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3.1IntroductiontoIndustrialHygiene
3.2ChemicalSafetyManagement
3.3IndoorAirQuality
3.4WorkinginConfinedSpace
HEALTH HAZARDS
Chemical agents
Gases,vapours,solids,fibres,liquids,
dusts,mists,fumes,etc.
Physical agents
Noiseandvibration
Heatandcold
Electromagneticfields,lightingetc.
Biological agents
Bacteria,fungi,etc.
Ergonomic factors
Lifting,stretching,andrepetitivemotion
Psychosocial factors
Stress,workloadandworkorganisation
EVALUATION
EVALUATIONoftheextentofexposuretothechemicalhazards,
physicalorbiologicalagents(oradverseergonomicsituation)inthe
workplace.Thisofteninvolvesmeasurementofthepersonal
exposureofaworkertothehazard/agentintheworkplace,
particularlyattherelevantinterfacebetweentheenvironmentand
thebody,e.g.breathingzone,hearingzone,andassessmentofthe
dataintermsofrecommendedoccupationalexposurelimits(OELs),
wheresuchcriteriaexist.
CONTROL
CONTROLofthechemical,physicalorbiological
agent-oradverseergonomicsituation,by
procedural,engineeringorothermeanswherethe
evaluationindicatesthatthisisnecessary.
Exposure
Occupational
Hygiene
Occupational
Health
Disease
Occupational
Medicine
HistoryofOccupationalHygiene
Ca400BCHippocratesin
ancientGreecefirstnotedillness
inmercurysulphideworkers.
1890s-HaldaneundertakesworkonthetoxicityofCarbon
Monoxidebyexposingratsmiceandevenhimselftovarying
concentrationswithinanexposurechamber.
Heusedtheseresultstodevelop
dosevtimeplotsforseverityand
discomfortofhealtheffects.
Heintroducestheuseofsmall
animalsandinparticularCanaries
asthefirstwayofmonitoringtogive
anindicationofthelevelsoftoxic
gas.
1917-Duringthefirstworldwar,theurgencyoftheworkinmunitionsfactoriesled
topoorworkingconditions.
TheworkoftheHealthofMunitionsWorkersCommitteelaidthe groundformany
subsequentpracticesinergonomics,psychology,welfareandshift-workregimes.
1920s-30s - Industrial hygiene develops and grows in the USA in both the
PublicHealthService(PHS)andlargeprivatecompanies.Thesedevelopments
laythefoundationsforthecreationoftwoprofessionalorganisations.
1953-BritishOccupationalHygieneSociety(BOHS)founded.Societystarts
publishingAnnalsofOccupationalHygienein1958.
1970s - Occupational Safety and Health Act in the USA and the Health
and Safety at Work Act in the UK lay the path for Risk Assessment /
performancebasedlegislation.
1980/90s-ThepracticeofoccupationalhygienegrowswidelyintheUSA,
UK, The Netherlands and Australia with legislation in these countries
beingintroducedspecificallytofocusonchemicalandphysicalhazards.
Thatmeansapproximately228peoplehave
diedfromworkrelatedinjuryorillhealthsince
westartedanhourago.
Theyarenotanindexoftoxicity
Theydonotrepresentafinedemarcationbetweengoodandbadpractice.
Theyarebasedonthecurrentbestavailableinformationandareliableto
change.
Ifthereisnotahygienestandardsetforachemicalsubstance,itdoesnot
meanthatsubstanceissafe.
Goodoccupationalhygienepracticeistokeepairbornecontaminantstoas
lowalevelaspossible,nottojustbelowtherelevanthygienestandard(s).
Theyapplytooccupationalexposureofadults.Theyarenotapplicableto
environmentalexposurewheremoresusceptiblegroupsexiste.g.pregnant
women,children,infirm.
Forchemicalstheygenerallyrelatetoairborneconcentrationsi.e.theyonly
takeintoaccounttheinhalationrouteofentry.
Theygenerallyrefertosinglesubstances,althoughsomeguidancemaybe
givenonmixedexposures.
Country / Union
TLVThresholdLimitValue
USA
MAK-MaximaleArbeitsplatz-Konzentration
Germany
MAC
Russia
WELWorkplaceExposureLimit
UnitedKingdom
IOELVs(IndicativeOccupationalExposureLimitValue)
Europe
OESOccupationalExposureStandards
Australia
WESWorkplaceExposureStandards
NewZealand
Byvolume-atmosphericconcentrationinpartsper
million(ppm)
Byweight-milligramsofsubstancepercubicmetreof
air(mg.m-3).
mg=mg/m3=mgm-3
m3
Concbyweight(mg.m-3)=Concbyvolume(ppm)xMolecularweight(g)
24.06
at20Cand760mmHg(1atmospherepressure)
Concbyvolume(ppm)
Concbyvolume(ppm)
=Concbyweight(mg.m-3)x24.06
Molecularweight(g)
Ceiling Limitsaresometimesusedandareconcentrationsthatshouldnot
beexceededduringanypartoftheworkingexposure.
Synergistic substances:knowncasesofsynergismare
considerablylesscommonthantheothertypesofbehaviourin
mixedexposures.
Additive substances:wherethereisreasontobelievethatthe
effectsoftheconstituentsareadditive,andwheretheWELSare
basedonthesamehealtheffects,themixedexposureshouldbe
assessedusingaformula.
Independent substances:wherenosynergisticoradditiveeffects
areknownorconsideredlikely,theconstituentscanberegardedas
actingindependentlyandthemeasuresneededtoachieve
adequatecontrolassessedforeachseparately.
(C1xT1)+(C2xT2)+.+(CnxTn)
8
Where:
Cnistheoccupationalexposure
Tnistheassociatedexposuretimeinhoursinany24-hourperiod.
Theoperatorworksfor6h00minonaprocessinwhichheisexposedtoa
substancehazardoustohealth.Theaverageexposureduringthatperiodis
measuredas0.5mgm-3.Theoperatorthenworksforafurther1hourinwhich
heisexposedto1.5mgm-3.
Whatisthe8-hourTWA
Theoperatorworksfor6h00minonaprocessinwhichheisexposedtoa
substancehazardoustohealth.Theaverageexposureduringthatperiodis
measuredas0.5mg.m-3.Theoperatorthenworksforafurther1hourinwhich
heisexposedto1.5mg.m-3.
Whatisthe8-hourTWAthereforeis:
6h00min(6.00h)at0.5mgm-3
1h00min(1.00h)at1.5mgm-3
1h00min(1.00h)at0.0mgm-3
Thatis:
(0.5x6.00)+(1.5x1.00)+(0x1.00)=0.56 mg m-3
8
Exposureshouldberecordedastheaverageoverthespecifiedshort-termreference
period(usually15minutes)andshouldnormallybedeterminedbysamplingoverthat
period.
Iftheexposureperiodislessthan15minutes,thesamplingresultshouldbe
averagedover15minutes.Forexample,ifa5minutesampleproducesalevelof150
ppmandisimmediatelyfollowedbyaperiodofzeroexposurethenthe15-minute
averageexposurewillbe50ppm.
Thatis:
5x150=50ppm
15
Complimentarytechniquetoairmonitoring.
Biologicalmonitoringisthemeasurementandassessmentof
hazardoussubstancesortheirmetabolitesintissues,excretaor
expiredairinexposedworkers.
Measurementsreflectabsorptionofasubstancebyallroutes.
Particularlyusefulwhereexposureisbyroutesotherthaninhalation
InmostcaseslimitsforBiologicalMonitoringarenotstatutory.
Biologicalmonitoringundertakenneedstobeconductedona
voluntarybasis(i.e.withthefullyinformedconsentofall
concerned).
Occupational Hygiene
PRINCIPLES
Anticipation
Recognition
Evaluation
Control
...of chemical,physical, or biological
agents arising from work activities
so as to prevent or reduce risks to
health
ANTICIPATION OF RISK
DURINGDESIGNSTAGEOFAPROCESS/
EQUIPMENTORFORMULATIONOFCHEMICALS
ORBEFORESTARTINGPROCESSORWORK
OPERATIONS
ANTICIPATEPOTENTIALHEALTHRISKS:
Processcharacteristics
Physicochemicalproperties
Possiblehealtheffects
Pastexperiences
Similarityofthechemicalstructuretoa
knownhazardouschemical
RECOGNITION OF HAZARD
INFORMATION
Material-
Inventory,CSDS/MSDS,specification
Process
Processflow&description
Plantlayout
Equipment
Specification
IDENTIFICATION TECHNIQUES
WORKPLACEOBSERVATION
-Sourceofhazard
-Workpractice
-Natureofexposure
-Existingcontrols
IDENTIFICATION TECHNIQUES
FEEDBACK
-Management&supervisors
-Workers
-Companydoctor/industrialnurse
HEALTHRECORDS
-Poisoning&diseasecases
-Prevalence
EVALUATE RISKS
ESTIMATEEXPOSURE
Qualitatively
Quantitativemeasurementorsampling
Frequency,duration,magnitude
CHARACTERISERISK
Applyexposurestandards
Acceptableornot
Tocontrolornot
QUALITATIVE ASSESSMENT
OF HEALTH RISK
EXPOSURE
HAZARD
LOW
MEDIUM
HIGH
LOW
VERY LOW
RISK
LOW
RISK
MODERATE
RISK
MEDIUM
HIGH
EXPOSURE STANDARDS
LimitsBelowWhichWorkersMayBe
ExposedToHealthRisksWithout
ExperiencingAnyAdverseHealthEffects
UsefulInMakingDecisionWhetherTo
InstituteControlMeasures
P.E.L.,TLV(USA),MEL&OES(UK)
MALAYSIAN EXPOSURE
STANDARDS
CHEMICALS
PermissibleExposureLimits(PEL)underF&M(Lead)
Regulations1984
PELunderF&M(AsbestosProcess)Regulations1989
PELunderF&M(MineralDust)Regulations1989
PELunderOSH(USECHH)Regulations2000
TIMEWEIGHTEDAVERAGE(TWA)
CEILING
MAXIMUMEXPOSURELIMITS(MEL)
NOISE
PELunderF&M(NoiseExposure)Regulations1989
CONTROL OF RISK
Whenriskisunacceptableorwhen
exposurelimitsareexceeded
ApproachesToControllingRisk:
-EliminateorreducehazardattheSource
-InterventionatthePath
-ProtecttheReceiver
PRINCIPLE OF CONTROL
SOURCE
PATH
Distance
Barrier
Dilution
RECEIVER
Controlroom
Workpractice
Awareness/Attitude
Surveillance
PersonalProtection
Elimination
Substitution
Enclosure
Engineeringcontrol
HIERARCHY OF
CONTROL MEASURES
Elimination
Of Risk
Substitution
Total Enclosure
Isolation Of Risk
Modification Of Process
Engineering Methods
Safe Work System & Procedure
Personal Protection
ENGINEERING CONTROLS
Minimisingexposuresbytheapplicationof
engineeringprinciples
Suchastheuseof
generalordilutionventilation
localexhaustventilation
waterspray
Allowschemicalemissionstomixwiththe
workroomair
then
dilutestoacceptableexposurelevels
Air Movement
Generation
LOCAL EXHAUST
VENTILATION
LEVSystemIsASystemTo
RemoveContaminantsAtIts
PointOfGenerationSoAsTo
PreventInhalationByWorkers
DUCTING
AIR
CLEANER
HOOD
FAN
DEFINITION OF PPE
-USECHH Regulations
PERSONALPROTECTIVE
EQUIPMENT(PPE)MEANS
Any equipment which is intended to
be worn or held by a person at work
& which protects him against one or
more risks to his health or safety &
any additional accessory designed to
meet that objective
When
ImpracticableApplicationOfOther
ControlMeasures;
AsAnInterimMeasure;
ComplementaryToOtherControl
Measures
PERSONAL PROTECTIVE
EQUIPMENT
HEAD&FACEPROTECTION
Helmets,goggles,safetyglasses,face
shield
HEARINGPROTECTION
Earmuffs,earplugs
Disposable,reusable
PERSONAL PROTECTIVE
EQUIPMENT
RESPIRATORYPROTECTION
Oxygendeficientatmosphere
Particulateorgas/vapour
Dust
RESPIRATORY
PROTECTION
Fume
O2 21%
Gas
1 % Others
N2 78%
Mist
Vapour
Smoke
PERSONAL PROTECTIVE
EQUIPMENT
BODY
Apron,uniform,protectivesuits
HANDPROTECTION
Glove,barriercream
Physicalorchemicalresistant
LEGPROTECTION
Safetyshoes,Wellingtonboots