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TEAM
William Kelly, Maxy Nwosu, Tuyet Nguyen,
Cole Clabough, Joseph Amoabeng, Sabrina Smith
May 2, 2017
Crude Blend
Our Process
Atm Tower
Desalter
Pre-Frac Tower
Pre-Frac Tower
Vac
Tower
Vac Tower
Aspen Simulation
• Property Method: Grayson
Aspen Technology,Inc. ASPEN PLUS User Guide: ASPEN PLUS Release 9. Cambridge,
Massachussetts: Aspen Technology, 1994. Print.
Why choose a Pre-Frac?
• 21 stages
• 50 MBBL/D Light Naphtha
• Inlet Temp: 425°F
• Condenser, no reboiler
• Height: 53 ft.
• Diameter: 33 ft.
Pre-Frac Tower Results
Kaes, Gerald L. Refinery Process Modeling: A Practical Guide to Steady State Modeling of
Petroleum Processes (using Commercial Simulators). Athens, GA: Athens Printing, 2008. Print.
Money Saved is Money Earned
Atmospheric Column
• 40 Stages
• Inlet Temp: 650°F
• 3 Pumparounds
• 3 Strippers
• Height: 93 ft.
• Diameter: 31 ft.
Atmospheric Results
http://blog.jazzfactory.in/2010/07/how-to-present-excel-tables-in.html
Vacuum Tower
• 17 Stages
• Inlet Temp: 760°F
• 2 Pumparounds
• No reboiler or
condenser
• ASTM D1160 95%
• Large vapor volumes
for feed rate
• Height:98 ft.
• Diameter: 39 ft.
http://www3.aiche.org/proceedings/content/Annual-2013/extended-abstracts/P318278.pdf
http://www.koch-glitsch.com/Document%20Library/KGSP.pdf
Vacuum Tower Results
Kaes, Gerald L. Refinery Process Modeling: A Practical Guide to Steady State Modeling of
Petroleum Processes (using Commercial Simulators). Athens, GA: Athens Printing, 2008. Print.
CONTINUOUS CATALYST
REGENERATION (CCR) REFORMER
WHY CCR????
• Produces higher octane number
• Less shut down time
• Operates at lower pressure
• Uses catalyst with less stability but higher selectivity
and yield
• Produces more reformate with higher aromatic
content
• Steady production of hydrogen with constant purity
Feed Characteristics
Le-Goff, P. Y., and J. Lopez. "Special Report Refining Developments - Axens." Www.axens.net.
Axens, Sept. 2012. Web. 1 May 2017.
Reactor Specifications
http://nptel.ac.in/courses/103107082/module6/lecture6/lecture6.pdf
Reactor Structure
Iranshahi, Davood, Mohsen Karimi, Shahram Amiri, Mitra Jafari, Razieh Rafiei, and Mohammad Reza
Rahimpour. "Modeling of naphtha reforming unit applying detailed description of kinetic in
continuous catalytic regeneration process." Chemical Engineering Research and Design 92.9 (2014):
1704-727. Web.
Why Radial Flow Reactor????
Heat Integration
• Cold Streams • Hot Streams
• Desalter Feed • Pre-Frac Off Gas
• Pre-Fractionation • Wet Gas
Tower Feed • Light Naphtha
• Heavy Naphtha
• Atmospheric Tower
• Kerosene
Feed
• Diesel
• Vacuum Tower Feed • AGO
• Vacuum Tower Off Gas
• Light Vacuum Gas Oil
• Heavy Vacuum Gas Oil
• Vacuum Bottoms
Limitations & Considerations
• Minimum Approach temperature: 10 deg.
Celsius
• Avoid Temperature Crossing
• Reducing heat duty needed from hot utility
(high pressure steam)
• Mass flow rates & Heat Capacities (m*Cp)
• Utility cost vs. Equipment Cost
Turton, Richard, Richard C. Bailie, and Wallace B. Whiting. Analysis, synthesis, and design of chemical
processes. Upper Saddle River, NJ: Pearson Education International, 2015. Print.
Heat Integration Streams
Temperature Interval Diagram
Composite Curves
Heat Exchanger Calculations
Heat Integration
Atmospheric Feed
Vacuum
Feed
Savings From Heat Integration
• Utility Required without Integration:
$153 million per year
• Utility Required with Integration:
$79 million per year
• Savings:
$74 million per year
48.36% utilities saved
SAFETY
•Safety incidents in refineries can be very
costly in terms of human and infrastructure.
• 180 Injuries
• $2 Billion
• Mechanical Integrity
http://www.csb.gov/bp-america-refinery-explosion/
Tesoro Refinery Explosion, 2010
• 7 Fatalities
• $40 Million
• Lack of Oversight
• Mechanical Integrity
http://www.csb.gov/tesoro-refinery-fatal-explosion-and-fire/
Safety Assurance
How to minimize safety risks ?
•Mechanical Integrity
•Safety culture.
OBJECTIVE
The following areas will be scrutinized and
examined to ensure proper adherence to safety
in all the refinery expansion units:
•Oversight and Coordination
•Heat Exchanger
•Furnace
CCR Reactor
1. Toxic Release
•Gas monitors
•Fire and gas detection system
2. Catalyst Poisoning
3. Combustion Hazards
•Purging
•Burner valves
•Safety control systems
HEAT EXCHANGERS
1. Fouling
•Regular inspection and cleaning
2. HTHA prevention
•Use of appropriate M.O.C ( low alloy steel
over copper steel)
•Inspection via pyrometer
FIRED HEATERS
Safety systems to prevent:
1. Fuel accumulation
•Explosions
2. Overheating or Overfiring
•Metallurgical impact
http://www2.emersonprocess.com/en-us/brands/deltav/sis/applications/pages/bms.aspx
Distillation Towers
1. Liquid detection and relief systems
•Prevent overpressure
2. Control systems
•Liquid level detection
3. Corrosion control
•NH3/Alkaline solution injection
Environmental
• Construction Permitting
• Operating Permitting
• Regulations on Major Emission Sources
Environmental Permit-
Construction
AIR WASTE
WETLANDS MARINE
AIR
https://www.tceq.texas.gov/
Environmental Permit- Air
TITLE V PERMIT
https://www.tceq.texas.gov/
Economics
The light and heavy crude; Algerian Condensate and Dalia were used for this expansion. The
plant was assumed to operate for 330 days out of the year. These crudes were priced using
the WTI index and market data.
Amount
Cost of Crude Total Cost of Raw
Price per BBL Purchased per Days
per year Materials
day (BBL)
Dalia Crude $42.69 226302 330 $3,188,074,685 $5,140,600,079
Algerian
Condensate $55.25 98698 330 $1,799,511,285
Crude Breakdown
Below is the breakdown of the product produced for the process. 273MBD of our crude
product was produced from the 325MBD of Dalia and Algerian Condensate fed into the
process.
● 22 MBD Gasoline
● 26 MBD Diesel
● 41 MBD Kerosene
● 17 MBD Atmospheric Gas Oil
● 31 MBD Heavy Naphtha
● 16 MBD Heavy Vacuum Gas Oil
● 32 MBD Heavy Naphtha
● 50 MBD Light Naphtha
● 69 MBD Light Vacuum Gas Oil
● 51 MBD Vacuum Resid
Revenue Breakdown
Amount Produced per Estimated Sell
Products Day Days Operating Price Profit per day Profit per year
Gasoline 22014 330 $61.54 $1,354,742 $447,064,715
Diesel 26195 330 $62.93 $1,648,432 $543,982,715
Kerosene 41696 330 $65.10 $2,714,377 $895,744,427
AGO 16747 330 $60.76 $1,017,542 $335,788,743
Heavy
Naphtha 31915 330 $54.25 $1,731,389 $571,358,288
Light Naphtha 50000 330 $48.83 $2,441,500 $805,695,000
HVGO 16000 330 $58.59 $937,440 $309,355,200
LVGO 68506 330 $58.59 $4,013,767 $1,324,542,958
Vac Resid 50936 330 $28.21 $1,436,905 $474,178,505
• Utility Cost with the use of heat integration and the addition of
the pre-frac
$177,536 861 USD
$0.60 $0.54
$0.50 $0.43
$0.40 $0.30
$0.30
$0.20 $0.15
$0.10
$-
$(0.10) 0 1 2 3 $(0.01)
4 5 6 7 8 9 10 11 12
$(0.20) $(0.15)
$(0.30) $(0.21)
$(0.40) $(0.29)
$(0.50) $(0.42)
$(0.60)
$(0.70)
$(0.80)
$(0.90)
$(1.00)
Year
Thank
You!