w w w. z ig y a .

co m

Previous Year Paper

Chemistry - 2018
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Multiple Choice Questions

1. A n a l k a l i is t i t r a t e d a g a i n s t a n a c i d w i t h m e t h y l o r a n g e as i n d i c a t o r , w h i c h o f t h e f o l l o w i n g is a c o r r e c t
combination?

Base Acid End Point

Str ong Str ong Pink t o colour le ss

Base Acid End Point

Weak Str ong Colourless t o pink

Base Acid End Point

Str ong Str ong Pinkish Red t o Yellow

Base Acid End Point

Weak Str ong Yellow t o Pinkish Red

Answer
2. T h e p r e d o m i n a n t f o r m o f h i s t a m i n e p r e s e n t i n h u m a n b l o o d is ( p K a , H i s t i d i n e = 6 . 0 )

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 2 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answer
3. W h i c h o f t h e f o l l o w i n g l i n e s c o r r e c t l y s h o w t h e t e m p e r a t u r e d e p e n d e n c e o f e q u i l i b r i u m c o n s t a n t K, f o r a n
exothermic reaction?

A and D
A and B
B and C
C and D
Answ er

4. T h e c o m b u s t i o n o f b e n z e n e ( l) g i v e s C O 2 ( g ) a n d H 2 O( l) . G i v e n t h a t h e a t o f c o m b u s t i o n o f b e n z e n e a t

c o n s t a n t v o l u m e is – 3 2 6 3 . 9 kJ m o l – 1 a t 2 5 0 C ; t h e h e a t o f c o m b u s t i o n ( i n kJ m o l – 1 ) o f b e n z e n e a t c o n s t a n t

p r e s s u r e w i l l b e (R = 8 . 3 1 4 JK–1 m o l – 1 )

–3267.6

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 3 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

4152.6
–452.46
3260
Answer
5 . T h e r a t i o o f m a s s p e r c e n t o f C a n d H o f a n o r g a n i c c o m p o u n d (C X H Y O Z ) is 6 : 1 . If o n e m o l e c u l e o f t h e a b o v e

c o m p o u n d (C X H Y O Z ) c o n t a i n s h a l f a s m u c h o x y g e n as r e q u i r e d t o b u r n o n e m o l e c u l e o f c o m p o u n d C X H Y

c o m p l e t e l y t o CO 2 a n d H 2 O . T h e e m p i r i c a l f o r m u l a o f c o m p o u n d C X H Y O Z is

C2 H 4O 3

C3 H 6O 3

C2H4O

C3 H 4O 2

Answer
6. Which of the following are Lewis acids?
BCl 3 a n d AlC l 3

PH 3 a n d BC l 3

AlCl 3 a n d SiCl 4

PH 3 a n d SiCl 4

Answer
7. According to molecular orbital theor y, w hich of the following will not be a viable molecule?
H22-
He22+
He2+
H2-

Answer
8. Which of the following c o m p o u n d s contain(s) no covalent bond(s)?
KCl, PH 3 , O 2 , B 2 H 6 , H 2 SO 4

KCl, B 2 H 6
KCl, B 2 H 6 , PH 3

KCl, H 2 SO 4

KCl
Answer

9 . T o t a l n u m b e r o f l o n e p a i r o f e l e c t r o n s i n I - i o n is
3

12

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 4 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

3
6
9
Answer
10. H ydr ogen per oxide oxidises Fe(CN)6]4- to [Fe(CN)6]3- in acidic m e d i u m b u t reduces [Fe(CN)6]3-
to [Fe(CN)6]4- in alkaline m e d i u m . The other products f o r m e d are, r espectively

H O a n d ( H O + O H -)
2 2

(H2O + O2) a n d H2O

( H O + O ) a n d ( H O + OH - )
2 2 2

H2O a n d (H2O + O2)

Answer
1 1 . W h e n m e t a l ‘ M ’ is t r e a t e d w i t h N a O H , a w h i t e g e l a t i n o u s p r e c i p i t a t e ‘ X ’ is o b t a i n e d , w h i c h is s o l u b l e i n
e x c e s s o f N a O H . C o m p o u n d ‘ X ’ w h e n h e a t e d s t r o n g l y g i v e s a n o x i d e w h i c h is u s e d i n c h r o m a t o g r a p h y as a n
a d s o r b e n t . T h e m e t a l ‘ M ’ is
Fe
Zn
Ca
Al

Answer
1 2 . T h e r e c o m m e n d e d c o n c e n t r a t i o n o f fl u o r i d e i o n i n d r i n k i n g w a t e r is u p t o 1 p p m as fl u o r i d e i o n is r e q u i r e d
to m a k e t e e t h e n a m e l har der by conver ting [3Ca3 (PO4)2.Ca(OH)2] t o

[ 3 { C a ( O H ) 2 } . CaF2]

[CaF2]

[3( C aF 2 ) . C a ( O H ) 2 ]

[3C a 3 ( PO 4 ) 2 . C a F 2 ]

Answer
1 3 . F or 1 m o l a l a q u e o u s s o l u t i o n o f t h e f o l l o w i n g c o m p o u n d s , w h i c h o n e w i l l s h o w t h e h i g h e s t f r e e z i n g p o i n t ?
[Co(H2O)3 Cl3].3H2O

[Co(H2O)6]Cl3

[Co(H2O)5Cl] Cl2.H2O

[ C o ( H 2 O )4C l2 ] C l. 2 H 2O

Answer
1 4 . H o w l o n g ( a p p r o x i m a t e ) s h o u l d w a t e r b e e l e c t r o l y s e d b y p a s s i n g t h r o u g h 1 0 0 a m p e r e s c u r r e n t so t h a t t h e

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 5 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

o xyg e n released can co m p le t e ly burn 27.66 g of diborane? (Atomic w e ig h t of B = 10.8 u)

1.6 hours
6.4 hours
0.8 hours
3.2 hours
Answer
15. Consider the following reaction and s t a t e m e n t s :
[ C o ( N H 3 ) 4 B r 2 ] + + Br - →[ C o ( N H 3 ) 3 B r 3 ] + N H 3

( I ) T w o i s o m e r s a r e p r o d u c e d if t h e r e a c t a n t c o m p l e x i o n is a c i s - i s o m e r
( I I ) T w o i s o m e r s a r e p r o d u c e d if t h e r e a c t a n t c o m p l e x i o n is a t r a n s - i s o m e r
( I I I ) O n l y o n e i s o m e r is p r o d u c e d if t h e r e a c t a n t c o m p l e x i o n is a t r a n s - i s o m e r
( I V ) O n l y o n e i s o m e r is p r o d u c e d if t h e r e a c t a n t c o m p l e x i o n is a cis – i s o m e r
The correct st a t e m e n t s are

(II) a n d ( I V)
(I) a n d (II)
(I) a n d (III)
(III) a n d ( I V)
Answ er

1 6 . A n a q u e o u s s o l u t i o n c o n t a i n s a n u n k n o w n c o n c e n t r a t i o n o f B a 2 + . W h e n 5 0 m L o f a 1 M s o l u t i o n o f N a SO is
2 4

a d d e d , BaSO 4 j u s t b e g i n s t o p r e c i p i t a t e . T h e fi n a l v o l u m e is 5 0 0 m L . T h e s o l u b i l i t y p r o d u c t o f B a S O 4 is 1 x

1 0 – 1 0 . W h a t is t h e o r i g i n a l c o n c e n t r a t i o n o f B a 2 + ?

1.0 x 10–10 M

5 x 10–9 M

2x10–9 M

1.1 x 10–9M
Answer
17. At 518C the r ate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 3 6 3 Torr,

w a s 1 . 0 0 T o r r s – 1 w h e n 5 % h a d r e a c t e d a n d 0 . 5 T o r r s – 1 w h e n 3 3 % h a d r e a c t e d . T h e o r d e r o f t h e r e a c t i o n is

2
3
1

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 6 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answer
18. The trans-alkenes are f o r m e d by the reduction of alkynes w it h
Sn - H C l

H 2 – Pd/C, Ba SO 4

NaBH4

Na/liq. NH3

Answer

19. Which t y p e of ‘defect’ has the presence of cations in the interstitial sites?
Metal deficiency defect
Schottky defect
Vacancy defect
Frenkel defect

Answer
2 0 . A n a q u e o u s s o l u t i o n c o n t a i n s 0 . 1 0 M H 2 S a n d 0 . 2 0 M HCl. If t h e e q u i l i b r i u m c o n s t a n t s f o r t h e f o r m a t i o n o f

HS– f r o m H S is 1 . 0 x 1 0 –7
and t h a t of S
2- –
f r o m HS i o n s is 1 . 2 x 1 0
–13
t h e n the concentr at i on of S ions in
2-
2

a q u e o u s s o l u t i o n is

5 x 10-19
5 x 10-8

3 x 10–20

6 x 10-21
Answer
2 1 . T h e o x i d a t i o n s t a t e s o f Cr i n [ C r ( H 2 O ) 6 ] C l 3 , [ C r ( C 6 H 6 ) 2 ] , a n d K 2 [C r ( C N ) 2 ( O ) 2 ( O 2 ) ( N H 3 ) ] r e s p e c t i v e l y a r e :

+ 3 , + 2 , and + 4
+ 3 , 0, and + 6
+ 3 , 0, and + 4
+ 3 , + 4 , and + 6
Answer
22. Which of the following c o m p o u n d s will be suitable for Kjeldah1’s m e t h o d for nitr ogen estimation?

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 7 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answer
2 3 . G l u c o s e o n p r o l o n g e d h e a t i n g w i t h HI g i v e s
6-iodohexanal
n-Hexane
1-Hexene
Hexanoic acid
Answer

2 4 . T h e i n c r e a s i n g o r d e r o f b a s i c i t y o f t h e f o l l o w i n g c o m p o u n d s is:

(d) < (b) < (a) < (c)

( a ) < ( b ) < ( c) < ( d )
( b ) < ( a ) < ( c) < ( d )
(b) < (a) < (d) < (c)
Answ er

2 5 . P h e n o l r e a c t s w i t h m e t h y l c h l o r o f o r m a t e i n t h e p r e s e n c e o f N a O H t o f o r m p r o d u c t A. A r e a c t s w i t h B r 2 t o

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 8 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

f o r m p r o d u c t B. A a n d B a r e r e s p e c t i v e l y :

Answer
26. T h e m a j o r p r o d u c t f o r m e d i n t h e f o l l o w i n g r e a c t i o n is:

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 9 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answ er

2 7 . P h e n o l o n t r e a t m e n t w i t h CO 2 i n t h e p r e s e n c e o f N a O H f o l l o w e d b y a c i d i fi c a t i o n p r o d u c e s c o m p o u n d X a s

t h e m a j o r p r o d u c t . X o n t r e a t m e n t w i t h ( C H 3 C O) 2 O i n t h e p r e s e n c e o f c a t a l y t i c a m o u n t o f H 2 SO 4 p r o d u c e s :

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 1 0 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answer
2 8 . T h e m a j o r p r o d u c t o f t h e f o l l o w i n g r e a c t i o n is,

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 1 1 o f 1 2
 Chemistry Exam
JEE 2018 Year
2018
Study, Assignments, Solved Previous Year Papers . Questions and Answers. Free Forever.

Answ er

2 9 . T h e c o m p o u n d t h a t d o e s n o t p r o d u c e n i t r o g e n g a s b y t h e t h e r m a l d e c o m p o s i t i o n is
( N H 4 ) 2 SO 4

Ba(N3)2

( N H 4 ) 2C r2O7

NH4NO2

Answer
3 0 . W h i c h o f t h e f o l l o w i n g s a l t s is t h e m o s t b a s i c i n a q u e o u s s o l u t i o n ?
Pb( C H 3 C OO) 2

Al( C N ) 3

C H 3 COOK

F e C l3

Answer

Like. Share. B o o k m a r k . D o w n l o a d . M a k e Notes. Print - Your F avour ite Questions. Join w w w . z i g y a . c o m

Page 1 2 o f 1 2