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Carbon nanotubes
Main interest: 1. Prototypes for a onedimensional quantum wire. 2. Strength
1970: Morinobu Endo-- First carbon filaments of nanometer dimensions, as part of his PhD studies at the University of Orleans in France. He grew carbon fibers about 7 nm in diameter using a vapor-growth technique. Filaments were not recognized as nanotubes and were not studied.
1991:Sumio Iijima-- NEC Laboratory in Tsukuba-- used highresolution transmission electron microscopy to observe carbon nanotubes.
Graphite
Hexagonal graphite:
I.
II.
Graphite has a structure containing layers of atoms arranged at the corners of contiguous hexagons.
(not to be confused with hexagonal close packed).
III. The ease with which layers slide against each other is consistent with the much larger distance between carbon atoms in different layers (335 pm) than between carbon atoms in the same layer (142 pm).
IV. The lattice constant a = 246.6 pm V. C=669 pm
Graphite
Graphite
(n, 0) or (0, m) and have a chiral angle of 0, armchair nanotubes have (n, n) and a chiral angle of 30, while chiral nanotubes have general (n, m) values and a chiral angle of between 0 and 30.
5,5
9,0
10,0
Some thoughts:
E(kx, ky) Then because we have a cylinder: E(kxn , ky) Where Kxn = ((2*pi) /P) * n n=1,2,3 (1-D bands)
2.
3.
Cobalt-nickel catalyst helps the growth of the nanotubes, presumably because it prevents the ends from being "capped" during synthesis.
By using two laser pulses 50 ns apart, growth conditions can be maintained over a larger volume and for a longer time. This scheme provides more uniform vaporization and better control of the growth conditions. Flowing argon gas sweeps the nanotubes from the furnace to a water-cooled copper collector just outside of the furnace.
4.
Catherine Journet, Patrick Bernier and colleagues at the University of Montpellier in France: carbon-arc method to grow arrays of single-wall nanotubes.
Look like ?
Scanning electron microscope: looks like a mat of carbon ropes Ropes are between 10 and 20 nm across and 100 m long. Transmission electron microscope: each rope is found to consist of a bundle of single-wall carbon nanotubes aligned along a single direction. X-ray diffraction, which views many ropes at once, shows that the diameters of the single-wall nanotubes have a narrow distribution with a strong peak.