CHEMICAL

OXYGEN
DEMAND (COD)
ANALYSIS AND
REDUCTION IN
RETANNING
PROCESS

Oktavia Puspita Nurazila

 COD Value Based on Article
COD Load of All Drain Float
300000

250000

200000
COD Load (mg/L)

150000

100000

50000

0
Analysis from article that have high
COD and low COD
High Low
COD COD

1. Long recipe (7-12

Float) 1. Short recipe
2. Many washing 2. A few washing
3. Top dyeing 3. No top dyeing
 Retanning Process

Prefat, Retanning,
Washing netralization Dyeing,
washing
Fatliquoring,
Fixation
 COD Value Based on Fatliquor-
Fixation Float
COD Load of Fatliquoring-fixation Float
90000
80000
70000
60000
50000
40000
30000
20000
COD
10000
0
Analysis
 First Project ( Increase Fixation
Time)
Article Name Colour Material Area Pieces
Weight (
kg)
Recipe
Fixation Time (
after main
fatliquor)
pH

268 20 minutes 2
Camelia main pearl LD ADC 6955 side 1206 Standard times 3,4
1214 grey 262 30 minutes, 2
LD FS 6170 side 998 Trial Times 3,54
402
8330 side 1145 Standard 20 minutes 2 times 3,4
The Natural 1214 Mink V2 J2
366
7579 side 1055 Trial 30 minutes, 2 times 3,4
256
Cocoa 5155 side 632 Standard 20 minutes 4 times 3,4
Endore 1214 J2
Brown 278
5211 side 675 Trial 30 minutes, 4 times 3,4
468
8000 side 1045 Standard 20 minutes, 3 times 3,7
Jabuck 1113 Night Blue J1
466
8115 side 1008 Trial 30 minutes, 3 times 3,7
248
Cow Veg Insole 6020 side 960 Standart 20 minutes, 2 times 3,48
Lion LD
1214 254 30 minutes, 2
6350 side 1070 Trial Times 3,43
Result of Increase Fixation Time

80000
70000
60000
50000
40000
30000
20000
10000 Standart Recipe
0
Trial
 Second Project (Change
Recip Amount of
Percentage of FA)
Article Name Colour
Materi
al
Weigh e
Area Pieces t (kg)
Formic Time
Acid(%) (Minutes) pH
312 Stand
3,7
Oil Nubuck 6650 side 1315 ard 0,8+1+1 60(@20)
Black LS
HM 1416 352 1.4+1.4 3.8. after extra FA
Trial
7912 side 1212 +extra 1 60(@20) pH =3.6
382 Stand 1+1+1+ 3,8 after extra FA
The Natural 7912 side 1135 ard extra 1+1 80 (@20) pH= 3,5
Amber J2
1213 398 80
Trial 3,4
7912 side 1080 1.5+1.5+1.5 (20,30,30)
256 Stand
3,4
Cocoa 5155 side 632 ard 0,8+0,8+1+1 80(@20)
Endore 1214 J2
Brown 430 80(20,30,3
Trial 3,5
7677 side 942 1,2+1,2+1,2 0)

Stand 4, after extra pH

310 ard 0,5+1+1+ =3,69
Jabuck 1113 Night Blue J1 5559 side 660 extra 1+1 80 (@20)
332 Trial 80(20,30,3 3,58
5705 side 790 1,5+1,5+1,5 0)
 Result
70000
Change Percentage

60000
50000
COD (mg/L)

40000
30000
Standard Recipe
20000
Trial
10000
0
Oil The Endore Jabuck
Nubuck Natural 1214 1113
HM 1416 1213
Artichle
Change Retanning Agent
Third Project
 Artichle : Sambal
 Colour : Lion
 Material : J5

Prefat, Retanning,
Wetting Back Rechrome & Dyeing,
Washing
Netralization Fatliquoring,
Fixation
Standart Recipe Trial Chemical Description
6% Magnopal PGN 4% Magnopal PGN Acrilic Copolymer
combination of phenolic sulphonic acids
10% Sellasol HFN F Liq 7% Sellasol HFN F Liq
With Protein derivates
3.5% Syntan DF 585 3.5% Syntan DF 585 Dyciandiamide
Blancotan MKS : syntan
3.5% Blancotan MKS 6% Novaltan PW
Novaltan PW : Polymer
 Result
48000

46000

44000

42000
COD (mg/L)
40000

38000

36000
Production Sample (Std sample (Trial)
Recipe)
Conclution
 Factors affecting COD :
1. Fixation
2. Different Dyestuffs affect COD differently
3. Retanning and Fatliquoring
4. Chemical derived from organic material
affect to COD