

2.82E-10
1.00E-11
2.29E-13
3.16E-15
2.47E-17
1.03E-19
2.10E-22
1.94E-25
7.28E-29
1.00E-32
4.48E-37

Curva di distribuzione ponderale del peso molecolare

E-01
Primo reattore

E-01

Secondo reattore
Terzo reattore

E-01

E-01

sica

E-01

E-01

E-01
+00

2000

4000

6000

DPn

8000

10000

12000

VARY 1
1-STY1/F
1-STY2/F
1-STY3/F
PMN1
PMN2
FEED
EED
EED
EED
MIXED
TOTAL MA
SSFLOW
KG/HR
4000
37%
73%
88% 176287.229 141963.328
5000
33%
70%
86% 175313.776 137400.913
6000
30%
68%
84% 174673.099 133703.745
7000
27%
65%
83% 174229.762 130616.933
8000
25%
63%
81% 173911.091 127982.862
9000
23%
62%
80% 173675.051 125697.096

Conversione
100%
90%
80%
70%
60%
50%
40%
30%
20%
10%
0%
4000

4500

5000

5500

6000

Reattore 1

6500

7000

Reattore 2

Peso molecolare medio ponderale

310000
300000
290000
280000
270000
260000
250000
240000
230000
220000
210000
4000

5000

Reattore 1

6000

7000

Reattore 2

8000
Reattore 3

9000

7500
Reattore 3

8000

8500

9000

PMN3

134259.516
129502.841
125747.238
122556.545
119825.295
117490.761

PMW1

PMW2

304263.041
302317.059
301036.251
300149.385
299511.244
299037.951

PMW3

259190.937
251545.741
245309.713
240058.442
235535.457
231573.468

IPD1

249165.22
240892.664
234209.686
228518.328
223596.687
219316.333

IPD2

1.72595056
1.72443413
1.72342652
1.72272166
1.72220899
1.72182446

1.8257598
1.83074286
1.83472582
1.83788148
1.84036716
1.84231359

Peso molecolare medio numerico

180000
170000
160000
150000
140000
130000
120000
8500

9000

110000
4000

4500

5000

5500

6000

Reattore 1

6500
Reattore 2

Indice di polidispersit
1.9
1.85
1.8
1.75
1.7
1.65
1.6
4000

5000
Reattore 1

6000

7000

Reattore 2

8000

9000

Reattore 3

7000

7500
Reattore 3

8000

8500

9000

IPD3

1.85584774
1.8601342
1.86254338
1.86459505
1.86602242
1.86666876

ico

00

ore 3

8000

8500

9000

VARY 1 1-STY1/F
1-STY2/F
1-STY3/F
PMN1
PMN2
B3
EED
EED
EED
1
T-SPEC
TEMP
C
160 0.27367559 0.65495913 0.82738247 174229.762 130616.933
170 0.27367559 0.65495913 0.84046647 174229.762 130616.933
180 0.27367559 0.65495913
0.8539542 174229.762 130616.933
190 0.27367559 0.65495913 0.86765052 174229.762 130616.933
200 0.27367559 0.65495913 0.88260067 174229.762 130616.933
210 0.27367559 0.65495913 0.89611542 174229.762 130616.933
220 0.27367559 0.65495913 0.90866406 174229.762 130616.933
230 0.27367559 0.65495913 0.92073851 174229.762 130616.933
240 0.27367559 0.65495913 0.93203497 174229.762 130616.933

Conversione
0.95
0.9

Conversione 0.85
0.8
0.75
160 170 180 190 200 210 220 230 240

Temperatura

Peso molecolare medio ponderale

240000
230000
220000

MWW 210000
200000
190000
180000
160 170 180 190 200 210 220 230 240

Temperatura

PMN3

PMW1

122556.545
120689.323
118154.686
114796.013
110516.925
105588.256
100127.718
94259.6145
88167.759

PMW2

300149.385
300149.385
300149.385
300149.385
300149.385
300149.385
300149.385
300149.385
300149.385

PMW3

240058.442
240058.442
240058.442
240058.442
240058.442
240058.442
240058.442
240058.442
240058.442

IPD1

228518.328
225890.6
222721.247
218993.202
214685.82
210218.477
205685.524
201148.116
196727.067

1.72272166
1.72272166
1.72272166
1.72272166
1.72272166
1.72272166
1.72272166
1.72272166
1.72272166

Peso molecolare medio numerico

125000
120000
115000
110000
105000
MWN 100000
95000
90000
85000
80000
160 170 180 190 200 210 220 230 240

Temperatura

Indice di polidispersit
2.3
2.2
2.1
2

PDI 1.9
1.8
1.7
1.6
160

170

180

190

200

210

Temperatura

220

230

240

IPD2

1.83788148
1.83788148
1.83788148
1.83788148
1.83788148
1.83788148
1.83788148
1.83788148
1.83788148

IPD3

1.86459505
1.87167012
1.88499716
1.90767253
1.94256057
1.9909267
2.05423162
2.13397982
2.23128125

VARY 1
VARY 1
1-STY1/F
1-STY2/F
1-STY3/F
PMN1
FEED
FEED
EED
EED
EED
MIXED
MIXED
TBP MASS
TBP MASS
FLOW
FRAC
KG/HR
2.1
0.0003
27%
65%
83% 174229.762
4.2
0.0006
33%
71%
84% 141200.159
6.3
0.0009
37%
75%
86% 120149.882
8.4
0.0012
40%
78%
87% 105274.491
10.5
0.0015
43%
81%
88% 94079.9067
12.6
0.0018
45%
82%
89% 85287.5112
14.7
0.0021
47%
84%
89% 78163.8839
16.8
0.0024
49%
85%
90% 72253.9551
18.9
0.0027
51%
86%
91%
67258.409
21
0.003
52%
87%
91% 62971.2813

Conversione
100%
80%
60%
40%
20%
0%
0.0003

0.0008

Reattore 1

0.0013

0.0018

Reattore 2

0.0023

0.0028

Reattore 3

Peso molecolare medio ponderale

350000
300000
250000
200000
150000
100000
50000
0
0.0003

0.0008

Reattore 1

0.0013

0.0018

Reattore 2

0.0023

0.0028

Reattore 3

50000
0
0.0003

0.0008

Reattore 1

0.0013

0.0018

Reattore 2

0.0023

0.0028

Reattore 3

PMN2

130616.933
110604.812
94509.5112
82060.6691
72358.6784
64654.2304
58413.2536
53264.8947
48949.4778
45281.7833

PMN3

122556.545
108555.225
94726.4049
82954.8332
73345.5039
65546.5347
59163.4415
53874.5113
49435.3017
45663.3598

PMW1

PMW2

300149.385
236897.896
198192.98
171583.919
151958.222
136781.12
124635.945
114661.89
106302.486
99180.3728

PMW3

240058.442
196382.091
164895.213
141990.787
124843.792
111603.693
101091.768
92545.2488
85456.3111
79476.4639

IPD1

228518.328
194265.587
166542.023
144947.226
128086.647
114729.895
103949.778
95095.2403
87703.8147
81445.2256

1.72272166
1.67774525
1.64954785
1.62987174
1.61520379
1.60376494
1.59454647
1.58692891
1.58050849
1.5750096

Peso molecolare medio numerico

200000
150000
100000
50000
0
0.0003 0.0008 0.0013 0.0018 0.0023 0.0028
Reattore 1

Reattore 2

Reattore 3

Indice di polidispersit
1.9
1.8
1.7
1.6
1.5
1.4
0.0003

0.0008
Reattore 1

0.0013

0.0018

Reattore 2

0.0023

0.0028

Reattore 3

1.5
1.4
0.0003

0.0008
Reattore 1

0.0013

0.0018

Reattore 2

0.0023

0.0028

Reattore 3

IPD2

1.83788148
1.77552936
1.74474728
1.73031477
1.7253465
1.72616226
1.73063066
1.73745296
1.74580639
1.75515313

IPD3

1.86459505
1.78955537
1.75813727
1.74730296
1.74634627
1.75035791
1.75699342
1.76512488
1.77411307
1.78360125