Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Exhaust Temperature
(oC)
Gas Flow
(TPH)
5371 (PA)
485
446
7121 (EA)
536
1070
9171 (E)
543
1484
9351 (FA)
608
2318
13
15
18
22
24
HP Economizer drain
tube
Feed Pipe
Feed Pipe
25
26
Formation of Magnetite:
When carbon steel is exposed to oxygen-free
water, the following reaction occurs:
Fe + 2H2O Fe2+ + 2OH- +H2 Fe(OH)2 + H2 (1)
This reaction is then followed by the Schikorr
reaction where precipitated ferrous hydroxide is
converted into magnetite:
3Fe(OH)2 Fe3O4 + 2H2O + H2 (2)
Dissolution of Magnatite
29
30
Temperature
pH
O2 concentration
Mass flow rate
Geometry
Quality of fluid
Alloys of construction
37
43
44
S + O2 SO2
2H2S + 3O2 2SO2 + 2H2O
2SO2 + O2 2SO3 (V2O5, Fe2O3 catalyzes reaction)
SO2 + O [Atomic Oxygen] SO3
SO3 + H2O H2SO4
47
49
Case 1:
120 MW Oil Fired Boiler
Location: LHS Water Wall
Size : 76.1 x 5.5 mm
Specification: SA210 GR A1
Working Temp. & Pressure: 350C & 90
kg/cm
Service: 254378 Hrs
50
53
54
55
56
57
Conclusion:
Micro examination reveals presence of
copper coloured copper rich phase on the ID
surface and blister edges of the tube. Also
damage due to Hydrogen embrittlement is
observed in the PM, weld and HAZ regions of
the weld joint.
The blisters observed on the OD surface is
attributed to waterside corrosion may be
due to condenser leakage.
The circumferential crack observed near the
fusion line of the butt joint is attributed
Hydrogen embrittlement caused by
waterside corrosion.
Swab analysis shows presence of some
chloride and sulphur with a pH value
of 7.8.
58
Case 2:
120 MW Oil Fired Boiler
Location: Goose Neck Rear Water Wall
Size : 76.1 x 5.5 mm
Specification: SA210 GR A1
Working Temp. & Pressure: 350C & 90
kg/cm
Service: 250000 Hrs
59
Outside Diameter
0-180
90-270
Thickness
0 90 180
270
5.78
5.67
On
Opposite
the failed
region, the
a ring to
section
a littleaway
from the failed
microstructure
of is
polygonal
grains
region,
a similarconsists
structure
observed
of ferrite and pearlite
63
Conclusion:
Several oxide filled discontinuous cracks are
observed on the ID surface of the tube. The
flattening test result indicates hydrogen
embrittlement.
The failure of the tube is attributed to
hydrogen embritlement.
64
Case 3:
120 MW Oil Fired Boiler
Location: Primary SH Coil
Size : 57.15 x 4.2 mm
Working Temp. & Pressure: 510C & 85
kg/cm
Service: 243000 Hrs
65
Outside Diameter
0-180
Near failed lip
-Ring section
59.21
90-270
-61.81
0 90 180
3.03
-3.35
3.68
Thickness
270
4.27
3.93
little away
67
-3.82
68
69
Conclusion:
Micro examination indicates several rounded
pits filled with oxides on the ID surface of
the tube.
The failure is attributed to waterside
corrosion.
70
72
73
74
Case 4:
30 MW BFB Boiler
Location: Bed Coil Tubes
Size & Spec : 51 x 6.35 mm & SA 210 Gr.A1
Bed Temperature: 905C
Service: less than 1 year
76
Tube Location
BFB Boiler
77
Failed Tube
Failed Tube
Failed Tube
81
Case 5:
120 MW Tangential Fired PF Boiler
Location: 1. Platen SH Assy No 3 Tube No. 2
2. Platen SH Assy No 4 Tube No. 1
3. Platen SH Assy No 4 Tube no. 3
Size & Spec: 38.0 x 4.5 mm and CSN 15123.1
Working Temp. & Pressure: 500C & 158.2
kg/cm
Service: 1, 60, 000Hrs
82
Tube 1
The tube has burst open with thick lips. Oxide scaling
is seen on the ID and OD surfaces
83
Tube 2
Tube 3
Location
Outer Diameter
0-180
1.Failed lip
1.Ring section
a little
away
2.Failed lip
2.Ring section
a little
away
3.Failed lip
3.Ring section
a little
away
Thickness
9-270
90
180
270
3.52
4.30
38.43
40.83
3.49
4.49
3.91
4.15
2.76
4.10
38.90
40.52
1.70
3.86
3.64
3.55
1.93
3.94
36.70
37.90
2.17
3.89
3.92
4.29
86
87
88
89
90
91
92
THANKS
93