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Group 32
ADITHA OKTARIANY| FITRIANI MEIZVIRA| IVA RAUDYATUZZAHRA| RICKY|
YUGO WIDHI NUGROHO| ZHOFRAN BINTANG
CHAPTER I
INTRODUCTION
Background
Background
Indirect emissions from burning fossil fuels to heat the kiln can be
reduced by switching to alternative fuels.
Efficiency measures can reduce the demand for fuel by addressing the
production process itself or through technical and mechanical
improvements.
Reducing emissions from the calcination process means looking to a
material other than limestone.
CO2 emissions can be captured after they are produced through carbon
capture and storage (CCS).
CHAPTER I
INTRODUCTION
Literature Review
Raw Material Analysis
Cement Manufacturing
Limestone
Component Percentage
SiO2 40-60
Al2O3 20-30
Fe2O3 4-10
CaO 5-30
Loss on Ignition 0-3
Iron Ore
Supplier
Raw
Supplier Price /unit
Materials Location Travel Time
Company (Rp)
CV Red
Limestone Cilegon 1 day Rp300/kg
Production
Fly Ash Cilegon PLTU Suralaya 1 day Rp500/kg
CV Kharisma
Iron Ore Surabaya 2 days Rp900/kg
Nusantara
PT
Gypsum Gresik Metabisulphite 2 days Rp300/kg
Nusantara
Market Analysis
Indonesia Cement Supply and Demand Indonesia Cement Future Supply and Demand
120 500
450
100
400
350
300
60 250
200
40 150
100
20
50
0
0
2017 2018 2019 2020 2021 2022 2023 2024 2025 2026 2026
2011 2012 2013 2014 2015 2016 2017
Year
Year
Supply Demand
Supply Demand
Overseas Cement Demand
Below are the facts that should be concerned regarding plant location:
Availability of raw material
Infrastructure facilities
Environment and climate conditions
Labour force availability
Based on that fact, we choose Jln. Narogong km 18, Kp. Rawa hingkik,
Limusnunggal, Desa Pasir Angin, Cileungsi, Bogor, West Java.
CHAPTER II
PROCESS SELECTION
Process Synthesis
Process Alternatives and Description
Process Selection
Process Synthesis
Mainly limestones
Grinding the Uniform materials are then fed to the
cement kiln
raw materials
Clinker Substitution
Heuristic 1: Select raw materials and chemical reactions to avoid, or reduce, the
handling and storage of hazardous and toxic chemical.
Based on this heuristic, Fuel Substitution and CCS have good potential because it
does not involve any toxic materials.
For Clinker Substitution. our choice is fly ash, residue from coal combustion, at
some point is being debated whether it is environmentally safe or not, but recent
studies show that the toxic materials in fly ash is binded and sealed upon reaction
with another cementitious material. In conclusion, the benefit of fly ash in cement
making weighs more than its drawbacks, and with suitable handling and material
scheduling, the possible harm of fly ash can be diminished.
Process Selection
Advanced Process
P 1Q 1P 1 0,333333 P 1Q 1P 1 0,25
Q 2Q 3 0,75
Q 1R 1 0,333333
R 0 0
R 1 0,333333
TOTAL 3 1 TOTAL 4 1
P 1P 2P 3 0,75 P 1Q 2P 2 0,5
Q 1Q 1 0,25 Q 1Q 2 0,5
R 0 0 R 0 0
TOTAL 4 1 TOTAL 4 1
Final Score
A B C D TOTAL %
Material Substitution Fuel substitution Crushing Grinding Blending Raw Mill Silo
The process
The cooled
Raw meal is heated to a to capture
clinker is
certain temperature (1350- flue gas
grinded
1450oC) until CaCO3 is The cooling produced in
together
thermally decomposed to process of the process
with
CaO. Pre-heaters are used to clinker, to and
gypsum, to
make the process more tempe- separating
reach a
efficient and also making use rature the fly ash
certain
of the very hot gas that about from the gas
composition
coming out from the kiln. 150oC. to be the
of good
material in
cement
The output is called clinker. manufacture
product.
process.
B
Block Flow Diagram
F
D
Stream Information
Stream Name
No Stream Name No Stream Name No Stream Name No
Cement to packaging
2 Limestone and iron ore 7 Raw meal 12 17 Palm shell
station
4 Gypsum 9 Clinker 14 Exhaust gas to ESP 19 Dried coal and palm shell
5 Activated fly ash 10 Cooled clinker 15 ESP exit gas 20 Fuel to kiln
P
Block Flow Diagram
F
D
Stream Information
CHAPTER III
MASS AND ENERGY
BALANCE
Mass Balance
Mass Balance for Limestone Jaw Crusher
Components
Type of Reactant
Reaction No. List of Reactions
Reactions Conversion
Input Output
Components
Clinker Gypsum Recycled Cement
C2S 604.40 0 28.78 575.62
C3S 352.52 0 16.79 335.73
C3A 333.65 0 15.89 317.77
C4AF 86.81 0 4.13 82.68
CaCO2 1469.87 0 69.99 1399.88
SiO2 72.89 0 3.47 69.42
Al2O3 99.04 0 4.72 94.32
Fe2O3 22.46 0 1.07 21.39
MgCO3 34.10 0 1.62 32.48
MgO 20.75 0 0.99 19.76
Inerts 55.29 0 2.63 52.66
CaO 0 34.91 1.66 33.25
H2O 0 22.43 1.07 21.37
SO3 0 49.84 2.37 47.47
Total 3151.78 107.19 155.19 3103.78
CO2 from Fuel Combustion
Total 1375.32
Temperatures
Cliinker Analysis (Loss Free oC
TC Feed entering kiln
Basis) oC
TSa Secondary air
TPa Primary air oC
HSi Percent SiO2 % oC
TBe Kiln exit gas
HAl Percent Al2O3 % oC
TSt Cooler stack
HFe percent Fe2O3 % oC
TCl Clinker at cooler exit
HCa Percent CaO % oC
TF Fuel as fired
HMg percent MgO %
Average shell,lower
HS percent SO3 % oC
TZ1 third
percent alkalies (total as
Average shell,middle
HAlk Na2O) % oC
TZ2 third
HIg percent Ignition loss %
Average shell,upper
TZ3 third oC
T Kiln room oC
Heat Balance
Enthalpy Enthalpy
Input Stream % Output Stream %
kcal/kg.clinker kcal/kg.clinker
17 11
Heat Inputs from the 646.48 64.67 Heat Required for clinker 419.29 41.95
Combustion of Fuel cooling
17
9
Heat Inputs from Sensible 0.73 0.07 567.85 56.81
Heat Loss with kiln exit gas
Heat in Fuel
8 9a
Heat Input from Sensible Heat 285.94 28.61 Heat Loss Due to Moisture in 73.27 7.33
In Kiln Feed Feed or Slurry
10 11
Heat Input from Cooler Air 18.12 1.81 Heat Loss with Clinker at 27.75 2.78
Sensible Heat Cooler Discharge
9
11
Heat input from Primary Air 1.10 0.11 131.27 13.13
Heat Loss at Cooler Stack
Sensible heat
11
Heat Losses By radiation on 23.78 2.38
Kiln Shell
Unaccounted losses -269.54 -26.96
Total 999.60 100 Total 999.60 100
Overall Energy Balance
(Simulation Result)
Equipment In (kJ/h) Out (kJ/h) Requirement (kJ/h)
2 3
CR-101 0.00.E+00
-9.8476.E+08 -9.8476.E+08
1 5
MI-101 0.00.E+00
-3.277E+08 -3.277E+08
3 6
MI-102 0.00.E+00
-9.848E+08 -9.848E+08
5 7
-3.277E+08
BR-101 -4.000E+04
6 -1.313E+09
-9.848E+08
7 8
CY-101 8.810E+07
-1.313E+09 -1.224E+09
8 10
RK-101 7.374E+08
-1.224E+09 -4.870E+08
10 11
E-101 -6.928E+08
-4.870E+08 -1.180E+09
11 12
MI-103 0.00.E+00
-1.180E+09 -1.180E+09
15 16
DR-101 0.00E+00
-3.572E+07 -3.572E+07
16 17
MI-104 0.00E+00
Energy Required per 1 kg Product
kJ
132,630,000 24
h
= 1,043.92
3043 1000
CHAPTER III
MASS AND ENERGY
BALANCE
Process Simulation
Cement Manufacturing Process Simulation
Fuel Combustion Process Simulation
CHAPTER IV
HEAT INTEGRATION
Heat Integration Network
Energy Integration in Cement Plant
In this plant, whole materials processed are in the form of solids. There is little amount
of heat transfer found in the main process because most of the process in the plant is
mechanical.
Because the main stream is solid, it is impossible to use heat exchanger to recover heat from
stream. So, instead of applying HEN using mentioned method above, the heat integration in the
plant is applied in the overall process.
The heat integration is created through the flue gas usage from the clinker that is transferred to
the preheater cyclones. Hot gas that has been used in calcination process still has much enthalpy
in it, so instead of releasing it right away, it is moved to the preheater cyclones to heat the raw
meal.
Cyclone Preheater
Fuel
Utility: Fuel
Fuel
Coal 22950 0.7 13288.51582 422347000
Target Duty is the power requirement for rotary kiln. Total Mass is substituted by any
value at first, and then the Fuel Requirement will be calculated by multiplying NHV
and mass percentage. Duty column will be calculated by multiplying NHV and Fuel
Requirement. After that, by using Goal Seek feature in Excel, the value in Duty is set to
Target Duty, to acquire Total Mass from the fuel.
By knowing the Total Mass, Fuel Requirement column will calculate mass needed for
each fuel.
CHAPTER V
UTILITY
Electricity
EQUIPMENT ELECTRICITY REQUIREMENT
To prevent power outage, there should be built a power generator that might be used if there
is any disturbance and electricity failure from Perusahaan Gas Negara. Diesel power generator
is a common type of power generator that has been used by many cement plant, since solar
fuel has a higher calorific value and lower carbon dioxide emission than the coal fuel.
To count the total fuel and cost required, the SAIDI ( system average interruption duration
index) and SAIFI (system average interruption frequency) should be known first, we can get it
from data that surveyed and issued by BPPT in 2013, for West Java Province the SAIDI number
is 1.22 and for the SAIFI number is 1.89
Specifications Value
Type 3612
Frequency 50 Hz
Fuel Diesel
Solar cost from Pertamina is about IDR 8,200.00 per Liter for industrial category. So, the total
cost for electricity need in this basis is:
Fuel (Solar) Cost = IDR 8,200/L 2975 L = IDR 24, 395, 000.00
CHAPTER VI
Conclusion
Conclusion
Cement is manufactured through several steps such as crushing, grinding, preheating, pre-calcining, clinker
production in rotary kiln, cooling and storing.
The cement plant is located in Cileungsi, Bogor, West Java.
The plant capacity is 911,448.25 per year or 3,103.8 tonnes cement per day.
The process selected to develop low carbon cement is by substituting limestone in clinker with fly ash, and
substituting coal as fuel by biomass.
The chosen process has lower CO2 emission compared to average CO2 emission by 55.4%
Total energy requirement per 1 kg cement is 1,043.92 kJ.
The main stream is solid, it is impossible to use heat exchanger to recover heat from stream. So, instead of applying
HEN, the heat integration in the plant is applied in the overall process
The plant needs fuel for 18.98 ton/hour, rounded up to 19 ton/hour, with coal 13.29 ton/hour and biomass 5.7
ton/hour.
Total annual plant operation electricity requirement is 31,410.324 MWh
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Thank You