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D. R. Kirk
1
1-D STEFAN PROBLEM
Governing equations Solution
2
LIQUID VAPOR INTERFACE BOUNDARY CONDITIONS
Key question: How can we assess the value of YA,i?
• Equilibrium exists between liquid and vapor phase of species A
• Partial pressure of species A on gas side of interface must equal saturation pressure associated
with temperature of liquid: PA,i = Psat(Tliq,i)
• Partial pressure, PA,i, can be related to mole and mass fraction of species A
Psat
c A ,i
P
Psat Tliq,i MW A
YA,i
P MWmix,i
• Molecular weight of mixture also depends on cA,i, and hence on psat
• Analysis has transformed problem of finding vapor mass fraction at interface to finding temperature at
the interface
– Must be found by writing an energy balance for liquid and gas phases and solving them with
appropriate boundary conditions, including that at interface
– In cross liquid-vapor boundary, temperature continuity is maintained:
• Tliq,i(x = 0-) = Tvap,i(x = 0+) = T(0)
– Energy is conserved at interface:
• Heat is transferred from gas to liquid with some of energy going into heating liquid and
remainder causing phase change
Q g i Q i l m hvap hliq m h fg
Q net m h fg
3
LATENT HEAT OF VAPORIZATION, hfg
• In many combustion systems a liquid ↔ vapor phase change is important
– Example: Liquid fuel droplet must first vaporize before it can burn
– Example: If cooled sufficiently, water vapor can condense from combustion products
• Latent Heat of Vaporization (also called enthalpy of valorization), hfg: Heat required in a
constant P process to completely vaporize a unit mass of liquid at a given T
– hfg(T,P) ≡ hvapor(T,P)-hliquid(T,P)
– T and P correspond to saturation conditions
dPsat h fg dTsat
2
Psat R Tsat
– Assumptions:
• Specific volume of liquid phase is negligible compared to vapor
• Vapor behaves as an ideal gas
– If hfg is constant integrate to find Psat,2 if Tsat,1 Tsat2, and Psat1 are known
– We will do this for droplet evaporation and combustion, e.x. D2 law
4
SIMPLE EXAMPLE
• Liquid benzene (C6H6) at 298 K is contained in a 1 cm diameter glass tube and
maintained at a level 10 cm below the top of the tube, which is open to the
atmosphere
• Given data:
– Tboil = 353 K at 1 atm
– hfg = 393 kJ/kg at Tboil
– MWC6H6 = 78 kg/kmol
– Density of liquid benzene = 879 kg/m3
– DC6H6-Air = 0.99x10-5 m2/s at 298 K
– DH20-Air = 2.6x10-5 m2/s at 298 K
5
DROPLET EVAPORATION
• Evaporation of a single liquid droplet in a quiescent atmosphere is the Stephan
problem for spherical symmetry
– Key question: How long does it take for a liquid drop to evaporate?
6
D2 LAW RESULTS
7
SIMPLE EXAMPLE: DROPLET EVAPORATION
• In mass-diffusion-controlled evaporation of a fuel droplet, the droplet surface temperature is
an important parameter
• Estimate the droplet lifetime, td, of a 100 mm diameter n-dodecane droplet evaporating in
dry nitrogen at 1 atmosphere if the droplet temperature is 10 K below the n-dodecane
boiling point.
• Repeat the calculation for a temperature 20 K below the boiling point and compare
• Assume that in both cases the mean gas density of nitrogen is that of nitrogen at 800 K and
use the same temperature to estimate the fuel vapor diffusivity
• Given properties
– Density of n-dodecane is 749 kg/m3
– Tboil = 489.5 K
– hfg = 256 kJ/kg
– MW = 170
– Dn-dodecane-N2 = 8.1x10-6 m2/s at 400 K and 1 atmosphere