N010007 PDF

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA
Secondo l'articolo 31 e l'Annesso II del Regolamento EU REACH Versione: 2.1 Data di revisione: 14.12.2010 Sostituisce la data: 28.06.2010
N010007
XIAMETER(R) PMX-200 SIL FLUID .65CS

1. ELEMENTI IDENTIFICATIVI DELLA SOSTANZA O DEL PREPARATO E DELLA SOCIET/IMPRESA PRODUTTRICE 1.1 Nome del prodotto : XIAMETER(R) PMX-200 SIL FLUID .65CS Numero di registrazione REACH: 01-2119496108-31 Intermedio Cosmetici Solvente Chimici di laboratorio Nessuno(a) conosciuto(a). Dow Corning Europe S.A. rue Jules Bordet - Parc Industriel - Zone C B-7180 Seneffe Belgio sdseu@dowcorning.com
1.2 Usi identificati
Usi sconsigliati 1.3 Societ
: :
Indirizzo e-mail (Scheda di Sicurezza)
Servizio Assistenza Clienti :
English Franais
Tel: +49 611237507 Tel: +32 64511149 Fax: +49 611237601 Fax: +32 64888683
1.4 Numero di telefono d'emergenza
Dow Corning (Barry U.K. 24h) Dow Corning (Wiesbaden 24h) Dow Corning (Seneffe 24h)
Tel: +44 1446732350 Tel: +49 61122158 Tel: +32 64 888240
2. INDICAZIONE DEI PERICOLI 2.1 Classificazione della sostanza o della miscela Secondo il Regolamento (CE) Num. 1272/2008: Liquido infiammabile: Categoria 2 Pericolo acuto per l'ambiente acquatico: Categoria 1
Secondo le Direttive EU 67/548/CEE o 1999/45/CE: R11 Facilmente infiammabile. R50 Altamente tossico per gli organismi acquatici.
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2.2 Elementi per etichettatura
Avvertenza: Pericolo Indicazioni di pericolo: Liquido e vapori facilmente infiammabili. Molto tossico per gli organismi acquatici. Consigli di prudenza: Tenere lontano da fonti di calore/scintille/fiamme libere/superfici riscaldate. - Non fumare. Prendere precauzioni contro le scariche elettrostatiche. Conservare in luogo fresco e ben ventilato. Non disperdere nell'ambiente. Non respirare i aerosol. Utilizzare soltanto all'aperto o in luogo ben ventilato. 2.3 Altri pericoli Essi possono formare miscele explosive con l'aria.
3. COMPOSIZIONE / INFORMAZIONI SUGLI INGREDIENTI Caratterizzazione chimica: Silicone. Secondo le Direttive EU 67/548/CEE o 1999/45/CE: Nome No. CAS EINECS/ ELINCS No. 203-492-7 Classificazione Conc. Numero di registrazione (% w/w) REACH 01-21194961 100,0 F R11 08-31 N R50
Esametildisilossano
107-46-0
Secondo il Regolamento (CE) Num. 1272/2008: Nome No. CAS EINECS/ ELINCS No. 203-492-7 Classificazione Conc. Numero di registrazione (% w/w) REACH Liquido infiammabile: Categoria 2 - H225 01-21194961 100,0 08-31
Esametildisilossano
107-46-0
Pericolo acuto per l'ambiente acquatico: Categoria 1 - H400
Per il testo completo delle frasi R menzionate in questa sezione, riferirsi alla sezione 16. Per quanto riguarda il testo completo delle dichiarazioni-H menzionate in questo paragrafo, consultare il paragrafo 16. Le classificazioni CLP si basano su tutti i dati attualmente disponibili, inclusi quelli provenienti da organizzazioni internazionali. Queste classificazioni sono
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soggette a revisione, non appena sono rese disponibili ulteriori informazioni.
4. MISURE DI PRONTO SOCCORSO 4.1 Descrizione delle misure di pronto soccorso: Contatto con gli occhi Contatto con la pelle Se inalato Ingestione : : : : Non necessario un pronto soccorso. Non necessario un pronto soccorso. Portare all'aria aperta. Non necessario un pronto soccorso.
5. MISURE ANTINCENDIO 5.1 Mezzi di estinzione appropriati : In caso di incendi di grande entit usare estintore AFFF con schiuma compatibile con alcool oppure con acqua nebulizzata (nebbia). In caso di piccoli incendi usare estintore AFFF con schiuma compatibile con alcool, CO2 oppure con acqua nebulizzata (nebbia). L'acqua pu essere utilizzata per raffreddare i contenitori esposti al fuoco. Nessuno(a) conosciuto(a).
Mezzi di estinzione inadatti 5.2 Pericoli durante l'estinzione degli incendi.
Il fuoco brucia pi intensamente di quanto si possa prevedere. I vapori sono pi pesanti dell'acqua e possono muoversi lungo il suolo verso sorgenti d'ignizione lontani. Cariche elettrostatiche possono essere generate durante il trasferimento del prodotto dal suo recipiente. Assicurarsi che tutta l'attrezzatura sia collegata a terra. Essi possono formare miscele explosive con l'aria. La decomposizione termica di questo prodotto durante la combustione o in condizioni di calore estremo, pu dar luogo ai seguenti prodotti di decomposizione: Silice. Anidride carbonica e tracce di composti di carbonio parzialmente incombusti. Formaldeide. Conviene indossare un respiratore autonomo e abiti protettivi. Determinare la necessit di evacuare o di isolare l'area secondo il piano di emergenza locale. Usare vaporizzazione d'acqua per mantenere freddi i contenitori esposti al fuoco.
Prodotti di combustione pericolosi 5.3 Metodi antincendio speciali
6. MISURE IN CASO DI FUORIUSCITA ACCIDENTALE 6.1 Precauzioni personali, equipaggiamento protettivo e procedure d'emergenza 6.2 Precauzioni ambientale : Conviene indossare un respiratore autonomo e abiti protettivi. Determinare la necessit di evacuare o di isolare l'area secondo il piano di emergenza locale. Eliminare tutte le possibili sorgenti d'ignizione.
Non gettare i residui nelle fognature. Impedire la dispersione o la diffusione nelle fogne, nelle fosse o nei fiumi usando sabbia, terra od altre barriere appropriate. Informare le autorit locali se la perdita non pu essere contenuta. Determinare la necessit di evacuare o di isolare l'area secondo il piano di emergenza locale. Eliminare tutte le possibili sorgenti d'ignizione. Se il prodotto si spande su una 3 di 42
6.3 Procedure e materiali per il contenimento e la


raccolta a scopo di pulizia superficie estesa, necessario contenerlo con sistemi di barriere, ecc. Togliere o asciugare con materiale assorbente e mettere in un recipiente dotato di un coperchio. Il prodotto rovesciato crea una superficie estremamente scivolosa.
7. MANIPOLAZIONE E STOCCAGGIO 7.1 Precauzioni per una manipolazione sicura : E' necessaria una ventilazione generale. E' raccomandata la ventilazione locale. Evitare il contatto con gli occhi. Non respirare i vapori. Non gettare i residui nelle fognature. Non respirare le polverizzazioni o nebbie. Immagazzinare in una zona ben ventilatata e resistente alle fiamme. Cariche elettrostatiche possono essere generate durante il trasferimento del prodotto dal suo recipiente. Assicurarsi che tutta l'attrezzatura sia collegata a terra. Tenere il contenitore chiuso ermeticamente. Essi possono formare miscele explosive con l'aria. Riferirsi alla scheda tecnica disponibile su richiesta.
7.2 Condizioni di stoccaggio
7.3 Usi specifici
8. CONTROLLO DELL'ESPOSIZIONE/PROTEZIONE INDIVIDUALE 8.1 Parametri di controllo Nome Esametildisilossano 8.2 Controlli dell'esposizione Controlli di esposizione : Ventilazione : Seconda dalla sezione 7.1 No. CAS 107-46-0 Limiti di esposizione 200 ppm TWA-8h. raccomandazione Dow Corning.
Equipaggiamento di protezione individuale Protezione respiratoria : Conviene utilizzare una protezione respiratoria adeguata se il prodotto viene usato in grandi quantit, in spazi ristretti o in circostanze in cui vengono raggiunti o superati i limiti di esposizione. Servirsi di un apparecchio respiratorio adatto se il prodotto viene utilizzato nelle circostanze dove una formazione di nebbia o aerosol pu succedere, per esempio durante una pulverizzazione o attivit similari. Secondo le condizioni di lavoro, indossare una maschera respiratoria fornita di filtro(i) AP oppure usare un autorespiratore autonomo. La scelta di uno tipo di filtro dipende dalla quantit e dal tipo di prodotto chimico manipolato al posto di lavoro. Per quanto riguarda le caratteristiche del filtro, contatti il Suo fornitore di protezioni respiratorie. In principio, i guanti non sono necessari. Conviene indossare occhiali di sicurezza. In principio, non necessario un equipaggiamento protettivo. 4 di 42
Protezione delle mani Protezione degli occhi/del viso Protezione della pelle
: : :


Misure di igiene : Usare corrette pratiche di igiene industriale. Lavarsi dopo la manipulazione, specialmente prima di mangiare, di bere o di fumare. Queste precauzioni sono valide per usi a temperatura ambiente. L'uso ad alte temperature e le applicazioni aerosol/spruzzo possono necessitare ulteriori precauzioni. Per ulteriori informazioni riguardo l'uso di siliconi / oli organici in applicazioni aerosol dei consumatori vogliate riferirvi al documento illustrativo che riguarda l'uso di questi tipi di materiale in applicazioni aerosol personali che sono stati sviluppati d'industria di silicone (www.SEHSC.com) o contattare il servizio clienti del gruppo Dow Corning. Riferirsi alla sezione 6 e 12.
Altre informazioni
Controllo dell'esposizione ambientale
9. PROPRIET FISICHE E CHIMICHE Stato fisico Colore Odore Punto/intervallo di ebollizione Punto/intervallo di fusione Punto di infiammabilit : : : : : : Liquido. Incolore. Odore caratteristico. 100 C -68 C -3,3 C (Pensky-Martens Closed Cup) 1,50 % 14,65 % 352 C No Essi possono formare miscele explosive con l'aria. 4,2 kPa a 20C. 0,76 4,76 760 g/l 162 0,65 mm2/s a 25C. No
Limiti di esplosione inferiore : Limiti di esplosione superiore Temperatura di autoinfiammabilit Propriet esplosive : : :
Pressione di vapore Peso specifico Coefficiente di ripartizione (n-ottanolo/acqua) VOC Peso Molecolare Viscosit Propriet comburenti (ossidanti)
: : : : : : :
Le informazioni fornite sopra non vanno utilizzate nella preparazione delle specifiche del prodotto.
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10. STABILIT E REATTIVIT 10.1 Reattivit 10.2 Stabilit 10.3 Possibilit di reazioni pericolose 10.4 Condizioni da evitare 10.5 Materie da evitare : : : Nessuno(a) conosciuto(a). Stabile in normale condizioni di uso. Nessuno(a) conosciuto(a).
: :
Eliminare tutte le possibili sorgenti d'accensione. Pu reagire con agenti ossidanti forti. La decomposizione termica di questo prodotto durante la combustione o in condizioni di calore estremo, pu dar luogo ai seguenti prodotti di decomposizione: Silice. Anidride carbonica e tracce di composti di carbonio parzialmente incombusti. Formaldeide.
: 10.6 Prodotti di decomposizione pericolosi
11. INFORMAZIONI TOSSICOLOGICHE Tossicit acuta: Contatto con gli occhi Contatto con la pelle Se inalato Ingestione LC50 inalazione (Ratto) : : : : : Pu incommodare temporaneamente. In linea di principio, non si rileva nessun effeto negativo. In linea di principio, non si rileva nessun effeto negativo. In linea di principio, non si rileva nessun effeto negativo. 87 mg/l - 4 ore Vapore
Tossicit cronica: Contatto con la pelle Se inalato Ingestione Effetti tossicocinetici, effetti sul metabolismo e distribuzione Altri effetti pericolosi per la salute : : : : In linea di principio, non si rileva nessun effeto negativo. In linea di principio, non si rileva nessun effeto negativo. In linea di principio, non si rileva nessun effeto negativo. Non sono disponibili informazioni specifiche.
Il prodotto pu formare vapore di formaldeide a temperatura al di sopra di 150C in presenza dell' aria. Vapore di formaldeide sospetta essere cancerogeno, tossico per inalazione e irritante per gli occhi e le vie respiratorie. Limiti di esposizione devono essere rispettati rigorosamente.
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1 2
Basato su risultati di test sul prodotto. Basato su risultati di test relative a prodotti similari.
12. INFORMAZIONI ECOLOGICHE 12.1 Ecotossicit molto tossico per gli organismi acquatici. Pesce Invertebrati Alghe : : : Oncorhynchus mykiss 96 Ore LC50 0,46 mg/l Daphnia magna 72 Ore EC50 0,79 mg/l Selenastrum capricornutum 96 Ore EC50 > 0,93 mg/l
12.2 Persistenza e degradabilit I silossani volatili con basso peso molecolare hanno una solubilit in acqua poco elevata ed evaporano all'aria. I silossani volatili con basso peso molecolare si degradano nell'aria tramite reazione con radicali idrossili, i quali costituiscono il processo di degradazione maggiore per la maggior parte dei prodotti chimici nell'atmosfera. I silossani volatili con basso peso molecolare presenti nel suolo, vengono eliminati tramiti diversi processi simultanei quali la volatilizzazione, l'idrolisi e la degradazione catalizzata con argilla. Il prodotto idrolizza in acqua, rilasciando idrossisilanos. 12.3 Bioaccumulazione I silossani volatili con basso peso molecolare bioconcentrati in pesce esposto alle condizioni di controllo in laboratorio che non sono rappresentativi delle condizioni trovate nell'ambiente. 12.4 Scarico nelle acque / Mobilit nel suolo Impatti sull' impianto di trattamento delle acque di rifiuto: Nessun effetto negativo sui batteri prevedibile. I silissani contenuti in questo prodotto non contribuiscono al BOD. I silossani volatili con basso peso molecolare vengono efficacemente eliminati (>90%) durante il trattamento per l'eliminazione dell'acqua usata, con approssimativamente una quantit identica che viene dispersa nell'atmosfera et la fogna. I silossani volatili con basso peso molecolare presenti nello scarico d'acqua trattata, verranno legati a materia parcellizzata a causa della loro bassa solubilit in acqua.
13. CONSIDERAZIONI SULLO SMALTIMENTO Eliminazione del prodotto e dell'imballaggio : Questo materiale deve essere eliminato come rifiuto pericoloso. Eliminare nel rispetto della normativa vigente in materia. Secondo il catalogo europeo dei rifiuti, i codici dei rifiuti non sono specifici al prodotto, ma specifici all'applicazione. I codici dei rifiuti devono essere assegnati dall'utilizzatore, di preferenza dopo discussione con le autorit responsabili per lo smaltimento dei rifiuti.
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14. INFORMAZIONI SUL TRASPORTO Strada / Ferrovia (ADR/RID) N. NU Proper Shipping Name Classe Gruppo d'imballaggio Etichettatura Via marittima (IMDG) N. NU Proper Shipping Name Classe Gruppo d'imballaggio EmS : : : : : UN 1993 FLAMMABLE LIQUID, N.O.S.(Hexamethyldisiloxane) 3 II F-E S-E Hexamethyldisiloxane flammable liquid : : : : : UN 1993 LIQUIDO INFIAMMABILE, N.A.S.(Hexamethyldisiloxane) 3 II 3
Inquinante marino Etichettatura Transporte aereo (IATA) N. NU Proper Shipping Name Classe
: :
: : :
UN 1993 Flammable liquid, n.o.s.(Hexamethyldisiloxane) 3
Gruppo d'imballaggio Etichettatura
: :
II Flammable Liquid
15. INFORMAZIONI SULLA REGOLAMENTAZIONE 15.1 Sicurezza, salute e regolamentazioni ambientali/legislazione specifica per la sostanza o la miscela Stato EINECS : Tutti gli ingredienti elencati, esenti da o sottoposto alla notifica (ELINCS). 8 di 42


TSCA AICS IECSC KECL PICCS DSL : : : : : : Tutti gli ingredienti elencati o esenti da. Tutti gli ingredienti elencati, esenti da o sottoposto alla notifica. Tutti gli ingredienti elencati o esenti da. Tutti gli ingredienti elencati, esenti da o sottoposto alla notifica. Tutti gli ingredienti elencati, esenti da o sottoposto alla notifica. Tutti gli ingredienti elencati o esenti da.
16. ALTRE INFORMAZIONI La scheda di sicurezza di questo prodotto stata preparata in conformit con l'articolo 31 e l'Annesso II del Regolamento EU REACH e con gli emendamenti significativi successivi sull'adeguamento alle leggi, regolamenti e norme amministrative relative alla classificazione, imballaggio, etichettatura di sostanze pericolose e preparati. E responsabilit delle persone che ricevono questa Scheda di Sicurezza del Prodotto di assicurarsi che le informazioni qui contenute siano lette e capite correttamente da tutte le persone che possano usare, manipolare, eliminare il prodotto o che in ogni caso ne possano venire a contatto. Se il destinatario, produrr in seguito una formulazione contenente il prodotto, lo stesso destinatario sar unico responsabile del trasferimento di tutte le informazioni importanti dalla Scheda di Sicurezza del Prodotto sulla propria Scheda di Sicurezza del Prodotto in conformit con l'articolo 31 e l'Annesso II della Regolamentazione EU REACH. Tutte le informazioni ed istruzioni riportate nella presente Scheda di Sicurezza del Prodotto si basano sulle conoscenze scientifiche e tecniche alla data indicata su detta Scheda. Dow Corning in qualit di societ fornitrice non sar ritenuta responsabile per eventuali difetti del prodotto oggetto di questa Scheda nel caso in cui detti difetti non possono essere individuati in base alle attuali conoscenze scientifiche e tecniche. Come menzionato sopra, questa Scheda di Sicurezza stata preparata in conformit con la legge europea applicabile. Se voi acquistate questo materiale al di fuori dell'Europa, dove la conformit alla legge pu essere differente, voi dovreste ricevere dal vostro fornitore locale una Scheda di Sicurezza applicabile al paese dove questo prodotto viene venduto e dove si suppone sia usato. Si prega di notare che l'aspetto e il contenuto della SDS pu variare - anche per lo stesso prodotto - tra paesi diversi, rispecchiando diversi requisiti di conformit. Sorgente dell'informazione : Dati interni e informazioni disponibili pubblicamente R11 Facilmente infiammabile., R50 Altamente tossico per gli organismi acquatici. H225 Liquido e vapori facilmente infiammabili., H400 Molto tossico per gli organismi acquatici. XIAMETER(R) is a trademark of Dow Corning Corporation http://www.xiameter.com
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Scenario d'esposizione
1. Short title of Exposure Scenario: Manufacturing and on-site use of Hexamethyldisiloxane (CAS 107-46-0).
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information
: SU3 : SU8, SU9, SU10 : : PROC1, PROC2, PROC3, PROC4, PROC8b, PROC9 : : ERC1, ERC6a, ERC6c :
2.1 ERC1, ERC6a, ERC6c

Remarks Product characteristics Concentration of the Substance in Mixture/Article Viscosity, kinematic Viscosity, dynamic Amount used Annual amount used per site Remarks (Msafe) Remarks Frequency and duration of use Single exposure Continuous exposure
: 100% : :
0.5 mPa.s at 25C
: 3,500 tpa : : :
: :
Environment factors not influenced by risk management Flow rate : Dilution Factor (River) : 900 1000 Dilution Factor (Coastal Areas) : Other data - Other information : Remarks : Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : 350/site Emission or Release Factor: Air : 1E-04 kg/kg Emission or Release Factor: Water : 4E-07 kg/kg Emission or Release Factor: Soil : 0 10 di 42


Remarks Parameter Remarks : : :
Technical conditions and measures / Organizational measures Exposure time : Compartment : Air : Water : Soil : Sediment : Remarks : Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : Sludge may be sent to landfill or incinerated. Spreading of sludge is assumed as a worst-case scenario. Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : Solid wastes from production are ultimately disposed of via landfill or incineration, or are recycled outside of the process. Landfill is the most common disposal route. Details of the treatment of aqueous waste vary at different production sites but as a minimum the effluent is treated in on-site secondary biological treatment plants prior to discharge. Non-aqueous waste may be disposed off site as hazardous waste. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Recovery of sludge for agriculture or horticulture Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC4, PROC8b, PROC9
Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : 10 tonnes/day 11 di 42 100 % : Liquid : 4451 Pa at 20C : :


: Frequency and duration of use Duration Frequency of use
: 15-60 minutes (PROC2, PROC3, PROC4) <15 minutes (PRCO8b, PROC9) : 1/day (PROC1, PROC2, PROC3, PROC4) 2-5 days (PROC8b, PROC9) :
Remarks
Human factors not influenced by risk management Exposed skin area : 240 cm2 (PROC1, PROC3) 480 cm2 (PROC2, PROC4, PROC8b, PROC9) Other Factors: : Remarks : Other operational conditions affecting workers exposure Outdoor / Indoor : Room size : NA for tier one exposure tool Temperature : Ventilation rate per hour : NA for tier one exposure tool Remarks : Parameter :
Technical conditions and measures Local exhaust ventilation required (Effectiveness: ) Organisational measures to prevent /limit releases, dispersion and exposure Standard handling procedures include bonding and grounding requirements and purging and inerting procedures due to the materials flammability. Sites producing and using the registered substance also handle large volumes of highly corrosive and flammable chlorosilanes, including as starting materials in the production process. All aspects of chlorosilane handling, including on-site storage and transfer, are subject to highly controlled conditions. The Centre Europen des Silicones (CES) manual on Safe Handling of Chlorosilanes, which these site subscribe to, recommends that on-site storage vessels are located outside, remote from other buildings, overhead utilities or piping. Build-up of static electricity must be prevented. Equipment such as transfer lines, pumps, valves and vessels must be thoroughly dried, and should be fully enclosed to prevent contact with atmospheric moisture. Carbon steel vessels and piping are suitable in the absence of water, and leak tight systems are employed . General Standard Operating Procedures which control routine activities. Confined Space Entry Permits and general Permit to Work (PTW) govern all cleaning and maintenance activities. Flushing, purging and venting of vessel lines are implemented before cleaning or maintenance. Plant integrity checks. Operator monitoring. Safety and environmental audits. Regular training of workers with respect to substance hazards and safe handling; fully trained chemical operators, EMAS/ISO14001, integrated safety management systems etc Conditions and measures related to personal protection, hygiene and health evaluation Nitrile gloves Safety glassed or goggles Apron or impervious overalls where appropriate Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice : 12 di 42

2.3 Contributing scenario controlling consumer exposure for: Exposure to consumers is not relevant for this scenario.
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3. Exposure estimation and reference to its source
Environment Contributing Scenario ERC1, ERC6a, ERC6c ERC1, ERC6a, ERC6c ERC1, ERC6a, ERC6c ERC1, ERC6a, ERC6c ERC1, ERC6a, ERC6c ERC1, ERC6a, ERC6c Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Specific conditions Compartment Value type Level of Exposure 2.23E-06 mg/l 3.05E-05 mg/l 2.16E-06 mg/kg ww 2.49E-04 mg/kg ww 1.15E-04 mg/kg ww 1.48E-03 mg/l Risk characterisation ratio 2.78E-04 0.0381 2.78E-03 0.381 0.0268 <1.48E-04
Freshwater Marine water Sediments (fresh water) Sediments (marine water) Agricultural soil Sewage Treatment Plant
PEC PEC PEC PEC PEC PEC
Workers Contributing Scenario PROC8b PROC8b PROC2 Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure .01 mg/cm2 0.69 mg/kg bw/d 5 mg/m3/8h 5 mg/m3/8h Risk characterisation ratio NA 5.84E-03 NA
With LEV With LEV With LEV, including modification for exposure duration. With LEV, including modification for exposure duration.
Dermal local exposure Dermal systemic exposure Inhalation local exposure Inhalation systemic exposure
PROC2
5.62E-03
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario
This exposure scenario covers production of HMDS in the EU, and on-site use as in polymer production or as a chemical intermediate. In addition, the scenario also covers use at sites either importing from non-EU manufacturers, or purchasing material from EU manufacturers, where HMDS itself is not produced, but other silanes are manufactured. These additional sites are included because high levels of control and emission abatement are employed at such locations due to the highly reactive nature of other materials produced and used there. Production is carried out in a closed continuous process, described in terms of REACH descriptors as PROC2, or a closed batch process (PROC3). PROC 8b also applies for packaging of material for shipment off-site. 14 di 42


1. Short title of Exposure Scenario: Use of Hexamethyldisiloxane (CAS 107-46-0) as an end-blocker in the production of silicone polymers and resins.
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information : : : : SU3 SU8, SU9 PC19 PROC1, PROC2, PROC3, PROC8b
: : ERC6c :
2.1 ERC6c
: 100% : :
0.5 mPa.s at 25C
: Unknown, but low : : :
: :
Environment factors not influenced by risk management Flow rate : Dilution Factor (River) : 40 (referenced from ES entitled Use of Hexamethyldisiloxane (CAS 107-46-0) as a chemical intermediate at site other than production sites) Dilution Factor (Coastal Areas) : Other data - Other information : Remarks : Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : Unknown, but few/site Emission or Release Factor: Air : 1E-04 (referenced from ES entitled Use of Hexamethyldisiloxane (CAS 107-46-0) as a chemical intermediate at site other than production sites) Emission or Release Factor: Water : 1.25E-04 (referenced from ES entitled Use of Hexamethyldisiloxane (CAS 107-46-0) as a chemical intermediate at site other than production sites) Emission or Release Factor: Soil : 0 Remarks : Parameter : 15 di 42


Remarks :
Technical conditions and measures / Organizational measures Exposure time : Compartment : Air : Water : Soil : Sediment : Remarks : Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : Sludge may be sent to landfill or incinerated. Spreading of sludge is assumed as a worst-case scenario. Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : Solid wastes from use as a monomer are ultimately disposed of via landfill or incineration, or are recycled outside of the process. Details of the treatment of aqueous waste vary at different sites but as a minimum the effluent treated in either in on-site or municipal secondary biological treatment plants prior to discharge. Non-aqueous waste may be disposed off site as hazardous waste. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Recovery of sludge for agriculture or horticulture Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC8b
Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : Unknown, but low/day : Frequency and duration of use 16 di 42 100 % : Liquid : 4451 Pa at 20C : :


Duration Frequency of use Remarks : 15-60 minutes (PROC1, PROC2, PROC3) <15 minutes (PROC8b) : 1/day :
Human factors not influenced by risk management Exposed skin area : 240 cm2 (PROC1, PROC3) 480 cm2 (PROC2, PROC8b) Other Factors: : Remarks : Other operational conditions affecting workers exposure Outdoor / Indoor : Room size : NA for tier one exposure tool Temperature : Ventilation rate per hour : NA for tier one exposure tool Remarks : Parameter :
Technical conditions and measures Local exhaust ventilation required (Effectiveness: ) Organisational measures to prevent /limit releases, dispersion and exposure HMDS is volatile, flammable liquid and as such should be stored in a flameproof, well ventilated area. Sites producing and using the registered substance also handle large volumes of highly corrosive and flammable chlorosilanes, including as starting materials in the production process. All aspects of chlorosilane handling, including on-site storage and transfer, are subject to highly controlled conditions. The Centre Europen des Silicones (CES) manual on Safe Handling of Chlorosilanes, which these site subscribe to, recommends that on-site storage vessels are located outside, remote from other buildings, overhead utilities or piping. Build-up of static electricity must be prevented. Equipment such as transfer lines, pumps, valves and vessels must be thoroughly dried, and should be fully enclosed to prevent contact with atmospheric moisture. Carbon steel vessels and piping are suitable in the absence of water, and leak tight systems are employed . General Standard Operating Procedures which control routine activities. Confined Space Entry Permits and general Permit to Work (PTW) govern all cleaning and maintenance activities. Flushing, purging and venting of vessel lines are implemented before cleaning or maintenance. Plant integrity checks. Operator monitoring. Safety and environmental audits. Regular training of workers with respect to substance hazards and safe handling; fully trained chemical operators, EMAS/ISO14001, integrated safety management systems etc Conditions and measures related to personal protection, hygiene and health evaluation Safety glasses or goggles. Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
17 di 42

18 di 42


Environment It can be seen from the table that the RCR for marine sediment is nominally above 1 (having applied EUSES default), indicating that direct discharge of waste water containing HMDS from this exposure scenario is not safe. Treatment of waste water in a waste water treatment plant before discharge into the marine water is required to determine safe use. Therefore, downstream users are required to apply risk management measures of treating waste water to maintain this use. Applying this risk management measure would give marine RCR similar to the fresh water value. Contributing Scenario ERC6c ERC6c ERC6c ERC6c ERC6c ERC6c Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Specific conditions Compartment Value type Level of Exposure 1.27E-05 mg/l 1.00E-04 mg/l 1.04E-04 mg/kg ww 8.15E-04 mg/kg ww 3.77E-05 mg/kg ww 4.85E-04 mg/l Risk characterisation ratio 1.59E-03 0.125 0.0159 1.25 8.8E-03 <4.85E-05
Workers Contributing Scenario PROC8b Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure 0.1 mg/cm2 Risk characterisation ratio NA
PROC8b
PROC2
PROC2
With LEV, including modification for exposure duration. With LEV, including modification for exposure duration. With LEV, including modification for exposure duration. With LEV, including modification for exposure duration.
Dermal local exposure Dermal systemic exposure Inhalation local exposure Inhalation systemic exposure
0.69 mg/kg bw/d 3.3 mg/m3/8h 3.3 mg/m3/8h
5.47E-03
NA
3.71E-03
This exposure scenario covers the use of HMDS as an end-blocker in the production of siloxane polymers and resins. Polymer production is carried out in continuous or batch processes, described in terms of REACH descriptors as PROC1 (closed process), PROC2 (closed continuous process), and PROC3 (closed batch processes). PROC8b applies for unloading of raw material. 19 di 42


For the purpose of environmental exposure, downstream use as an intermediate or as a monomer are considered together, because use as a specialist intermediate is by far the major application. Therefore ES entitled Use of Hexamethyldisiloxane (CAS 107-46-0) as an end-blocker in the production of silicone polymers and resins does not include environmental assessment.
20 di 42

1. Short title of Exposure Scenario: Use of Hexamethyldisiloxane (CAS 107-46-0) as a chemical intermediate at site other than production sites.
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information
: : : :
SU3 SU8, SU9 PC19 PROC1, PROC2, PROC3, PROC4, PROC8b, PROC9
: : ERC6a :
2.1 ERC6a
: 100% : :
0.5 mPa.s at 25C
: 200 tpa : : :
: :
Environment factors not influenced by risk management Flow rate : Dilution Factor (River) : 40 Dilution Factor (Coastal Areas) : Other data - Other information : Remarks : Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : 200/site Emission or Release Factor: Air : 1E-04 Emission or Release Factor: Water : 1.25E-04 Emission or Release Factor: Soil : 0 Remarks : Parameter : Remarks :
21 di 42


Technical conditions and measures / Organizational measures Exposure time : Compartment : Air : Water : Soil : Sediment : Remarks : Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : 10,000 m3/d effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : Sludge may be sent to landfill or incinerated. Spreading of sludge is assumed as a worst-case scenario. Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : Solid wastes from use as a monomer are ultimately disposed of via landfill or incineration, or are recycled outside of the process. Details of the treatment of aqueous waste vary at different sites but as a minimum the effluent treated in either in on-site or municipal secondary biological treatment plants prior to discharge. Non-aqueous waste may be disposed off site as hazardous waste. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Recovery of sludge for agriculture or horticulture Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC4, PROC8b, PROC9
Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : 1 tonne/day : Frequency and duration of use Duration 100 % : Liquid : 4451 Pa at 20C : :
: 15-60 minutes (PROC1, PROC2, PROC3, PROC4, PROC9) <15 minutes (PROC8b) 22 di 42


Frequency of use Remarks : 1/day :
Human factors not influenced by risk management Exposed skin area : 240 cm2 (PROC1, PROC3) 480 cm2 (PROC2, PROC4, PROC8b, PROC9) Other Factors: : Remarks : Other operational conditions affecting workers exposure Outdoor / Indoor : Room size : NA for tier one exposure tool Temperature : Ventilation rate per hour : NA for tier one exposure tool Remarks : Parameter :
Technical conditions and measures Local exhaust ventilation required (Effectiveness: ) Organisational measures to prevent /limit releases, dispersion and exposure HMDS is volatile, flammable liquid and as such should be stored in a flameproof, well ventilated area. Conditions and measures related to personal protection, hygiene and health evaluation Safety glasses or goggles. Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :

Environment It can be seen from the table that the RCR for marine sediment is nominally above 1 (having applied EUSES default), indicating that direct discharge of waste water containing HMDS from this exposure scenario is not safe. Treatment of waste water in a waste water treatment plant before discharge into the marine water is required to determine safe use. Therefore, downstream users are required to apply risk management measures of treating waste water to maintain this use. Applying this risk management measure would give marine RCR similar to the fresh water value.
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Contributing Scenario ERC6a ERC6a ERC6a ERC6a ERC6a ERC6a
Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1
Specific conditions
Compartment
Value type
Level of Exposure 1.27E-05 mg/l 1.00E-04 mg/l 1.04E-04 mg/kg ww 8.15E-04 mg/kg ww 3.77E-05 mg/kg ww 4.85E-04 mg/l
Risk characterisation ratio 1.59E-03 0.125 0.0159 1.25 8.8E-03 <4.85E-05
Workers Contributing Scenario PROC8b PROC8b PROC3 Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure 0.1 mg/cm2 0.69 mg/kg bw/d 6.6 mg/m3/8h Risk characterisation ratio NA 5.48E-03 7.42E-03
With LEV With LEV With LEV, including modification for exposure duration.
Dermal local exposure Dermal systemic exposure Inhalation local exposure
This exposure scenario covers the use of HMDS as chemical intermediate. The substance is unusual in that it is used at relatively high levels as an intermediate in specialist sectors such as the pharmaceutical industry. Use as an intermediate may be carried out in continuous or batch processes, described in terms of REACH descriptors as PROC1 (closed process), PROC2 (closed continuous process) or PROC3 (closed batch process) and PROC4 (Use in batch and other process (synthesis) where opportunity for exposure arises). PROC8b applies for unloading of raw material.
24 di 42

1. Short title of Exposure Scenario: Use of Hexamethyldisiloxane (CAS 107-46-0) as a laboratory reagent (human health only).
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information : : : : SU3 SU24 PC21 PROC15
: : N/A :
2.1 N/A
: 100% : :
0.5 mPa.s at 25C
: N/A : : :
: :
Environment factors not influenced by risk management Flow rate : Dilution Factor (River) : N/A Dilution Factor (Coastal Areas) Other data - Other information Remarks : : :
Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : N/A Emission or Release Factor: Air : N/A Emission or Release Factor: Water : N/A Emission or Release Factor: Soil : N/A Remarks : Parameter : Remarks : Technical conditions and measures / Organizational measures 25 di 42


Exposure time Compartment Air Water Soil Sediment Remarks : : : : : : :
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : N/A Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : N/A Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Recovery of sludge for agriculture or horticulture Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC15

Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : <10 grams/day : Frequency and duration of use Duration Frequency of use Remarks 100 % : Liquid : 4451 Pa at 20C : :
: <15 minutes : 1/day :
Human factors not influenced by risk management Exposed skin area : 240 cm2 (PROC15) Other Factors: Remarks : : 26 di 42


Other operational conditions affecting workers exposure Outdoor / Indoor : Room size : NA for tier one exposure tool Temperature : Ventilation rate per hour : NA for tier one exposure tool Remarks : Parameter :
Technical conditions and measures Containment plus good work practice required. Local exhaust ventilation required (Effectiveness: ) Organisational measures to prevent /limit releases, dispersion and exposure HMDS is volatile, flammable liquid and as such should be stored in a flameproof, well ventilated area. Conditions and measures related to personal protection, hygiene and health evaluation Safety glasses or goggles
Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :

Environment Given the very small scale use, it is not appropriate to assess environmental exposure for this scenario. There is no intentional release of HMDS to waste water and any fugitive releases to air will be of negligible volume. Contributing Scenario N/A N/A N/A N/A N/A N/A N/ Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Specific conditions Compartment Value type Level of Exposure N/A N/A N/A N/A N/A N/A N/A Risk characterisation ratio
Freshwater Marine water Sediments (fresh water) Sediments (marine water) Agricultural soil Grassland Sewage Treatment Plant 27 di 42
PEC PEC PEC PEC PEC PEC PEC

28 di 42


Workers Contributing Scenario PROC15 PROC15 PROC15 Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure Risk characterisation ratio NA 2.78E-04 7.42E-04
Dermal local 0.001 mg/cm2 exposure With LEV Dermal systemic 0.035 mg/kg exposure bw/d Assumes LEV and Inhalation local 0.66 modification for duration exposure mg/m3/8h of exposure. With LEV
This scenario covers the use of HMDS as a laboratory reagent for small-scale synthesis and research. All applications involve the use of very small quantities of material and all procedures are carried out in a fume cupboard. These are considered as PROC15 and the duration of exposure is considered to be <15 minutes, since the only potential for exposure to HMDS is during transfer of small quantities of reagent. In most locations, these activities are expected to be carried out infrequently, but as a reasonable worst case it is assumed that a worker may use the substance once per day.
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1. Short title of Exposure Scenario: Use of Hexamethyldisiloxane (CAS 107-46-0) for formulation of personal care products.
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information : : : : SU3 SU10 PC31, PC35, PC39 PROC1, PROC2, PROC3, PROC5, PROC8a, PROC8b, PROC9
: : ERC2 :
2.1 ERC2
: 10% : :
0.5 mPa.s at 25C
: 20tpa : : :
: :
Environment factors not influenced by risk management Flow rate : Dilution Factor (River) : Dilution Factor (Coastal Areas) Other data - Other information Remarks : : :
Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : 200/site Emission or Release Factor: Air : 0.0002 Emission or Release Factor: Water : 0.0009 Emission or Release Factor: Soil : 0 Remarks : Parameter : Remarks : Technical conditions and measures / Organizational measures 30 di 42


Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : 2,000 m3/d effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : N/A Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : Solid wastes are ultimately disposed of via landfill or incineration. Details of the treatment of aqueous waste vary at different sites but as a minimum the effluent treated in either in on-site or municipal secondary biological treatment plants prior to discharge. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Recovery of sludge for agriculture or horticulture Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC5, PROC8a, PROC8b, PROC9
Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : 0.1 tonne/day : Frequency and duration of use Duration Frequency of use Remarks 10 % : Liquid : 4451 Pa at 20C : :
: 15-60 minutes (PROC5) >4 hours (PROC8a, PROC8b, PROC9) : 1/day : 31 di 42


Human factors not influenced by risk management Exposed skin area : 480 cm2 (PROC5, PROC8b, PROC9) 960 cm2 (PROC8a) Other Factors: Remarks : :
Other operational conditions affecting workers exposure Outdoor / Indoor : Room size : NA for tier one exposure tool Temperature : Ventilation rate per hour : NA for tier one exposure tool Remarks : Parameter : Technical conditions and measures Local exhaust ventilation required (Effectiveness: ) Organisational measures to prevent /limit releases, dispersion and exposure HMDS is volatile, flammable liquid and as such should be stored in a flameproof, well ventilated area. Conditions and measures related to personal protection, hygiene and health evaluation Safety glasses or goggles
Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :

Environment It can be seen from the table that the RCR for marine sediment is nominally above 1 (having applied EUSES default), indicating that direct discharge of waste water containing HMDS from this exposure scenario is not safe. Treatment of waste water in a waste water treatment plant before discharge into the marine water is required to determine safe use. Therefore, downstream users are required to apply risk management measures of treating waste water to maintain this use. Applying this risk management measure would give marine RCR similar to the fresh water value.
32 di 42

Contributing Scenario ERC2 ERC2 ERC2 ERC2 ERC2 ERC2
Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1
Specific conditions
Compartment
Value type
Level of Exposure 2.19E-04 mg/l 4.50E-04 mg/l 1.78E-03 mg/kg ww 3.67E-03 mg/kg ww 1.67E-04 mg/kg ww 2.18E-03 mg/l
Risk characterisation ratio 0.0274 0.562 0.274 5.62 0.0395 <2.18E-04
Workers Contributing Scenario PROC8b PROC8b PROC8a Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure 0.1 mg/cm2 0.69 mg/kg bw/d 33 mg/m3/8h Risk characterisation ratio NA 5.48E-03 0.0371
With LEV With LEV With LEV
This exposure scenario covers the formulation (mixing) of HMDS into products used as personal care products (PC39 in terms of REACH descriptors (ECHA, 2010a). Mixing of products takes place using continuous or batch processes (PROCs 2, 3 or 5) and the scenario also covers transfer of the substance to and from bulk containers at non-dedicated and dedicated facilities (PROCs 8a and 8b respectively), and into smaller packaging for supply to end users (PROC9). Since PROC5 represents the worst case in respect of worker exposure during the mixing stage, this will be taken forward for quantitative exposure assessment.
33 di 42

1. Short title of Exposure Scenario: Hexamethyldisiloxane (CAS 107-46-0) for use of personal care products.
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information : SU21, SU22 : : PC39 : PROC19 : : ERC8a :
2.1 ERC8a
: 5-25% : :
0.5 mPa.s at 25C
: N/A : : :
: :
Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : 365/site Emission or Release Factor: Air : 0.9 Emission or Release Factor: Water : 0.1 Emission or Release Factor: Soil : 0 Remarks : Parameter : Remarks : Technical conditions and measures / Organizational measures Exposure time : 34 di 42


Compartment Air Water Soil Sediment Remarks : : : : : :
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : 2,000 m3/d effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : N/A Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : Solid wastes are ultimately disposed of via landfill or incineration. Aqueous waste is discharged to municipal waste water treatment. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : Assume standard municipal WWTP with disposal of sludge by agricultural spreading. Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC19

Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : 100 tonnes/year : Frequency and duration of use Duration Frequency of use Remarks 5-25 % : Liquid : 4451 Pa at 20C : :
: >4 hours : 1/day :
Human factors not influenced by risk management Exposed skin area : 1980 cm2 (PROC19) Other Factors: : 35 di 42


Remarks :
Technical conditions and measures Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.3 Contributing scenario controlling consumer exposure for: Exposure to consumers is not within the scope of REACH for personal care products. 3. Exposure estimation and reference to its source
Environment Contributing Scenario ERC8a ERC8a ERC8a ERC8a ERC8a ERC8a Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Specific conditions Compartment Value type Level of Exposure 3.91E-06 mg/l 3.74E-07 mg/l 3.19E-05 mg/kg ww 3.05E-06 mg/kg ww 2.55E-06 mg/kg ww 3.33E-05 mg/l Risk characterisation ratio 4.89E-04 4.68E-04 4.89E-03 4.68E-03 6.02E-04 <3.33E-06
Workers Contributing Scenario PROC19 Exposure Assessment Method ECETOC TRA predictions Specific conditions Value type Level of Exposure 0.5 mg/cm2 Risk characterisation ratio NA
Assuming 10% in formulated product.
Dermal local exposure 36 di 42


PROC19 PROC19 ECETOC TRA predictions ECETOC TRA predictions Assuming 10% in formulated product. Assuming 5-25% in formulated product. Dermal systemic exposure Inhalation local exposure 16.5 mg/kg bw/d 398 mg/m3/8h 0.13 0.45
This exposure scenario covers the end use of personal care products. The environmental exposure assessment covers use of such products by both professionals and consumers. The human health assessment considers professional uses only, since consumer use of personal care products is outside the scope of REACH. Professionals in salon are make use of and are exposed to large volumes of personal care products on a regular basis, compared to the individual consumer. For the product types used, the most relevant descriptor is PROC19: Hand-mixing with intimate contact.
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1. Short title of Exposure Scenario: Use of Hexamethyldisiloxane (CAS 107-46-0) for the manufacturing of semiconductors and electronics (human health only).
Main User Groups Sector of use Product category Process category Article category Environmental release category Further information : : : : SU3 SU16 PC33, PC35 PROC1, PRCO2, PROC7, PROC8b, PROC13
: : ERC8f :
2.1 ERC8f
: 25% : :
0.5 mPa.s at 25C
: N/A : : :
: :
Other given operational conditions affecting environmental exposure Exposure Type Number of emission days per year : N/A Emission or Release Factor: Air : N/A Emission or Release Factor: Water : N/A Emission or Release Factor: Soil : N/A Remarks : Parameter : Remarks : Technical conditions and measures / Organizational measures 38 di 42


Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Flow rate of sewage treatment plant : N/A effluent Effectiveness (of a measure) : Percentage removed from waste eater : Sludge Treatment : N/A Procedures to limit air emissions from : Sewage Treatment Plant Remarks : Conditions and measures related to external treatment of waste for disposal Waste treatment : N/A. Disposal methods : Remarks : Conditions and measures related to external recovery of waste Recovery Methods : N/A Remarks : Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.2 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC7, PROC8b, PROC13
Product characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Vapour pressure Process Temperature Remarks Amount used : N/A : Frequency and duration of use Duration Frequency of use Remarks 25 % : Liquid : 4451 Pa at 20C : :
: >4 hours : 1/day :
Human factors not influenced by risk management Exposed skin area : 240 cm2 (PROC1) 420 cm2 (OECD default) 480 cm2 (PROC2, PROC13) 39 di 42


Other Factors: Remarks : :
Technical conditions and measures Containment plus good work practice required Local exhaust ventilation required plus good work practice Organisational measures to prevent /limit releases, dispersion and exposure Safety glasses Conditions and measures related to personal protection, hygiene and health evaluation Additional good practice advice beyond the REACH Chemical Safety Assessment Additional good practice advice :
2.3 Contributing scenario controlling consumer exposure for: Exposure to consumers is not within the scope of REACH for personal care products.

Environment Given the very small scale use, it is not appropriate to assess environmental exposure for this scenario. There is no intentional release of HMDS to waste water and any fugitive releases to air will be of negligible volume. Contributing Scenario ERC8f ERC8f ERC8f ERC8f ERC8f ERC8f ERC8f Exposure Assessment Method Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using EUSES 2.1.1 Calculated using Specific conditions Compartment Value type Level of Exposure N/A N/A N/A N/A N/A N/A N/A Risk characterisation ratio
Freshwater Marine water Sediments (fresh water) Sediments (marine water) Agricultural soil Grassland Sewage 40 di 42
PEC PEC PEC PEC PEC PEC PEC


EUSES 2.1.1 Treatment Plant
41 di 42


Workers Contributing Scenario PROC13 PROC13 PROC13 Exposure Assessment Method ECETOC TRA predictions ECETOC TRA predictions ECETOC TRA predictions Specific conditions Value type Level of Exposure 0.1 mg/cm2 0.69 mg/kg bw/d 33 mg/m3/8h Risk characterisation ratio NA 5.48E-03 0.0371
With LEV With LEV With LEV
This scenario covers the use of HMDS in spin-on processes e.g. dielectrics, photoresists and anti-reflective coatings for semiconductor, photovoltaic or integrated circuit board manufacture, and use as a solvent/cleaning agent in these industries. Worker activities in the process involve the transfer of the photoresist to the application apparatus and the transfer of the wafer from one apparatus used in the process to another. After spinning, some resist chemical may remain on the spin-coat apparatus and must be cleaned. The workers may also transfer the photoresist-covered wafers to other processing steps throughout the manufacturing process (OECD, 2004).
This Safety data sheet annex was prepared on the basis of requirements under article 31 of the EU REACH Regulation, its relevant amendments and the current European Chemical Agency relevant guidance. All information and instructions provided in this annex are based on the state of scientific, technical knowledge and understanding of regulatory requirements available at the date indicated on the present annex. European Chemical Agency guidance relative to Safety data sheets annexes are currently still under development and the present document may be adapted based on any guidance modification. Dow Corning shall not be held responsible for any defect in the product covered by this e-SDS, should the existence of such defect not be detectable considering the current state of scientific and technical knowledge and regulatory requirements understanding. Should you require further information or clarification with regard to this e-SDS, please refer to your local Dow Corning supplier.
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1.2 Usi identificati

Usi sconsigliati 1.3 Societ

Indirizzo e-mail (Scheda di Sicurezza)

Servizio Assistenza Clienti :

1.4 Numero di telefono d'emergenza

Tel: +44 1446732350 Tel: +49 61122158 Tel: +32 64 888240

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Pericolo acuto per l'ambiente acquatico: Categoria 1 - H400

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Mezzi di estinzione inadatti 5.2 Pericoli durante l'estinzione degli incendi.

Prodotti di combustione pericolosi 5.3 Metodi antincendio speciali

6.3 Procedure e materiali per il contenimento e la

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7.2 Condizioni di stoccaggio

7.3 Usi specifici

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Controllo dell'esposizione ambientale

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: 10.6 Prodotti di decomposizione pericolosi

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

UN 1993 Flammable liquid, n.o.s.(Hexamethyldisiloxane) 3

Gruppo d'imballaggio Etichettatura

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

2.1 ERC1, ERC6a, ERC6c

0.5 mPa.s at 25C

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

PEC PEC PEC PEC PEC PEC

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

0.5 mPa.s at 25C

: Unknown, but low : : :

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA

XIAMETER(R) PMX-200 SIL FLUID .65CS

3. Exposure estimation and reference to its source

PEC PEC PEC PEC PEC PEC

0.69 mg/kg bw/d 3.3 mg/m3/8h 3.3 mg/m3/8h

XIAMETER(R) SCHEDA DI DATI DI SICUREZZA