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Uniform Pitting Crevice Corrosion or Concentration Cell Galvanic or Two-Metal Stress Corrosion Cracking Intergranular Dealloying Erosion Corrosion
http://www.intercorr.com/failures.html
Galvanic Corrosion:
Possibility when two dissimilar metals are electrically connected in an electrolyte* Results from a difference in oxidation potentials of metallic ions between two or more metals. The greater the difference in oxidation potential, the greater the galvanic corrosion. Refer to Galvanic Series (Figure 13-1) The less noble metal will corrode (i.e. will act as the anode) and the more noble metal will not corrode (acts as cathode). Perhaps the best known of all corrosion types is galvanic corrosion, which occurs at the contact point of two metals or alloys with different electrode potentials.
Galvanic Series: Questions: 1. Worst combination? 2. Aluminum and steel? 3. Titanium and Zinc? 4. Stainless Steel and Copper? 5. Mild steel and cast iron?
Show Demo!
GALVANIC SERIES
Galvanic Series in Seawater (supplements Faraq Table 3.1 , page 65), EIT Review Manual, page 38-2
Figure 1 illustrates the idea of an electro-chemical reaction. If a metal is placed in a conducting solution like salt water, it dissociates into ions, releasing electrons, as the iron is shown doing in the figure, via the ionization reaction Fe m Fe++ + 2eThe electrons accumulate on the iron giving it a negative charge that grows until the electrostatic attraction starts to pull the Fe++ ions back onto the metal surface, stifling further dissociation. At this point the iron has a potential (relative to a standard, the hydrogen standard) of 0.44 volts. Each metal has its own characteristic corrosion potential (called the standard reduction potential), as plotted in Figure 2. If two metals are connected together in a cell, like the iron and copper samples in Figure 1, a potential difference equal to their separation on Figure 2 appears between them. The corrosion potential of iron, -0.44, differs from that of copper, +0.34 , by 0.78 volts, so if no current flows in the connection the voltmeter will register this
Figure 1. A bi-metal corrosion cell. The corrosion potential is the potential to which the metal falls relative to a hydrogen standard.
dry cell is a galvanic electrochemical cell with a pasty lowmoisture electrolyte. A wet cell, on the other hand, is a cell with a liquid electrolyte, such as the lead-acid batteries in most cars
Dry Cell - Zinc-carbon battery Zn(s) Zn2+(aq) + 2 e- - oxidation reaction that happens at zinc = anode Mn2O3(s) + H2O(l) - reduction reaction at carbon rod = cathode
2MnO2(s) + 2 H+(aq) + 2 e-
What does the voltmeter read? What is the most powerful battery combo??
Amount of separation in the galvanic series Relative surface areas of the two. Severe corrosion if anode area (area eaten away) is smaller than the cathode area. Example: dry cell battery
Factors:
Must consider metal and environment. What to watch for: Stainless steels at elevated temperature in chloride solutions. Steels in caustic solutions Aluminum in chloride solutions 3 Requirements for SCC: 1. Susceptible alloy 2. Corrosive environment 3. High tensile stress or residual stress
Intergranular Attack:
Corrosion which occurs preferentially at grain boundries. Why at grain boundries?
Higher energy areas which may be more anodic than the grains. The alloy chemistry might make the grain boundries dissimilar to the grains. The grain can act as the cathode and material surrounding it the anode.
Intergranular Attack:
How to recognize it?
Near surface Corrosion only at grain boundries (note if only a few gb are attacked probably pitting) Corrosion normally at uniform depth for all grains.
Intergranular Attack:
Dealloying:
When one element in an alloy is anodic to the other element. Example: Removal of zinc from brass (called dezincification) leaves spongy, weak brass. Brass alloy of zinc and copper and zinc is anodic to copper (see galvanic series).
Dealloying:
Danger!
The alloy may not appear damaged May be no dimensional variations Material generally becomes weak hidden to inspection!
Dealloying:
Two common types:
Dezincification preferential removal of zinc in brass
Try to limit Zinc to 15% or less and add 1% tin.
Cathodic protection
Erosion:
Basically a repeat of Chapter 3 (seeErosion Wear) Forms of Erosion:
Liquid Impingement Liquid erosion Slurry Erosion Cavitation
Intergranular watch grain size, environment, temperature, etc.. Careful with Stainless Steels and AL.
Corrosion Control:
Bluing
Bluing is a passivation process in which steel is partially protected against rust, and is named after the blueblack appearance of the resulting protective finish. True gun bluing is an electrochemical conversion coating resulting from an oxidizing chemical reaction with iron on the surface selectively forming magnetite (Fe3O4), the black oxide of iron, which occupies the same volume as normal iron. Done for bolts called blackening
Material Selection:
Importance of Oxide films The fundamental resistance of stainless steel to corrosion occurs because of its ability to form an oxide protective coating on its surface. This thin coating is invisible, but generally protects the steel in oxidizing environments (air and nitric acid). However, this film loses its protectiveness in environments such as hydrochloric acid and chlorides. In stainless steels, lack of oxygen also ruins the corrosion protective oxide film, therefore these debris ridden or stagnant regions are susceptible to corrosion.
Recall CES Rankings: strong acid, weak acid, water, weak alkali, strong alkali
-2
Often several approaches to control corrosion Often several system constraints pertain
Types of CP:
Galvanic or sacrificial anodes zinc, magnesium or aluminum. The sacrificial anodes are more active (more negative potential) than the metal of the structure theyre designed to protect. The anode pushes the potential of the steel structure more negative and therefore the driving force for corrosion halts. The anode continues to corrode until it requires replacement, Impressed current CP done for large structures (pipes, offshore platforms, etc) where a galvanic (or sacrificial) anode can not economically deliver enough current. Galvanized steel (see above slide) again, steel is coated with zinc and if the zinc coating is scratched and steel exposed, the surrounding areas of zinc coating form a galvanic cell with the exposed steel and protects in from corroding. The zinc coating acts as a sacrificial anode.
Aluminium anodes mounted on a steel jacket structure using galvanic corrosion for corrosion control! Called cathodic protection (aka sacrificial anode)
http://www.westcoastcorrosion.com/Papers /Why%20Metals%20Corrode.pdf