Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
N.Kishorekumar
Assistant Professor
Mechanical Engineering Dept
AITS.
LOCALIZED PARTICLES
• Donors, Acceptors, and Deep Traps
Donors
• When a type V atom such as P, As, or Sb, which has five electrons in
its outer or valence electron shell, is a substitutional impurity in Si it
uses four of these electrons to satisfy the valence requirements of the
four nearest-neighbor silicons, and the one remaining electron
remains weakly bound. The atom easily donates or passes on this
electron to the conduction band, so it is called a donor, and the
electron is called a donor electron.
METAL NANOCLUSTERS
JELLIUM MODEL
• It envisions cluster as a large atom.
• Positive nuclear charge of each
Cluster is assume to be uniformly
distributed over a sphere the size of
the cluster.
• Interaction of electron with positive
sphere is described as a spherically
symmetric potential well.
• Energy levels can be obtained by
solving Schrodinger equation.
A comparison of energy levels of
hydrogen atom and Jellium model of
clusters
• Orbital calculation based on the
density functional method predict
that the Icosahedral form has lower
energy than other forms.
• In late 1970s and early 198s, G.D.
Stien determine the structure of BiN,
PbN, and AgN nanoparticles.
• Deviation from FCC were observed
for cluster smaller than 8 nm in
diameter.
Some calculated structure of small
Boron nanoparticles
ELECTRONIC STRUCTURE
• DENSITY OF STATES: it refers to the no of
energy levels in a given interval of energy.
• Moving from bulk to small metal clusters
density of states changes dramatically.
• The continuous density of states in band Illustration of how energy levels of metal
changes when no. of atoms of the material is reduced
is replaced by a set of discrete energy
levels.
• Clusters of different sizes will have
different electronic structures, and
different energy level separations.
Mass spectrum of Al nanoparticles before (left) and after (right) exposer to oxygen gas
• shows that the reaction rate of
iron with hydrogen is as a
function of size of the iron
particles.
• A group of Oksaka National
Research institute in Japan
discovered that high catalytic
activity is observed to switch on
for Gold nanoparticles smaller
then 3-5 nm, where the structure
is icosahedral instead of bulk Reaction rate of hydrogen gas with iron nanoparticles versus
the particle size.
arrangement.
MAGNETIC CLUSTERS
PROPERTIES OF NANOPARTICLES
STRENGTH OF NANO CRYSTALLINE SIC
• The mechanical properties like flexural strength and the fracture toughness have
been studied on a sintered silicon carbide, which is prepared by the pressureless
sintering route from the nano crystalline silicon carbide particles of an Acheson
type α-SiC that is processed by high energy attrition grinding route.
• The average flexural strength is found to be 390 MPa and the average fracture
toughness is found to be 4.3 MPa . m1/2
• Usually, the dense silicon carbide materials have lower strength compared to
silicon nitride materials. The latter experience a degradation of strength at 1200°C
- 1300°C, while silicon carbide materials do not show any decrease of strength up
to 1500°C.
• Weibull statistics as it is typical for many other ceramic materials
Most of earlier work is based on a 4-point bending test. Depending on the
manufacturer and the type of silicon carbide, the average room temperature strength
varies between 350 and 550 MPa. For such cases, the Weibull modulus which is a
measure of the 'dispersion' in strength varies between 6 and 15 depending on the
strength of the ceramic materials.
• Schwetz and Lipp also studied the effect of the dopants on the flexural
strength. They observed that the materials doped with aluminium had a higher
strength than that doped with boron, and with the improvement in the processing
parameters, it would be as strong as the 'hot-pressed' SiC materials. They also
found that the production of the materials with ultrafine grains occurred in a very
narrow range of sintering temperature (2050-2075°C). The exaggerated grain
growth at temperatures above 2075°C was the cause of the reduction in strength of
boron doped materials. The materials sintered with aluminium nitride, which acted
as a grain growth inhibitor, showed a higher strength
• The Weibull distribution is one of the most widely used lifetime distributions in
reliability engineering. It is a versatile distribution that can take on the
characteristics of other types of distributions, based on the value of the shape
parameter
MECHANICAL PROPERTIES
• Comparison of Mechanical Data of α- and β-SiC
• Flexural Strength of α-SiC
• Microstructure
Comparison of Mechanical Data of α- and β-SiC