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Doshisha Univ.,Kyoto,Japan
Kaho Matsuoka
Kazuya Okubo
Toru Fujii
1
Backgrounds
1/16
Focus
2/16
Purpose
3/16
Material
method
Bacterial Cellulose produced during vinegar fermentation
(BCV)
Sterilizing
48[h]
BCV
Web-like network
BCV
crashing
(Bacterial Cellulose
produced during
Vinegar fermentation)
4/16
Material method
100[]
1[h]
BCN
running water
BCN
(Bacterial Cellulose
made of Nata de coco )
crashing
Material method
5/16
Bamboo
180[]
0.7-0.8[MPa]
9[times]
NaOH 1[wt%]
100[]
20[min]
Steam exported
NaOHtreatment
BF
BF
crashing
(Bamboo Fiber)
*T. Shito, et al., Bamboo J., 19, 15-23 (2002) **N. Takahashi, et al., Bamboo J., 22, 81-92 (2005)
6/16
Procedure of experiments
BCV
BCN
BF
Process homogenizer
Stone Milling
High Pressure
Homogenizer
MFC
40MPa, 30 cycles
Hot press
Vacuum Filter /
Oven
24h, 70C
7/16
Table 1. All types of materials used in this study
Pre-process
Finish-process
Stone milled
Processhomogenizatio
n
High-pressure
homogenized after preprocess
sBCV
sBCV-h
sBCN
sBCN-h
pBCN
pBCN-h
BF
BF-h
8/16
Experiments
Tearmal Expansion Tests
Shimadzu Thermomechanical Analyzer
Specimens dimensions : L 20mm, W 8mm, T 1.5 mm
Temperature Range 30-100
JIS C2141
Thermal
expansion
heating
Thermal Expansion m
9/16
linear
Thermal Properties
10/16
heating
Stone milling
Process homogenizer
11/16
12/16
The specimens fabricated with sBCVh had good property of bending strength
compared with that with original sBCV.
Effective bending strength was obtained
by high-pressure homogenization.
13
13/16
Bending strength of
sBCN composites
sBCN
sBCN-h
Fracture surface
14/16
15/16
16/16
CONCLUSIONS
The process-homogenization was effective as the pre-process
before high-press homogenization to reduce the coefficient of
thermal expansion.
The BCs (bacterial celluloses), which contained few or no lignin,
were useful for the materials of prove disks to reduce the
coefficient of thermal expansion.
The bending strength of the specimen fabricated with Bacterial
Cellulose was about 220MPa that was equivalent to that of an
aluminum alloy and was enough for the application of prove disk.
Excellent mechanical property was obtained when the highpressure homogenizing technique was applied to the fabrication
of prove disk for semiconductor testing device.
END
Prove Card
IC IC
.
IC LSI
stiffener
10-12mm
0.4
>5000pins
mid
Value of middle layer of ceramic disk
Target Value
Bending strength 160MPa
Youngs Modulus 65Gpa
Hardness 2.2Hv
Coefficients of thermal expansion 9.8ppm/
TOP
MID
BTM
4.4-4.7ppm/
12-13GPa
300-320MPa
9.8 ppm/
65GPa
100-160MPa
Repeatability( )
Technique
Good point
Simple way
Material is stable
Problem
vacuum time is long.
I have to consider about this near future
PC and BC
PC BC
BF
It was find that a part of the web-like network was broken due to high levels
homogenization.
The tests results suggested that local deformation was available into the
gap in the web-like structure of BCN.
Diameter of nano-fiber
sBCV
sBCV-h
sBCN
sBCN-h
43.2nm
14.9nm
33.7nm
8.7nm
Aspect ratio
Aspect ratio=L/d
1. Materials
7/19
Reinforcement 4
4. Bamboo Monofilament
Steam explosion
Steam
High temp.
High pressure
Suddenly
released
Steam
exploded
Monofilament
50m
Steam
High temp.
High pressure
Suddenly
released
Steam
exploded
Pressure MPa
Steam explosion
230oC
160oC
130oC
11 times
60
0.15
0.0
time[min]
Why Biocomposites?
Problems
Persistence of plastics in the environment
Shortage of landfill space
Depletion of petroleum resources
Concern over emissions during incineration( )
Disadvantages
Moisture absorption
Low Density
Cost Advantages
Why Bamboo?
Abundant resource
High growth speed
High strength
Low density
Bamboo pollution
Backgrounds
Prove disk Semiconductor testing devices
made of ceramics not thermally expands
However
the ceramic disk often introduces
engineering problems
The part of the ceramic disk makes cracks due to the brittle behavior of the materials
An alternative is necessary
Cost
Ceramics
500,000yen
Weight
Ceramics
14Kg
Cellulose
2Kg
Another application
I think MFC can use another application
(dish ,small things and so on).
But this research limited prove disk.
So we did not think another application.