TPC Vina

Plastic & Chemical Corp., Ltd.

VINA
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Introduction
Basic of PVC Resin Process
DEVELOPMENT OF PVC PLASTIC FROM
PETROCHEMICAL IN VIETNAM
Crude Oil
Naptha
Ethylene
Propylene
Butadiene
Benzene
Toluene
Xylene
Natural
gas
Propylene
OXO-Gas
CO + H
2
O- Xylene
2EH
PA
DOP
Ethylene
Salt Chlorine
VCM PVC
PVC
Compound
Step 2 Step 1
Scope of Petrochemical
Scope of Plastic processing
Scope of Oil Refinery
PVC
Processing
Household goods
Machine parts
Construction materials
Medical appliances
2-Ethylhexanol
PVC Resin
PhtalicAnhydride
Electrolysis
Vinyl Chloride
Monomer
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What is PVC ?
PVC is one kind of thermoplastic resin
produced by polymerization of Vinyl
Chloride monomer (VCM).
Formular: (-CH
2
-CHCl-)
n
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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PVC POLYMERIZATION
MECHANISM
1. INITIATION : Under positive temp., Initiators will be
discomposed into some forms of free radical.
RO- C-O- O- C- OR 2 RO-C-O
.
2RO
.
+ 2CO2
O O O
RO
.
+ CH2 = CHCl RO- CHCl CH2
.
Free radical
Active radical
VINA
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TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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2. CHAIN DEVELOPMENT:
RO- CHCl CH
2
.
+ CH
2
= CHCl
-Q
RO- CHCl CH
2
- CHCl CH
2
RO- CHCl CH2 - CHCl CH2
.
+ CH2 = CHCl +
........
(- CHCl CH2 -)
n-1
- CHCl CH2
3. CHAIN END:
j 2-(- CHCl CH
2
-)
n-1
- CHCl CH
2
.
(- CHCl CH
2
-)
2n
j 2-(- CHCl CH2 -)n-1- CHCl CH2
.
(- CHCl CH2 -)n +
(- CHCl CH2 -)n-1- CHCl =
CH2
j Others
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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PVC APPLICATION
PVC resin is used extensively in water
supply and drainage pipe, electric wire
and cable, building materials, wrapping
and packaging film for fresh product and
other fields, supporting our daily life on
a basic level
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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APPLICATION OF TPC Vina PRODUCT
GRADE K VALUE APPLICATION
SG580
56 - 59
65 - 67 SG660
SG710 70 - 72
RIGID PROFILES, SEMI-RIGID & RIGID
FILM & SHEET, BOTTLE, FITTING,...
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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RIGID PIPE, FLEXIBLE HOSES, FILM &
SHEET, WIRES & CABLES, PROFILES,...
WIRES & CABLES, ARTIFICIAL LEATHER,..
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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SUPERIOR FEATURES OF PVC
Rigid PVC Flexible PVC
Resistant to corrosion, chemicals, oil, and
weathering
Easy to process
Lightweight (1/5 of iron or 1/10 of lead)
Flame-resistant and self-extinguishing
Excellent electric insulation
Easy coloring and printing with vivid tones for
many colors
Choice of transparent, semi-transparent, or
opaque products according to application
Excellent transparent
and lustrous properties
Superior elasticity and
tear resistance
Soft and flexible
Barrier to oxygen
Resistant to weathering
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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GENERAL FULL FLOW CHART OF
VCM & PVC PRODUCTION
(CH
2
-CHCl)
n
Natural gas
Crude oil Naphtha
Ethylene
Dichloride
Ethylene
Vinyl chloride
monomer
PVC resin
Salt
(NaCl)
Chlorine
(Cl
2
)
CH
2
=CH
2
CH
2
Cl-CH
2
Cl CH
2
=CHCl
Electrolysis
NAPHTHA SEPARATION
Crude oil
Synthetic rubber
Detergent materials
Plastics
Synthetic textile
materials
Solvents
Others
Crude oil is refined for separating Naphtha (naphtha
is the oil with the mixing of Hydrocarbon C
10
), up to the boiling temperature,
and many products of petrochemicals.
OIL REFINERY
Gas
Gasoline
Naphtha
Jet fuel
Kerosene
Diesel oil
Heavy oil
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- Ethylene (C2H4) : 28-38 %
- Propylene (C3H6) : 13-18 %
- Butadiene (C4H6) : 4-5 %
- Butane/ Butylene : 4-5 %
- Aromatic : 7-4 %
NAPHTHA
CRACKING
(750-870
0
C and pressure)
DISTILLATION
COLUMN
ETHYLENE
ETHYLENE PRODUCTION
Naphtha is led into the cracker to yield the mixing
products of Hydrocarbon with high percentage of
Ethylene (C
2
H
4
). Then, this mixture is distilled for
separating Ethylene (C
2
H
4
).
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CHLORINE PRODUCTION
PURIFICATION ELECTROLYSIS
FREEZER DRYER
Salt
solution
Hydro (H
2
)
CHLORINE
(Cl
2
)
NaOH
The pure Salt solution is led into the electrolysis for
producing Chlorine, Chlorine is frozen and dried for VCM
production
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CHLORINE PRODUCTION
Strong Strong
Caustic Caustic
Soda Soda
H
2
O
Na+
Cl
2
Cl-
Cl-
H
2
OH-
H
2
O
Na+
Chlorine Chlorine
Gas Gas
Hydrogen Hydrogen
Gas Gas
Depleted Depleted
Brine Brine
Anolyte
Metal Anode
Saturated Brine Saturated Brine
Water Water
Catholyte
Metal Cathode
Cation Exchange
Membrene
(Chlo (Chlo- -Alkaline Plant) Alkaline Plant)
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VINYL
CHLORIDE
COMBINED
CHLORINATION AND
OXYCHLORINATION
PURIFICATION
VINYL CHLORIDE
PURIFICATION
DICHLOROETHANE
PYROLYSIS
Ethylene
Chlorine
Oxygen
Recycle
HCl
Water
HCl stream
VCM PRODUCTION
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VCM PRODUCTION
EDC Purification
(Distillation and Extraction units)
EDC EDC
EDC EDC
VCM Purification
(Distillation and Extraction units)
VCM VCM
Purified VCM to PVC Plants Purified VCM to PVC Plants
Oxy Chlorination (Fluidized Bed Reactor)
C
2
H
4
+2HCl+1/2 O
2
C
2
H
4
Cl
2
+H
2
O
Direct Chlorination (Fixed Bed Reactor)
C
2
H
4
+Cl
2
C
2
H
4
Cl
2
Ethylene
Chlorine
Oxygen
Ethylene dichloride (EDC) Section
EDC Cracking
C
2
H
4
Cl
2
C
2
H
3
Cl+HCl
Recycle
HCl
Import EDC
Purified EDC Purified EDC
Process Description Process Description
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MONOMER RECOVERY AND
WASTE WATER TREATMENT
VCM MONOMER
SUSPENDING
AGENTS
DE-MIN WATER
POLYMERIZATION
VCM RECOVERY
DE-WATERING
DRYING
PACKING
MONOMER
RECOVERY
WASTE WATER
TREATMENT
RAW MATERIALS HANDLING MAIN PROCESS
MONOMER
PURIFICATION
SCREEN
INITIATOR
ADDITIVES
PVC SUSPENSION PROCESS FLOW CHART
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TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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Materials used in TPC Vina process
Phenolic resin RCS 1
T-C
9
H
19
-C(O)OO-C(CH
3
)
2
-C
6
H
5
Cumyl
peroxyneodecanoate
C-29 10
[C
4
H
9
-CH(C
2
H
5
)-CH
2
-OC(O)O]
2
Di-2-ethylhexyl
peroxyneodecanoate
C-19 9
C(CH
3
)
3
(OH)C
6
H
2
(CH
2
)
2
COOC
18
H
37
Octadecyl 3 propionate AD-5 8
HOC
6
H
4
-C
3
H
6
-C
6
H
4
OH 2,2-Diphenyl propane AD-3 7
C
6
H
7
O
2
(OH)
x
(OCH
3
)
y
(OC
3
H
7
)
z
(x + y + z = 3)
Metylhydroxyl propyl
cenlulose
AG-5 6
Polyvinyl alcohol AG-2 5
[CH
2
CH-OC(O)CH
3
]
x
[CH
2
CH-
OH]
y
Polyvinyl alcohol AG-1 4
CH2=CH-CL Vinyl chloride VCM 3
H
2
O Demin. water PW 2
Formula Chemical name Material No
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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Materials used in TPC Vina process
HCL Hydrochloric Acid HA 21
C
9
H
19
-C(O)OO-C(CH
3
)
3
Ter-butyl
peroxyneodecanoate
C-26 11
KOH Potassium hydroxide CH-25 20
NaOH Pellet Sodium hydroxide CH-6 19
NaOH Flake Sodium hydroxide CH-6 18
C
6
H
5
C(CH
3
)=CH
2
- Methyl styrene INH-3 17
(CH
3
)
3
CC
6
H
3
(OH)
2
P-Tert-butyl catechol
INH-1 16
CH
3
-OH Methanol CH-12 15
HO-CH
2
-CH
2
-OH Ethylene glycol CH-9 14
HO-CH
2
-CH
2
-SH 2-Mercapto Ethanol CH-20 13
[T-C
4
H
9
-CH
2
CH(CH
3
)CH
2
-
C(O)O]
2
Di-3.5.5-
trimethylhexanoylperoxide
C-30 12
Formula Chemical name Material No
O H
C(CH
3
)
3
C(CH
3
)
3
(CH
2
)-COOC
18
H
37
AD5-Octadexyl 3-(3,5 di-ter
butyl-4-hydroxyphenyl)
O H
CH
3
CH
3
C OH AD3-2,2-Di phenyl propane
CH
3
CH
3
C
H
3
C
OH
OH
P-tert -butyl catechol
C=CH
2
CH
3
Alpha metyl styren-INH3
(C
4
H
9-
CH-CH
2
-O-C-O)
2
C
2
H
5
O
CH-19: di-2 etylhexyl-peroxidicarbonate
C
9
H
19
-C-O-O-C(CH
3
)
3
O
CH-26E: ter-butyl-peroxineodecanoate
CH
3
CH
3
C
t-
C
9
H
19
-C-O-O-
O
CH29: Cummylperoxineodecanoate
(CH
3
-C-CH
2
-CH-CH
2
-C-0-)
2
CH
3
CH
3
CH
3 O
CH-30E: di-3,5,5 -trimetyl hexanoyl peroxide
Chemicals formular
structure of RM used in
PVC resin production
MAIN PROPERTIES OF SOME MATERIALS
Material n Hydrolysis (%) Clouding point (
o
C)
AG-1 700 71 33.8
AG-2 2000 80 53.5
Material Molecular
W (g/mol)
T
1/2
at 1 hr.
(
o
C)
Assay
(%)
Active
Oxygene
(%)
SADT
(
o
C)
C-19 346.5 64 75 3.46 5
C-29 306.4 56 75 3.92 10
C-26 244.4 64 50 3.27 25
C-30 314.5 77 50 2.54 30
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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Materials Used For Reactor Of Each Grade
No Material SG580 SG660 SG710 REMARK
1 RCS x x x Anti fouling agent
2 PW x x x
3 VCM x x x
4 AG-1 x x x
5 AG-2 x x x
6 AG-5 x
7 AD-3 x x x
8 AD-5 x x x
Use in Reactor &
Recovery Tank
9 CH-20 x
10 C-19 x x
11 C-29 x x
12 C-26 x
13 C-30 x
COMBINATION SYSTEM OF INITIATORS
C-19
C-29
C-19 + C29
Reaction time (hr.)
R
e
a
c
t
i
o
n

r
a
t
e
Maximum heat removal capacity of Reactor
1. Utilize the heat removal capacity of the system
2. Shorten reaction time
VINA
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TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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Function of Material in TPC Vina process
No Material Function Original
state
Used state
1 RCS Reactor coating to wall
fouling removal
Solution
5.5%
Solution 5.5%
2 PW Make reaction environment Liquid Liquid
3 VCM Main ingredient of PVC Liquid Liquid
4 AG-1 Primary Suspension agent Solid 7% solution
5 AG-2 Suspension agent Solid 5.5% solution
6 AG-5 Suspension agent Solid 2% solution
7 AD-3 Chain break Solid 10.2%
solution
8 AD-5 Heat stable and de-foam Emul. 50% Emul. 50%
9 C-19 Initiator Sol. 75% Sol. 75%
10 C-29 Initiator Sol. 75% Sol. 75%
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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No Material Function Original
state
Used state
11 C-26 Initiator Emul. 50% Emul. 50%
12 C-30 Initiator Emul. 50% Emul. 50%
13 CH-20 Chain transfer agent Liquid Solution 13%
14 CH-9 Reduce freezing point of RW Liquid Solution 20%
15 CH-12 Methanol solvent Liquid 163 kg CH-12
+ 20 kg INH-1
16 INH-1 Inhibiting self-reaction Solid
17 INH-3 Inhibiting reaction Liquid Liquid
18 CH-6 NaOH (make base
environment)
Solid
2m
3
PW + 250kg
AD-3 +175kg CH-
6
19 CH-6 Dehydrate for RVCM Solid Solid
20 CH-25 Dehydrate & remove inhibitor Solid Solid
21 HA Neutralizing waste water Sol. 32% Sol. 32%
Function of Material in TPC Vina process
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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MECHANISM OF CHAIN TRANSFER IN SG580 PRODUCTION
RO- CHCl CH
2
.
+ CH
2
= CHCl
-Q
RO- CHCl CH
2
- CHCl CH
2
RO- CHCl CH2 - CHCl CH2
.
+ CH2 = CHCl +
........
(- CHCl CH2 -)
n-1
- CHCl CH2
CHAIN TRANSFER:
j (- CHCl CH
2
-)
n-1
- CHCl CH
2
.
+ HO-CH
2
-CH
2
-SH
-(- CHCl CH2 -)
n-1
- CHCl CH3 + CH
3
-CH-S
.
CH
3
-CH-S
.
+ CH
2
=CH-Cl CH
3
-CH-S-CH
2
-CH
.
Cl
QUALITY SPECIFICATION
ITEM UNIT
SG580 SG660 SG710
K-Value
Bulk Density
Volatile Matter
Sieve Analysis
- Retained on 250 micron
- Retained on 75 micron
g/ml
%
%
%
56 - 59 65 - 67 70 - 72
0.48 - 0.55 0.46 - 0.52 0.50 - 0.60
0.3 Max 0.3 Max 0.3 Max
2.0 Max 2.0 Max 2.0 Max
90.0 Min 90.0 Min 90.0 Min
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Air
Distillation 25 tray
D=0.75, H=8.6
Dehydrator (use 1/3)
D=1.5, H=4.3 m
KOH 38x35x18mm
Dehydrator (use 2/3)
D=0.65, H=4.3 m
NaOH 38x35x18mm
PW
Dryer
Silo
B
Silo
A
Slurry
tank A
Stripping
column
Steam
(LS)
VCM recovery by
NASH compressor
Recovery
tank
AG
OSBL
VCM
Crude VCM tank
Polymerizer
AD
Packing
VCM
Slurry
tank B
LS
Decanter
VCM recovery by
800 section
ATM
Screen
PROCESS FLOW DIAGRAM
Cat.
KOH & NaOH supplier
Quadrimex-France
Tel: +33(0)490787085
Fax: +33(0)490787081
export@quadrimex.com
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PVC Production Process Flow
Diagram
Screen
PVC
bag
Sil
o A
Silo
B
Packing
VCM
vessel
VCM
Tank
A
VCM
Tank
B
VCM
Tank
C
VCM Daily
Tank
Water
Suspending agent
Additives
Catalysts
A B
Reactor
Recovery
Tank
Slurry
Tank A
Slurry
Tank B
Strippin
g
Column
A
B
Decanter
Dryer
Sub
materials
VCM
Tank
D
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CENTRAL CONTROL ROOM
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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POLYMERIZATION PROCESS
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
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CATALYST PREPARATION
RCS COAT
READY
AD-5 CHARGE
VCM CHARGE
PW CHARGE
AG CHARGE
HEADER WASH
CHARGE
POLYMERIZATION
CAT FEED
HEAT UP
TEMP. CONTROL
DEPRESS
DISCHARGE
SELF DISCHARGE AD-3 FEED
PUMP DISCHARGE
RINSE
VCM RECOVERY
TC1301A
SP 58.30
o
C
PV 58.34
o
C
OP 33.1 %
PI1301A
8.83 KG/cm
2
DW
AG1
AG2
AG5
GA1113A,B
DW
GA1111
FA1302A-1
GA1103A
GA1103B
GA1104
TO FA1303
DPW
DPW
DPW
LS
TO FA1803
GA1306
M S GA1327
GA1305
LS
T-cont start 56.3
o
C
10 ton DW GD start
M S
AF STEP &
CHARGING
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CHARGING PATTERN
5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100
PW
AD-5
AG-1
AG-2
AG-5
HPW
VCM
Catalyst
Heat Up
CH-20
Charging section
M S
LI1101
LI1102
LI1103
FA1102A
AG-1
FA1102B
AG-2
FA1103B
AG-5
TC1101
FA1104B
AD-5
FA1106A
CH-20
FA1201
PW
GA1101A
GA1101B
GA1102B
GA1103B
GA1113AB
M
M
FA1105
VCM
GA1104
DC1301A HEAT UP GR01>GR205
CAT
CHARGING
CAT
CHARGING
TREND
GROUP035
TREND
GROUP035
TEMP
CONT. A
TEMP
CONT. A
TREND
GROUP036
TREND
GROUP036
CH-20
CHARGE
CH-20
CHARGE
TREND
GROUP037
TREND
GROUP037
AD3
CHARGE
AD3
CHARGE
TREND
GROUP038
TREND
GROUP038
TREND
GROUP039
TREND
GROUP039
TREND
GROUP040
TREND
GROUP040
TREND
GROUP041
TREND
GROUP041
TREND
GROUP042
TREND
GROUP042
FA1328A
FA1318A
DW
GA1312A
GA1311A
GA1204A
GA1204B GA1305A
1322A
LS LC
CW
CWR
CW
EI1301A
42.5 AMP
1325A
1321A
FI1323A
1850 l/h
FQ1323A
1398 L
FQ1324A
SP 7699 L
PV 0 L
CATFEED CATFEED
CATWASH CATWASH
FC1324A
SP 1593 l/h
PV 0 l/h
OP -5.0 %
TI1302A
58.0
o
C
1323A
1324A
FA1303
(RVCM)
A INERT
SP 10 MIN
PV 10 MIN
HW
TI1307A
34.4
o
C
CWR
FC1316A
SP 0 m
3
/h
PV 0 m
3
/h
OP -5.0 %
PREAGI TM
SP 10 MIN
PV 0 MIN
FI1316A2
4.8 m
3
/h
FM1316A
0 m
3
/h
TI1306A
28.8
o
C
TI1309A
31.6
o
C
FI1315A
504.8 m
3
/h
94.7 %
TC1303A
SP 70.0
o
C
PV 70.1
o
C
OP 25.0 %
A REAC TM
SP 275 MIN
PV 0 MIN
A DEPRESS
SP 135 MIN
PV 0 MIN
TI1308A
49.1
o
C
DC1301A
TC1301A
SP 58.30
o
C
PV 50.34
o
C
OP -5.0 %
PI1301A
7.83 KG
GA1113A
GA1113B
1109
1349 1399
FQ1329A
SP 10 L
PV 110 L
l/h
GA1103A
1310A
FQ1329A
SP 134 L
PV 133 L
l/h
0.00
0.00
CH20
AD3
LI1108
1.065 M
(11.588 m
3
)
LI1110
0.481 M
(10.868 m
3
)
M S
0.0 %
BACK UP BACK UP
DC1301A POLY SECTION GR01>GR205
CAT
CHARGING
CAT
CHARGING
TREND
GROUP035
TREND
GROUP035
TEMP
CONT. A
TEMP
CONT. A
TREND
GROUP036
TREND
GROUP036
CH-20
CHARGE
CH-20
CHARGE
TREND
GROUP037
TREND
GROUP037
AD3
CHARGE
AD3
CHARGE
TREND
GROUP038
TREND
GROUP038
TREND
GROUP039
TREND
GROUP039
TREND
GROUP040
TREND
GROUP040
TREND
GROUP041
TREND
GROUP041
TREND
GROUP042
TREND
GROUP042
FA1328A
FA1318A
DW
GA1312A
GA1311A
GA1204A
GA1204B GA1305A
1322A
LS LC
CW
CWR
CW
EI1301A
42.5 AMP
1325A
1321A
FI1323A
3371 l/h
FQ1323A
10198 L
FQ1324A
SP 7699 L
PV 3702 L
CATFEED CATFEED
CATWASH CATWASH
FC1324A
SP 1593 l/h
PV 1607 l/h
OP 16.5 %
TI1302A
58.0
o
C
1323A
1324A
FA1303
(RVCM)
A INERT
SP 10 MIN
PV 10 MIN
HW
TI1307A
34.4
o
C
CWR
FC1316A
SP 472.8 m
3
/h
PV 471.9 m
3
/h
OP 61.2 %
PREAGI TM
SP 10 MIN
PV 14 MIN
FI1316A2
4.8 m
3
/h
FM1316A
477 m
3
/h
TI1306A
28.8
o
C
TI1309A
31.6
o
C
FI1315A
254.8 m
3
/h
94.7 %
TC1303A
SP 70.0
o
C
PV 29.1
o
C
OP -5.0 %
A REAC TM
SP 275 MIN
PV 140 MIN
A DEPRESS
SP 135 MIN
PV 0 MIN
TI1308A
49.1
o
C
DC1301A
TC1301A
SP 58.30
o
C
PV 58.34
o
C
OP 30.1 %
PI1301A
8.83 KG
GA1113A
GA1113B
1109
1349 1399
FQ1329A
SP 10 L
PV 110 L
l/h
GA1103A
1310A
FQ1329A
SP 134 L
PV 133 L
l/h
0.00
0.00
CH20
AD3
LI1108
1.065 M
(11.588 m
3
)
LI1110
0.481 M
(10.868 m
3
)
M S
0.0 %
BACK UP BACK UP
REACTION PROFILE
Reaction time (hr.)
P
,

T
x
End press.= 6.0 SG660
Reaction pressure
Reaction Temp.
Depress. Point = Preact. 0.5
x
Heat up cut =
T
react.
5
T-Cont start =
T
react.
2
Grade SG580 SG660 SG710
Reaction temp. (oC) 66.3 58.3 51.7
Reaction press. (kg/cm
2
) 10.87 8.83 7.38
End press. (kg/cm
2
) 8.0 6.0 6.0
Conversion
84% 87%
82%
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RECOVERY TANK GR01>GR403
CAT
CHARGING
CAT
CHARGING
TREND
GROUP035
TREND
GROUP035
TEMP
CONT. A
TEMP
CONT. A
TREND
GROUP036
TREND
GROUP036
CH-20
CHARGE
CH-20
CHARGE
TREND
GROUP037
TREND
GROUP037
AD3
CHARGE
AD3
CHARGE
TREND
GROUP038
TREND
GROUP038
TREND
GROUP039
TREND
GROUP039
TREND
GROUP040
TREND
GROUP040
TREND
GROUP041
TREND
GROUP041
TREND
GROUP042
TREND
GROUP042
PW
GA1316
GA1314
GA1103C
GA1302
LS
EI1303
0.1 AMP
1326A
LI1109
0.633 M
FQ1322
SP 0.0 L
PV 0.0 L
LC1305
SP 4.000 M
PV 12.703 M
OP 5.0 %
1383
1381
DISCHARGING
SLURRY
NASH2 W TM
SP 0 MIN
PV 10 MIN
FA1304
PC1305
SP 0.55 KG
PV 0.50 KG
OP 5.0 %
TI1310
53.1
o
C
M S
1359
1387
1385
1327A
1375 1393
PI1503
8.51 KG
1386
1382
PC1305
40.0 %
1326B 1327B
LI1308
4.90 M
LI1309
10.22 M
GA1307
WASH COUNT
05
1384
DW
1379
HALF HALF FULL FULL
1378
1380
LA1315
1397
1394
1398
LI1501A
4.99 M
1396 1395
EI1305
0.0 AMP
PW
PW
FA1310
FA1501A
FA1501B GRADE
MVP66 MVP66
FA1501A GRADE
MVP66 MVP66
FA1304 GRADE
FA1803
FA1303
EQ
PW
LEQ
PW
D P W
A D 5
LS
JF1302
PC1802
SP 0.020 kg/cm
2
PV 0.164 kg/cm
2
OP 105.0 %
PC1404
SP 4.800 kg/cm
2
PV 3.919 kg/cm
2
OP 120.0 %
PC1403
SP 5.000 kg/cm
2
PV 3.919 kg/cm
2
OP 120.0 %
LC1302
SP 0.200 M
PV 10.191 M
OP 1122.2 %
PI1303
0.85 KG
MVP66 MVP66
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FA1403
SLURRY TRANSFER SECTION GR01>GR502
RECOVERY
SECTION
RECOVERY
SECTION
TREND
GROUP005
TREND
GROUP005
SLURRY
FEEDSEC
SLURRY
FEEDSEC
TREND
GROUP053
TREND
GROUP053
UNIT
SUMMARY
UNIT
SUMMARY
TREND
GROUP054
TREND
GROUP054
EQ
LINE
EQ
LINE
TREND
GROUP055
TREND
GROUP055
TREND
GROUP056
TREND
GROUP056
GA1302
GA1502
1524
LS
SLURRY
FA1501A
LC1502
SP 3.600 M
PV 3.579 M
OP 1147.0 %
WASH WASH
FC1502
SP 111500 kg/h
PV 111499 kg/h
OP 55.0 %
TI1501A
54.5
o
C
PW
DA CYCLE
SP 30 MIN
PV 27 MIN
PI1504
0.329 KG
FA1501B DA1501
SLYA
NO
SLYA
NO
PC804
SP -260.0 mmHg
PV -261.5 mmHg
OP 145.6 %
GA1501A
TI1502
36.8
o
C
GB1801
HALF HALF FULL FULL
1502
GA1501B
WASH WASH
FC1501
SP 40.00 t/h
PV 40.32 t/h
OP 142.8 %
GRADEMVP66 MVP66
PI1501A
0.598 KG
LI1501A
1.11 M
LT1501A
24.3 m
3
LEQ
1518A
1503
LI1308
14.35 M
FA1801
HALF HALF FULL FULL
1501
PI1501B
10.00 KG
LI1501B
1.02 M
LT1501B
22.6 m
3
TC1501B
SP 170.0
o
C
PV11 64.8
o
C
OP11 5.0 %
TI1505
95.7
o
C
TI1504
90.6
o
C
TI1503
87.3
o
C
TI1506
99.4
o
C
CR
CW
PW
GRADEMVP66 MVP66
EI1501A
21.20 AMP
EI1502
31.69 AMP
EI1501B
23.16 AMP
SLYB
NO
SLYB
NO
PI1503
7.91 KG
PW
WASH CNT
0
PW
1518B
LA1503
LA1506
1514
1515B
1516
1515A
1517
TCV
1501B
LS
AIR
GB1505A
PW
FI1502
Nm
3
/h
1513
1
4 3
2
107
FA1501B WASH
SP 30 MIN
PV 0 MIN
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Cake moisture: SG580: 18%
SG660: 22%; SG710: 25%
DRYER SECTION GR01>GR603
DRY TROUBLE
DRYER
GFFEED1
GFFEED2
SLURRYB
DFEED
WASH
SILO
A
B
DATA
SAMPLING
DATA
SAMPLING
TREND
GROUP062
TREND
GROUP062
UNIT
SUMMARY
UNIT
SUMMARY
TREND
GROUP063
TREND
GROUP063
PF
MOITURE
PF
MOITURE
TREND
GROUP064
TREND
GROUP064
AIR
CONDI.
AIR
CONDI.
TREND
GROUP065
TREND
GROUP065
HW
SECTION
HW
SECTION
TREND
GROUP066
TREND
GROUP066
SCREEN
PNEUMA
SCREEN
PNEUMA
TREND
GROUP068
TREND
GROUP068
TREND
GROUP069
TREND
GROUP069
TREND
GROUP085
TREND
GROUP085
%RH
EI1506
26.57
AMP
TC1514
SP 58.7
o
C
PV 62.9
o
C
OP 0.2 % GA1503
LAMP OP TM
SP 60 MIN
PV 40 MIN
mmH
2
O
PI1901
8.90 KG
EI1507
113.3 AMP
PI1601
0.912 KG
FA1502
JF1501
JF1503
JF1502
TI1515
63.9
TI1516
60.8
TI1517
57.8
TI1518
41.8
(
o
C)
GB1502
GB1501
JF1505
LS
TI1512
91.1
o
C
FI1511
323.8
m
3
/h
PDI1523
267.3 mmH
2
O
PDI1525
27.5 mmH
2
O
GB1503
FA
`
FC1502
FC1501
JF1504
PI1516
99 ATM
TI1519
62.3
MC1506A
SP 7.70 t/h
PV 7.85 t/h
OP 43.8 %
MC1506B
SP 5.80 t/h
PV 5.88 t/h
OP 49.2 %
PC1511
SP 90.0 mmH
2
O
PV 1 89.0 mmH
2
O
OP 65 %
TC1702
SP 75.0
o
C
PV 74.7
o
C
OP 80.1 %
FC1512
SP 310.0 Nm
3
/min
PV 309.7 Nm
3
/min
OP 76.2 %
FC1513
SP 52.0 Nm
3
/min
PV 52.1 Nm
3
/min
OP 79.2 %
TC1511
SP 96.5
o
C
PV 97.2
o
C
OP 49.9 %
AI1511
85.0
TI1500
30.3
o
C
AC1502
SP 0.200 %
PV 0.218 %
OP 139.1 %
AC1501
SP 1.000 %
PV 1.020 %
OP 164.3 %
TC1513
SP 90.0
o
C
PV 89.9
o
C
OP 33.1 %
FC1518
SP 250.0 kg/h
PV 110.0 kg/h
OP 1130.0 %
HC1511
50.0
SI1511
48.9
LI1501
A 6.0 M
B 5.1 M
`
1536
HC1701
5.0 %
EI1505
126.3
AMP
BED FIN TM
SP 30 MIN
PV 1 0 MIN
PDI1521
490.7 mmH
2
O
HC1512
0.0
%
%
%
o
C
HC1502
70.0 %
XA
1511
XA
1512
FD1502
FF1501
DRY
NO MVP66
GRADE
1533
FI1514BM
265.0
Nm
3
/min
FI1514
44.63
Nm
3
/min
1532
SCREEN PNEUMA GR01>GR607
BED FIN TM
SP 60 MIN
PV 40 MIN
OFFSPEC TM
SP 60 MIN
PV 40 MIN
DRYER
SECTION
TREND
GROUP067
SILO
CHANGE
TREND
GROUP069
AIR
CONDI.
TREND
GROUP084
DATA SET
AIR
PI1601
0.912 kg/cm
2
EI1601
119.3 AMP
TO SILO
A B
TI1601
30.2
o
C
LS
FC1621
SP 0.0
PV 0.0
OP -5.0
kg/h
kg/h
%
LS
PVC
IA
AIR 1537A
1537B
1606 1607
1603 1604 1605
1602 1601
1610
FD1503
XA1512
XA1511
LA1511
FLEXIBLE
BAG
1623
1622 1621
1608 1609
1538
IA IA
IA
JF
1601B
JF
1601A
JF
1601C
FC1516
SP 0.0
PV 0.0
OP -5.0
kg/h
kg/h
%
HC1601A
65.0 %
TS1602
TS1603
GB1601
HV
LOCK
PA
STAR
FD1502PA
SP 60 MIN
PV 40 MIN
PNEUMA FIN
SP 60 MIN
PV 40 MIN
HC1502
70.0 %
TI1500
30.3
o
C
AI1511
85.3 %RH
FI1515
107.3 Nm
3
/h
HV1531
FACTOR 0.000
CALC 0.0
FD1502
`
`
`
LA1511
CW
SCREEN PNEUMA
FD1602 EA1601
FE1501
SILO CHANGE GR01>GR608
DRYER
SECTION
DRYER
SECTION
TREND
GROUP084
TREND
GROUP084
SCREEN
PNEUMA
SCREEN
PNEUMA
UNIT
SUMMARY
UNIT
SUMMARY
TS1602
FE9601A
GRADE
MVP66
9602A
FQ9601A
170.9 T
USE
A
LA9603A
LA9601A
LA9602A
XC9601A
SILO
A NO
GRADE
MVP66
9602B
FQ9601B
135.4 T
USE
B
LA9603B
LA9601B
LA9602B
XC9601B
SILO
B NO
` ` `
135.4
1606
1601
1607
1602
JF1601A JF1601B JF1601C
PI1601
0.912 kg/cm
2
EI1601
119.3 AMP
TI1601
30.2
o
C
HC1601A
70.0 %
GB1601
SILO
CHNG
TS1603
FD1502
SCREEN
FD1503
OFF SPEC
SCREEN
JFA JFB
H13N0812 H13N0813
ONEWAY
BATCH
SILO PURGE
SP 15 SEC
PV 1 0 SEC
SILO BATCH
SP 300 MIN
PV 110 MIN
PNEUMA FIN
SP 11120 MIN
PV 10 MIN
9601
FE9601B
PACKING MACHINE
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
GB1302
FA1105
GA1205
PW
FA1803
FA1803
DW
GA1204A
GA1204B
FA1305
FA1309
GB1301
GA1306
GA1305
EA1303
1361
1362
1302
1315
1391
1392
1363
1333
1331
1320
1318
1321
1312
1303
1316
1314
POLYMERIZER A / V SECTION
FA1703
Y
LS
DPW
GA1305
VG
1392 1311 1391
1315
1401
1322
1320
1318
1316
GA1204A
GA1204B
1321
POLYMERIZER V / A SECTION
FA1401 FA1402
GA1401 GA1402
GB1401
GB1402
PC1401
SP 1.000KG
PV 1.050KG
LC1401
SP 0.300M
PV 0.357M
LC1402
SP 0.200M
PV 0.167M
PC1402
SP 0.500KG
PV 1.050KG
LC1302
SP 0.200M
PV 0.180M
EA1401 EA1402
INH-3 Section
1341A-1
1343A-1
1342A-1
1341A-2
1343A-2
1342A-2
FA1302A-1
INH-3
FA1302A-2
INH-3
NITROGEN
40l x 6 x 23 Bar
NITROGEN
40l x 150 Bar
NITROGEN
40l x 6 x 23 Bar
DC1301A
TC1301A
SP 58.30
o
C
PV 58.34
o
C
OP 30.1 %
PI1301A
PV 8.83 KG
INH-3 Auto Charge condition:
1. Power failure
2. Reaction Flag ON (From Cat.
Feed to final press.)
3. Pressure reach set value:
SG580: P = 12.0 bar
SG660: P = 10.0 bar
SG710: P = 9.0 bar
92.5
kg
92.5
kg
400 SECTION GR01>GR411
RAW MAT
MENU
RAW MAT
MENU
TREND
GROUP008
TREND
GROUP008
DW
CHARGING
DW
CHARGING
RINSE
VALVE CK
RINSE
VALVE CK
HW
SECTION
HW
SECTION
IW
FA1804 AD1411
FA1403
DA1401A B C
DA1403
EA1407
EA1409A
FA1406
FA1409
FA1408
FA1804
FA1405
GA1403A
GA1403B
GA1405B
GA1405A
GA
1406
1425
1426A 1426B 1426C
1427
1410
1406
1411
IW
LS
CW
RW
FA1105
OSBL
VG
VG
EA1404
FI1408
1462 kg/h
TI1402
16.1
o
C
PC1404
SP 4.80 KG
PV 4.10 KG
OP 120.0 %
PC1403
SP 5.00 KG
PV 4.10 KG
OP 120.0 %
LI1409
0.486 M
LI1410
0.156 M
LI1403
1.285 M
TI1404
29.8
o
C
TI1408
38.8
o
C
TI1409
43.8
o
C
TI1412
29.2
o
C
TI1413
31.53
o
C
TI1410
36.2
o
C
PI1405
0.39 KG
FC1404
SP 1900 kg/h
PV 1905 kg/h
OP 1172.7 %
LMC1403
SP 111.300 M
PV 111.285 M
OP 176.0 %
PC1409
SP 1.00 KG
PV 0.97 KG
OP 0.0 %
FC1409
SP 0.000 m
3
/h
PV 0.000 m
3
/h
OP 6.9 %
PC1406
SP 5.00 KG
PV 5.01 KG
OP 163.7 %
FC1407
SP 1500 kg/h
PV 1503 kg/h
OP 1135.6 %
PC1407
SP 5.00 KG
PV 5.01 KG
OP 148.1 %
LC1407
SP 0.500 M
PV 0.501 M
OP 50.0 %
FC1406
SP 400.7 kg/h
PV 399.9 kg/h
OP 1132.7 %
LC1408
SP 0.250 M
PV 0.249 M
OP 43.5 %
RESIDUE
RUN FL
DRAIN
PURGE
RUN FL
CUSHION TANK PANEL GR01>GR612
INH-1
INJECT
INH-1
INJECT
TREND
GROUP071
TREND
GROUP071
EQ
LINE
EQ
LINE
TREND
GROUP072
TREND
GROUP072
FA1403
CRUDEVCM
FA1403
CRUDEVCM
DA1801
W/W
DA1801
W/W
FA
FA
FA
1501A
FA
1304
HALF HALF FULL FULL
DA1501 DA1801
FA1803
FA1801
FA1802
FA1804
RESIDUE
RECOVERY
RESIDUE
RECOVERY
1524
LS
CW
1PC1804
SP 260.0 mmHg
PV 259.1 mmHg
OP 153.3 %
1802
1801
1803
1PC1801
SP 0.700 KG
PV 0.590 KG
OP 1 6.9 %
PC1802
SP 0.020 KG
PV 0.185 KG
OP 1105.0 %
PC1403
SP 5.00 KG
PV 4.10 KG
OP 120.0 %
TC1801
SP 45.0
o
C
PV 44.8
o
C
OP 135.3 %
LC1802
SP 0.300 M
PV 0.300 M
OP 72.5 %
DA1801
LC1803
SP 0.500 M
PV 0.811 M
OP 1105.0 %
LC1801
SP 0.200 M
PV 0.200 M
OP 37.1 %
FI1801
16.70 m
3
/h
LI1804
0.608 M
PI1803
0.61 KG
AI1801
18.89 pH
AI1802
0.008 %
GA1801
GA1802
EA1802 FA
1803
1379
GB1801
GB1802
FA1804
CR
PROCESS FLOW BLOCK DIAGRAM
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
(AG, Cat,
PW, AD)
POLYMERIZATION
VCM RECOVERY
DE-WATER
DRYING
SCREENING
BLOWING TO SILO
PACKING
PVC
OVERSIZE
VCM PURIFICATION
VCM
PVC RESIN
JETTY
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
VCM TANK YARD
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
PRODUCTION AREA
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
WASTE WATER TREATMENT
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C
THANK
YOU!
TPC Vina
Plastic & Chemical Corp., Ltd.
VINA
T
P
C