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Viscoelasticity
Plastics 001
Viscoelasticity
Plastics 001
KEY POINTS:
After reviewing the Viscoelasticity presentation,
students should:
Viscoelasticity
Plastics 001
Overview
Because of the entanglement of the molecules
thermoplastic materials have different properties
compared to other materials like metals.
The polymer chains can slide past each other because
they do not share chemical bonds with the other chains
around them.
Polymer materials have viscoelastic properties
They stretch (elastic) and they flow (viscous)
Viscoelasticity
Plastics 001
Viscoelasticity
If you put a load on a metal rod, it will stretch to a certain
length.
As long as the load does not exceed the yield strength of
the rod, when the weight is removed, the rod will return
to its original length.
This is elastic behavior
If you put a load on a plastic rod, it too will stretch. If you
remove the load quickly the rod may return to its
original length, but if you leave the load on the rod for
a length of time, the polymer chains will slide past each
other and flow to make the rods length longer (an
increase in strain)
The longer the load is applied, the more the rod will
lengthen (the more the chains will have flowed) until
the bar ruptures.
Viscoelasticity
Plastics 001
Viscoelasticity
This cold flow exhibits the viscoelastic nature of
thermoplastic materials.
An increase in length with a constant load over time is
known as creep.
Think of a plastic plant hanger stretching over time
A decrease in stress with a constant strain is known as
stress relaxation.
Think of a plastic cap that loosens as it sits on a
shelf.
If you roll silly putty into a ball, and set it on the desk, it
flattens out by itself. This is viscoelastic behavior.
Gravity causes the molecules to flow to relieve the
stress.
Viscoelasticity
Plastics 001
Viscoelasticity
There are two main things that will affect the
viscoelasticity of a plastic part.
Viscoelasticity
Plastics 001
Viscoelasticity
It is important to remember that Viscoelasticity
only deals with solidified plastic materials.
Viscoelasticity
Plastics 001
Viscoelasticity
Why is viscoelasticity important?
Thermoplastic materials have both long-term and short
term
properties they flow due to stress over time
Most mechanical testing of plastic materials is actually
testing the
materials viscoelasticity how the
plastic flows when different
stresses are applied
Plastics are rate sensitive
It is important to understand the viscoelasticity of
plastic
materials so you know how they will behave
in their intended
application
Viscoelasticity is a fundamental concept of plastic
behavior that you need to understand
Viscoelasticity
Plastics 001
Viscoelasticity
A good way to understand how material factors affect the
viscoelasticity of a polymer is to look at how they are
commonly tested.
Some common mechanical tests performed on most
plastic materials are:
Tensile testing
Impact testing
Viscoelasticity
Plastics 001
Testing - Tensile
In a tensile test, a test bar commonly called a dog-bone
is pulled from one end while the other end is fixed.
Fixed
Viscoelasticity
Testing Tensile
The test machine causes the
moveable grip to move away
from the fixed grip at a
constant rate.
While the grip is moving away, the
equipment measures the force
necessary to maintain the
constant speed and creates a
curve to evaluate the results.
Plastics 001
Viscoelasticity
Plastics 001
Testing Tensile
Some important properties gained from the stress/strain
graph are:
Modulus
Yield stress
Ultimate elongation
Toughness
The stress is the load divided by the cross sectional
area of the test bar and the strain is the
change in length divided by the initial length.
Viscoelasticity
Plastics 001
Testing Tensile
Viscoelasticity
Plastics 001
Testing Tensile
The yield point is taken when the slope of the line is zero
and is sometimes called the zero slope yield.
Viscoelasticity
Plastics 001
Testing Tensile
Viscoelasticity
Plastics 001
Testing Tensile
Viscoelasticity
Plastics 001
Testing Tensile
These figures shows how the curve indicates the material
properties.
Viscoelasticity
Plastics 001
Properties Tensile
How would the tensile properties change:
if the temperature were increased?
if the strain rate (test speed) were increased?
If the molecular weight was higher?
If a filler were added to the material?
If there were a higher level of crystallinity in the
material?
If the material had a higher level of branching?
Viscoelasticity
Plastics 001
Properties Tensile
How would the tensile properties change if the
temperature were
increased?
More free
volume allows
the chains to
flow past each
other easier
Viscoelasticity
Plastics 001
Properties Tensile
How would the tensile properties change if the strain rate
(test speed) were increased?
The polymer chains
dont have time to
slide past each other.
Like
running
Your
fingers
quickly
through
long hair
Viscoelasticity
Plastics 001
Properties Tensile
How would the tensile properties change if the strain rate
(test speed) were increased?
Bar run at 1 in/min strain rate
Viscoelasticity
Plastics 001
Properties Tensile
How would
the tensile
properties
change if
the strain
rate (test
speed)
were
increased?
Run at 1 in/min
Run at 20 in/min
Viscoelasticity
Plastics 001
Properties Tensile
How would the tensile properties change if the strain rate
(test speed)
were increased?
Run at 1 in/min
Run at 20 in/min
Viscoelasticity
Plastics 001
Properties Tensile
Changing the temperature in one direction is comparable
to changing
the test speed in the other
direction in terms of
the effect on the
materials properties.
Viscoelasticity
Plastics 001
Properties Tensile
How would a higher molecular weight affect the tensile
properties?
A higher molecular weight will affect some of the
properties, but typically the modulus does not change
much.
A higher molecular weight increases the entanglement
of the polymer chains, which will increase the
elongation, toughness, and yield strength (slightly).
The modulus is more dependent on the structure
of the molecule and less on entanglement forces,
so it is relatively unaffected by longer chain lengths.
Viscoelasticity
Plastics 001
Properties Tensile
How would adding a filler affect the tensile properties?
Fillers hinder molecular movement, they prevent the
molecules from sliding past one another
Fillers make the material stiffer
Increase modulus and yield strength
Decrease elongation and toughness
Viscoelasticity
Plastics 001
Properties Tensile
How does the amount of crystallinity affect the tensile
properties?
In a semi-crystalline material, a higher level of
crystallinity will provide:
Higher modulus and yield stress
Lower elongation and toughness
Viscoelasticity
Plastics 001
Properties Tensile
How would a higher level of branching affect the tensile
properties?
More shorter branches would cause a higher degree of
entanglement and the material would behave similarly
to if you increased the molecular weight.
Viscoelasticity
Plastics 001
Testing Impact
The most common impact test performed on plastic
materials is probably the notched Izod impact test.
Viscoelasticity
Plastics 001
Testing Impact
A weighted hammer is released and swings through the test bar.
Viscoelasticity
Plastics 001
Testing Impact
A weighted hammer is released and swings through the
test bar.
ABS sample
-note the hinged
break
Polypropylene
sample -note the
complete break
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change:
if the temperature were increased?
if the strain rate (test speed) were increased?
If the molecular weight was higher?
If a filler were added to the material?
If there were a higher level of crystallinity in the
material?
If the material had a higher level of branching?
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if the
temperature were increased?
Impact properties generally increase with a rise in
temperature to a point.
The polymer chains being able to move more easily
allows them to absorb more energy before failure, but
as you approach the melting
temperature the material cannot absorb the energy and
fails sooner.
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if the strain
rate (test speed) were increased?
An increase in the rate of impact will reduce the impact
strength
The chains cannot slide fast enough to absorb the
energy.
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if the molecular
weight was higher?
An increase in molecular weight would provide more
entanglement and definitely allow the material to
absorb more energy before failure?
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if a filler were
added to the material?
The impact properties would change depending on the
same factors that would affect a materials tensile
properties
Amount of filler
Type of filler
Shape and size of the filler particle
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if there were a
higher level of crystallinity in the material?
A higher level of crystallinity generally lowers impact
strength in polymers.
The dense crystal structure does not allow the chains to
slide past each other to absorb as much energy as
when the material is in a random amorphous state.
Viscoelasticity
Plastics 001
Properties Impact
How would the impact properties change if the material
had a higher level of branching?
Small short branches would increase the impact strength
by improving the entanglement, but large branches
could allow the chains to slide too easily making the
material too ductile.
BRITTLE
DUCTI
LE
Viscoelasticity
Plastics 001
Conclusion
Having a firm grasp on the concept of viscoelasticity and
how it affects part properties will provide an
understanding of how plastic materials will behave in
different applications and under different conditions.
As was mentioned previously, this is one of the
fundamental concepts dealing with polymeric material
behavior and you need to understand it if you plan on
working in the plastics industry.
Viscoelasticity
Viscoelasticity
Questions?
Plastics 001