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ELECTROCHEMICAL
PHYSICAL
CHEMICAL CORROSION RESISTANCE METALLURGICAL
THEMODYNAMIC
BASIC CORROSION PROCESS
THE LESS NOBEL METAL BECOME ANODE (POSITIVE ELECTRODE)
WHILE MORE NOBLE METAL ACT A CATHODE( NEGATIVE ELECTRODE)
electrical path
electrolyte (soil)
cathode anode
Conventional current
HOW CORROSION TAKES PLACLE
Conventional current flow ( + to v)
e- e-
e- e- e- H2 Fe(OH)2 OH- Fe+
e- H+
e-
cathode
e- e- H2
H+ e-
Iron anode
Fe(OH)2 OH- Fe+
At Anode:
2H2O (OH)- +H + + 2e-
FE + + 2(OH) - FE(OH)2
FE(OH)2+ FE + + (OH) - FE2(OH)3
At Cathode
2e- + H + H(atom)
H +H plarisation film
CARROSSION CONTROL METHODS
Passive method : Coating
Continuous film of Electrically insulating material over the metal
surface to isolate it from surrounding electrolyte
Anode
Anode Cable
+
CP unit
-
Cathode Cable
Anodic Area
Cathodic Protection Design for MSV
Primary Protection:
Coating
2 : Current requirement
30% of the surface area (considering bare area), current density @10mA/Sqmt
3: Anode flex Selection and length calculation (50 years design life)
Anode flex (1500-1 ) standard rating 52mA/mt for 20 years
Anode flex derated to 20.8mA/mt for 50 years
Length calculated and distributed in no. of strings (33mt Hazira)