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Chapter 19
Structure and classification of lipids
• Lipids are organic
compounds that are
found in living organisms
that are soluble in non-
polar organic solvents.
• Unlike the other types of
compounds we’ve seen
so far, there are no
characteristic functional
groups in lipids that
indicate their structure.
Structure and classification of lipids
• Lipids can be divided into five categories, on
the basis of lipid function
1. Energy-storage lipids (triacylglycerols)
2. Membrane lipids (e.g. phospholipids)
3. Emulsification lipids (bile acids)
4. Messenger lipids (e.g. steroid hormones)
5. Protective-coating lipids (biological waxes)
Fatty acids and types of fatty acids
• Fatty acids are structural components of all the lipids we’ll
study except cholesterol, bile acids and steroid hormones.
• They are naturally occurring monocarboxylic acids that tend
to have even numbers of carbon atoms, and may be classified
as:
– long-chain (C12 to C26)
– medium-chain (C8 and C10)
– short-chain (C4 and C6)
Fatty acids are not like most lipids in that they may be recognized distinctly by the presence of a
COOH group on a carbon chain.
Fatty acids and types of fatty acids
Saturated and unsaturated fatty acids
16:0
Fatty acid with 16 C-atoms
and no double bonds
18:1 D9
Fatty acid with 18 C-atoms
and one double bond at C-9
18:3 D9,12,15
Fatty acid with 18 C-atoms
and three double bonds at
C-9, C-12, and C-15
Fatty acids and types of fatty acids
Unsaturated fatty acids and double-bond position
1 3
1 3 5
Physical properties of fatty acids
Water-solubility of fatty acids
Triacylglycerols are lipids formed by the esterification of three fatty acids to a glycerol molecule.
Energy storage lipids
Fats and oils
oxidation oxidation