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Properties
Introduction/Introduzione
. Navi trasportatori di gas
Gas Carriers carry gas in liquefatto trasporto in liquidi
a liquefied form. This is
the liquid state of forma Questo è stato liquido di
substances that under sostanze che, ai sensi 'normale'
'normal' conditions would condizioni sarebbe gassosi. La
be gaseous. Most
liquefied gases are maggior parte dei gas liquefatti
hydrocarbons, which is sono idrocarburi, che è il nome
the collective name for a collettivo di un gruppo di
group of organic
substances that are sostanze organiche che sono
made up of molecules of costituiti da molecole di
hydrogen and carbon.
idrogeno e carbonio
Understanding the nature
and behaviour of
hydrocarbons, both in
liquid and gaseous form, Comprensione della natura e
is critical to their safe del comportamento degli
carriage. This idrocarburi, sia in liquidi e
presentation will describe gassosi forma, è fondamentale
the important per il loro trasporto sicuro.
characteristics and their Questo presentazione descrive
implications. le caratteristiche e le loro
implicazioni
The International Maritime L'Organizzazione
Organization (IMO), for the marittima internazionale
purposes of its Gas Carrier (IMO), in sua Gasiera
Codes, defines liquefied Codici, IGC definisce gas
gases carried at sea as: liquefatto trasportato in
'Liquids with a vapour mare come:
pressure exceeding 2.8 'Liquidi con una
bar absolute at a pressione di vapore
temperature of 37.8°C” superiore a 2,8 bar
assoluto ad una
temperatura di 37,8 ° C
Liquefied gases are Gas liquefatti sono divisi
divided into three in tre categorie:
categories: GPL - o gas di
LPG - or Liquefied petrolio liquefatto
Petroleum Gases GNL - o di gas
LNG - or Liquefied naturale liquefatto
Natural Gases LCG- o gas chimica
LCG Chemical Gases liquefatto
Liquefied Petroleum Gases (LPG)/
Gas di petrolio liquefatto (GPL)
LPG covers GPL copre
propane, propano,
butane or butano o
butane/ propane butano / propano
mixtures miscele
The two main sources Le due principali fonti
of LPG are: di GPL sono:
IN GAS STATE
Alkanes
Methane is the first member of the series of
hydrocarbon compounds where all valencies
(arms) are used to the greatest combining power.
Each of these compounds is said to be saturated
and they are known as Alkanes.
They are sometimes given the alternative name of
"Paraffins".
Alkanes generally show a lower reactivity because
their C-H and C-C bonds are relatively stable and
cannot be easily broken. Alkanes are both
important raw materials of the chemical industry
and also the most important fuels of the world
economy.
The general molecular formula of an Alkane is:
CnH(2n+2)
(where 'n; is the number of atoms).
State of alkanes
Methane CH4 Gas
Ethane C2H6 Gas
Propane C3H8 Gas
Butane C4H10 Gas
Pentanes C5H12 Liquid
Hexanes C6H14 Liquid
The atoms in alkanes with four or more
carbon atoms can be arranged in multiple
ways to form different isomers, which are
molecules that contain the same number
and kind of atoms but have a different
structure. "Normal" alkanes have a linear,
Butane isomers
Methane and ethane are the main
components of natural gas; they are normally
stored as gases under pressure. However, it
is easier to transport them as liquids,
although this requires both compression and
cooling of the gas. Propane and butane can
be liquefied at fairly low pressures, and are
well known as liquefied petroleum gas (LPG).
All of the gases are flammable and will burn
in air and/or oxygen to produce heat, carbon
dioxide and water vapors Because they are
relatively non-reactive they do not present
chemical compatibility problems with the
materials commonly used in handling
although, in the presence of moisture, the
saturated hydrocarbons may form hydrates.
Because saturated hydrocarbons are
colourless and odourless in their natural
state, a harmless, non-toxic chemical called
a mercaptan is added to make it easier to
detect. Mercaptans contain sulphur and in a
concentrated form the smell is almost
unbearable. It takes only a few parts per
million to give natural gas a smell and the
process is referred to as "stenching".
Alkenes and Alkynes
Structure wich double bonds occur between
2 carbon atoms, such as in the ethene
(ethytene) example, and where triple bonds
occur, such as in ethyne (acetylene), the
carbon is called "unsaturated". These
structures belong to hydrocarbon alkene
and alkyne groups.
Alkenes
The relationship
between volume and
pressure at constant
temperature.
pV = constant
In other words, as the
pressure increases,
the volume decreases
Charles' Law
Says that for a fixed
amount of gas (fixed
number of moles) at a
fixed pressure, the
volume is proportional to
the temperature.
V/T = constant
In other words, as the
temperature increases,
the volume increases.
(When you heat a balloon
the volume of the balloon
goes up.)
Gay-Lussac's Law
Gay-Lussac's Law
says that for a fixed
amount of gas (fixed
number of moles) at a
fixed volume, the
pressure is
proportional to the
temperature.
p/T = constant
Some definitions of terms
Absolute temperature
is the fundamental temperature scale used in
theoretical physics and chemistry and in certain
engineering calculations. Absolute temperatures
are expressed either in degrees Kelvin or degrees
Rankine corresponding respectively to the Celsius
and Fahrenheit temperature scales. To convert a
Celsius temperature, if above 0°C, to Kelvin add
273; if below 0°C subtract the Celsius temperature
from 273. Similarly to convert a Fahrenheit
temperature to Rankine add or subtract 460 as
appropriate.
Absolute zero
is the temperature at which the volume of a gas
theoretically becomes zero and all thermal motion
ceases. Generally accepted as being -273.16°C or
-459.69°F.
Boiling point
is the temperature of a liquid at which its vapour
pressure is equal to or very slightly greater than
the atmospheric pressure of the environment. For
water at sea level it is 100°C.
Bubble point
of a liquid mixture at a given pressure is defined
as that temperature at which the liquid will begin to
boil on rising temperature
Dew point
of a vapour mixture at a given pressure is defined
as the temperature at which the vapour begins to
condense as the temperature decreases. For a
liquid mixture in equilibrium with its vapour, the
bubble point and the dew point are at different
temperatures.
Boil Off
is the vapour produced above a cargo liquid
surface due to evaporation caused by the
heat flow through the cargo tank insulation.
Reliquefaction
Converting cargo boil-off vapour back into a
liquid by increasing the pressure or reducing
the temperature and/or both (e.g. steam
condensing).
Viscosity
The viscosity of an oil is its resistance to
flow. High viscosity oils flow with difficulty
whilst those with low viscosity are highly
mobile. Viscosities decrease with increasing
temperature and so seawater temperature
and absorption of heat from the sun are
important considerations