KIMIA ORGANIK KELOMPOK aniline yellow

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Aniline Yellow

Aniline Yellowis a yellowazo dyeand anaromatic amine. It is a derivate ofazobenzene. It has the appearance of an orange powder. It is a carcinogen. Aniline Yellow was the firstazo dye. It was first produced in 1861 by C. Mene. The second azo dye wasBismarck Brownin 1863. Aniline Yellow was commercialized in 1864 as the first commercial azo dye, a year afterAniline Black. It is manufactured fromaniline.

Aniline Yellow

Molecular formula C6H5N=NC6H4NH2

Anilin yellow / 25 grams

Aniline yellowIUPAC name 4-Phenyldiazenylaniline

Other names
para-aminoazobenzene, 4phenylazoaniline, AAB, Brasilazina oil Yellow G, Ceres Yellow, Fast spirit Yellow, Induline R, Oil Yellow AAB, Oil Yellow AN, Oil Yellow B, Oil Yellow 2G, Oil Yellow R, Organol Yellow, Organol Yellow 2A, Solvent Yellow, Somalia Yellow 2G, Stearix Brown 4R, Sudan Yellow R, Sudan

Uses
Aniline

Yellow is used inmicroscopyforvital staining, inpyrotechnicsfor yellowcolored smokes, in yellowpigmentsandinksincluding inks forinkjet printers. It is also used in insecticides, lacquers, varnishes, waxes, oil stains, andstyreneresins. It is also an intermediate in synthesis

Toxic Oil Syndrome

Aniline Yellow was involved in the 1981 SpanishToxic Oil Syndrome(TOS). A Madrid-based company importeddenaturatedrapeseed oil, dyed by aniline yellow to mark it as unsuitable for human consumption, to be used as a fuel insteel mills. However, the company distilled the oil to remove the dye, and sold it as a much more valuableolive oilfor cooking. The result was a rash

AZO COUPLING

Anazo couplingis anorganic reactionbetween adiazonium compoundand another aromatic compound that produces anazo compound. In thiselectrophilic aromatic substitutionreaction, the aryldiazonium cation is theelectrophileand theactivatedareneis anucleophile.In most cases, including the examples below, the diazonium compound is also aromatic.

Uses of the Reaction

The product will absorb longer wavelengths of light (specifically they absorb in the visible region) than the reactants because of increasedconjugation. Consequently, aromatic azo compounds tend to be brightly colored due to the extended conjugated systems. Many are used as dyes (seeazo dye).Important azo dyes includemethyl redandpigment red 170. Azo coupling is also used to produceprontosiland othersulfa drugs.

Examples of Coupling Reactions

Many procedures have been described. The related dye called aniline yellow is produced from the reaction of aniline and the diazonium salt.

Aniline Yellow (amino Azobenzene) as a Dye

This is another azodye and has little value as a dye. This is because it is sensitive to acids. This is the simplest basic azo dye. This can be obtained by coupling benzene diazomium chloride with aniline.

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