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Chemistry™

Colloidal
Systems ™
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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

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EXIT PROPERTIES OF MAKING SYSTEM
COLLOID SYSTEMS COLLOID
Water Treatment
COLLOID
PRESENTATION
COMPARISON OF
SOLUTIONS,
COLLOID, AND
SUSPENSION Colloidal systems composed of dispersed phase of a
COLLOID IN DAILY certain size in the dispersing medium. Dispersed
LIFE
substance called dispersed phase, whereas the medium
used to disperse called dispersing medium.
TYPES OF COLLOID

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EXIT PROPERTIES OF MAKING SYSTEM
COLLOID SYSTEMS COLLOID
Water Treatment
COLLOID
PRESENTATION
COMPARISON OF
SOLUTIONS,
COLLOID, AND Comparison of solution properties, colloids, and
SUSPENSION
suspensions
COLLOID IN DAILY SOLUTION COLLOID SUSPENSION
LIFE Production Se_A_Ti
(MOLECULAR DISPERSION) (COLLOID DISPERSION) (DISPERSION ROUGH)

TYPES OF COLLOID Homogeneous Are you sure want to exit?


Macroscopically Heterogeneous
homogeneous but if
observed
microscopically
Yes heterogeneous ultra No.
One / all of the
All particle dimension <1 Particle dimension
dimensions of the
nm between 1 nm - 100 nm
particles> 100 nm

1 phase 2 phases 2 phases

Stable Generally stable Unstable

Can not be filtered Can not be filtered filterable


except with ultra filter
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EXIT PROPERTIES OF MAKING SYSTEM
COLLOID SYSTEMS COLLOID
Water Treatment
COLLOID
PRESENTATION
COMPARISON OF
SOLUTIONS,
COLLOID, AND
SUSPENSION

COLLOID IN DAILY EXAMPLE SOLUTION: sugar solution, saline solution, spirit,


LIFE alcohol 70%, vinegar,
Production Se_A_Tisea water, clean air, gasoline.

EXAMPLE COLLOID:
Are you soap,
sure milk,
wantjelly, butter, and
to exit?
TYPES OF COLLOID
mayonnaise.

EXAMPLEYes SUSPENSION: turbid river water,


No.a mixture of
water with sand, coffee mix with water, and mix oil with water.

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EXIT PROPERTIES OF MAKING SYSTEM
COLLOID SYSTEMS COLLOID
Water Treatment
COLLOID
PRESENTATION
COMPARISON OF
SOLUTIONS, the dispersed PHASE
COLLOID, AND NAME EXAMPLE
phase dispersant
SUSPENSION

COLLOID IN DAILY Solid Gas aerosol solid Smoke, dust in the air
LIFE Production Se_A_Ti
Gold sol, sol sulfur, ink,
Solid Liquid sole
paint
TYPES OF COLLOID Are you sure want to exit?
Colored glasses, a black
Solid Solid Sol solid
diamond
Yes No.
Liquid Gas liquid aerosol Fog and clouds

Liquid Liquid Emulsion Milk, coconut milk, fish oil

Liquid Solid solid emulsion Jelly, pearl, opal


NEXT

Soap scum, whipped


Gas Liquid Froth
cream

Gas Solid solid foam Rubber foam, pumice

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EXIT PROPERTIES OF MAKING SYSTEM
COLLOID SYSTEMS COLLOID
Water Treatment
COLLOID
PRESENTATION

COMPARISON OF
AEROSOL
SOLUTIONS, COLLOID,
Colloidal system of solid or liquid particles dispersed in gas called aerosols. If a
AND SUSPENSION
substance is dispersed in the form of solids, calledsolid aerosols; if the substance
is dispersed in the form of liquid, calledliquid aerosol,
A DAY IN THE LIFE OF
COLLOID-HARI
SOLProduction Se_A_Ti
Colloidal system of solid particles in liquids terdipersi called sol.
EXAMPLE SOL: river water (river of clay in water), sol soaps, detergents soles,
TYPES OF COLLOID Are you sure want to exit?
insoles kanji, writing inks, and paints.

EMULSION
Yes are two types of liquids that are notNo.
Terms of the emulsion mutually dissolve.
Emulsions can be classified into two parts, the oil-in-water emulsion (O / W) or water-
in-oil emulsion (W / O).
EXAMPLE M / A: coconut milk, milk, latex
EXAMPLE A / M: mayonnaise, oil, and fish oil

FROTH
PREVIOUS Colloidal system of gas dispersed in a liquid substance called froth. Foam used in
the processing of ore and in fire extinguishers. Substances that break down the foam
include ether, isoamyl, and alcohol.

GEL
Semi-rigid colloidal (between solid and liquid) is called gel.
example: gelatin, starch paste, jam, gelatine, soap gel, and silica gel.
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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT
How do I recognize the
MOTION BROWN colloidal system?

CONTENT COLLOID Production Se_A_Ti

coagulation
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PROTECTIVE COLLOID Very simple way is to impose
a beam of light on the
Yes object. True solution
No.
dialysis
transmit light, whereas
colloidal scatter.
LIOFIL COLLOID AND
COLLOID LIOFOB

TYNDALL
EFFECT
IMAGES

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN
True solution
CONTENT COLLOID Production Se_A_Ti transmit light,
invisible light
beam
coagulation
Light Are you sure want to exit?
Scree
PROTECTIVE COLLOID n
Solution
Yes No.
dialysis

LIOFIL COLLOID AND


COLLOID LIOFOB Colloidal systems
scatter light, visible
light beam
NEXT
Light
Scree
n
Solution

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN Is there a Tyndall effect


in everyday life?
CONTENT COLLOID Production Se_A_Ti

coagulation
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PROTECTIVE COLLOID Certain. Such as headlights on a
foggy night, headlights cinema
Yes No.
projector in smoky / dusty, and
dialysis
a beam of light through a crack
matagari leaves of the tree on a
LIOFIL COLLOID AND
foggy morning.
COLLOID LIOFOB

PREVIOUS

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN

CONTENT COLLOID Production Se_A_Ti

coagulation
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PROTECTIVE COLLOID
Yes No.
dialysis

LIOFIL COLLOID AND


COLLOID LIOFOB
Brownian motionshow the truth of the kinetic molecular theory
which says that the molecules in liquid water is in constant motion.
Brownian motion occurs as a result of unbalanced collision of the
molecules of the medium on the colloidal particles. In the Brownian
motion of suspension did not happen because the particle size large
enough so that the collision that happened balanced.

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

electrophoresis
MOTION BROWN Electrophoresis is the movement of colloidal particles in an electric field. Negatively
charged colloids will move to the anode (positive electrode), while the positively
CONTENT COLLOID Production
charged colloidal moveSe_A_Ti
to the cathode (negative electrode). Thus electrophoresis can
be used to determine the type of cargo colloids.
coagulation
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adsorption
PROTECTIVE COLLOID Is the ability to absorb ions or electrical charge on the surface. Colloidal particles
Yesions or electrical charge but also otherNo.
can adsorb not only substances that form a
dialysis neutral molecule. Adsorption properties of these colloids are used in various
processes, such as:
LIOFIL COLLOID AND 1.Bleaching Cane Sugar
COLLOID LIOFOB Still colored sugar dissolved in water then flowed through diatomaceous earth and
bone charcoal. Dyes in order to obtain the sugar to be adsorbed on the clean
white sugar.
2.norit
Norit is a tablet which is made from activated carbon Norit. In the gut norit form
colloidal systems which can adsorb gases or toxins.
3.Water purification
To purify the water used alum or aluminum sulfate. In the water, aluminum sulfate
is hydrolyzed to form colloidal Al (OH)3 which can adsorb dyes or contaminants in
water
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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN
coagulation
Coagulation is the agglomeration of colloidal particles. Which would negatively
CONTENT COLLOID Production
charged Se_A_Ti
colloid is coagulated at the anode, while the positively charged colloid to be
coagulated at the cathode. Coagulation of colloids as the addition of electrolytes
coagulation occurs as follows. Negatively charged
Are you surecolloids
want willto
attract positive ions, while positively
exit?
charged colloid will attract negative ions.
PROTECTIVE COLLOID
-
Yes - No.
dialysis 3-
- +
+ + + + + +
LIOFIL COLLOID AND + + 3-
+ - 3- +
COLLOID LIOFOB + + +
+
- +
+ - +
+ +
+ + + + 3-
NEXT 3- +
- -

- Sol Fe (OH)3 ion


- surrounded PO43-
+
Sol Fe (OH)3 ion
surrounded Cl-
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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT
Some examples of coagulation in
MOTION BROWN everyday life and industry: Smoke
gases
CONTENT COLLOID Production
1.Delta formationSe_A_Ti
in estuaries
2.Rubber in latex by adding formic
coagulation
acid Are you sure want to exit?
3.Colloidal mud in river water can
PROTECTIVE COLLOID
be coagulated by adding alum
Yes
4.Smoke and dust from the plant
No.
dialysis
can be coagulated by means of
LIOFIL COLLOID AND electrical coagulation of Cottrel -
COLLOID LIOFOB
+

Cottrel
PREVIOUS

Exhaust
gases
smoky +

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN PROTECTIVE COLLOID


Will wrap wrapping colloidal particles dispersed substances
CONTENT COLLOID Production Se_A_Ti
that it can not be clustered.
coagulation example:
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1.In the manufacture of ice cream gelatin used to prevent
PROTECTIVE
COLLOID formation of large ice crystals or sugar
2.Paint andYes No. it uses a
ink can last a long time because
dialysis
protective colloid.
LIOFIL COLLOID AND 3.Pengelmusi substances, such as soaps and detergents,
COLLOID LIOFOB
are also classified as protective colloid

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

MOTION BROWN dialysis


Dialysis is the process of removing ions nuisance that can
destabilize the colloids.
CONTENT COLLOID Production Se_A_Ti

coagulation
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PROTECTIVE COLLOID - +
- +
Yes + No.
dialysis +
- -
+
+
- -
LIOFIL COLLOID AND +
COLLOID LIOFOB

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT

LIOFIL COLLOID AND COLLOID LIOFOB


MOTION BROWN
Colloid liquid dispersion medium that has distinguished liofil colloids
CONTENT COLLOID andProduction
colloidal liofob.A colloid is called colloidal liofil if there is enough
Se_A_Ti
affinity between substances dispersed medium. Conversely, a colloid
coagulation called liofob if the attractive
Are force does
you sure want notto
exist or is very weak. If
exit?
PROTECTIVE
mediumdispersi used is water, it is the second type of fluid on top of
COLLOID each calledhdrofil colloids and colloidal hydrophobic.
example:Yes No.
dialysis
1.hydrophilic colloids : proteins, soaps, detergents,
LIOFIL COLLOID AND gelatin, starch, and gelatin.
COLLOID LIOFOB
2.hydrophobic colloidal : milk, mayonnaise, sulfur sol, sol Fe
(OH)3, Sol-sol sulphides, and metal sols.
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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

TYNDALL EFFECT
Comparison with a hydrophilic nature Sol Sol hydrophobic
MOTION BROWN

CONTENT COLLOID Sol hydrophilic


Production Se_A_Ti Sol hydrophobic

coagulation adsorbing medium Not adsorbing medium


Are you sure want to exit?
PROTECTIVE Can be made with a relatively Only stable at small
COLLOID large concentration concentrations
Yes No.
dialysis
Not easily coagulated by Easy to agglomerate on addition
LIOFIL COLLOID AND addition of electrolytes elktrolit
COLLOID LIOFOB
The viscosity is greater than the Viscosity is almost equal to the
medium medium
PREVIOUS
PREVIOUS is reversible not reversible

Weak Tyndall effect The effect is more obvious tyndalll

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

Water treatment based on the properties of colloids, namely


coagulation and adsorption. The materials used for water
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treatment is alum (aluminum sulfate), sand, chlorine or chlorine,
calcium oxide, and activated carbon. Alum sludge agglomerate
Are
colloidal useful for you
makingsure want
it easier to exit?
filtered. If the water turbidity
level is too high then the use of activated carbon. The sand acts
as a filter. Chlorine or chlorine serves as pest control, while the
Yes No.
lime will be useful to raise the pH, which is to neutralize the
acidity that occurs due to the use of alum.

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

HOW TO
CONDENSATE Colloidal particle size lies between real particles and particle
suspensions. Therefore, the system can be created by grouping
HOW TO colloidal particles true solution or soften the material in rough shape
DISPERSION andProduction
then dispersedSe_A_Ti
into the dispersing medium.

COLLOID Are you sure want to exit?


ASSOCIATION

Yes No.

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

HOW TO
CONDENSATE
How Condensation
By way of a true solution of condensation particles (molecules or ions) merge into
HOW TO colloidal particles. This can be done through chemical reactions, such as redox
DISPERSION Production
reaction, hydrolysis andSe_A_Ti
decomposition duplicate, or by solvent replacement.

COLLOID
a.
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Redox reaction
ASSOCIATION
Redox reactions are reactions accompanied by changes in
oxidation number
Yesexample: Sol manufacture of sulfur from
No.a reaction between
hydrogen sulphide (H2S) and sulfur dioxide (SO2), Namely the gas
stream H2S into SO2 solution.
2H2S(G) + SO2(Aq) 2H2O(L) + 3S (colloidal)

b. Hydrolysis
NEXT Hydrolysis is the reaction of a substance with water.
example: Preparation of sol Fe (OH)3 hydrolysis of FeCl3, When
boiling water is added to a solution of FeCl3 sol will form Fe (OH)3,
FeCl3(Aq) + 3H2O(L) Fe (OH)3(Colloidal) +
3HCl(Aq)

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

HOW TO
CONDENSATE

HOW TO
DISPERSION c. Double
Production decomposition
Se_A_Ti
example: Sol As2S3 can be prepared from the reaction
COLLOID between
Are youH3sure
Aso3 with
wanta solution of H2S.
to exit?
ASSOCIATION 2H3Aso3(Aq) + 3H2S(Aq) US2S3(Colloidal) +
6H2O(L)
Yes No.
d. Solvent Substitution
example: If a saturated solution of calcium acetate
mixed with alcohol will form a colloid in the form of a gel.

PREVIOUS

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

HOW TO How Dispersion


CONDENSATE By dispersion, coarse aprtikel broken into colloidal particles. By dispersion can be done
mechanically, peptasi, or with an electric spark jumps
HOW TO
DISPERSION Production a.
Se_A_Ti
How Mechanic
According to this method coarse grain crushed with a
colloid mill to obtain a certain level of refinement, then
COLLOID Are you
stirredsure want tomedium.
with a dispersion exit?
ASSOCIATION example: Sol sulfur can be made by grinding sulfur
powder together with an inert (such as sugar), then mixed
with water.
Yes No.
b. How peptizing
How is the peptizing colloidal manufacture of coarse grains
or of a precipitate with the aid of a substance pemeptisasi
(solver). Substance pemeptisasi solve Kassar grains into
grains of colloid.
- +
c. How Bows Bredig
How Bredig arc used to make the soles of metal. Colloidal
metal that will be used as the electrode is dipped in a
dispersion medium, and then given electric stepping in
between the two ends.

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EXIT COLLOID PROPERTIES OF MAKING SYSTEM
Water Treatment
PRESENTATION SYSTEMS COLLOID COLLOID

HOW TO
CONDENSATE Association colloids
Various types of substances, such as soaps and detergents form a colloid. Soap or
HOW TO detergent molecules consist of a polar part (head) and a nonpolar part (tail).
DISPERSION Emulsifying power of soap and detergents due to the nonpolar groups of soap will
Production Se_A_Ti
attract dirt particles (grease) of laundry ingredients and then dispersing into the water.

COLLOID Are you sure want to exit?


ASSOCIATION
fabri dirt
c Yes No.

(A) Any dirt or grease spots on


the laundry material
(C) Dirt lifted

(B) soap molecules attract dirt with (D) Dirt dispersed in water
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