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For examples,
– Lithium
– Sodium
– Potassium
– Rubidium
– Caesium
– Fransium
• They are also known as alkali metals
which react with water to form
alkaline solutions.
In general:
X2 + H2O HX + HOX ; X is halogen
Example:
Cl2 + H2O HCl + HOCl
Hydrochloric hypochlorous(I) acid
acid
Group 17 Elements - Chemical Properties
b) Halogens in gaseous state react with
hot iron
• To form a brown solid , iron (III) halides
In general:
2 Fe + 3X2 2FeX3 ; X is halogen
Example:
2 Fe + 3Br2 2FeBr3
Group 17 Elements - Chemical Properties
c) Halogens react with sodium hydroxide
solution , NaOH.
• To form sodium halide, sodium halate and water
• The halogens are decolourised during these reaction
In general:
X2 + NaOH NaX + NaOX + H2O ; X is halogen
Example:
2NaOH + I2 NaI + NaOI + H2O
sodium iodide sodium iodate(I)
• Chlorine, Bromine and Iodine have similar
chemical properties but differ in reactivity. Why
they have the similar properties??
Proton number 9 17 35
Proton number 9 17 35
3. Act as catalysts
• Transition elements or compounds can act as
catalysts in certain reactions.
• Catalysts are chemicals which can increase the
rate of a chemical reaction
Transition element Process Product
Iron Haber Process Ammonia
Vanadium (V) oxide Contact Process Sulphuric acid
Platinum Ostwald Process Nitric acid
F. Elements in Period
1. Properties of Elements in Period 3
Proton
Number 11 12 13 14 15 16 17 18
Electron
arrangement 2.8.1 2.8.2 2.8.3 2.8.4 2.8.5 2.8.6 2.8.7 2.8.8
Atomic
Radius (pm) 186 160 143 118 110 104 100 94
Physical state
at room
temperature Solid Solid Solid Hjklh
Solid Solid Solid Gas Gas
Electronegati
vity 0.9 1.2 1.5 1.8 2.1 2.5 3.0 -
Based on the table above, we notice the trends of changes across Period 3,
i. The proton number increases by one unit from one element to the next
element.
ii. All the atoms of the elements have three shells occupied with electrons.
iii. The number of valence electrons in each atom increases from 1 to 8.
iv. All the elements exist as solid except chlorine and argon which are gases.
1. Properties of Elements in Period 3
Element of
Period 3 Na Mg Al Si P S Cl Ar
Proton
Number 11 12 13 14 15 16 17 18
Electron
arrangement 2.8.1 2.8.2 2.8.3 2.8.4 2.8.5 2.8.6 2.8.7 2.8.8
Atomic
Radius (pm) 186 160 143 118 110 104 100 94
Physical state
at room
temperature Solid Solid Solid Hjklh
Solid Solid Solid Gas Gas
Electronegati
vity 0.9 1.2 1.5 1.8 2.1 2.5 3.0 -
Based on the table above, we notice the trends of changes across Period 3,
v. The atomic radius of elements decreases. This is due to the increasing nuclei
attraction on the valence electrons.
vi. The electronegativity of elements increases. This is also due to the increasing
nuclei attraction on the valence electrons and the decrease in atomic size.
Properties of oxides elements
• Elements of periods 3 can be classified into
metals or non-metals based on the basic or
acidic properties of their oxides.
• Metal form oxides with basic properties.
• Non- metal form oxides with acidic properties.
• Some metals show both acidic and basic
properties.
• These oxides are known as AMPHOTHERIC
OXIDES.
• Na and magnesium form basic metal oxides:
Na2O, MgO.
• Aluminium ,form amphoteric oxide: Al2O3.\
• Silicon, Phosporus, sulphur and chlorine form
acidic non-metal oxides.
• Refer figure 4.10(pg 74).
• The properties of the oxides of elements in P3
change frm basic properties the acidic properties
when going across the period.
2. Acid-base properties of oxides of elements in Period 3.