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Yi
Ki
Xi
Where, Ki = equilibrium ration of component
Yi = mole fraction of component i in the the vapour phase
Xi = mole fraction of component i in the liquid phase
Basic Vapour-liquid Equilibrium
Calculations Cont’d
For a given volume of gas-condensate reservoir fluid
consisting of a mixture of different components.
If we define:
n = total number of moles in mixture
L = total number of moles of liquid
V = total number of moles of vapour
Zi = mole fraction of component i in mixture
Then,
Zin = moles of component i in total mixture
XiL = moles of component i in liquid equilibrium
YiL = mole of component i in vapour at equilibrium
Basic Vapour-liquid Equilibrium
Calculations Cont’d
A material balance of the mixture in a given volume gives:
n =L + V
A material balance on the ith component gives:
Zin = XiL + YiV
At equilibrium, the mole fraction of the components in both phases must sum to
unit
Xi = 1
Yi = 1
Thus:
nX i
Xi 1
L VK i Using the equation, the equilibrium composition
and gas and liquid phases can be calculated at any
given pressure.
Yi L
nZ i
1
The calculation procedure is a trial and error
V process.
K
Material Balance Calculations Of Gas-
condensate Reservoirs
If oil zone is negligible MBE takes the same the same
form as dry gas reservoir under both volumetric and
water drive performance.
The MBE can then be written as:
Pb Gp PV
i i
P Vi We B w Wp Note:
Then the MBE for gas condensate reservoir (also gas reservoirs) becomes:
P Pi Gp
1
Z Zi G
P/Z
Reserve Estimation
abandonment
Cumulative Production, Gp G
Material Balance Calculations Of Gas-
condensate Reservoirs Cont’d
Calculation Procedure:
Obtain field production data .
Convert the stock tank oil production to an equivalent quantity of
vapour and add it to measure gas production to obtain Gp.
Determine the tow-phase compressibility.
Calculate P/Z
Make a graph of P/Z vs. Gp
From the graph determine G
Calculate gas and oil reserves.
Vapour Equivalent of Stock Tank Oil
The equivalent vapour volume of stock tank oil is developed
from depletion data given in the fluid analysis
It is reported as a function of pressure
Vapour Equivalent of STO
MSCF/bbl
Pressure psi
Estimation of Well Fluid Gravity
The equation for calculating the condensate well fluid
gravity, given by Ikoku (1980):
R gGg 4584G o
Gw
Go
R g 132800
Mo
6084
Mo
o
API - 5.9
Operating Programs For Gas Condensate
Reservoir