Informe Analitica 226

Integrantes:

Katherine Madrid 4-780-879, Salvador Nicosia 7-711-526

Grafica Potenciometrica

Tabla de datos 1. Titulación de Na2CO3 con HCl 0.1N

V(mL) pH 21 6.87
0 11.28 21.5 6.82
0.5 11.18 22 6.76
1 11.08 22.5 6.72
1.5 11.01 23 6.68
2 10.93 23.5 6.61
2.5 10.85 24 6.57
3 10.77 24.5 6.53
4 10.66 25 6.47
5 10.54 25.5 6.44
6 10.44 26 6.39
7 10.33 26.5 6.36
8 10.23 27 6.33
9 10.13 27.5 6.28
10 10.03 28 6.25
11 9.95 28.5 6.2
12 9.79 29 6.14
13 9.69 29.5 6.08
14 9.5 30 6.04
15 9.29 30.5 5.97
15.5 9.18 31 5.91
16 8.99 31.5 5.83
16.5 8.77 32 5.75
17 8.34 32.58 5.67
17.5 7.9 33 5.57
18 7.57 33.5 5.44
18.5 7.41 34 5.28
19 7.23 34.5 5.05
19.5 7.09 35 4.57
20 7.03 35.5 3.62
20.5 6.94

Grafica 1. Volumen vs pH
 Volumen ml vs pH
12
10
8
6
pH

pH
4 3.62
2
0
0 5 10 15 20 25 30 35 40
Volumen ml

Tabla de datos 2. Delta volumen vs delta pH

delta V(mL) delta pH 3 7

1.00894454 0.92857142
0 4 9 1.02
1.00902527 0.93333333 1.02260495
0.5 1 3 2
0.66666666 1.00635785 0.96774193 1.01198257
7 6 5 1
1.00731930 1.02113459
0.75 5 0.96875 4
1.00737327 1.02508551
0.8 2 0.96969697 9
0.83333333 1.00742804 0.97058823 1.05155875
3 1 5 3
1.01031894 0.97142857 1.05569620
0.75 9 1 3
1.01138519 0.97222222 1.04359313
0.8 9 2 1
0.83333333 1.00957854 0.97297297 1.02159244
3 4 3 3
0.85714285 1.01064859 0.97368421 1.02489626
7 6 1 6
1.00977517 0.97435897 1.01974612
0.875 1 4 1
0.88888888 1.00987166 1.00853485
9 8 0.975 1
0.9 1.00997009 0.97560975
0.90909090 1.00804020 6 1.0129683
9 1 0.97619047 1.01018922
0.91666666 1.01634320 6 9
7 7 0.97674418 1.00733137
0.92307692 1.01031991 6 8
0.97727272 0.98507462 1.02389705
7 1.00887574 7 9
0.97777777 1.00595238 0.98529411
8 1 8 1.03030303
1.00598802 0.98550724 1.04554455
0.97826087 4 6 4
0.97872340 1.01059001 0.98571428 1.10503282
4 5 6 3
0.97916666 0.98591549 1.26243093
7 1.00608828 3 9
0.97959183 1.00612557
7 4
0.98 1.00927357
0.98039215 1.00465838
7 5
0.98076923 1.00782472
1 6
0.98113207 1.00471698
5 1
0.98148148 1.00473933
1 6
0.98181818 1.00796178
2 3
0.98214285
7 1.0048
1.00806451
0.98245614 6
0.98275862 1.00977198
1 7
0.98305084 1.00986842
7 1
0.98333333 1.00662251
3 7
0.98360655 1.01172529
7 3
0.98387096 1.01015228
8 4
0.98412698 1.01372212
4 7
1.01391304
0.984375 3
0.98219766 1.01410934
7 7
0.98727272 1.01795332
7 1
Grafica 2. Cambio de volumen vs cambio de pH

delta pH
1.3
1.25
1.2
1.15
1.1
1.05
1
0.95
0.9
0.9 0.91 0.92 0.93 0.94 0.95 0.96 0.97 0.98 0.99 1

Tabla de datos 3. Titulación de NaOH con HCl 0.1N

V (mL) pH 14 11.85
0 12.3 15 11.76
0.5 12.37 16 11.65
1 12.39 17 11.57
1.5 12.38 18 11.55
2 12.37 18.5 11.38
2.5 12.37 19 11.26
3 12.36 19.5 11.08
3.5 12.35 20 10.87
4 12.34 21 10.87
4.5 12.33 21.5 10.6
5 12.31 22 10.38
5.5 12.3 22.5 10.02
6 12.29 23 9.55
6.5 12.27 23.5 8.43
7 12.26 24 6.86
7.5 12.24 24.5 6.28
8 12.17 25 5.84
9 12.14 25.5 5.23
10 12.1 26 3.51
11 12.04 26.5 2.74
12 11.99 27 2.54
13 11.92

Grafica 3. Volumen vs pH
 volumen vs pH
14

12

10

8
pH
PH

0
0 5 10 15 20 25 30
Volumen mL

Tabla de datos 4. Cambio de volumen vs cambio de pH

V(mL) pH 0.93333333 1.00163398

0.99434114 3 7
0 8 1.00575184
0.99838579 0.9375 9
0.5 5 0.88888888
0.66666666 1.00080775 9 1.00247117
7 4 1.00330578
1.00080840 0.9 5
0.75 7 0.90909090 1.00498338
0.8 1 9 9
0.83333333 1.00080906 0.91666666 1.00417014
3 1 7 2
0.85714285 1.00080971 0.92307692 1.00587248
7 7 3 3
1.00081037 0.92857142 1.00590717
0.875 3 9 3
0.88888888 0.93333333 1.00765306
9 1.00081103 3 1
1.00162469 0.9375 1.00944206
0.9 5 0.94117647 1.00691443
0.90909090 1.00081300 1 4
9 8 0.94444444 1.00173160
0.91666666 4 2
7 1.00081367 0.97297297 1.01493848
0.92307692 1.00162999 3 9
3 2 0.97368421 1.01065719
0.92857142 1.00081566 1 4
9 1 0.97435897 1.01624548
 4 7 0.97916666 1.22886297
1.01931922 7 4
0.975 7 0.97959183 1.09235668
0.95238095 7 8
2 1 1.07534246
0.97674418 1.02547169 0.98 6
6 8 0.98039215 1.11663479
0.97727272 1.02119460 7 9
7 5 0.98076923
0.97777777 1.03592814 1 1.49002849
8 4 0.98113207 1.28102189
0.97826087 1.04921466 5 8
0.97872340 1.13285883 0.98148148 1.07874015
4 7 1 7

Grafica 4. Cambio de volumen vs cambio de pH

delta volumen vs delta pH

1.55
1.45
1.35
1.25
delta pH

1.15 pH
1.05
0.95
0.85
0.75
0.96 0.97 0.97 0.98 0.98 0.99 0.99 1 1
delta volumen