DEFENCE ENGINEERING COLLEGE

THERMODYNAMICS
MV2011
BASIC CONCEPTS OF
THERMODYNAMICS
Definition, Meaning and Application of
Thermodynamics
 The name thermodynamics stems from the Greek words therme
(heat) and dynamics (power), which is most descriptive of the early
efforts to convert heat into power.
 Today the same name is broadly interpreted to include all aspects
of energy and energy transformations, including power generation,
refrigeration, and relationships among the properties of matter.
Thermodynamics is the branch of physical science that deals with
the various phenomena of energy and related properties of matter,
especially of the laws of transformations of heat into other forms of
energy and vice-versa.
 Or in simple words Thermodynamics is a branch of science which
deals with energy.
For analyzing any system, there are basically two approaches available
in engineering thermodynamics
 Macroscopic (Classical thermodynamics) is the one in which
complete system as a whole is considered and studied without
caring for what is there constituting the system at microscopic level.
• study large number of particles (molecules) that make up the
substance in question
• does not require knowledge of the behavior of individual
molecules
 Microscopic (Statistical thermodynamics) is one having
fragmented the system under consideration up to microscopic level
and analyzing the different constituent subsystems or
Microsystems.
• concerned within behavior of individual particles (molecules)
• study average behavior of large groups of individual particles
 Concepts and Definitions (Vocabulary)
 Thermodynamic system is the quantity of matter or a region of space
chosen for study.
 Surroundings is the physical space outside the system or it is defined as
every thing that surrounds the system.
 Boundary is real or imaginary layer that separates the system from its
surroundings.
 Universe is the system and its surroundings together.

= Universe

Fig. 1 System, Surroundings, Boundary and Universe

Application of thermodynamics
Application of thermodynamics
Application of thermodynamics
Application of thermodynamics
 Thermodynamic systems
 Based on the energy and mass interactions of the systems
with surroundings/other systems across the boundary the
system can be classified as the open, close, and isolated
system.
 Open system is the one in which energy and mass interactions
take place at the system boundary, for example automobile
engine.
 Closed system is the one in which only energy interactions
take place at its boundary, for example boiling water in a
closed pan.
 Isolated system is the one in which neither mass interaction
nor energy interaction take place across the system boundary,
for example Thermos Flask
1.2
Thermodynamic Properties
 Any characteristic of a system in equilibrium is called a property.
 Some familiar properties are pressure P, temperature T, volume V,
and mass m.
 Extensive properties are properties that vary directly with the size
of the system.
Examples: volume, mass, total energy
 Intensive properties are properties that are independent of the size
of the system.
Examples: temperature, pressure, color
State & Equilibrium
 If a system is Considered as not undergoing any change then all
the properties can be measured or calculated throughout the
entire system which gives us a set of properties that completely
describes the condition. At this point its said a state of the
system.
 State Postulate
– The thermodynamic state of a simple compressible substance
is completely specified by two independent intensive
properties.

 The word equilibrium implies a state of balance.

 In an equilibrium state there are no unbalanced potentials (or
driving forces) within the system.
 Thermal equilibrium is when the temperature is the same
throughout the entire system.
 Mechanical equilibrium is related to pressure, and a system is in
mechanical equilibrium if there is no change in pressure at any
point of the system with time.
 If a system involves two phases, it is in phase equilibrium when
the mass of each phase reaches an equilibrium level and stays
there.
 A system is in Chemical equilibrium if its chemical composition
does not change with time, that is, no chemical reactions occur.
 A system is in Thermodynamic equilibrium when the conditions
of all the relevant types of equilibrium are satisfied.
 Processes & cycle
 Any change that a system undergoes from one equilibrium state to
another is called a process.
 The series of states through which a system passes during a
process is called the path of the process.
 some special processes:
• isobaric process - constant pressure process
• isothermal process - constant temperature process
• isochoric process - constant volume process
• isentropic process - constant entropy process
 A Cycle process is a process (or a series of connected processes) in
which the initial state and final state are identical.
 Process
P 2 B

A Process

Process
A

A Cyclic process
V
 When a process proceeds in such a manner that the system remains
infinitesimally close to an equilibrium state at all times, it is called a
quasistatic, or quasi-equilibrium, process.
 A quasi-equilibrium process can be viewed as a sufficiently slow
process that allows the system to adjust itself internally so that
properties in one part of the system do not change any faster than
those at other parts.
 When a gas in a piston-cylinder device is compressed suddenly, the
molecules near the face of the piston will not have enough time to
escape and they will have to pile up in a small region in front of the
piston, thus creating a high-pressure region there and is not in
equilibrium However, if the piston is moved slowly, the molecules
will have sufficient time to redistribute and the pressure inside will
rise at the same rate at all locations. Since equilibrium is maintained
at all times, this is a quasi-equilibrium process.
Steady flow processes
 The term steady implies no change with time.
 The opposite of steady is unsteady, or transient.
 The term uniform implies no change with location over a
specified region.
 large number of engineering devices operate for long periods
of time under the same conditions, and they are classified as
steady-flow devices.
 Processes involving such devices can be represented
reasonably well by a somewhat idealized process, called the
steady-flow process, which can be defined as a process
during which a fluid flows through a control volume steadily.
During a steady-flow process, fluid properties within the control
volume may change with position but not with time.
Zeroth Law of Thermodynamics
 Zeroth law of thermodynamics states that if the bodies A and B
are in thermal equilibrium with a third body C separately then
the two bodies A and B shall also be in thermal equilibrium with
each other.
 By replacing the third body C with a thermometer, the zeroth
law can be restated as two bodies are in thermal equilibrium if
both have the same temperature reading even if they are not in
contact.
Measurement of temperature, pressure,
density & specific gravity
 All temperature scales are based on some easily reproducible
states such as the freezing point (ice point) and boiling point
(steam point) of water.
 A mixture of ice and water that is in equilibrium with air saturated
with vapor at 1 atm pressure is said to be at the ice point, and a
mixture of liquid water and water vapor (with no air) in
equilibrium at 1 atm pressure is said to be at the steam point.
 The temperature scales used in the SI and in the English system
today are the Celsius scale and the Fahrenheit scale.
 On the Celsius scale, the ice and steam points were originally
assigned the values of 0 and 100°C, respectively and the
corresponding values on the Fahrenheit scale are 32 and 212°F.
 In thermodynamics, it is very desirable to have a temperature scale
that is independent of the properties of any substance or
substances.
 Such a temperature scale is called a thermodynamic temperature
scale.
 The thermodynamic temperature scale in the SI is the Kelvin scale,
designated by K .
 The thermodynamic temperature scale in the English system is the
Rankine scale designated by R.
 The Kelvin scale is related to the Celsius scale by

 The Rankine scale is related to the Fahrenheit scale by

 The temperature scales in the two unit systems are related by

 The lowest temperature on the Kelvin scale is absolute zero, or 0 K.
 Note that in thermodynamic relations involving temperature T. If
the relation involves temperature differences (such as a = b∆T), it
makes no difference whether it is in K or °C and either can be used.
 However, if the relation involves temperatures only instead of
temperature differences (such as a = bT) then K must be used.
Pressure
 Pressure is defined as a normal force exerted by a fluid per unit
area.
 The counterpart of pressure in solids is normal stress.
 It has the unit of newtons per square meter (N/m2), which is called
a pascal (Pa).
 Three other pressure units commonly used in practice, especially
in Europe, are bar, standard atmosphere, and kilogram-force per
square centimeter:
 The actual pressure at a given position is called the absolute
pressure, and it is measured relative to absolute vacuum (i.e.,
absolute zero pressure).
 Most pressure-measuring devices, however, are calibrated to read
zero in the atmosphere and so they indicate the difference
between the absolute pressure and the local atmospheric pressure.
 This difference is called the gage pressure.
 Pressures below atmospheric pressure are called vacuum pressures
and are measured by vacuum gages that indicate the difference
between the atmospheric pressure and the absolute pressure.
 Absolute, gage, and vacuum pressures are all positive quantities
Absolute, gage, and vacuum pressures
Density
 Density is defined as mass per unit volume.

 The reciprocal of density is the specific volume v, which is

defined as volume per unit mass. That is,

 The density of a substance, in general, depends on temperature

and pressure. The density of most gases is proportional to
pressure and inversely proportional to temperature.
 Liquids and solids, are essentially incompressible substances, and
the variation of their density with pressure is usually negligible.
Specific Gravity
 Specific gravity or relative density is defined as the ratio of the
density of a substance to the density of some standard substance at
a specified temperature (usually water at 4°C,for which density of
water is 1000 kg/m3).

 Note that the specific gravity of a substance is a dimensionless

quantity.