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from one form to another. The general restrictions within which all
such transformations are observed to occur are known as the first
SYSTEM
Boundary
Gas
2 kg
3 m3
Gas
2 kg
Moving boundary 1 m3
Fixed boundary
Mass Yes
Control
Hot volume
Water
in
Cold
Water Energy Yes
in
An open system ( a control volume) with Both mass and energy can cross the
one inlet and one exit boundaries of a control volume
Energy can exist in numerous forms. The total energy of a system
(E) is made up of macroscopic and microscopic forms. The
macroscopic forms are those a system possesses as a whole w.r.t.
some outside reference frame , such as kinetic (KE) and potential
(PE) energies.
Macroscopic E = KE + PE
2. Pv work V
dW F .dl P. A.d ( ) P.dV
A
V2
W P.dV
V1
3. Electrical work
W Q(Coulomb).V (volt)
W I (ampere).V (volt). ( s )
Work (cont.)
:
5. Elastic work
F K S . y (deflectio n, m) Hooke' s law
y1 y22
y2
KS 2
W K S . ydy
y1
2
• Energy 1
Ek mu 2
• If a body of mass m is acted upon by the force F 2
during a differential interval of time dt, the W Ek
displacement of the body is dl:
, m3/kg
e, kJ/kg
u, kJ/kg
T T T
P P P Intensive properties
m = 2 kg
T2 = 20 oC
V2 = 3 m3
m = 2 kg
T1 = 20 oC
V1 = 1.5 m3
P
Final state
Process path
Initial state
System
nH nU P(nV)
Q nH (constant pressure)
Heat Capacity
dQ
It may define as: C
dT
dU
CV
dT V
dH
CP
dT P
T2
Q n CV dT (constant volume)
T1
T2
Q n C P dT (constant pressure)
T1
First law