Physical chem

State function
• All state functions are independent of path
• Eg:temperature,pressure
• Because their value does not reply on path

• Eg on path dependent function: Heat,Work

• Path dependent function depend on how you go from state 1 to state 2

• Determine state function

Ideal gas
• Compressibility factor,z=1
• pV=n RT
• pV= mRT/M
• pV= ɐRT /M
Thermal expansion
coefficient&Isothermal
compressibility coefficient
• Thermal expansion:pressure is fixed
• Thus the change is per unit volume

• Isothermal:Temperature is fixed
• Thus, the change is per unit volume
Ideal gas
• Low density
• Do not interact during collision
• (N is number of molecules)