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reduction
of
NOx
KUSHAGRA ABHISHEK
11/CH/25
WHAT IS NOX
NOX - Family of SEVEN Nitrogen compound
(NO,NO2,N2O2,N2O3,N2O,N204,N2O5)
Of these NO2 is surrogate of this family of compound as it is most prevalent form
of NOx in the atmosphere generated by anthropogenic activities.
Combustion sources
Automobiles
Boilers
Incinerators
High-temperature industrial operations
Metallurgical furnaces
Blast furnaces
Plasma furnaces
Kilns
Other sources
Nitric acid plants
Industrial processes that use nitric acid
NOX EFFECTS:
formation of ozone
Acid rain
Toxic chemicals
Global warming
Causes visibility impairment.
Deteriorates water quality
4 NO 4 NH 3 O2 TiO
2 4 N 2 6 H 2O
or V2O5 supportedcatalyst
2 NO2 4 NH 3 O2 TiO
2 3N 2 6 H 2O
or V2 O5 supportedcatalyst
3)Efficiency Up to 95 %.
SCR THE PROCESS
Catalyst used in SCR for reduction of NOx
Titanium oxide
Oxide of base metals like vanadium and tungsten
Zeolites
Etc
Aqueous ammonia
must be hydrolyzed in order to be used, but it is substantially safer to store and
transport than anhydrous ammonia.
Urea
the safest to store, but requires conversion to ammonia through thermal
decomposition in order to be used as an effective reductant
Limitations of SCR:
The most common limitation of SCR in power plants is the ammonia slip
emission of ammonium sulfate and ammonium bisulfate
Very high capital cost
High operating cost
Catalyst bed increases pressure drop
Possible water wash Required
High Space requirements
Conclusion: