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HOMOGENEOUS HETEROGENEOUS
SYSTEM SYSTEM
BULK SUSPENSION POLYMERIZATION
POLYMERIZATION
EMULSION POLYMERIZATION
SOLUTION
POLYMERIZATION
PRECIPITATION
POLYMERIZATION
polymer
not very reactants are usually
exothermic of low activity
Step-growth
polymerization = polimerisasi
kondensasi
Solution
the viscosity
• In solution polymerization, the monomer,
initiator, and resulting polymer are all soluble in
the solvent.
• Solution polymerization may involve a simple
process in which a monomer, catalyst, and
solvent are stirred together to form a solution
that reacts without the need for heating or
cooling or any special handling.
• On the other hand, elaborate equipment may
be required.
• For example, a synthetic rubber process using a
coordination catalyst requires rigorous exclusion of air
(to less than 10 ppm), moisture, carbon dioxide, and
other catalyst deactivators from the monomer,
solvent, and any other ingredient with which the
catalyst will come in contact before the reaction.