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Neutralization Titrations
By: Andie Aquilato
Solutions and
Indicators Used
Slides 2-6
Standard
Variables:
Indicators
Acid/Base
or
Ka = [H3O+][In-]
[HIn]
[H3O+] = Ka[HIn]
[In-]
Indicators (contd)
Indicators (contd)
Commonly Used Indicators
Indicator
pH Range
Acid
Base
Thymol Blue
1.2-2.8
red
yellow
Thymol blue
8.0-9.6
yellow
blue
Methyl yellow
2.9-4.0
red
yellow
Methyl orange
3.1-4.4
red
orange
Bromcresol green
4.0-5.6
yellow
blue
Methyl red
4.4-6.2
red
yellow
Bromcresol purple
5.2-6.8
yellow
purple
Bromothymol Blue
6.2-7.8
yellow
blue
Phenol red
6.4-8.0
yellow
red
Cresol purple
7.6-9.2
yellow
purple
Phenolphthalein
8.0-10.0
colorless
red
Thymolphthalein
9.4-10.6
colorless
blue
Alizarin yellow GG
10.0-12.0
colorless
yellow
Calculating pH in
Titrations of Strong
Acids and Strong Bases
Slides 7-11
Equivalence Point
[OH-] = [H3O+], pH = 7
Choosing
Buffer Solutions
Slides 12-19
Calculating pH of Buffer
Solutions
Calculating pH of Buffer
Solutions (contd)
[HA] cHA
[A-] cNaA
Properties of Buffers
Preparing Buffers
Calculating pH in Weak
Acid (or Base) Titrations
Slides 20-24
Steps
1.
2.
3.
4.
Example Calculation
Determine the pH for the titration of 50.00 mL of 0.1000 M acetic acid after adding
0.00, 5.00, 50.00, and 50.01 mL of 0.100 M sodium hydroxide
HOAc + H2O H3O+ + OAcOAc- + H2O HOAc + OHKa = 1.75 x 10 -5
Starting Point:
[H3O+] = 1.32 x 10-3
pH = -log(1.32 x 10-3) = 2.88
Alpha Values
[OAc-] = Ka[HOAc]
[H3O+]
*substitute mass-balance into the dissociation-constant expression*
0 = [HOAc] = [ H3O+ ]
cT
[H3O+] + Ka
For 1, we rearrange the dissociation-constant expression to:
[HOAc] = [H3O+] [OAc-]
Ka
*substitute mass-balance into the dissociation-constant expression*
1 = [OAc-] = _____Ka________
cT
[H3O+] + Ka