1.

T= -87°f
V= 3 ft3
M= 7,5 lb

A- Por Ecuación de Gases ideales

𝑷𝑽 = 𝒏𝑹𝑻

*Pasar de °f a °k
5
°𝑐 = (°𝑓 − 32)
9
5
°𝑐 = (−87 − 32)
9
°𝑐 = −66.11

°𝐾 = °𝑐 + 273.15
°𝑘 = −66.11 + 273.15
°𝑘 = 𝟐𝟎𝟕. 𝟎𝟒

*Se pasa de ft3 a m3

0,0283168𝑚3
3𝑓𝑡 3 ∗ = 0,085𝑚3
1𝑡𝑓 3
1000𝐿
0,085𝑚3 ∗ = 85𝐿
1𝑚3
Pasar lb a mol
500𝑔 1𝑚𝑜𝑙
7,5𝑙𝑏 ∗ ∗ = 133.9𝑚𝑜𝑙 𝑑𝑒 𝐶𝑂
1𝑙𝑏 28,01𝑔

*Despejamos P de la ecuación
𝑛𝑅𝑇
𝑃=
𝑣
𝑎𝑡𝑚 ∗ 𝐿
(133,9𝑚𝑜𝑙)(0,082 )(207,04°𝑘)
𝑃= 𝑚𝑜𝑙 ∗ °𝑘
(85𝐿)
1,01325𝑏𝑎𝑟
𝑃 = 26,74𝑎𝑡𝑚 ∗
1𝑎𝑡𝑚
𝑃 = 𝟐𝟕, 𝟎𝟗 𝒃𝒂𝒓

B- Por ecuación de Van der Waals

𝒂
(𝑷 + 𝟐 ) (𝒗 − 𝒃) = 𝑹𝑻
𝒗

Hallamos datos
*𝑇𝑐 = −140,23°𝑐 = 132,92°𝑘
*𝑃𝑐 = 34,53𝑎𝑡𝑚

𝟐𝟕𝑹𝟐 𝑻𝒄𝟐
𝒂=
𝟔𝟒𝑷𝒄
 𝑎𝑡𝑚 ∗ 𝐿 2
27(0.082 ) (132,92°𝑘)2
𝑎= 𝑚𝑜𝑙 ∗ 𝑘
64(34,53𝑎𝑡𝑚)2
𝐿 ∗ 𝑎𝑡𝑚
3207,5
𝑎= 𝑚𝑜𝑙 2
2209,9
𝐿2 𝑎𝑡𝑚
𝑎 = 1,45
𝑚𝑜𝑙 2

𝑹𝑻𝒄
𝒃=
𝟖𝑷𝒄
𝑎𝑡𝑚 ∗ 𝐿
(0,082 )(132,92°𝑘)
𝑏= 𝑚𝑜𝑙 ∗ 𝑘
5(34,53𝑎𝑡𝑚)
𝐿
108,99
𝑏= 𝑚𝑜𝑙
276,24
𝐿
𝑏 = 0,39
𝑚𝑜𝑙
𝟖𝟓𝑳
𝒗= = 𝟑, 𝟎𝟑𝑳/𝒎𝒐𝒍
𝟐𝟖, 𝟎𝟏𝒎𝒐𝒍

*Despejamos P de la ecuación de Van de Waals

𝑹𝑻 𝒂
𝑷= − 𝟐
(𝒗 − 𝒃) 𝒗
𝑎𝑡𝑚 ∗ 𝐿 𝐿2
(0,082 )(207,04°𝑘) (1,45𝑎𝑡𝑚 )
𝑃= 𝑚𝑜𝑙 ∗ °𝑘 − 𝑚𝑜𝑙 2
𝐿 (85𝐿)2
(85𝐿) − (0,39 )
𝑚𝑜𝑙
𝑎𝑡𝑚 ∗ 𝐿 𝐿2
(0,082 )(207,04°𝑘) (1,45𝑎𝑡𝑚 )
𝑃= 𝑚𝑜𝑙 ∗ °𝑘 − 𝑚𝑜𝑙 2
𝐿 𝐿 𝐿 2
(3,03 ) − (0,39 ) (3,03 )
𝑚𝑜𝑙 𝑚𝑜𝑙 𝑚𝑜𝑙
2
𝑎𝑡𝑚 ∗ 𝐿 𝐿
16,98 𝑎𝑡𝑚 ∗ 1,45𝑎𝑡𝑚 2
𝑃= 𝑚𝑜𝑙 − 𝑚𝑜𝑙
𝐿 𝐿2
2,64 9,18
𝑚𝑜𝑙 𝑚𝑜𝑙 2
𝑃 = 6,43𝑎𝑡𝑚 − 0,16𝑎𝑡𝑚
1,01325𝑏𝑎𝑟
𝑃 = 6,27𝑎𝑡𝑚 ∗
1𝑎𝑡𝑚
𝑷 = 𝟔, 𝟑𝟓𝒃𝒂𝒓

2. CH4 diario
P= 130KPa
M= 280 Kg
T°= 34°c
V= ?m3

*Cambiamos medidas
0,00987𝑎𝑡𝑚
𝑃 = 130𝐾𝑃𝑎 ∗ = 𝟏, 𝟐𝟖𝒂𝒕𝒎
1𝐾𝑃𝑎
 1000𝑔 1𝑚𝑜𝑙
𝑚 = 280𝑘𝑔 ∗ ∗ = 𝟏𝟕𝟒𝟓𝟔, 𝟑𝟔𝒎𝒐𝒍
1𝑘𝑔 16,04𝑔
°𝑘 = 34°𝑐 + 273,15=307,15°k

Ecuación de gases ideales

𝑷𝒗 = 𝒏𝑹𝑻

*Despejamos v
𝑛𝑅𝑇
𝑣=
𝑝
𝑎𝑡𝑚 ∗ 𝐿
(17456,36𝑚𝑜𝑙)(0,082 )(307,15°𝑘)
𝑣= 𝑚𝑜𝑙 ∗ °𝑘
1,28𝑎𝑡𝑚
439652,05𝐿
𝑣=
1,25
0,001𝑚3
𝑣 = 343478,17𝐿 ∗
1𝐿
𝑣 = 343,5𝑚3 𝑒𝑠𝑡𝑒 𝑠𝑒𝑟𝑖𝑎 𝑒𝑙 𝑣𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒𝑙 𝑔𝑎𝑠 𝑒𝑛 1 𝑑𝑖𝑎
𝑣𝑡𝑎𝑛𝑞𝑢𝑒 = (343,5𝑚3 ) ∗ 16 = 𝟓𝟒𝟗𝟔𝒎𝟑

Graficar LnK en 1T

T°(°C) K(1/M.s) T°(°K) 1/T Lnk

600 1.87x10-3 873 0.001145 -6.28
650 0.011 923 0.001083 -4.5
700 0.057 973 0.001027 -2.86
750 0.244 1023 0.000977 -1.41
 0
Lnk
-1 0.001145 0.001083 0.001027 0.00977

-2
-3
-4
-5
-6
-7

Lnk

Ecuación general: 𝑦 = 𝑚𝑥 + 𝑏

𝑦 = −29014𝑥 + 26,935
****
𝐸𝑢 1
𝐿𝑛𝑘 = ( ) + 𝐿𝑛(𝐴)
𝑅 𝑇
1
𝑦 = 𝐿𝑛𝐾, 𝑥 =
𝑇
𝐿𝑛(𝐴) = 26,935
𝐸𝑢
− = 29017
𝑅

El valor de R según la constante es de 8,3143 j*K-1mol-1

𝐸𝑢
= (−29014) ∗ (−8,3142) = 241231,1002𝑗/𝑚𝑜𝑙
𝑅