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CHEE 3201
CHAPTER-1
INTRODUCTION
TO MASS TRANSFER
By
MR.C.MARIMUTHU
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MASS
A
Mass
But
Mass
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WEIGHT
"Heaviness".
Even
For example
grams, kilograms and, tones (Metric) and
pounds (US units)
1 Kilogram = 2.204 pounds.
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Course Objective
The course should enable the student to
understand the fundamental Principles
and applications of Mass Transfer
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Course Resources
Mass
Unit
Transport
INTRODUCTION
Mass
INTRODUCTION
Occurrence of Mass Transfer
Concentration Gradient
Ceases at equilibrium
Need for Mass Transfer
Reacting
system
due
to
incomplete conversion
Separation of components from a
mixture
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Transfer Operations
Depends on type of phases
involved
Phases
Mass
Transfer Operations
Types of
Operations
GasLiquid
Absorption,
Desorption,
Humidification,
Dehumidification, Distillation
Extraction
LiquidLiquid
SolidLeaching,
Liquid/G Desorption,
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as
Crystallization
Adsorption,
Drying,
CHEE 3201, HCT MUSCAT
Flow
Similarities in M T Operations
Attainment
of equilibrium
Mass transfer both by diffusion
and convection or turbulence
High rate of mass transfer with
high rate of deviation from
equilibrium
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is a Gas-Liquid Operation
Based on Thermal Energy
Depends on difference in volatility i.e.,
difference in vapor pressure
Example:
Separation of Crude into fractions
Separation of heaving boiling
components using steam
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is a gas-liquid Operation
Useful for component separation from a
gaseous mixture
Needs a new Solvent
Separation depends on solubility of component
Example:
Separation of ammonia from ammonia air
mixture
Removal of hydrogen sulphide from
hydrocarbons by alkali solution
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is a liquid-liquid operation.
It needs solvent which has preferential
solubility with one of the component.
Commonly used when separation is not
possible by distillation
Example:
Separation of penicillin from fermentation
Separation of acetic acid-water mixture
Separation of dioxane from water-dioxane
mixture
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Extraction Column
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is a liquid-solid separation
It needs a super saturated solution
and seed crystal
It provides uniform sized particles
from liquid phase
Example:
Sugar crystal from sugar solution
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Expression of Composition
Gram
It
Weight
For
Weight%
23
Expression of Composition
24
Expression of
Composition
Partial
25
Problems
1.
26
27
28
Boyles law
Boyle's
The
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Boyles law
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Charles's law
Charles's lawstates that if a
given quantity of gas is held at a
constant pressure, its volume is
directly
proportional
to
the
absolute temperature.
V/T =Constant
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Avagadros hypothesis
Avogadro's
For
32
Daltons Law
It states that total pressure of a gas mixture
is equal to partial pressure of gas
components.
Mathematically,
Pt = pA + pB + pc + .
where,
Pt = Total pressure exerted by the gaseous
mixture and pA, pB, pc= partial pressure of
component gases A, B and C
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Raoults Law
It states that the equilibrium pressure
of component A is equal to the
product of the vapor pressure and
mole fraction of A in the liquid phase.
PA = P0A * xA
PA is also related to yA by equation
PA = y A P
yA is the mole fraction of A in the
gas phase.
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Henrys Law
It is applicable for dilute gas liquid
solutions.
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Henrys Law
Mathematically, Henrys law is given as
PA = H x A
Where, H is Henrys law constant.
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Phase Rule
It is the relationship that governs all
heterogeneous equilibrium. It is given
by the relation
F= C-P+2
Where,
C = number of components
P = number of phases &
F= Number of degrees of freedom or
number of intensive variables
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Phase Rule
The degrees of freedom for a system
can
be
temperature,
pressure,
composition that must be specified.
For a system, if degrees of freedom is
fixed, the remaining variables will get
fixed automatically
and makes a
completely defined system.
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Diffusion
It
Molecular
Molecular
39
Diffusion(cont)
The
Mechanical
The
40
Diffusion(cont)
The
molecular
diffusion
phenomena is usually considered
to take place in stationary fluid
i.e., fluid at rest and under
laminar flow.
Diffusion
can be altered by
changing the temperature and
pressure
conditions
in
the
system.
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Diffusion
For
example,
In
42
Molecular diffusion
43
If,
In
Ficks
44
Concentration
There
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Mass concentration:
It
For
46
Molar concentration:
It is the number of moles of species A per unit
volume of the solution.
CA = A/MA
Where,
CA = Molar concentration of species A per unit
volume (moles/m3)
A = Mass concentration of species A per unit volume
(mass/m3)
MA = Molecular weight of component A (mass/mole)
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Molar
concentration(cont):
For a binary mixture, total molar
concentration is
C = CA + C B
Where,
C= Total molar concentration (mole/m 3)
CA = Molar concentration of A (mole/m3)
CB = Molar concentration of B (mole/m 3)
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Molar
concentration(cont):
It
a
gas
mixture,
to
determine
the
concentration
of species in a gas mixture ideal gas law
relation is used.
The
concentration of component is
expressed in terms of partial pressure.
We
49
Molar
concentration(cont):
Similarly for a component A
pAV = nART
OR
CA = nA/V = pA/RT
Where
pA - is the partial pressure of species A in the mixture,
nA- is the number of moles of A in the mixture,
V- is molar volume of the mixture,
T- is the absolute temperature and R is universal gas
constant.
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Molar
concentration(cont):
Rewriting, in terms of mole fraction, xA
XA = CA/C = pA/RT/P/RT = pA/P
Where,
P is the total pressure exerted by the gas mixture.
Total
pressure is also expressed as Pt.
Also, Total concentration, C is
C = CA + CB = pA/RT + pB/RT = P/RT
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Problem
3. A mixture of noble gases (helium, argon,
krypton and xenon) is at a total pressure of
100 kPa and a temperature of 200 K. If the
mixture has equal kmole fractions of each
of the gases,
a) determine Composition of the
mixture in terms of mass fractions.
(b) Total molar concentration of mixture.
(c) Mass density of the mixture .
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Problem
4. Air is stored in a 30 m3 container at 340
K and 101.3 kPa is saturated with water
vapor. Partial pressure of water vapor is
27.35 kPa. Determine the following of the
gas mixture (Molecular Weight of Air =
28.97 and Molecular weight of water=18)
a) Mole fraction of the water vapor
b) Average molecular weight of the mixture
c) Total mass contained in the tank
d) Mass of water vapor in the tank
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Velocities
In
The
54
Velocities(cont)
The
In
The
55
56
57
58
For
59
Diffusion Velocity
diffusion velocity of component in
a
mixture can be expressed either in
terms
of mass average velocity or molar
average
velocity.
1. mass diffusion velocity
2. molar diffusion velocity
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i.e.,
u = ui u
For
Mass
u = uA u
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Molar
For
Molar
62
Fluxes
The flux is defined as the rate of
transport
of species I per unit area in a
direction
normal to the transport. The flux
is
calculated with respect to a fixed
frame of
reference. In mass transfer the flux
can be
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Mass Flux
The
The
The
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Molar Flux
It
The
The
65
Mass
66
Inter-relationship with
various types of Fluxes
show that nA = xAni +jA
We know,
nA = AuA
= A (u+uA-u)
= Au + A (uA- u)
= Au + jA
To
We also know, xA = A/ or A = xA
Therefore,
nA = xA(u) +jA
We know,
ni =iui or ni = iui=u
nA = xAni +jA
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Inter-relationship with
various types of Fluxes
To
We know,
NA = CAuA
=CA (U+uA-U)
= CAU + CA (uA-U)
NA = CAU + JA
We know,
CA =xA C
NA = xACU + JA
We Know,
Ni= Ciui or Ni=CiUi=CU
NA = xA(Ni) + JA
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Ficks law of
diffusion(cont)
Mathematically,
Where,
JA Molar flux of A in the direction of Z
CA -Concentration of A ( in moles of A per unit volume)[ kmol/m 3]
dCA/dZ is concentration gradient in the Z-direction
DAB = Molecular diffusivity or diffusion coefficient for component A
diffusing through B.
Z - Distance in the direction of diffusion in m.
The
70
Diffusivity (DAB)
71
72
JA = - DAB
JA = DAB (CA!-CA2)/(z2-z1)
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Molecular Diffusion in
Gases(cont):
For
an ideal gas,
PV = nRT
OR
n/V = P/RT = C
Where
n is kgmole of A plus B
V volume in m3
T is temperature in K
R =8314.3 Pa m3/kgmole K
If total pressure P is constant, and c is constant, then c can be expressed
as
C= n/v= p/RT or CA1 = nA1/V= pA1/RT
Hence,
JA = DAB (pA1-pA2)/RT (z2-z1)
It has been found that, for a binary gas mixture the diffusivity coefficient of
A
w.r.t B or diffusivity coefficient of B w.r.t A will be equal. i.e., DAB = DBA
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Problems
1.
2.
3.
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76
77
N = cum = NA+NB
um= NA+NB/c
NA = JA+cA/c * (NA+NB)
NA = JA +xA (NA+NB)
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In
The
In
the above case, benzene vapor (A) diffuses through the Air (B) in the tube.
The
Hence
At
point 2 the partial pressure pA2 = 0 since large volume of air is passing by.
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Problem
4.
5.
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But
83
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86
Problems
6.
7.
8.
87
88
binary
(I)
(II)
89
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90
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Chapman-Enskog equation
92
T is temperature in K,
MA, MBare molecular weights of A and B,
P is total pressure in bar and
VA and VB are atomic diffusion volume in
m3.
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Table
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problem
9.
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Liquid Diffusion
96
Rate
The
Hence
97
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Equimolar counterdiffusion
NA = DAB (cA1-cA2)/ (z2-z1) = DAB*cav* (xA1-xA2)/(z2-z1)
where
NA is the flux of A in kgmol A/s.m2;
DAB-the diffusivity of A in B m2/s;
cA1 is the concentration of A in kgmol A /m3 at point 1;
xA1 mole fraction of A at point 1,
cav = (/M)av = (1/M1+2/M2)/2
Where
cav is the average total concentration of A+B in kgmole/m 3,
M1 is the average molecular weight of the solution at point 1 in kg
mass/kg mol
1 the average density of solution in kg/m3 at point 1
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Problems
10. An
10
Diffusion in Solids :
The
10
10
10
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For
The
10
10
Problem:
12. A
10
10
Mass Transfer
Coefficient(cont):
For
This
This
10
Mass Transfer
Coefficient(cont):
The
Mass
11
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where,
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where,
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of component A through
non-diffusing B
(b) equimolar
counter diffusion.
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Or
Where
11
Where
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11
Schmidt Number(Sc):
It is the ratio of momentum diffusivity to the diffusivity for
mass transfer DAB. It is used to characterize fluid flows in
which there is simultaneous momentum and mass
diffusion by convection process. It physically relates the
relative thickness of the hydrodynamic layer and mass
transfer boundary layer.
Sc = Viscous diffusion rate/ molecular(mass) diffusion rate
Sc=/DAB
where:
is the dynamic viscosity of the fluid (Pas or Ns/m or
kg/ms)
is the density of the fluid (kg/m).
DABis the mass diffusivity (m2/s).
It is analogous to Prandtl number in heat transfer.
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Sherwood Number(Sh):
It is called the mass transfer Nusselt
number. It represents the ratio of
convective to diffusive mass transport.
Sh = Convective mass transfer
coefficient/Diffusive mass transfer
coefficient
Sh= kcL/D
where
L is a characteristic length (m)
D is mass diffusivity (m2.s1)
Kc is the mass transfer coefficient (m.s 1)
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12
12
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various analogies:
The various analogies used in
mass transfer are
Reynolds Analogy
2.
Chilton Colburn Analogy
Stanton Number (St):
3.
Taylor Prandtl Analogy
4.
Von Karman Analogy
1.
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Characteristics of Reynolds
analogy:
The assumptions considered are
Only
to Reynolds analogy
f/2 = h/Cpu0=kc/u0
Where,
f
= friction factor
h
= Convective heat transfer coefficient
Cp = Specific heat of fluid
uo= velocity of fluid at leading edge
kc= mass transfer coefficient
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Characteristics of Colburn
Analogy:
The assumptions considered are
Only turbulent core is present
Velocity, temperature and concentration
profiles are same
Pr and Sc are not equal to unity
12
12
Characteristics of Von
Karman Analogy:
In this analogy, the assumptions considered are
presence
12
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Where,
CA is exit concentration
CAo is inlet concentration
CAi concentration at the interface between the wall and gas
The dimensionless W/DABL denotes
W is flow rate in kg/s
L is length of mass transfer section in m.
The above graph is useful for fully developed and parabolic
form of entrance.
On the other hand, for liquids that have small values of DAB,
data follow the parabolic flow line, which is as follows for
W/DABL over 400
CA-CAo/CAi-CAo = 5.5 (W/DABL)-2/3
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Turbulent Flow
For
13
13
13