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Documenti di Professioni
Documenti di Cultura
Text Book:
Applied Chemistry: A Textbook for Engineers and
Technologists by: O.V. Roussak H. D. Gesser: 2013 edition:
Springer
Reference Books:
Chemistry, The Central Science, Theodore L. Brown et al.
13th Edition (2014)
Physical Chemistry (3rd Edt.) by Thomas Engel and Philip
Reid : Prentice Hall, (2013)
Chemistry for Engineering Students (William H. Brown and
Lawrence S. Brown), Cengage Learning; 2 edition (2010)
Essential of Physical Chemistry 19th Edition by Arun Bahl, B
S Bahl & G D Tuli : S. Chand Publishing, India
Easiest part
Convert measurements
Rearrange
Reasonable?
Read the question, did you
answer it?
Check your work
Estimate
Conceptual Problems
Lets Start!!
and dont forget what
happened in
Engineering
Materials!!!
Unit
Any standard measure used to
express a physical quantity is a unit
Convenient size (not too large or too small)
Universally followed
Easily reproducible
System of units
(1) FPS Foot, pound and second
(2) CGSCentimetre, gram and second
(3) MKSMetre, kilogram and second
(4) SIModified form of MKS. System in which besides
metre, kilogram and second, kelvin,candela,
ampere and mole are also used to express
temperature,luminous intensity, electric current
and quantity of matter
Metric system
Fundamental units of metric
systems:
Mass
Gram
Length
Meter
Volume
Litre
(i) Accuracy
(ii) Precision
% of tin in an alloy are 3.65,
3.62 and 3.64
% of tin determined by another analyst are 3.72, 3.77 and
3.83.
Which set of the measurement is more precise?
Precision is expressed without any sign.
Significant Figures
Significant figures in 1.007,
12.012 and 10.070 are 4, 5 and
5 respectively.
Significant figures are the meaningful digits in a measured
or calculated quantity.
Rules to determine
significant figures
i.
Matter
Matter occupies space and mass.
Solid
Matter
Liquid
Gas
Com
2
H
O
2
H
O
22
2
p
u
n
dE
le
m
n
ts
Compound
For example,
Mixture
Mixture contains two or more
components.
i.
ii.
Illustrative Problem
Which of the following is not a homogeneous
mixture?
(a) A mixture of oxygen and Nitrogen
(b) Brass
(c) Solution of sugar in water
(d) Milk
Solution
Milk
Milk contains solid casein protein particles and water.
Hence answer is (d).
H2 + Cl2
2g
71g
2 HCl
73g
Illustrative
Problem
8.4 g of sodium bicarbonate on reaction with
20.0 g of acetic acid (CH3COOH) liberated 4.4 g
of carbon dioxide gas into atmosphere. What is
the mass of residue left?
Solution
8.4 + 20 = m + 4.4
m = 24 g
It proves the the law of conservation of mass.
Ice water
H2O
1:8
1:8
Sea water
1:8
H2O
Illustrative Problem
Two gaseous samples were analyzed.
One contained 1.2g of carbon and
3.2 g of oxygen. The other contained
27.3 % carbon and 72.7% oxygen. The
above data is in accordance with, which law?
(a)Law of conservation of mass
(b)Law of definite proportions
(c)Law of multiple proportions
(d)Law of reciprocal proportions
Solution
1.2
100 27.3%
1.2 3.2
Which is same as in the second sample.
Hence law of definite proportion is obeyed.