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Elastomers
2. According to behavior of the impression after setting
We used ß-Ca sulfate and not used (α- Ca sulfate or) improved
stone due to:
1. It is weaker so, it will break during removal from undercut to avoid
injury.
2. It requires high w/p which increase the flow so record fine details.
3. High w/p will reduce exothermic heat. During impression taking.
IMPRESSION COMPOUND
Uses:
1.It is used for full jaws impressions in completely edentulous patients.
2.Impression trays for double technique impression (selective pressure
impression).
3.It is used as peripheral seal materials.
Function Ingredient
Soften on heating and give the flow and cohesion. Natural resins and waxes
(unreacted) + water
Setting time controlled by:
1)Heat.
2)Addition of ethyl alcohol.
3)Humidity.
Used in close fitting acrylic special tray
with space 2-3 mm,
or used over impression compound ( wash
technique)
Disinfections:
Can be disinfected by immersion in 2%
glutraldehydes
Properties
very accurate impression.
It has enough fluidity to record the fine details.
Dimensional stability
There is no or very little changes on setting, (setting shrinkage 0.15)
No change during storage, the only impression material which is
stable but at high temperature can make distortions due to presence
thermoplastic resins.
Elasticity: It is non elastic not used for undercuts areas
it is removed from the cast by using hot water at 60 o C for 5-10 minutes.
Adhesion to the tray: Adhere well to the tray.
Cast compatibility: Not need separating medium
Other properties:
It's irritant due to eugenol, giving tingling or burning sensation,
unpleasant taste for some patients, adhere to the tissues so the lips
usually coated with (Vaseline) before the impression
It is accelerated by incorporating one or two drop
of water or ethyl alcohol into the eugenol paste
before it is mixed.
Setting may be retarded by a drop or two of
glycerin.
Zinc oxide & eugenol solvent is oil of orange.
Disinfections: Can be disinfected by immersion in
2% glutraldehyde.
Elastic Impression Materials
(Reversible Hydrocolloid)
Agar
Disinfections
By immersion in solution of:
1. Sodiumhypochlorate,
2. lodophors,
3. phenolic glutraldehydes.
4. Glutraldehyde.
ALGINATE
1.Partial dentures .
2.Primary impressions .
3.Occlusal analysis.
4.Orthodontics .
5.Crown, bridge and implant planning.
6.Mouthguards.
Composition:
1.Potassium alginate, (main ingredient forms solution
with water and becomes cross linked to form gel)
2.Sodium phosphate,(retarder to control working time)
3.Calcium sulphate dihydrate, (reactor, source of Ca
ions which cause cross linking of alginate chains)
4.(Fillers, control stiffness, gel firmer, aids information of sol
by dispersing alginate powder particles)
5.Colouring and flavouring.
6.Chemical indicator:
Violent ,pink and white colors
Two main reactions occur when the powder reacts with water during
setting
(1)The sodium phosphate reacts with. the calcium sulphate to provide
adequate working time
2) After the sodium phosphate has reacted the remaining calcium
sulphate reacts with the sodium alginate to form an insoluble calcium
alginate, which forms gel with the H2o
(1)To avoid the inhalation problems of alginate dust, some materials had
introduced in a dust less version in which the powder coated with glycol
Disinfection
Some products contain a chemical disinfectant in the alginate
powder.
Studies have shown that test viruses have inactivated in
alginate in impressions by: -
(1) 10 minutes soak in 0.5% sodium hypochlorite.
(2) 20 minutes immersion in 2% glutraldehydes
diluted 1:4
(3) 20 minutes immersion in phenyl phenol diluted 1:3
Measurements of dimensional changes showed that immersion of
alginate impressions for 30 minutes did not affect their clinical
accuracy
ELASTIC IMPRESSION MATERIALS
SYNTHETIC ELASTOMERS
POLYSULPHIDES
Clinical uses:
1. Polysulfide rubbers are widely used for crown and bridge
application.
2. Useful for multiple impressions.
3. It is available in low, medium and high viscosities
Composition:
supplied in tubes of base and catalyst paste which are mixed
Base : Contains 80% Polysulphide polymer.
Fillers: (Zinc oxide, titanium dioxide, zinc sulfide, and
silica) Varies from 12% to 50% (depending on the
light, regular or heavy)
(3) Plasticizers.(Di-N-butyl phthalate)
The catalyst Contains:
1. Lead dioxide 30%
2. Hydrated copper oxide or organic peroxide, as a catalyst.
3. Sulfur 0.5% as a promoter, (bad smell).
4. Dibutylphthalate or other non reactive oils 17% to form paste.
5. Inorganic fillers to adjust the consistency and reactivity.
Properties
Disadvantage:
1.It should pour within one hour.
2.They very hydrophobic require very dry field.
3. It is difficult to pour in stone.
Silicones Rubber (Addition Curing)
Clinical Use:
1. For crown and bridge impressions and denture manufacture..
2. Not used for routine study models due to high rigidity and
expensive.
Composition:
Base
Silicone prepolymers with vinyl and hydrogen side groups
(Vinyl polydimethylsiloxane) prepolymers
Catalyst
Siloxane prepolymers + hydrogen side groups
A platinum catalyst (chloroplatinic acid)
Some manufacturers include hydrogen absorbers in their
formulation to eliminate the hydrogen gas , that can on
rare occasion produce porosity.
Addition silicones have much greater dimensional stability
than condensation silicone.
Some manufacturers include a retarder for extending the
working and setting times.
Properties
Advantages:
1. Are highly accurate.
2. Have high dimensional stability after setting
3. Elastic recovery, excellent.
4. Does not stain.
Polyether Rubber
Clinical uses
Accurate impressions
of few prepared teeth
without severe undercuts
High stiffness.
short working time (5 minutes)
restricts their use to impressions of few teeth.
It is available in light consistency, regular and heavy
consistency.
It is hydrophilic consequently so they can record an
accurate impression when it is difficult to achieve perfect
moisture control.
Composition
Base paste
low molecular weight : Polyether with
ethylene- amine terminal groups
Fillers such as colloidal silica
Plasticizers
Catalyst
Aromatic sulfonic acid ester and thickening
agent to form a paste
Properties
setting mechanism (addition polymerization)
It is highly accurate.
Working time: short 2.5 minutes
Setting time: short 4.5 minutes
Flexibility: Low, its least flexible in all rubbers so very
difficulty in removal from the mouth
Thinners were available to increase the working time
without any significant loss of other physical or
mechanical properties
Shrinkage values 0.25% in 24 Hours
Elastic ity: it is viscoelastic 98.9%
Flow : very low ( the stiffness is high )
Manipulation
1-Polyethers is similar to that of Polysulphide and silicone
two equal lengths of base and catalyst paste are mixed
vigorously and rapidly (30 to 45 seconds) Also, an auto mixed
cartridge format.
2-Can be readily silver plated to produce accurate dies
3-Precautions should take to avoid contact of the catalyst with
the skin or mucosa because tissue reactions have observed
Advantages
1.It is pleasant handling and ease mixing.
2.It is more accurate and fine detail reproduction.
3.Easily poured in stone.
4.Dimensionally stable for up to one week
.
Disadvantages
1.High cost,
2.Short working and setting times
3. Rigidity:
When set this can make removal of impression very
difficult in undercut areas.
4. Distort if stored in water or high humidity
more than 10 minutes due to its hydrophilic nature.
5. Cannot left for long periods in disinfectant solutions.
6.Allergic reactions: due to sulphonic acid catalyst system
Disinfections:
Immersion in sodium hypochlorite 10 minutes .
is unlikely to have a deleterious effect on the accuracy.
Properties
Addition Condensation
Polyether Silicone
Polysulfide Alginate Agar
Silicone
Working
2.5 2 –4.5 3 5–7 2.5 7 – 15
Time (min)
Setting Time
4.5 3–7 6–8 8 – 12 3.5 5
(min)
Wettability
Fair to
Good Fair Fair Excellent Excellent and
good
castability
High to
Very high Moderate Low Very low Low Cost
very high
Addition Condensation
Polyether Silicone
Polysulfide Alginate Agar
Silicone
Elastic
98.3 – 99.0 99 – 99.9 98.2 – 99.6 94.5 – 96.9 97.3 98.8
Recovery (%)
Flexibility
1.9 – 3.3 1.3 – 5.6 3.5 – 7.8 8.5 – 20.0 12 11
(%)
< 0.05 < 0.05 < 0.10 0.4 – 1.9 -- -- Flow (%)
Shrinkage, 24
0.2 – 0.3 0.01 – 0.2 0.2 – 1.0 0.4 – 0.5 Extreme Extreme
hours (%)
11 12 3 4 5 7 % Flexibility
98.8 97.5 98.5 99.8 99.5 97.9 % Elastic recovery