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PENELTIAN
STUDY OF EQUILIBRIUM AND KINETICS OF Pb (II) METAL IONS ADSORPTION ON CARBON NANOFIBERS AND
ITS TEST APLICATION AS X-RAY ANTI RADIATION MATERIAL
NURYANI
F1C1 13 057
SUPERVISIOR I : SUPERVISIOR II :
Dr. LA ODE AHMAD NUR RAMADHAN, M.Si. Dr. ALIMIN, S.Si, M.Si
CHEMISTRY DEPARTMENT
FACULTY OF MATHEMATHIC AND NATURAL SCIENCES
UNIVERSITAS HALU OLEO
KENDARI
KENDARI
2017
2017
LOGO
INTRODUCTION
Nanocompocite
indusrty Unic
Hardstructure
and strange
Power plants
Censor
Medical science
Nanotechnology
military
LOGO
INTRODUCTION
Electromagnetic radiation
Generally, those materials are applied in such as reactor zone
Extensive
Radiation
corresponding studies
exposure
to have
X-raybeen
electromagnetic carried
excessive
radiationcantoout
bring by many
a threat
overcome the
researchers
radiation effect foron generating
human body.materials
It isand which
alsothe
possible are able to
to fabricate
onXiang
the of the patient body operators who
project electromagnetic
et
electromagnetic al ., radiation radiation.
protective For instances,
materials which sheet
directly
lead,work
2014
Alimin around
concrete,
et al ., andradiation. such
aluminum-foam as carciogenic
have been agent, cell
produced
Ultra protect theethuman
Hossini al ., body from the radiation source such as clothes,
Gamma X-Ray for mutation,
protecting
2016
2015
Violet gloves, shoes, etc.
change
UV-Visible
against the cromosome, and
Microwave
electromagnetic etc . Radio waves
radiation.
Nambiar et al (2012); Hosseini et al (2015); dan Yang et al
Alimin et al (2016)
(2005)
CNFs
Pb(II)
82 207,19
High adsorption capacity and can be
usedTimbal
as an adsorbent to adsorb
(Pb) metal ions
11, 36
Adsorbat Liquid-phase Adsorbent Huang et al. (2013)
CNF (carbon nanofiber)
Adsorption
The Modification
Large ability
surfaceof area,
a material
of carbon
light tonanofibers
absorb X-Ray
weight, with radiation
elastic metal
moduls rate,
is influenced
can hight
thermal, increase bythethe
absorption
electrical density ofofradiation
conductivity the
and material,
relatively high
especially
electromagnetic of transition
Adsorption metals
is affected
attenuation. by which
et alhave
It time,
Khalil can be atomicas an
used
(2014)
numbers higher
electromagnetic shield
temperature, and protective
concentration, fabrics.
partcel
Anwar (2011); Herdiawan dkk
size and (Herdiawan
(2013);pH dkk.,
& Zuguchi et al2013 ; Zuguchi
(2008)
Fitriani dkk. (2016 )et al., 2008)
LOGO
STATE OF ART
• How does kinetics (reaction order and rate (k)) adsorption of Pb(II)
metal ions in CNFs ?
Adsorption test
CNFs-Pb(II)
Atomic Absoption
Spectrophotometer
Preparation
Preparation of of Pb(II)
Pb(II) metal
metal ions
ions solution
1000 mg/L
standard
solution
50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL
A
y = ax + b
0,001 mg/L
0,005 mg/L
0,01 mg/L
0,05 mg/L
0,1 mg/L
0, 5mg/L C
1 mg/L
AAS (Atomic Absorption Spectrophotometer)
50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL
15
10
30
120
210
60
50 mL 50 mL
Pb(II) 25 ppm Pb(II) 25 ppm
Filtered with
AAS (atomic Absorption milipore porous
Spectrophotomter)
Filtrat CNFs/Pb(II) filter (0,45 µm)
Variation of pH
pH11
pH 10,5
pH 8 Sitired with optimum time
pH 6,5 sonication
pH 5,5 pH 2
Filtered with milipore porous filter
pH 3,5 (0,45 µm)
0,005 gram CNFs
Variation of Concentrations
10
15
20
25
30
35
pH optimum
0,005 grams CNFs
Dispertion
LOGO
DATA ANALYSIS
The adsorption capacity is determined by the isothermal. Isothermal Freundlich or Langmuir isothermal
Ce 1 Ce 1
log qe log KF log Ce
qe qm.K qm n
Slope = 1/n
Slope = 1/qm
log qe
Ce /qe
Intersept = log KF
Intersept = 1/qmK
log Ce
Ce
Freundlich isotherm
Langmuir isostherm
LOGO DATA ANALYSIS
Pseudo Second-Order :
𝑘1
Slope = 1/qe
𝑙𝑜𝑔
(𝑞𝑒 − 𝑞𝑡 ) = log 𝑞𝑒 + 𝑡
2,303
t/qt
Intersept = 1/k2qe2
t Slope = k1/2,303
log
Pseudo First-Order : (qe-qt)
𝑡 1 1 Intersept = log qe
= + 𝑡
𝑞𝑡 𝑘2 𝑞𝑒2 𝑞𝑒 t
LOGO
. TERIMA KASIH
LOGO
250.10
250.00 120 waktu
60 210
(menit) qe (mg/g)
qe(mg/g)
249.90 30
10 249,53
249.80 15 249,65
30 249,91
249.70
15 60 250,00
249.60 120 249,98
the amount of Pb (II) metal ions (qe) adsorbed by carbon nanofibers in various contact
times
LOGO
Variation pH
250.50 Ph qe (mg/g)
250.00 8 2 248,29
11 3,5 248,37
qe(mg/g)
-0.4 0.080
Log (qt-qe)
t/qt
-0.6 0.060
Multilayer
Monolayer
Graph the relationship between the variation of the contact time with the amount of metallic
Pb (II) adsorbed by the activated carbon were irradiated with ultrasonic waves and without
irradiation.
LOGO
Pengenceran Larutan
Larutan Standar 10 mg/L Larutan NaOH 0,1 M
M1 x V1 = M2 x V2
Massa 1000
M= x
1000 mg/L x V1 = 10 mg/L x 100 mL Mr V
M2 Massa
V1 = x V2 1000
0,1 mol/mL = x
M1 500 mL
40 gr/mol
10 mg/L
V1 = x 100 mL 0,1 mol/mL x 40 gr/mol x 500 mL
1000 mg/L Massa =
V1 = 1 mL 1000
Massa = 20 gram
LOGO
Pengenceran Larutan
Larutan HCl 0,1 M
Jadi :
1000 x % HCl x ρ
M1 = M1 x V1 = M2 x V2
Mr
1000 x 37% x 1,19 gr/mL 11,96 mol/L x V1 = 0,1 mol/L x 500 mL
=
M2
V1 = x V2
36,5 gr/mol M1
12,06 mol/mL
V1 = 4,145 mL
LOGO
Persamaan Regresi Linear
Slop
Absorbans sampel
Y = ax + b Intersep
Konsentrasi