Cocamide DEA/Lauramide DEA

=O
Methyl + CH3OH
Ester R—C--OCH3
OR OR

=O CH2—OH
CH2—O—C—R1
+
=O + CH—OH
CH—O—C—R2 Base cat.
R-PKO
+ Ex. NaOH, NaOCH3
Lauramide DEA
=O Diethanol amine CH2—OH
CH2—O—C—R3 Cocamide DEA
(DEA)
OR
OR
Fatty + H2O
Acid

Reaction step:
Mix Fatty acid + DEA at mole ratio 1:1 to 1:2 with base catalyst at 60-80°C

Diethanol amine (DEA) Can be replaced with Monoethanol amine (MEA)

 2 STEPS FOR SYNTHESIS OF Cocoamidopropyl betaine (CAPB)
Step 1. Synthesis of cocamidopropyl dimethylamine (amidoamine)

=O
Methyl + CH3OH
Ester R—C--OCH3
OR OR
=O CH2—OH
CH2—O—C—R1
=O + + CH—OH
R-PKO CH—O—C—R2
=O CH2—OH
CH2—O—C—R3
OR
OR
Fatty + H2O
Acid

Reaction step:
1. 175°C with continuous water removal until FFA/ME/Trigly < 1%
2. Steam for 2-3h until DMAPA < 100 ppm (checked by GC)
3. Cooled down to RT
 Step 2. Synthesis of cocamidopropyl betaine

Amidoamine Sodium chloro acetate Cocamidopropyl betaine

Reaction condition:
1. Sodium mono chloro acetate (Na MCA) is added over 30 mins
2. Stirred at 80-85°C for 8 h
3. Maintaing pH between 7.5-8.2 with NaOH
4. Continue stirring for 8 h at 95°C
5. Cooling down to RT
6. Adjust pH to 4.5-5.5 with HCl
 Kawaken specification
PRODUCT Acid/Amine Free Loss on DEA (%) Packing
Acid Appearance pH Color(APHA) drying
NAME mole ratio Am-V (%)
200KG
Coconut Pale Yellow
AMISOL CDE 1:1 23 - 33 9.0- 10.7 max.300 max.1 - IRON
Fatty Acid Clear Liquid DRUM
200KG
Coconut Pale Yellow
AMISOL CDE-G Fatty 1:1 18 - 28 9.0- 10.7 max.300 max.1 Max. 5 IRON
Acid Clear Liquid DRUM
200KG
Coconut Pale Yellow
AMISOL FDE 1:1 18 - 28 9.0-10.7 max.300 max.1 - IRON
Fatty Acid Clear Liquid
DRUM
200KG
Coconut Pale Yellow
AMISOL CDC 1:2 100 -120 8.4-9.2 max.350 max.2 - IRON
Fatty Acid Clear Liquid
DRUM
200KG
Coconut Pale Yellow
AMISOL FD 1:2 128 -155 9.5- 10.5 max.350 max. 2 - IRON
Fatty Acid Clear Liquid DRUM
200KG
AMISOL KD-1 Palm Kernel Pale Yellow
1:1 18 - 30 9.0-10.7 max.350 max.1 - IRON
Fatty Acid Clear Liquid DRUM
200KG
AMISOL KD-3 Palm Kernel Pale Yellow
1:1 18 - 28 9.0-10.7 max.400 max.1 - IRON
Fatty Acid Clear Liquid DRUM
200KG
Palm Kernel Pale Yellow
AMISOL KD-4 1:2 125 - 155 9.5-10.5 max.400 max.2 - IRON
Fatty Acid Clear Liquid DRUM
 Specification
Cocamide DEA CAPB
Alfonal KD 1:1 Flavol KDA
Parameters Value Parameters Value

appearance at 20°C yellowish viscous liquid appearance at 20°C clear yellowish liquid

density at 20°C, g/cm3 0.9986 density at 20°C, g/cm3 1.07

viscosity at 20°C, mPa.s, c. 160
viscosity at 20°C, mPa.s, c. 1150
active matter, % wt. 40 ± 2
amide content, % wt., min. 80.0 sodium chloride, % wt. 5.0 - 7.0
free amine (DEA), % wt., max. 5.0 pH, 3% aqueous solution 5.0 - 7.0

free fatty acids, % wt., max. 0.5

water content, % wt., max. 0.5
pH, 1% aqueous solution 9.0 - 10.5