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Lecture 21
Deformation Behaviour and
Strength of Ceramic Materials
Ref: Kingery, Introduction to Ceramics, Ch14, John Wiley & Sons, 1991
Richerson, Modern Ceramic Engineering, Dekker, 1992
Topics to discuss....
Rocksalt [NaCl, KCl, KBr, LiF, MgO] and fluorite [CaF2, UO2]
cubic structures show some degrees of deformation
Rocksalt structure:
Slip occurs along {110} planes in [110] directions
The motion involved a minimum
distance of slip to restore the original
structural arrangement
Ions of similar polarity remain at
maximum distance from each other,
in order to avoid having to overcome
a large repulsion energy barrier
(a) (b)
Thus, plastic deformation
Fig. 4: Slip for crystals with rocksalt structure
will not occur unless In the <110> direction on (a) {110} plane, (b) {100} plane.
1. electrostatic balance is retained {110}<110> glide is preferred.
2. structural geometry is not altered
3. cation-anion ratio is maintained
Fig.5: Stress-strain curve for KBr and MgO Fig.6: Effect of solute concentration on stress-
single crystals tested in bending strain curve of MgO-NiO system
Limited plastic deformation through dislocation motion can
also occur in more complex, less symmetrical single crystals
ceramics.
Yield stress is much higher
mechanism of slip is more complex and restrictive
Eg ½
Estimation of theoretical strength:
(required to break atomic bond and pull a structure sth = a0
apart under tensile loading)
g = fracture surface energy
a0 = interatomic spacing
KIC
sTS = sTS = tensile strength
p am
Engineering ceramics
sTS 200 MPa Cement and concrete
KIC 2 MPa m1/2
Pottery, brick, stone
sTS 2 MPa
2am 60 mm Full of cracks and voids
( 5-20% porosity) This indicates the presence of at least
About same size of one crack a cm or more in length
original particles 2am Several mm long
E = E0 (1 - 1.9P + 0.9P2)
sfs = s0 exp(-nP)
where s0 is the flexural
strength with no porosity,
and n is a material
constant, depends on
distribution and
morphology of pore
Resulted due to
High-temperature grooving
Post-fabrication operations
Accidental damage during service
Basic principle:
To generate a surface layer with a higher volume than the original matrix
Common methods:
1. Incorporating an outer layer with lower coefficient of thermal expansion
(glaze technology, tempering in glass)
2. Using transformation stresses (zirconia ceramics)
3. Physically stuffing outer layer with ions/atoms (ion implantation)
4. Ion exchanging (smaller ions for larger ions)
Due to this outer compressive layer, a tensile stress is developed
at the inside of material
If any flaw propagates through the compressive layer, material fails more easily
than the materials without a compressive layer.
E.g., Tempered glass for car wind shield (release of residual stresses cause the
glass to shatter)
Temperature / atmosphere