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temperature on composite
materials
What do we mean by composite material?
Products made of composite materials are widely used in state of the art
technology. In some areas, they operate at a variable ambient temperature. Both
the temperature gradient and high or low temperatures cause thermal stresses.
Thermal stresses are caused not only by the uneven temperature field in structural
elements but also by the anisotropy of properties, the change in the coefficients of
thermal expansion depending on the direction. In some cases, the following
requirements are imposed upon the products: thermal stability (minimum
temperature induced deformations), high specific strength, and high stiffness.
Carbon fiber reinforced plastic (CFRP) is a promising material for manufacturing
such products. Their structure (as well as other reinforced materials) is nonuniform,
which may lead to fracture along the interface between fiber and matrix, as well as
fibers. Additionally, properties of the material may vary (as a rule, properties of the
matrix and interface) with time.
Effects of Moisture and Temperature on the
Tensile Strength of Composite Materials
The mechanical properties of composite materials may suffer when the
material is exposed to high temperature, high humidity environments.
Therefore, in order to utilize the full potential of composite materials, their
performance at elevated temperatures and at high moisture contents must be
known. The objective of this investigation was to evaluate the changes in the
ultimate tensile strengths of composite materials exposed to air in which the
relative humidity varied from 0 to 100 percent and the temperature ranged
from 200 K to 450 K.
The changes in the ultimate tensile strengths were assessed by performing
tensile tests on Thornel 300/Fiberite 1034 graphite epoxy composites
Effects of Moisture and Temperature on the
Tensile Strength of Composite Materials
Temperature Effects
1- For 0° and 45° laminates changes in temperature in the range 200 K to 380
K appear to have negligible effects on the ultimate tensile strength, regardless
of the moisture content of the material. There may be a slight decrease in
strength (<20%) as the temperature increases from 380 K to 450 K.
2- For 90° laminates the increase in temperature from 200 K to 450 K causes a
significant decrease in the ultimate tensile strength. The decrease depends
both upon the temperature and the moisture content and may be as high as
60 to 90 percent.
Effects of Moisture and Temperature on the
Tensile Strength of Composite Materials
Moisture Effects
1-For 0° and 45° laminates the moisture content of the composite material has only a
small effect on the ultimate tensile strength. At moisture contents (weight gain) below
1%, the effects of moisture seem to be negligible. At moisture contents above 1% the
tensile strength appears to decrease with increasing moisture content. The maximum
decrease in the ultimate tensile strength is about 20%.This reduction in strength seems
to be insensitive to the temperature of the material.
2- For 90° laminates the moisture content affects significantly the ultimate tensile
strength. The reduction in strength depends both on the moisture content and on the
temperature. The reduction in strength may be as high as 60% to 90%.
Long term effects of moisture on carbon fibre
and epoxy matrix composites
The aim of this work is to investigate the long term effects of moisture on the interface between a carbon
fibre and an epoxy matrix. High modulus carbon fibres were used to prepare single fibre model composites
based on an epoxy resin. The samples were immersed in the seawater and demineralised water and
their moisture uptake behaviour was monitored. The equilibrium moisture content and diffusion coefficients
for the samples were determined. DSC has been used to analyse the moisture effects on glass transition
temperature and thermal stability of the pure epoxy specimens. These results showed a reduction
in the glass transition temperature (Tg) after moisture absorption. Tensile tests were also carried out for
the epoxy specimens and a general decrease in the mechanical properties of the epoxy matrix was
observed. Raman spectroscopy was used to observe the effects of moisture on the axial strain of the carbon
fibre within the composite and stress transfer at the interface as a function of exposure time. The
results show that the decrease in the mechanical and interfacial properties of the model composites
under the seawater immersion is more significant than under demineralised water immersion.
Effect of moisture absorption on the mechanical
behaviour of carbon fiber/epoxy matrix composites